CN103045362B - Preparation method, products and use of lac-coated particles for cigarette filters - Google Patents
Preparation method, products and use of lac-coated particles for cigarette filters Download PDFInfo
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- CN103045362B CN103045362B CN201210580169.XA CN201210580169A CN103045362B CN 103045362 B CN103045362 B CN 103045362B CN 201210580169 A CN201210580169 A CN 201210580169A CN 103045362 B CN103045362 B CN 103045362B
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Abstract
The invention relates to a preparation method, products and use of lac-coated particles for cigarette filters. A release matrix and an organic polymer skeleton, as major raw materials, are processed by mixing, coating, granulating, drying, screening and finishing to form active release-type cigarette flavor particles, wherein the release matrix is composed of organic acids and a release base, the flavor curing agent is composed of anhydrous solvents and organic polymer skeleton and flavorings and subjected to the operations of rotary coating, drying and screening to produce the flavoring particles. The flavoring particles provided by the invention can actively and sustainedly release aroma materials and generate water after being exposed to the main stream smoke, and the reaction persists stably, so as to improve the flavor and smoking quality of the cigarette and achieve the moisturizing effect.
Description
[technical field]
The invention belongs to cigarette material technical field, the preparation method of the fragrant material of the benefit of particularly adding in cigarette filter and this material.
[background technology]
Lowering harm and decreasing coking problem is one of countries tobacco sixty-four dollar question.Whole nation cigarette list propped up weighted average tar content and dropped to less than 11 milligrams the first half of the year in 2011, and part cigarette product tar content has dropped to less than 10 milligrams.Also not rare on the cigarette market of 5 milligrams, 1 milligram even cigarette of 0.1 milligram also come out.
For reaching the object of reducing tar and reducing harm, introduce the technology industry such as filter tip, the fine composite filter of paper/vinegar, natural permeable degree tipping paper, online laser boring.They also can make the aspect such as original suction taste, mouthfeel, physiological strength of cigarette follow corresponding reduction while effectively reducing the harmful components in cigarette smoke.Especially the loss of aroma quality and perfume quantity in cigarette, easily make taste lose original style, this carries out part with regard to needing make up by adding other spices, one of effect of perfuming be reduce cigarette endanger while, make up the loss of fragrance, provide satisfied product to consumer.
Chinese invention patent 201010239046.0 discloses a kind of novel flavoring filter tip, choose diameter and cause fragrant particle in 20-40 object, by mouth rod forming machine, add equably described in 3 milligrams in the mouth rod tow of every millimeter and cause fragrant particle, make function mouth rod, described function mouth rod and the excellent length by 10: 15 of base are rolled into flavoring filter tip than by composite molding machine; It is described that to cause fragrant particle be that carrier is formed in comminutor: cloud and mist absolute oil 4 parts by weight with aluminosilicate by following component; Oak moss absolute 1.5 parts; Tree orchid essential oil 0.5 part; Maltol 4 parts; Caramel colorant 15 parts; Propane diols 65 parts; 10 parts, water.But find that its flavouring effect is not ideal through smokeing panel test, inhale taste natural not, have comparatively significantly artificial fragrance breath.
[summary of the invention]
The present inventor, through research, utilizes organic acid acid to meet water with carbonate mixture and reacts Heat of Formation or CO
2with the mechanism of water, establish flue gas Active Compensation system; Heat and CO
2can take the essence be added in soda acid particle out of reach flavor compensating effect during spilling, the generation moisture then added in flue gas of water reaches the effect of humectation; The aerosol formed due to fragrance and the moisture of spilling and the similitude of flue gas, make compensation effect more obvious.
For this reason, the invention provides the preparation method of a kind of cigarette filter with lac coated particle, step is as follows:
A, preparation release base-material: take the organic acid of 1:2 ~ 3:2 and release bed material with mass ratio range respectively, for subsequent use;
B, prepare spice solution: the anhydrous solvent and the spices that take 4:1 ~ 9:1 with mass ratio range, mix through emulsification or dissolving, obtain spice solution; Described spices is Zimbabwe's extract;
C, prepare solid spice: take described spice solution and the organic acid of 1:5 ~ 1:20 with mass ratio range and discharge bed material, being sprayed at by spice solution on described organic acid, air-dryly obtain solid spice;
D, prepare spray solidification agent: the absolute ethyl alcohol and the lac that take 4:1 ~ 19:1 with mass ratio range, dissolving mixes, and obtains spray solidification agent;
E, prepare particles cured dose: the acetone and the organic polymer skeleton that take 9:1 ~ 29:1 with mass ratio range, mix, obtain particles cured dose;
F, organic acid powder preparation: the spray solidification agent of the solid spice of step c and steps d is carried out coated, obtains organic acid powder; The quality of the lac preferably in described spray solidification agent is 4% of organic acid quality in solid spice;
G, release bed material powder: undertaken coated by the release bed material of step a and the spray solidification agent of Step d, obtain release bed material powder; Preferably coated ratio meets the quality of the lac in spray solidification agent is discharge bed material quality 4%;
H, batch mixing: the organic acid powder of step f is mixed with 2:1 ~ 10:1 ratio with the release bed material powder of step g, and mix with particles cured dose of step e, granulation, oven dry, screening, choosing particle diameter is 18 ~ 100 object particles, obtains described cigarette filter lac coated particle.
In the present invention, described organic acid is selected from one or more organic acids in citric acid, citric acid, tartaric acid and/or malic acid.
Described release bed material is selected from one or more release bed materials of sodium acid carbonate, saleratus, sodium carbonate, lithium carbonate and/or potash.
Preferably, the release bed material of step a and organic acid are sieved, choose the particle of more than particle diameter 40 order respectively as release bed material and organic acid.
In the present invention, described in step e, organic polymer skeleton is selected from cellulose acetate and/or PLA.
Preferably, the emulsification of step b is ultrasonic emulsification.
The present invention also provides the application of described cigarette filter lac coated particle in cigarette filter, and particularly with cigarette filter length gauge, the addition of described perfuming particle is 0.5-35mg/mm.
In the present invention, Zimbabwe's tobacco extract is product market can being bought acquisition, Zimbabwe's tobacco extract that such as Huabao Edible Essence & Condiment (Shanghai) sells.
In the present invention, coatedly to be undertaken by flat die rolling granulator, such as, select the flat die rolling granulator that Shandong Zibo Xing Ying Mechanology Inc. manufactures.
Similarly, the lac coated particle that the present invention prepares can also be applied in binary compound, tri compound, cavity composite filter.
Method of the present invention is simple, cost of manufacture is lower, and gained perfuming particle has homogeneous, the mellow and full advantage such as smooth of consolidation.The cigarette filter material utilizing the inventive method to prepare has nontoxic.Slowly disintegration after particle and main flume effect, produces CO
2with water as perfuming carrier can carry out initiatively perfuming, can ensure fragrance stablize and inhales the uniformity of taste, acid-base reaction generation water reaches humectation effect.
[accompanying drawing explanation]
Fig. 1 is preparation method's flow chart of the present invention.
[detailed description of the invention]
The present invention can be understood better by following embodiment.
Embodiment 1
Take citric acid 80g, tartaric acid 70g, saleratus 120g, sodium acid carbonate 30g; Take Zimbabwe's extract (alcohol extracting part) 3g propane diols 10g, alcohol 8g dissolved for subsequent use.
Citric acid 80g, tartaric acid 70g are mixed with 21g spice solution and homogeneously air-dryly obtains compound afterwards.
Take 12g lac to be dissolved in 168g absolute ethyl alcohol, obtain shellac solution 180g.
Take 10g cellulose acetate, 5g PLA is dissolved in 135g acetone, obtain particles cured dose.
Compound after air-dry and shellac solution 90g spray coated are obtained organic acid powder.
Just saleratus 120g, sodium acid carbonate 30g and shellac solution 90g spray coated must discharge bed material powder.
Organic acid powder is mixed homogeneous with release bed material powder, and mix with particles cured dose, then granulation is carried out, carry out microwave drying process again, preferably until 1% of the solvent < particle weight of products therefrom, finally sieve, choose 40 to 60 object materials as product.
It is shaping that products obtained therefrom is applied to composite particle filter stick by addition 25mg/mm, makes ternary cavity composite filter.
Select the finished cigarettes of quality between 0.880-0.900g, remove original filter stick, the active release type particle filter stick that tipping preparation is complete.Then cigarette is placed in 22 DEG C, the thermostatic constant wet chamber of 60% humidity balance 48h.Evaluate under environment in the spacious environment of smoothness, room temperature 22 DEG C, humidity 60% that ventilates again.Evaluation result is shown in description subordinate list 1.
Embodiment 2
Take citric acid 30g, tartaric acid 40g, citric acid 30g, sodium acid carbonate 100g, sodium carbonate 100g.
Take Zimbabwe extract 6g absolute ethyl alcohol 54g to be dissolved, obtain spice solution.Zimbabwe's extract used is alcohol extracting part, is tobacco aromatics product market can being bought acquisition.
Organic acid is mixed with spice solution homogeneous rear air-dry, obtain compound.
Take 12g lac to be dissolved in 48g absolute ethyl alcohol, obtain shellac solution 60g.
Take 2.5g PLA to be dissolved in 72.5g acetone, reach particles cured dose of 75g.
Compound after air-dry and shellac solution 20g spray coated are obtained organic acid powder.
By sodium acid carbonate 100g, sodium carbonate 100g shellac solution 40g spray coated must discharge bed material powder.
Mix homogeneous by organic acid powder with release bed material powder, and mix with particles cured dose, then carry out granulation, then microwave drying is until drying, finally sieves, the material chosen within 20 to 40 orders is initiatively release type and mends fragrant particle.
Mend that fragrant particle/mm filter stick is applied to composite particle filter stick by addition 2mg shaping, make binary compound filter candle.
Select the finished cigarettes of quality between 0.880-0.900g, as Yunnan Yuxi Cigarette Factory produces red plum board, remove original filter stick, the active release type particle filter stick that tipping preparation is complete.Then cigarette is placed in 22 DEG C, the thermostatic constant wet chamber of 60% humidity balance 48h.Evaluate under environment in the spacious environment of smoothness, room temperature 22 DEG C, humidity 60% that ventilates again.Evaluation result is shown in description subordinate list 1.
Embodiment 3
Take citric acid 50g, citric acid 100g, sodium carbonate 60g, lithium carbonate 90g.
Taking Zimbabwe extract 5g absolute ethyl alcohol 25g is dissolved for subsequent use, obtains spice solution 30g.
Organic acid is mixed with spice solution homogeneous rear air-dry, obtain compound.
Take 12g lac to be dissolved in 108g absolute ethyl alcohol, obtain 120g shellac solution.
Take 2g cellulose acetate, 2g PLA is dissolved in 56g acetone, obtain particles cured dose of 60g.
Compound after air-dry and shellac solution 60g spray coated are obtained organic acid powder.
By sodium carbonate 60g, lithium carbonate 90g mixes homogeneous, must discharge bed material powder with shellac solution 60g spray coated.
Organic acid powder is mixed homogeneous with release bed material powder, and mix with particles cured dose, then granulation is carried out, granulation is carried out microwave drying process makes its solvent < particle weight 1%, finally sieve, the material chosen within 20 to 40 orders is initiatively release type and mends fragrant particle.
Be applied to composite particle filter stick by addition 20mg/mm shaping, make ternary cavity composite filter.
Select the finished cigarettes of quality between 0.880-0.900g, remove original filter stick, the active release type particle filter stick that tipping preparation is complete.Then cigarette is placed in 22 DEG C, the thermostatic constant wet chamber of 60% humidity balance 48h.Evaluate under environment in the spacious environment of smoothness, room temperature 22 DEG C, humidity 60% that ventilates again.Evaluation result is shown in description subordinate list 1.
Embodiment 4
Take tartaric acid 180g, sodium acid carbonate 120g.
Taking Zimbabwe extract 3g absolute ethyl alcohol 12g is dissolved for subsequent use, obtains spice solution 15g.
Organic acid is mixed with spice solution homogeneous rear air-dry to dry, obtain compound.
Take 12g lac to be dissolved in 228g absolute ethyl alcohol, obtain shellac solution 240g.
Take 3g cellulose acetate dissolves in 27g acetone, obtain particles cured dose of 30g.
Compound after air-dry and shellac solution 144g spray coated are obtained organic acid powder.
Sodium acid carbonate 120g and shellac solution 96g spray coated must be discharged bed material powder.
Organic acid powder is mixed homogeneous with release bed material powder, and mixes with particles cured dose.
Granulation, oven dry, screening, the material chosen within 20 to 40 orders is initiatively release type and mends fragrant particle.
It is shaping that gained particle is applied to composite particle filter stick by addition 2mg/mm, makes binary compound filter candle.Select the finished cigarettes of quality between 0.880-0.900g, remove original filter stick, the active release type particle filter stick that tipping preparation is complete.Then cigarette is placed in 22 DEG C, the thermostatic constant wet chamber of 60% humidity balance 48h.Evaluate under environment in the spacious environment of smoothness, room temperature 22 DEG C, humidity 60% that ventilates again.Evaluation result is shown in description subordinate list 1.
Embodiment 5
Take tartaric acid 130g, sodium acid carbonate 120g, saleratus 50g.
Take Zimbabwe's extract (alcohol extracting part) 5g alcohol 25g to be dissolved, obtain spice solution 30g.
Organic acid is mixed with spice solution homogeneous rear air-dry to dry, obtain compound.
Take 12g lac to be dissolved in 108g absolute ethyl alcohol, obtain shellac solution 120g.
Take 8g cellulose acetate dissolves in 92g acetone, obtain particles cured dose of 100g.
Compound after air-dry and shellac solution 52g spray coated are obtained organic acid powder.
By sodium acid carbonate 120g, saleratus 50g and shellac solution 68g spray coated must discharge bed material powder.
Mix homogeneous by organic acid powder with release bed material powder, and mix with particles cured dose, through granulation, drying, sieve, the material chosen within 20 to 40 orders is initiatively release type and mends fragrant particle.
It is shaping that gained particle is applied to composite particle filter stick by addition 20mg/mm, makes ternary cavity composite filter.Select the finished cigarettes of quality between 0.880-0.900g, remove original filter stick, the active release type particle filter stick that tipping preparation is complete.Then cigarette is placed in 22 DEG C, the thermostatic constant wet chamber of 60% humidity balance 48h.Evaluate under environment in the spacious environment of smoothness, room temperature 22 DEG C, humidity 60% that ventilates again.Evaluation result is in table 1.
Table 1
Claims (2)
1. the cigarette filter preparation method of lac coated particle, is characterized in that step is as follows:
A, to get the raw materials ready: take the organic acid of 1:2 ~ 3:2 and release bed material respectively with mass ratio range, for subsequent use; Described organic acid is selected from one or more organic acids in citric acid, citric acid, tartaric acid and/or malic acid, and described release bed material is selected from one or more release bed materials of sodium acid carbonate, saleratus, sodium carbonate, lithium carbonate and/or potash;
B, prepare spice solution: the anhydrous solvent and the spices that take 4:1 ~ 9:1 with mass ratio range, mix through emulsification or dissolving, obtain spice solution; Described spices is Zimbabwe's extract;
C, prepare solid spice: the described spice solution and the organic acid that take 1:5 ~ 1:20 with mass ratio range, be sprayed at spice solution on described organic acid, air-dryly obtain solid spice;
D, prepare spray solidification agent: the absolute ethyl alcohol and the lac that take 4:1 ~ 19:1 with mass ratio range, dissolving mixes, and obtains spray solidification agent;
E, prepare particles cured dose: the acetone and the organic polymer skeleton that take 9:1 ~ 29:1 with mass ratio range, mix, obtain particles cured dose;
F, organic acid powder preparation: the spray solidification agent of the solid spice of step c and steps d is carried out coated, obtains organic acid powder; The quality of the lac in described spray solidification agent is 4% of organic acid quality in solid spice;
G, release bed material powder: undertaken coated by the release bed material of step a and the spray solidification agent of Step d, obtain release bed material powder; In step g, coated ratio meets the quality of the lac in spray solidification agent is discharge bed material quality 4%;
H, batch mixing: the organic acid powder of step f is mixed with 2:1 ~ 10:1 ratio with the release bed material powder of step g, and mix with particles cured dose of step e, granulation, oven dry, screening, choosing particle diameter is 18 ~ 100 object particles, obtains described cigarette filter lac coated particle.
2. method according to claim 1, is characterized in that described release bed material and organic acid powder to sieve, chooses the particle of more than particle diameter 40 order.
3. method according to claim 1, is characterized in that described in step e, organic polymer skeleton is selected from cellulose acetate and/or PLA.
4. method according to claim 1, is characterized in that the emulsification of step b is ultrasonic emulsification.
5. the cigarette filter that any one of claim 1-4, method described in claim the obtains application of lac coated particle in cigarette filter.
6. application according to claim 5, is characterized in that with cigarette filter length gauge, and the addition of described lac coated particle is 0.5-35mg/mm.
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| CN201210580169.XA CN103045362B (en) | 2012-12-27 | 2012-12-27 | Preparation method, products and use of lac-coated particles for cigarette filters |
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| CN201210580169.XA CN103045362B (en) | 2012-12-27 | 2012-12-27 | Preparation method, products and use of lac-coated particles for cigarette filters |
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| CN103045362B true CN103045362B (en) | 2015-04-22 |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012053048A1 (en) * | 2010-10-18 | 2012-04-26 | 日本たばこ産業株式会社 | Method for manufacturing flavor-releasing granules, flavor-releasing granules, and cigarette filter containing flavor-releasing granules |
| CN102533445A (en) * | 2012-02-05 | 2012-07-04 | 云南正邦生物技术有限公司 | Method for preparing active release type cigarette flavor complementing particles |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012053048A1 (en) * | 2010-10-18 | 2012-04-26 | 日本たばこ産業株式会社 | Method for manufacturing flavor-releasing granules, flavor-releasing granules, and cigarette filter containing flavor-releasing granules |
| CN102533445A (en) * | 2012-02-05 | 2012-07-04 | 云南正邦生物技术有限公司 | Method for preparing active release type cigarette flavor complementing particles |
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Address after: 850000 Lhasa economic and Technological Development Zone, Tibet autonomous region, road, investment building, Patentee after: HUABAO FLAVOURS & FRAGRANCES CO.,LTD. Address before: 850000 Lhasa economic and Technological Development Zone, Tibet autonomous region, road, investment building, Patentee before: Huabao flavor Ltd. |
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Address after: 850000 Lhasa economic and Technological Development Zone, Tibet autonomous region, road, investment building, Patentee after: Huabao flavor Ltd. Address before: 201821 Yecheng Road, Shanghai, No. 1299, No. Patentee before: Huabao Flavours & Fragrances Co.,Ltd |
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Effective date of registration: 20170123 Address after: 650503 Yunnan province Kunming city Kunming high tech Zone Jinpu rural Metro high-tech industrial base A6-2 Patentee after: YUNNAN XINYUN TECHNOLOGY DEVELOPMENT Co.,Ltd. Address before: 850000 Lhasa economic and Technological Development Zone, Tibet autonomous region, road, investment building, Patentee before: HUABAO FLAVOURS & FRAGRANCES CO.,LTD. |