CN103038325A - 抗细菌清洁组合物 - Google Patents

抗细菌清洁组合物 Download PDF

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CN103038325A
CN103038325A CN2011800374697A CN201180037469A CN103038325A CN 103038325 A CN103038325 A CN 103038325A CN 2011800374697 A CN2011800374697 A CN 2011800374697A CN 201180037469 A CN201180037469 A CN 201180037469A CN 103038325 A CN103038325 A CN 103038325A
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T·E·袍兹
L·M·沃克斯凯
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Abstract

本发明针对一种多表面清洁组合物,该组合物具有抗细菌成分,用于清洁家具表面。抗细菌清洁组分包括氯化季氨化合物或其组合。该组合物进一步包括pH值调节剂,用于提供在约6至约9的范围内的通常为中性的pH值,包括组分的组合,优选白蒸馏醋和胺化合物。清洗组合物对木材表面和其他家具表面提供良好的清洁和消毒而不留下纹。

Description

抗细菌清洁组合物
相关应用
本申请要求2010年6月17日提交的题为“抗细菌清洁组成”的美国临时申请序列61/344238号申请的权利。
发明技术领域
本发明涉及用于家具表面上的抗细菌清洁组合物。更具体地说,本发明涉及用于在多种类型的家具表面上使用发抗细菌清洁组合物,包括木材表面和玻璃表面,且其提供良好的清洗和消毒的效果且不产生纹。
发明背景
多表面抗细菌清洁组合物在本领域中是已知的。然而,这些清洗剂组合物要求极其苛刻的pH值,要么非常高或非常低,因此不利于用来清洁家具,特别是木材家具。
多表面抗细菌清洁组合物一般都要求具有低挥发性有机化合物(VOC)的含量,例如小于3%。低VOC含量多表面抗细菌清洁组合物的配方是很困难的,因为该组合物必须满足低VOC含量的要求并同时对家具表面提供最佳的清洗和消毒且不会损坏被处理的表面。
本发明提供一种新的和有用的抗细菌清洁组合物,该组合物克服现有技术的组合物的问题。
发明内容
本发明的抗细菌清洁组合物用于清洁不同的家具表面,包括木材、木材层压板、木材与玻璃的组合家具。此外,该组合物可用于清洗其他家具表面,包括大理石、花岗石、不锈钢。清洗组合物向家具提供良好的清洁效果,因为其使用的抗细菌化合物且其具有调节后的约6至9的范围内的pH值,更优选为7至9,最优选8至9。用相结合的成分来调节pH值,包括使用白蒸馏醋和胺。调节后的pH值倾向于不苛刻并可以安全有效地清洗和消毒家具表面,尤其是木材和木材层压板的表面。
本发明的清洗组合物,包括:抗细菌成分,其提供一般无微生物的表面。在本发明中有用的抗细菌成分是季氨氯化物或其组合。
本发明的清洗组合物还提供低发泡度,从而减少在家具和玻璃表面上产生的纹。组合物中的低发泡度,除其他方法外可通过使用非离子表面活性剂来实现。非离子表面活性剂的使用与阴离子或两性表面活性剂的不使用,与季氨氯化物活性清洁成分作用地很好。
本发明的清洗组合物优选在气溶胶输送系统中使用。然而,该组合物也可以由触发喷雾容器来输送或浸入擦拭物。
发明的详细说明
本发明针对一种多表面清洁组合物,该组合物具有抗细菌成分,用于清洁家具表面。抗细菌清洁组分包括氯化季氨化合物。该组合物进一步包括pH值调节剂,用于提供在约6至约9的范围内的通常为中性的pH值,更优选为7至9,最优选8至9,其包括组分的组合,优选白蒸馏醋和胺化合物。清洗组合物对木材表面和其他家具表面提供良好的清洁和消毒效果,包括娱乐中心的组合的木材和玻璃表面。该清洁组合物对家具表面不留下纹。
抗细菌/消毒清洁组分是季氨氯化物。该组分提供对微生物元素的有效杀死。季氨氯化物组分可以是氯化季氨化合物中的一个或其组合。一种优选的季氨氯化物组分是烷基二甲基苄基氯化氨和烷基二甲基乙基苄基氯化氨的组合。目前优选的季氨氯化物包括斯捷潘公司(Stepan Company)制造并销售的BTC 2125和龙沙公司(Lonza,Inc)制造并销售的BARQUAT 4280-Z。这些都是长链(即C12-C18)的季氨氯化物并与非离子表面活性剂结合地很好,将在下面进行讨论。抗细菌剂存在的量可以在(按重量百分比)约0.001至约0.25%的范围内。更优选的范围是约0.005至约0.15%。最优选的范围是约0.01至约0.1%。
清洁组合物包括一种提供约6至约9范围内的pH值的pH调节剂。这个pH值范围对包括木材表面的家具提供良好的清洁效果且不损坏这种表面,这种效果是不可能使用一般具有苛刻的pH值的已知抗细菌硬表面清洁组合物实现的,例如无论其pH值是在约3范围内的酸性或10至11范围内的碱性。对组合物有用的pH值促进剂是水溶性有机和/或无机助洗剂。优选地,pH值促进剂包括白蒸馏醋,即乙酸(15%活性)和胺。当与组合物的额外组分一起使用白蒸馏醋时一般提供的pH值在5至6的范围内。使用胺将pH值进一步调节至约8至约9的范围内,优选链烷醇胺,更优选乙醇胺。该胺提供pH值的调节并作用为清洗剂。pH值促进剂存在的量可以在(按重量百分比)约0.001至约2.0%的范围内。优选的范围是约0.05至约1.0%。最优选的范围是约0.2至约0.6%。
该组合物进一步包括与季氨氯化物作用地很好的非离子和/或阳离子表面活性剂。优选的非离子表面活性剂是烷氧基化的直链醇。优选的表面活性剂是仲醇烷氧基化物,特别是乙氧基化物,如陶氏化学公司(The DowChemical)制造和销售的Tergitol 15-S-9,其为C6-C17仲醇聚(3-6EO)乙氧基化物。对本发明的有用的附加非离子表面活性剂包括链烷醇酰胺、氧化胺和乙氧基化的脂肪酸酯。这些非离子表面活性剂,与对家具表面提供良好的清洁效果、去除微生物元素并避免产生纹的组合物的其它成分结合时具有低水平的发泡。表面活性剂存在的量可以在(按重量百分比)约0.001至约0.5%的范围内。优选的范围是约0.01至约0.2%。最优选的范围是约0.04至约0.12%。
清洗组合物不使用两性或阴离子表面活性剂。这些表面活性剂会与季氨氯化物相结合,从而由于减少了可用的活性剂的水平而减少抗细菌剂的有效性。此外,这种表面活性剂会将发泡增加至不希望的水平。
本发明的清洁组合物进一步包括水溶性溶剂和/或包括水、乙二醇、乙二醇醚和乙醇的增溶剂。优选的溶剂包括短碳链亚烷基乙二醇、亚烷基乙二醇醚和链烷醇,最优选包括乙烯乙二醇正己醚、丙二醇和异丙醇。溶剂和/或增溶剂存在的量在(按重量百分比)约95.0至约99.8%的范围内。优选的范围是约97.5至约99.8%。最优选的范围为约98.5至约99.8%。
优选在组合物中包含一种香料。目前优选的香料是向用户传送清新和清洁气味的柑橘香料。香料可在(按重量百分比)约0.001至约1.0%的范围内存在。优选的范围是约0.01至约0.8%。最优选的范围是约0.05至约0.4%。
用于本发明的清洗组合物的优选的输送系统是气溶胶输送系统。优选的气溶胶输送系统是压缩气体,更优选为压缩空气或氮气。然而,烃类气体的气溶胶也适合使用。本发明的清洗组合物也可以使用触发器(非气溶胶)输送系统或被浸渍在擦拭物中使用。
在本发明的一个优选的实施例中,用于清洁家具发有用的抗细菌清洁组合物包括:
Figure BDA00002794528900041
pH值=8.5
虽然上述组合物是本发明目前优选的实施例,但应当理解,也可以使用不同范围的成分以及基础成分或基础成分等同物的不同组合,包括本文所阐述的。
对本领域的技术人员来说,在现有技术中显而易见在上述说明的范围内可以进行各种修改。这种修改在本发明的组成部分的领域内的技术人员的能力之内。

Claims (19)

1.一种应用在家具表面上来对该表面进行清洁和消毒而不会产生纹的抗细菌清洁组合物,包括:
(a)约0.001至约0.25wt.%的至少一种季氨化合物;
(b)约0.001至约2wt.%的pH调节剂,其包括至少两种有机或无机助洗剂的组合;
(c)约0.001%至约0.5wt.%的至少一种表面活性剂,其包括至少一种非离子表面活性剂和,并可选择性地包括一种阳离子表面活性剂,且其中所述至少一种表面活性剂不包括阴离子表面活性剂和两性表面活性剂;
(d)约95至约99.8wt.%的至少一种水溶性溶剂或增溶剂,其包括水和乙醇、亚烷基乙二醇、乙二醇醚中的至少一种化合物,其中,水为所述至少一种溶剂或增溶剂的主要成分;
(e)可选的,一种或多种佐剂,其选自香料和着色剂;
其中,所述组合物具有的pH值为约6至约9,且组合物总重量基于100wt.%。
2.如权利要求1所述的抗细菌清洁组合物,其中,所述pH调节剂包括白蒸馏醋和胺。
3.如权利要求2所述的抗细菌清洁组合物,其中,所述胺是烷醇胺。
4.如权利要求1所述的抗细菌清洁组合物,其中,所述至少一种非离子表面活性剂是烷氧基化的直链醇、链烷醇酰胺、氧化胺或乙氧基化的脂肪酸酯中的一种或多种。
5.如权利要求1所述的抗细菌清洁组合物,其进一步包括促进剂。
6.如权利要求5所述的抗细菌清洁组合物,其中,所述促进剂是压缩气体或烃。
7.如权利要求1所述的抗细菌清洁组合物,其中,所述家具表面包括木材、木材层压板、木材与玻璃的组合、大理石、花岗岩、不锈钢或其组合制成的表面。
8.如权利要求1所述的抗细菌清洁组合物,其中,所述组合物被浸渍在擦拭物中或被从触发器喷雾器分配。
9.如权利要求1所述的抗细菌清洁组合物,其中,
(a)所述至少一种季氨化合物中存在的量为约0.005至约0.15wt.%;
(b)所述pH调节剂存在的量为约0.05至约1wt.%;
(c)所述至少一种表面活性剂存在的量为约0.01至约0.2wt.%;
(d)所述至少一种水溶性溶剂或增溶剂存在的量为约97.5至约99.8wt.%。
10.如权利要求9所述的抗细菌清洁组合物,其中,所述pH值为约7至约9。
11.如权利要求1所述的抗细菌清洁组合物,其中,
(a)所述至少一种季氨化合物存在的量为约0.01至约0.1wt.%;
(b)所述pH调节剂存在的量为约0.2至约0.6wt.%;
(c)所述至少一种表面活性剂存在的量为约0.04至约0.12wt.%;
(d)所述至少一种水溶性溶剂或增溶剂存在的量为约98.5至约99.8wt.%。
12.如权利要求11所述的抗细菌清洁组合物,其中,所述pH值为约8至约9。
13.一种应用在家具表面上来对该表面进行清洁和消毒而不会产生纹的抗细菌清洁组合物,包括:
(a)约0.001至约0.25wt.%的至少一种氯化季氨化合物;
(b)约0.05至约1wt.%的白蒸馏醋;
(c)约0.05%至约1wt.%的醇胺;
(d)约95至约99.8wt.%的至少一种水溶性溶剂或增溶剂,其包括水、乙醇、亚烷基乙二醇醚、亚烷基乙二醇,其中,水为所述至少一种溶剂或增溶剂的主要成分;
(e)约0.001至约0.5wt.%的至少一种表面活性剂,其包括至少一种非离子表面活性剂和,并可选择性地包括一种阳离子表面活性剂,且其中所述至少一种表面活性剂不包括阴离子表面活性剂和两性表面活性剂;
(f)可选的,一种或多种佐剂,其选自香料和着色剂;
其中,所述组合物具有的pH值为约6至约9,且组合物总重量基于100wt.%。
14.如权利要求13所述的抗细菌清洁组合物,其中,所述至少一种非离子表面活性剂包括烷氧基化的直链醇。
15.如权利要求14所述的抗细菌清洁组合物,其中,所述烷氧基化的直链醇是乙氧基化的直链醇。
16.如权利要求15所述的抗细菌清洁组合物,其中,所述乙氧基化的直链醇是带有3-6个环氧乙烯基团的C6-17的乙氧基化的直链醇。
17.如权利要求13所述的抗细菌清洁组合物,其进一步包括促进剂。
18.如权利要求17所述的抗细菌清洁组合物,其中,所述促进剂是压缩气体或烃。
19.如权利要求13所述的抗细菌清洁组合物,其中,所述组合物被浸渍在擦拭物中或被从触发器喷雾器分配。
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