CN103015169A - Clothing sterilization degreasing modification treatment finishing agent - Google Patents

Clothing sterilization degreasing modification treatment finishing agent Download PDF

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Publication number
CN103015169A
CN103015169A CN 201110278888 CN201110278888A CN103015169A CN 103015169 A CN103015169 A CN 103015169A CN 201110278888 CN201110278888 CN 201110278888 CN 201110278888 A CN201110278888 A CN 201110278888A CN 103015169 A CN103015169 A CN 103015169A
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China
Prior art keywords
finishing agent
clothing
modification treatment
quaternary ammonium
analog derivative
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CN 201110278888
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Chinese (zh)
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孙善家
孙尉鹏
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Individual
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Individual
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Priority to CN 201110278888 priority Critical patent/CN103015169A/en
Publication of CN103015169A publication Critical patent/CN103015169A/en
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Abstract

The present invention relates to a clothing sterilization degreasing modification treatment finishing agent, which is adopted as clothing sterilization degreasing and color losing modification treatment finishing remedial measures in laundry plants and laundries, can effectively control transmission of various skin diseases on the clothing, and has effects of strong detergency and high sterilization efficacy. In addition, with the modification treatment finishing agent, level dyeing property and color fastness of acidic dyes are not affected.

Description

The clothing degerming modification finishing agent that deoils
Technical field the present invention relates to a kind of clothing degerming modification finishing agent that deoils, fabric wear for a long time with the dyeing and finishing process in often can be stained with greasy dirt spot and bacterium, its removal method has dissolution with solvents, surfactant washing and add disinfectant with alkali saponification method.The deoil composition of modification finishing agent of clothing degerming of the present invention is to utilize amine-terminated hyperbranced compound quaternary ammonium salt (HBP-HTC) that fabric is carried out cation-modified processing, realize the neutral dyeing of fabric ACID DYES low temperature, studied modification real silk fabric acid dyeing performance, can under being 55 ℃ condition, pH=7, temperature realize the dyeing of ACID DYES through the real silk fabric of modification, and to weak acid dye and the equal tool applicability of highly acid dyestuff; In the modification finishing agent, add effective sterilization component algal polysaccharides analog derivative, biology enzyme, β-chitosan quaternary ammonium hyaluronic acid analog derivative, surfactant, be prepared from through special process.Be adapted at doing washing factory, laundry, laundry as clothing degerming deoil, the remedial measure of the modification that fades arrangement, can effectively control simultaneously the various dermopathic propagation on the clothing, has strong detergency, the degerming rate is high, and the modification agent is on the level-dyeing property of acid dyeing and the COLOR FASTNESS effect without impact.
Contain effective chlorine in the running water that background technology laundry is used and can destroy dyestuff and cause clothes that look occurs in water-washing process becoming vividness and descend, people's chloride washing agent commonly used cleans fabric also might cause the fabric color variation.Household washing has the greatest impact to the natural colour cotton fabric performance, and fabric has after first washing and limbers up and plentiful trend, and along with the increase of washing times, the Fabric Style richness descends gradually and makes fabric that the trend that becomes smooth be arranged; Compare with pure white COTTON FABRIC, the fabric that contains color cotton has the trend well-pressed, that mouldability improves through behind the household washing, the greasy dirt that produces is just for some reason burst and is stained with knot on fabric, the technique of stripping with routine is processed, may not obtain satisfied effect, and need to consume a large amount of chemical assistants and dye material, the fastness to light of fabric has adverse influence.In the multicomponent system and phase region of surfactant and cosurfactant and electrolyte ingredient, has ultralow interface, tension force has very high solubilizing power to hydrophile and oleophylic thing, and making medium in fabric decontaminating can combine organic solvent solubilization and the traditional characteristic that washes.Polybasic carboxylic acid class finishing agent isoreactivity dyestuff and dyeing concentration to COTTON FABRIC the degerming anti-chlorine COLOR FASTNESS of modification of deoiling soft wrinkle resistant and nano waterproof oil-proof finishing is influential.Utilize the anti-chlorine COLOR FASTNESS of REACTIVE DYES of different structure different; The anti-chlorine COLOR FASTNESS of light color fabric is hanged down the finishing agent of anti-chlorine to the anti-chlorine COLOR FASTNESS effect of having greatly improved of light fabric than deep-colour fabric usually, can put its effect with bath in order to fabric with the agent of soft finishing agent nano waterproof oil-proof finishing and have certain durability.The anti-bacteria health finishing technology is the marginal technology that modern medicine, fine chemistry industry combine with dyeing and finishing technique.Its key problem in technology is to carry out from chemical aspect that ribosome exhausts in the antibiotic body, thereby causes bacterium dead; Also optionally act on the ergosterol of fungal cell membrane from medical science aspect research Antibiotic-odor Resistant Agent, permeability of cell membrane is changed, cause that important substance runs off in the cell, make fungi dead.Solve combination and every fastness, brute force, whiteness and the gas permeability etc. of Antibiotic-odor Resistant Agent and fiber from dyeing and finishing engineering science aspect, adopt anti-bacteria health finishing agent that textile and polyester-cotton fabric are carried out antibiotic finish, emphasis will be studied finishing technique prescription and technological process.
Summary of the invention main points of the present invention are to select suitable component, and carry out rational mixture, through heating, a kind of clothing degerming of forming of the emulsion reaction modification finishing agent that deoils.
The prescription following (component and percentage by weight % thereof) that the present invention selects: polybasic carboxylic acid finishing agent 6.0-8.0, algal polysaccharides analog derivative 3.0-4.0, biology enzyme 0.5-1.0, β-chitosan quaternary ammonium hyaluronic acid analog derivative 3.0-4.0, polyhexamethylene guanide 0.5-1.0, amine-terminated hyperbranced compound quaternary ammonium HBP-HTC5.0-6.0, anion surfactant 5.0-6.0, deionized water add to 100.
Under acid condition, β-chitosan quaternary ammonium hyaluronic acid analog derivative has high viscosity and high deacetylized amino Cation adsorption with the bacterium of negative electrical charge, has fettered the free degree of microorganism, hinders its metabolism and breeding; Low-molecular-weight chitosan molecule enters in the cell by microorganism wall, hinder the microorganism hereditary password by DNA to the copying of RNA, thereby suppressed the breeding of bacterium.The algal polysaccharides analog derivative has the electrical of absorption, inhibition, intervention bacterium and virus, the alkaline enzyme of glutinous polysaccharide can destroy-acetylmuramic acid and the β between the NAG-1 in the cell membrane, 4 glycosidic bonds can with the electronegative direct combination of bacterium, virus protein, form double salt with DNA, RNA, apoprotein, algal polysaccharides has obvious inhibitory action to multiple viruses such as HIV, HSV, togavirus, arenavirus, influenza virus, giant cell virus, the thin virus of reverse transcription and rhabdovirus, so can be applied in the middle of the antiviral therapy medicine.β-chitosan quaternary ammonium hyaluronic acid analog derivative, algal polysaccharides analog derivative, marine organisms alpha-helix cecropin and the compositions such as biology enzyme and polyhexamethylene guanide are formulated by a certain percentage.β-chitosan quaternary ammonium hyaluronic acid analog derivative, algal polysaccharides analog derivative, marine organisms alpha-helix cecropin and biology enzyme are the natural active components of the biological species of natural marine, as main sterilization component, join in proportion in the mixture, purpose is by its characteristic, bacterial propagule and part virus are had preferably killing effect, fungi is also shown stronger killing action.The fragrant board marine organisms in sea plain bacteria remover alive is biological compound bacteria remover, any folk prescription in this component all can not killing bacteria gemma and virus, after forming compound in proportion, by its synergistic characteristic but rapidly killing bacteria gemma and virus, greatly improved sterilization effect.Contain Multiple components in the compound disinfectant, the content ratio of each single component reduces relatively, therefore additive effect has also been played in the side effects such as people's toxicity and excitant less, additive effect refers to the as a whole Disinfection Effect of formulation of disinfectant, greater than the independent Disinfection Effect sum of using of each component.Just can realize this novel quick-acting bactericidal effects according to specific ratio with specific sterilization component is formulated together.Biology enzyme can improve bacteria-eliminating efficacy as the synergistic component in this prescription, makes the effect that just can reach at short notice thorough cleaning.Polyhexamethylene guanide is the high molecular polymer of long-chain, guanidine radicals has very high activity, make polymer become electropositive, usually be electronegative each bacterioid, virus is easy to be adsorbed, then can firmly bacterium be twined, thereby suppress bacterium and viral splitting function, make bacterium, virus lose fecundity, add that polymer molecule has stopped up the respiration channel of microorganism, is choked to death rapidly microorganism.In addition, because the high molecular polymer long chain type structure of polyhexamethylene guanide uniqueness does not contain heterocyclic group, be difficult for being absorbed by animal body inner tissue, thus zooblast there is not toxicity, thus can accomplish human body nontoxic.And its unique physical sterilization mechanism can not develop immunity to drugs by the DNA variation each bacterioid, virus to it, thereby reaches fast, wide spectrum, the stable effect of killing all kinds of bacterial viruses.
The preparation method of product of the present invention is:
(1) by proportioning described component is added respectively in the aqueous solution, stir;
(2) by proportioning described component biology enzyme is added stirring, mix;
(3) deionized water adds to 100, stirs; Detect qualified after, packing.
The present invention compares with existing disinfectant has following advantage: (1) sterilization effect is remarkable, and is especially particularly remarkable to staphylococcus aureus and β hemolytic streptococcus; (2) sterilization, inhibition time are long; (2) nontoxic, non-stimulated, non-corrosiveness, smell delicate fragrance; (3) scope of application is wide, is suitable for the disinfection of every field personnel skin; (4) this product is the large molecular glue shaped polymers of marine organisms, and chemical property is very stable, the term of validity 2 years; (5) carry, be convenient to flushing, convenient and practical; (6) technique is simple, and cost is low.
The present invention is described in further detail below in conjunction with embodiment for the specific embodiment:
Be configured according to following table institute column data (percentage by weight %) and affiliated step thereof:
Prescription one:
Polybasic carboxylic acid finishing agent 6.0-8.0, algal polysaccharides analog derivative 3.0-4.0, biology enzyme 0.5-1.0, β-chitosan quaternary ammonium hyaluronic acid analog derivative 3.0-4.0, polyhexamethylene guanide 0.5-1.0, amine-terminated hyperbranced compound quaternary ammonium HBP-HTC5.0-6.0, anion surfactant 5.0-6.0, deionized water add to 100.
Prescription two:
Polybasic carboxylic acid finishing agent 7.0-8.0, algal polysaccharides analog derivative 3.0-4.0, biology enzyme 0.7-1.0, β-chitosan quaternary ammonium hyaluronic acid analog derivative 3.5-4.0, polyhexamethylene guanide 0.7-1.0, amine-terminated hyperbranced compound quaternary ammonium HBP-HTC5.5-6.0, anion surfactant 5.5-6.0, deionized water add to 100.
Prescription three:
Polybasic carboxylic acid finishing agent 7.0-7.7, algal polysaccharides analog derivative 3.5-4.0, biology enzyme 0.5-0.7, β-chitosan quaternary ammonium hyaluronic acid analog derivative 3.2-3.6, polyhexamethylene guanide 0.6-0.8, amine-terminated hyperbranced compound quaternary ammonium HBP-HTC5.5-5.8, anion surfactant 5.2-5.7, deionized water add to 100.

Claims (2)

1. the present invention relates to a kind of clothing degerming modification finishing agent that deoils, it is characterized in that having following prescription (component and percentage by weight % thereof): polybasic carboxylic acid finishing agent 6.0-8.0, algal polysaccharides analog derivative 3.0-4.0, biology enzyme 0.5-1.0, β-chitosan quaternary ammonium hyaluronic acid analog derivative 3.0-4.0, polyhexamethylene guanide 0.5-1.0, amine-terminated hyperbranced compound quaternary ammonium HBP-HTC5.0-6.0, anion surfactant 5.0-6.0, deionized water add to 100.
2. the described clothing degerming of claim 1 preparation method of modification finishing agent that deoils is characterized in that having following steps:
(1) by proportioning described component is added respectively in the aqueous solution, stir;
(2) by proportioning described component biology enzyme is added stirring, mix;
(3) deionized water adds to 100, stirs; Detect qualified after, packing.
CN 201110278888 2011-09-20 2011-09-20 Clothing sterilization degreasing modification treatment finishing agent Pending CN103015169A (en)

Priority Applications (1)

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CN 201110278888 CN103015169A (en) 2011-09-20 2011-09-20 Clothing sterilization degreasing modification treatment finishing agent

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Application Number Priority Date Filing Date Title
CN 201110278888 CN103015169A (en) 2011-09-20 2011-09-20 Clothing sterilization degreasing modification treatment finishing agent

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CN103015169A true CN103015169A (en) 2013-04-03

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103710970A (en) * 2013-11-27 2014-04-09 常熟市琴达针织印染有限公司 Degerming oil-removal modification treatment finishing agent for clothing
CN104672346A (en) * 2014-12-15 2015-06-03 四川吉百瑞生物医疗科技有限公司 Preparation method of guanidyl chitosan quaternary ammonium salt

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103710970A (en) * 2013-11-27 2014-04-09 常熟市琴达针织印染有限公司 Degerming oil-removal modification treatment finishing agent for clothing
CN104672346A (en) * 2014-12-15 2015-06-03 四川吉百瑞生物医疗科技有限公司 Preparation method of guanidyl chitosan quaternary ammonium salt
CN104672346B (en) * 2014-12-15 2018-05-25 四川吉百瑞生物医疗科技有限公司 The preparation method of guanidine radicals chitosan quaternary amine

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Application publication date: 20130403