CN103031459B - 一种掺杂有粉煤灰的铝合金熔炼用精炼剂制备方法 - Google Patents
一种掺杂有粉煤灰的铝合金熔炼用精炼剂制备方法 Download PDFInfo
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- CN103031459B CN103031459B CN201210515501.4A CN201210515501A CN103031459B CN 103031459 B CN103031459 B CN 103031459B CN 201210515501 A CN201210515501 A CN 201210515501A CN 103031459 B CN103031459 B CN 103031459B
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- parts
- sodium
- refining agent
- hour
- chloride
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- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 26
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 24
- 238000007670 refining Methods 0.000 title claims abstract description 24
- 239000010881 fly ash Substances 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 238000003723 Smelting Methods 0.000 title claims abstract description 9
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims abstract description 18
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 12
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims abstract description 12
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000002893 slag Substances 0.000 claims abstract description 10
- 239000002956 ash Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000004317 sodium nitrate Substances 0.000 claims abstract description 9
- 235000010344 sodium nitrate Nutrition 0.000 claims abstract description 9
- 239000011734 sodium Substances 0.000 claims abstract description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 6
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910001634 calcium fluoride Inorganic materials 0.000 claims abstract description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 6
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 3
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 3
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 34
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 239000011592 zinc chloride Substances 0.000 claims description 17
- 235000005074 zinc chloride Nutrition 0.000 claims description 17
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- 229910021536 Zeolite Inorganic materials 0.000 claims description 11
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 11
- 239000010457 zeolite Substances 0.000 claims description 11
- 239000008187 granular material Substances 0.000 claims description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 8
- 239000011574 phosphorus Substances 0.000 claims description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims description 8
- 235000015320 potassium carbonate Nutrition 0.000 claims description 8
- 229940001516 sodium nitrate Drugs 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000013618 particulate matter Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 229910020808 NaBF Inorganic materials 0.000 claims description 5
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 238000010298 pulverizing process Methods 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- PVGBHEUCHKGFQP-UHFFFAOYSA-N sodium;n-[5-amino-2-(4-aminophenyl)sulfonylphenyl]sulfonylacetamide Chemical compound [Na+].CC(=O)NS(=O)(=O)C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 PVGBHEUCHKGFQP-UHFFFAOYSA-N 0.000 claims description 3
- ZNRSXPDDVNZGEN-UHFFFAOYSA-K trisodium;chloride;sulfate Chemical compound [Na+].[Na+].[Na+].[Cl-].[O-]S([O-])(=O)=O ZNRSXPDDVNZGEN-UHFFFAOYSA-K 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000005266 casting Methods 0.000 abstract description 3
- 239000011148 porous material Substances 0.000 abstract description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 abstract 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 239000004113 Sepiolite Substances 0.000 abstract 1
- 235000013312 flour Nutrition 0.000 abstract 1
- 229910000027 potassium carbonate Inorganic materials 0.000 abstract 1
- 239000001103 potassium chloride Substances 0.000 abstract 1
- 235000011164 potassium chloride Nutrition 0.000 abstract 1
- 229910052624 sepiolite Inorganic materials 0.000 abstract 1
- 235000019355 sepiolite Nutrition 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 229910001495 sodium tetrafluoroborate Inorganic materials 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- 238000001125 extrusion Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229910000851 Alloy steel Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000003913 materials processing Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Abstract
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CN201210515501.4A CN103031459B (zh) | 2012-12-05 | 2012-12-05 | 一种掺杂有粉煤灰的铝合金熔炼用精炼剂制备方法 |
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CN201210515501.4A CN103031459B (zh) | 2012-12-05 | 2012-12-05 | 一种掺杂有粉煤灰的铝合金熔炼用精炼剂制备方法 |
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CN103031459A CN103031459A (zh) | 2013-04-10 |
CN103031459B true CN103031459B (zh) | 2015-03-04 |
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CN201210515501.4A Expired - Fee Related CN103031459B (zh) | 2012-12-05 | 2012-12-05 | 一种掺杂有粉煤灰的铝合金熔炼用精炼剂制备方法 |
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CN105316507B (zh) * | 2015-10-21 | 2018-07-27 | 广西平果铝合金精密铸件有限公司 | 一种含镧铒锆的铝合金精炼剂 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1718807A (zh) * | 2005-06-28 | 2006-01-11 | 严瑞山 | 粉煤灰提取铝硅合金的工艺方法 |
JP2008542548A (ja) * | 2005-06-07 | 2008-11-27 | テヒニッシェ・ウニベルジテート・クラウシュタール | アルミニウム滑り軸受合金 |
CN101343699A (zh) * | 2008-09-03 | 2009-01-14 | 营口经济技术开发区金达合金铸造有限公司 | 一种铝硅合金精炼剂及其制造方法 |
CN102181757A (zh) * | 2011-06-20 | 2011-09-14 | 岳阳德利亨新材料科技有限公司 | 一种铝合金熔炼用精炼剂及其制备方法 |
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- 2012-12-05 CN CN201210515501.4A patent/CN103031459B/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008542548A (ja) * | 2005-06-07 | 2008-11-27 | テヒニッシェ・ウニベルジテート・クラウシュタール | アルミニウム滑り軸受合金 |
CN1718807A (zh) * | 2005-06-28 | 2006-01-11 | 严瑞山 | 粉煤灰提取铝硅合金的工艺方法 |
CN101343699A (zh) * | 2008-09-03 | 2009-01-14 | 营口经济技术开发区金达合金铸造有限公司 | 一种铝硅合金精炼剂及其制造方法 |
CN102181757A (zh) * | 2011-06-20 | 2011-09-14 | 岳阳德利亨新材料科技有限公司 | 一种铝合金熔炼用精炼剂及其制备方法 |
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CB03 | Change of inventor or designer information | ||
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Inventor after: Wang Junxia Inventor before: Chen Xuesong Inventor before: Huang Debin |
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TR01 | Transfer of patent right | ||
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Effective date of registration: 20170818 Address after: 061304 Cangzhou city in Hebei Province town of San Cao Zhai Cun 258, Yanshan County Patentee after: Wang Junxia Address before: 243111 Anhui city of Ma'anshan province Dangtu County Gu Shu Industrial Park Patentee before: Anhui Huilv Aluminum Industry Co., Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150304 Termination date: 20171205 |