CN103045362A - Preparation method, products and use of lac-coated particles for cigarette filters - Google Patents
Preparation method, products and use of lac-coated particles for cigarette filters Download PDFInfo
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- CN103045362A CN103045362A CN201210580169XA CN201210580169A CN103045362A CN 103045362 A CN103045362 A CN 103045362A CN 201210580169X A CN201210580169X A CN 201210580169XA CN 201210580169 A CN201210580169 A CN 201210580169A CN 103045362 A CN103045362 A CN 103045362A
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Abstract
The invention relates to a preparation method, products and use of lac-coated particles for cigarette filters. A release matrix and an organic polymer skeleton, as major raw materials, are processed by mixing, coating, granulating, drying, screening and finishing to form active release-type cigarette flavor particles, wherein the release matrix is composed of organic acids and a release base, the flavor curing agent is composed of anhydrous solvents and organic polymer skeleton and flavorings and subjected to the operations of rotary coating, drying and screening to produce the flavoring particles. The flavoring particles provided by the invention can actively and sustainedly release aroma materials and generate water after being exposed to the main stream smoke, and the reaction persists stably, so as to improve the flavor and smoking quality of the cigarette and achieve the moisturizing effect.
Description
[technical field]
The invention belongs to the cigarette material technical field, the fragrant material of the benefit of particularly adding in the cigarette filter and this material preparation method.
[background technology]
The lowering harm and decreasing coking problem is one of countries tobacco sixty-four dollar question.The first half of the year in 2011 whole nation cigarette list props up the weighted mean tar content and drops to below 11 milligrams, and part cigarette product tar content has dropped to below 10 milligrams.Also not rare on 5 milligrams the cigarette market, the cigarette of 1 milligram even 0.1 milligram also comes out.
For reaching the purpose of reducing tar and reducing harm, the technology industries such as filter tip, the fine composite filter of paper/vinegar, natural permeable degree tipping paper, online laser boring have been introduced.In the time of their effective objectionable constituent that reduce in the cigarette smoke, also can be so that corresponding reduction be followed in the aspects such as original suction flavor of cigarette, mouthfeel, physiological strength.Especially the loss of fragrance matter and perfume quantity in the cigarette, easily make taste lose original style, this just need to carry out part and remedy by adding other spices, and one of effect of perfuming is when reducing cigarette harm, remedy the loss of fragrance, provide satisfied product to the human consumer.
Chinese invention patent 201010239046.0 discloses a kind of novel flavoring filter tip, choose diameter and cause fragrant particle in the 20-40 purpose, by the mouth rod forming machine, in every millimeter mouth rod tow, add equably 3 milligrams and describedly cause fragrant particle, make function mouth rod, described function mouth rod and the excellent Length Ratio by 10: 15 of base are rolled into flavoring filter tip by composite molding machine; Describedly cause fragrant particle and formed in tablets press take aluminosilicate as carrier by weight by following component: 4 parts of cloud and mist absolute oil; 1.5 parts of oak moss absolutes; 0.5 part of tree orchid essential oil; 4 parts of voitols; 15 parts of caramel colorants; 65 parts of propylene glycol; 10 parts in water.Yet find that through smokeing panel test its flavouring effect is not ideal, it is natural not to inhale flavor, and comparatively significantly artificial fragrance breath is arranged.
[summary of the invention]
The inventor utilizes organic acid acid and carbonate mixture to meet water reaction Heat of Formation or CO through research
2With the mechanism of water, set up flue gas Active Compensation system; Heat and CO
2Can take the essence that is added in the soda acid particle out of reach flavor compensating effect when overflowing, the generation of water has then increased the effect that the moisture in the flue gas reaches humectation; Because the aerosol that the fragrance that overflows and moisture form and the similarity of flue gas make compensation effect more obvious.
For this reason, the invention provides the preparation method that a kind of cigarette filter is used the lac coatedparticles, step is as follows:
A, preparation discharge base-material: get the organic acid of 1:2 ~ 3:2 and discharge bed material with weight ratio score another name, and for subsequent use;
B, preparation spice solution: take by weighing anhydrous solvent and the spices of 4:1 ~ 9:1 in weight ratio, mix through emulsification or dissolving, obtain spice solution; Described spices is Zimbabwe's extract;
C, preparation solid spice: take by weighing described spice solution and the organic acid of 1:5 ~ 1:20 and discharge bed material in weight ratio, spice solution is sprayed on the described organic acid the air-dry solid spice that obtains;
D, preparation spray solidification agent: take by weighing dehydrated alcohol and the lac of 4:1 ~ 19:1 in weight ratio, dissolving mixes, and obtains the spray solidification agent;
E, preparation particle solidifying agent: take by weighing acetone and the organic polymer skeleton of 9:1 ~ 29:1 in weight ratio, mix, obtain the particle solidifying agent;
F, organic acid powder preparation: the solid spice of step c and the spray solidification agent of steps d are coated, obtain the organic acid powder; Preferably the quality of the lac in the described spray solidification agent be in the solid spice organic acid quality 4%;
G, release bed material powder: the release bed material of step a and the spray solidification agent of d step are coated, obtain discharging the bed material powder; Preferably coating ratio satisfies the quality of the lac in the spray solidification agent for discharging 4% of bed material quality;
H, batch mixing: the organic acid powder of step f and the release bed material powder of step g are mixed with 2:1 ~ 10:1 ratio, and mix with the particle solidifying agent of step e, granulation, oven dry, screening, choosing particle diameter is 18～100 purpose particles, obtains described cigarette filter lac coatedparticles.
In the present invention, described organic acid is selected from one or more organic acids in Citric Acid, citric acid, tartrate and/or the oxysuccinic acid.
Described release bed material is selected from one or more release bed materials of sodium bicarbonate, saleratus, yellow soda ash, Quilonum Retard and/or salt of wormwood.
Preferably, release bed material and the organic acid of step a sieved, choose the above particle of particle diameter 40 orders respectively as discharging bed material and organic acid.
In the present invention, the described organic polymer skeleton of step e is selected from cellulose acetate and/or poly(lactic acid).
Preferably, the emulsification of step b is ultrasonic emulsification.
The present invention also provides the application of lac coatedparticles in cigarette filter of described cigarette filter, and particularly with the cigarette filter length-gauge, the addition of described perfuming particle is 0.5-35mg/mm.
In the present invention, Zimbabwe's tobacco extract is the product that can buy acquisition on the market, for example Zimbabwe's tobacco extract of Huabao Edible Essence ﹠ Condiment's sale.
In the present invention, coating is undertaken by flat die rolling granulator, for example selects the Shandong Zibo star to be full of the flat die rolling granulator that Mechanology Inc. manufactures.
Similarly, the lac coatedparticles for preparing of the present invention can also be applied to that binary is compound, in the tri compound, cavity composite filter.
Method of the present invention is simple, cost of manufacture is lower, and gained perfuming particle has consolidation homogeneous, the mellow and full advantage such as smooth.The cigarette filter that utilizes the inventive method to prepare has nontoxic with material.Slowly disintegration after particle and the main flume effect produces CO
2Can carry out the active perfuming, can guarantee that fragrance unity, acid-base reaction stable and the suction flavor produce water and reach the humectation effect as the perfuming carrier with water.
[description of drawings]
Fig. 1 is preparation method's schema of the present invention.
[embodiment]
Can understand better the present invention by following embodiment.
Embodiment 1
Take by weighing citric acid 80g, tartrate 70g, saleratus 120g, sodium bicarbonate 30g; It is for subsequent use with its dissolving with propylene glycol 10g, alcohol 8g to take by weighing Zimbabwe's extract (alcohol extracting part) 3g.
With the air-dry compound that obtains behind citric acid 80g, tartrate 70g and the 21g spice solution mixing homogeneous.
Take by weighing the 12g lac and be dissolved in the 168g dehydrated alcohol, obtain shellac solution 180g.
Take by weighing the 10g cellulose acetate, the 5g poly(lactic acid) is dissolved in the 135g acetone, obtains the particle solidifying agent.
Compound after air-dry and shellac solution 90g spray coated are got the organic acid powder.
Just saleratus 120g, sodium bicarbonate 30g and shellac solution 90g spray coated must discharge the bed material powder.
With the organic acid powder and discharge bed material powder mixing homogeneous, and mix with the particle solidifying agent, then carry out granulation, carrying out microwave drying processes again, preferably until the solvent＜particle weight of products therefrom 1%, sieve at last, choose 40 to 60 purpose materials as product.
Products obtained therefrom is applied to the composite particles filter stick formation by addition 25mg/mm, makes ternary cavity composite filter.
Select the finished cigarettes of quality between 0.880-0.900g, remove original filter stick, the active release type particle filter stick that the tipping preparation is complete.Then cigarette is placed 22 ℃, the balance 48h of thermostatic constant wet chamber of 60% humidity.In the spacious environment of smoothness, 22 ℃ of room temperatures, humidity 60% that ventilates, estimate under the environment again.Evaluation result is seen specification sheets subordinate list 1.
Embodiment 2
Take by weighing citric acid 30g, tartrate 40g, Citric Acid 30g, sodium bicarbonate 100g, yellow soda ash 100g.
Take by weighing Zimbabwe extract 6g and with dehydrated alcohol 54g it is dissolved, obtain spice solution.Used Zimbabwe's extract is the alcohol extracting part, is the tobacco aromatics using product that can buy acquisition on the market.
With air-dry behind organic acid and the spice solution mixing homogeneous, obtain compound.
Take by weighing the 12g lac and be dissolved in the 48g dehydrated alcohol, obtain shellac solution 60g.
Take by weighing the 2.5g poly(lactic acid) and be dissolved in the 72.5g acetone, reach particle solidifying agent 75g.
Compound after air-dry and shellac solution 20g spray coated are got the organic acid powder.
With sodium bicarbonate 100g, yellow soda ash 100g shellac solution 40g spray coated must discharge the bed material powder.
With the organic acid powder and discharge bed material powder mixings homogeneous, and mix with the particle solidifying agent, then carry out granulation, microwave drying is chosen 20 to 40 orders and is the active release type with interior material and mends fragrant particle until drying is sieved at last again.
Mending fragrant particle/mm filter stick by addition 2mg is applied to the composite particles filter stick formation, makes binary compound filter candle.
Select the finished cigarettes of quality between 0.880-0.900g, produce red plum board such as Yunnan Yuxi Cigarette Factory, remove original filter stick, the active release type particle filter stick that the tipping preparation is complete.Then cigarette is placed 22 ℃, the balance 48h of thermostatic constant wet chamber of 60% humidity.In the spacious environment of smoothness, 22 ℃ of room temperatures, humidity 60% that ventilates, estimate under the environment again.Evaluation result is seen specification sheets subordinate list 1.
Embodiment 3
Take by weighing citric acid 50g, Citric Acid 100g, yellow soda ash 60g, Quilonum Retard 90g.
It is for subsequent use with its dissolving with dehydrated alcohol 25g to take by weighing Zimbabwe extract 5g, obtains spice solution 30g.
With air-dry behind organic acid and the spice solution mixing homogeneous, obtain compound.
Take by weighing the 12g lac and be dissolved in the 108g dehydrated alcohol, obtain the 120g shellac solution.
Take by weighing the 2g cellulose acetate, the 2g poly(lactic acid) is dissolved in the 56g acetone, obtains 60g particle solidifying agent.
Compound after air-dry and shellac solution 60g spray coated are got the organic acid powder.
With yellow soda ash 60g, Quilonum Retard 90g mixing homogeneous must discharge the bed material powder with shellac solution 60g spray coated.
With organic acid powder and release bed material powder mixing homogeneous, and mix with the particle solidifying agent, then carry out granulation, the microwave drying processing is carried out in granulation made 1% of its solvent＜particle weight, sieve at last, choose 20 to 40 orders and be initiatively release type with interior material and mend fragrant particle.
Be applied to the composite particles filter stick formation by addition 20mg/mm, make ternary cavity composite filter.
Select the finished cigarettes of quality between 0.880-0.900g, remove original filter stick, the active release type particle filter stick that the tipping preparation is complete.Then cigarette is placed 22 ℃, the balance 48h of thermostatic constant wet chamber of 60% humidity.In the spacious environment of smoothness, 22 ℃ of room temperatures, humidity 60% that ventilates, estimate under the environment again.Evaluation result is seen specification sheets subordinate list 1.
Embodiment 4
Take by weighing tartrate 180g, sodium bicarbonate 120g.
It is for subsequent use with its dissolving with dehydrated alcohol 12g to take by weighing Zimbabwe extract 3g, obtains spice solution 15g.
With air-dry to dry behind organic acid and the spice solution mixing homogeneous, obtain compound.
Take by weighing the 12g lac and be dissolved in the 228g dehydrated alcohol, obtain shellac solution 240g.
Take by weighing the 3g cellulose acetate and be dissolved in the 27g acetone, obtain particle solidifying agent 30g.
Compound after air-dry and shellac solution 144g spray coated are got the organic acid powder.
Sodium bicarbonate 120g and shellac solution 96g spray coated must be discharged the bed material powder.
With the organic acid powder and discharge bed material powder mixing homogeneous, and mix with the particle solidifying agent.
Granulation, oven dry, screening are chosen 20 to 40 orders and are initiatively release type with interior material and mend fragrant particle.
The gained particle is applied to the composite particles filter stick formation by addition 2mg/mm, makes binary compound filter candle.Select the finished cigarettes of quality between 0.880-0.900g, remove original filter stick, the active release type particle filter stick that the tipping preparation is complete.Then cigarette is placed 22 ℃, the balance 48h of thermostatic constant wet chamber of 60% humidity.In the spacious environment of smoothness, 22 ℃ of room temperatures, humidity 60% that ventilates, estimate under the environment again.Evaluation result is seen specification sheets subordinate list 1.
Embodiment 5
Take by weighing tartrate 130g, sodium bicarbonate 120g, saleratus 50g.
Take by weighing Zimbabwe's extract (alcohol extracting part) 5g and with alcohol 25g it is dissolved, obtain spice solution 30g.
With air-dry to dry behind organic acid and the spice solution mixing homogeneous, obtain compound.
Take by weighing the 12g lac and be dissolved in the 108g dehydrated alcohol, obtain shellac solution 120g.
Take by weighing the 8g cellulose acetate and be dissolved in the 92g acetone, obtain particle solidifying agent 100g.
Compound after air-dry and shellac solution 52g spray coated are got the organic acid powder.
With sodium bicarbonate 120g, saleratus 50g and shellac solution 68g spray coated must discharge the bed material powder.
With the organic acid powder and discharge bed material powder mixings homogeneous, and mix with the particle solidifying agent, through granulation, drying, sieve, choose 20 to 40 orders and be the active release type with interior material and mend fragrant particle.
The gained particle is applied to the composite particles filter stick formation by addition 20mg/mm, makes ternary cavity composite filter.Select the finished cigarettes of quality between 0.880-0.900g, remove original filter stick, the active release type particle filter stick that the tipping preparation is complete.Then cigarette is placed 22 ℃, the balance 48h of thermostatic constant wet chamber of 60% humidity.In the spacious environment of smoothness, 22 ℃ of room temperatures, humidity 60% that ventilates, estimate under the environment again.Evaluation result sees Table 1.
Table 1
Claims (9)
1. cigarette filter is characterized in that step is as follows with the preparation method of lac coatedparticles:
A, preparation discharge base-material: get the organic acid of 1:2 ~ 3:2 and discharge bed material with weight ratio score another name, and for subsequent use;
B, preparation spice solution: take by weighing anhydrous solvent and the spices of 4:1 ~ 9:1 in weight ratio, mix through emulsification or dissolving, obtain spice solution; Described spices is Zimbabwe's extract;
C, preparation solid spice: take by weighing described spice solution and the organic acid of 1:5 ~ 1:20 and discharge bed material in weight ratio, spice solution is sprayed on the described organic acid the air-dry solid spice that obtains;
D, preparation spray solidification agent: take by weighing dehydrated alcohol and the lac of 4:1 ~ 19:1 in weight ratio, dissolving mixes, and obtains the spray solidification agent;
E, preparation particle solidifying agent: take by weighing acetone and the organic polymer skeleton of 9:1 ~ 29:1 in weight ratio, mix, obtain the particle solidifying agent;
F, organic acid powder preparation: the solid spice of step c and the spray solidification agent of steps d are coated, obtain the organic acid powder;
G, release bed material powder: the release bed material of step a and the spray solidification agent of d step are coated, obtain discharging the bed material powder;
H, batch mixing: the organic acid powder of step f and the release bed material powder of step g are mixed with 2:1 ~ 10:1 ratio, and mix with the particle solidifying agent of step e, granulation, oven dry, screening, choosing particle diameter is 18～100 purpose particles, obtains described cigarette filter lac coatedparticles.
2. method according to claim 1 is characterized in that described organic acid is selected from one or more organic acids in Citric Acid, citric acid, tartrate and/or the oxysuccinic acid.
3. method according to claim 1 is characterized in that described release bed material is selected from one or more release bed materials of sodium bicarbonate, saleratus, yellow soda ash, Quilonum Retard and/or salt of wormwood.
4. method according to claim 1 is characterized in that described release base-material and organic acid powder are sieved, and chooses the above particle of particle diameter 40 orders.
5. method according to claim 1 is characterized in that the described organic polymer skeleton of step e is selected from cellulose acetate and/or poly(lactic acid).
6. method according to claim 1, the emulsification that it is characterized in that step b is ultrasonic emulsification.
7. method according to claim 1 is characterized in that among the step f, the quality of the lac in the described spray solidification agent be in the solid spice organic acid quality 4%; The coating ratio satisfies the quality of the lac in the spray solidification agent for discharging 4% of bed material quality in the step g.
8. the cigarette filter that obtains of the described method of claim 1-6 is with the application of lac coatedparticles in cigarette filter.
9. the cigarette filter that obtains of the described method of claim 1-7 is characterized in that with the cigarette filter length-gauge that with the application of lac coatedparticles in cigarette filter the addition of described perfuming particle is 0.5-35mg/mm.
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| CN201210580169.XA CN103045362B (en) | 2012-12-27 | 2012-12-27 | Preparation method, products and use of lac-coated particles for cigarette filters |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022193749A1 (en) * | 2021-03-16 | 2022-09-22 | 深圳市智叶生物科技有限公司 | Preparation method for functional particles, filter tip, and electronic cigarette |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012053048A1 (en) * | 2010-10-18 | 2012-04-26 | 日本たばこ産業株式会社 | Method for manufacturing flavor-releasing granules, flavor-releasing granules, and cigarette filter containing flavor-releasing granules |
| CN102533445A (en) * | 2012-02-05 | 2012-07-04 | 云南正邦生物技术有限公司 | Method for preparing active release type cigarette flavor complementing particles |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012053048A1 (en) * | 2010-10-18 | 2012-04-26 | 日本たばこ産業株式会社 | Method for manufacturing flavor-releasing granules, flavor-releasing granules, and cigarette filter containing flavor-releasing granules |
| CN102533445A (en) * | 2012-02-05 | 2012-07-04 | 云南正邦生物技术有限公司 | Method for preparing active release type cigarette flavor complementing particles |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022193749A1 (en) * | 2021-03-16 | 2022-09-22 | 深圳市智叶生物科技有限公司 | Preparation method for functional particles, filter tip, and electronic cigarette |
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Address after: 850000 Lhasa economic and Technological Development Zone, Tibet autonomous region, road, investment building, Patentee after: HUABAO FLAVOURS & FRAGRANCES CO.,LTD. Address before: 850000 Lhasa economic and Technological Development Zone, Tibet autonomous region, road, investment building, Patentee before: Huabao flavor Ltd. |
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Address after: 850000 Lhasa economic and Technological Development Zone, Tibet autonomous region, road, investment building, Patentee after: Huabao flavor Ltd. Address before: 201821 Yecheng Road, Shanghai, No. 1299, No. Patentee before: Huabao Flavours & Fragrances Co.,Ltd |
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Effective date of registration: 20170123 Address after: 650503 Yunnan province Kunming city Kunming high tech Zone Jinpu rural Metro high-tech industrial base A6-2 Patentee after: YUNNAN XINYUN TECHNOLOGY DEVELOPMENT Co.,Ltd. Address before: 850000 Lhasa economic and Technological Development Zone, Tibet autonomous region, road, investment building, Patentee before: HUABAO FLAVOURS & FRAGRANCES CO.,LTD. |