CN103015160B - Method for producing bacteriostatic sole, lining or insole by using bacteriostatic agent - Google Patents
Method for producing bacteriostatic sole, lining or insole by using bacteriostatic agent Download PDFInfo
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- CN103015160B CN103015160B CN201210551269.XA CN201210551269A CN103015160B CN 103015160 B CN103015160 B CN 103015160B CN 201210551269 A CN201210551269 A CN 201210551269A CN 103015160 B CN103015160 B CN 103015160B
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Abstract
The invention discloses a method for producing a bacteriostatic sole, lining or insole by using bacteriostatic agent. The method comprises the following steps: (1) the bacteriostatic agent is prepared to bacteriostatic agent water solution, and is selected from siberian solomonseal rhizome extract, scutellaria baicalensis extract, forsythia suspensa extract, honeySuchle flowers extract, coptis chinensis extract, radix isatidis extract and pepper extract or a mixture of several thereof; (2) the bacteriostatic agent water solution permeates into the sole, lining or insole; (3) the irradiation grafting is implemented; and (4) the moisture is dried to obtain the bacteriostatic sole, lining or insole. The method adopts the bacteriostatic agent which is harmless to people; the raw materials are cheap, easy to get, and easy to be degraded; and the environmental pollution from heavy metals and substances toxic for the people is avoided. The grafting process of the bacteriostatic agent adopts the mode of grafting after radiating electronic beams or plasma bodies in the sole, lining or the insole, so that the processing method is easy and feasible, no chemical pollution is generated, and energy conservation and environmental friendliness are achieved.
Description
Technical field
The present invention relates to antibacterial textiles, refer to that a kind of bacteriostatic agent that utilizes manufactures antibacterial sole, footwear or the method for shoe-pad inside particularly.
Background technology
China is that footwear industry manufactures big country, is also the consumption big country of article of footwear.But in China, just have a people to suffer from pedopathy in every two people, the disease rates of adult is especially up to 75%, and the pedopathy more than 60% is fungal infection, wherein the incidence of disease of tinea pedis (being commonly called as beriberi) is 45.2%, and the beriberi incidence of disease of southern china some areas can reach 50 ~ 60%.
China's beriberi incidence of disease is high, and main cause is that shoes internal environment is conducive to microbial growth, and therefore, people's common demands carries out antibacterial and deodouring process to footwear.
Bacteriostatic agent kind is a lot, substantially can be divided into following a few class: 1, organic heavy metal compound, as: beta-hydroxy quinolinone, 3,5-dimethylphenyl tin acetic acid esters, the pungent mercury of phenyl two, tributyl lead acetate and alkanoic acid zinc etc.; 2, some dyestuffs or auxiliary agent, as: triphenylmethane dye, TMM-THPC etc.; 3, the antibiotic such as some organic titaniums, organo-aluminium, organic zirconate and tetracycline share; 4, aromatic halogen compounds, as: alpha-bromo-cinnamaldehyde, 2,4,4 '-three chloro-2 ' dihydroxy diphenyl ether, chloro-2-(2, the 4-dichlorophenoxy of 5-) phenol etc.; 5, organosilicone quaternary ammonium salt compounds.Although above-mentioned bacteriostatic agent can make textiles have antimicrobial performance, some bacteriostatic agents are simultaneously harmful.
Therefore, selecting cheap is the important selection in the antibacterial field of shoemaking to the bacteriostatic agent of health.
Summary of the invention
The present invention is directed to the deficiencies in the prior art, provide a kind of utilize bacteriostatic agent manufacture antibacterial sole, footwear inside, the method for shoe-pad.
The present invention utilizes bacteriostatic agent to manufacture antibacterial sole, footwear or the method for shoe-pad inside, comprises the following steps:
1) bacteriostatic agent is mixed with the bacteriostatic agent aqueous solution; Described bacteriostatic agent is selected from the mixture of one or more in Rhizoma Polygonati extract, Baical Skullcap root P.E, forsythia suspense extraction, Honegsukle flower P.E, coptis extract, isatis root extract, pepper extract;
2), make the bacteriostatic agent aqueous solution penetrate into sole, footwear inside or in shoe-pad inside by bacteriostatic agent aqueous solution soaking sole, footwear or shoe-pad, according to the sole of per kilogram, footwear inside or shoe-pad add 10 ~ 30 grams of bacteriostatic agents;
3) to adopt the sole of bacteriostatic agent process, footwear inside or shoe-pad carry out irradiation grafting;
4) at the bottom of shoe drying, the moisture of footwear inside or in shoe-pad, obtain antibacterial sole, footwear or shoe-pad inside.
In step 1) of the present invention, described Rhizoma Polygonati extract, Baical Skullcap root P.E, forsythia suspense extraction, Honegsukle flower P.E, coptis extract, isatis root extract, pepper extract are the powder by extracting rear dry gained.
In step 3) of the present invention, adopt the sole of bacteriostatic agent process, footwear inside or shoe-pad through electron beam or plasma radiation grafting, the energy of the generation of the accelerator that irradiation is used is 5 ~ 10Mev, and radiation dose rate is 80 ~ 100Gy.
The present invention's Rhizoma Polygonati extract used, Baical Skullcap root P.E, forsythia suspense extraction, Honegsukle flower P.E, coptis extract, isatis root extract, pepper extract are natural plants bacteriostatic agent, are the product that market can have been bought.
Research shows: the Rhizoma Polygonati extract aqueous solution of 1:320 concentration has inhibitory action to typhoid bacillus, staphylococcus aureus, acid-fast bacilli, and the 2% Rhizoma Polygonati extract aqueous solution has inhibitory action in various degree to common causative fungi in sabouraud culture medium.
Root of large-flowered skullcap decocting liquid, test tube slant method tests 4% control of the concentration dog denticle born of the same parents bacterium and trichophyton, 8% control of the concentration oidium schoenleinii, the mutation of 10% control of the concentration oidium schoenleinii Mongolia, 15% control of the concentration homocentricity trichophyta and rust trichophyta.Root of large-flowered skullcap water logging agent 1:3 concentration is in vitro to trichophyton, Trichophyton concentricum, and oidium schoenleinii, Microsporon audouini, wool sample microspore tinea bacterium, epidermophyton rubrum, K, W, family name Epidermophyton, star nocardia etc. have bacteriostasis in various degree.
The capsule of weeping forsythia all has inhibitory action to multiple Grain-positive and negative bacteria. and its concentrated decoction can suppress typhoid bacillus, paratyphosum Bacterium, Escherichia coli, shigella dysenteriae, corynebacterium diphtheriae and comma bacillus, staphylococcus, streptococcus etc. in vitro.Have report to point out, forsythol is the antibacterial active ingredient of the capsule of weeping forsythia. forsythol is 1:5120 to the Mlc of staphylococcus aureus in test tube; Be 1:1280 to shigella dysenteriae; Be 1:640 to corynebacterium diphtheriae and paratyphoid (first) bacillus.Capsule of weeping forsythia water logging agent (1:5) has some inhibitory action to star-shaped nocardia in vitro.
Honeysuckle to various pathogens as staphylococcus aureus, hemolytic streptococcus, Escherichia coli, shigella dysenteriae, comma bacillus, typhoid bacillus, paratyphosum Bacterium etc. all have certain inhibitory action.Honeysuckle is to Salmonella, particularly the inhibitory action of typhoid bacillus and hemolytic streptococcus seemingly exceedes the capsule of weeping forsythia, then seemingly better with the capsule of weeping forsythia to the suppression of shigella dysenteriae, staphylococcus aureus. the two conbined usage, there is no synergy in vitro, the compound formed with the coptis, the root of large-flowered skullcap, In Vitro Bacteriostasis is than being strong during the alone capsule of weeping forsythia.
The coptis all has certain inhibitory action to staphylococcus aureus, hemolytic streptococcus, pneumococcus, diplococcus meningitidis, shigella dysenteriae, bacillus anthracis etc.
Radix Isatidis has effect to various bacteria.Isatis root extract infusion has inhibitory action to hay bacillus, staphylococcus aureus, sarcine, Escherichia coli, typhoid bacillus, paratyphoid A bacillus, dysentery (will Hayes, Fu Shi) bacillus, bacillus enteritidis etc.
Chinese prickly ash has inhibitory action to corynebacterium diphtheriae, Diplococcus pneumopniae, staphylococcus aureus and some dermatophyte.
Beneficial effect of the present invention is: the present invention adopts the bacteriostatic agent harmless to people, and cheaper starting materials is easy to get, and raw material is easily degraded, avoid heavy metal and to the poisonous material of people to the pollution of environment.Bacteriostatic agent grafting process adopts electron beam or plasma radiation sole, footwear or the mode of shoe-pad and then grafting inside, and processing method is simple, does not have chemical contamination, energy-conserving and environment-protective.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment 1
1) Rhizoma Polygonati extract is mixed with the Rhizoma Polygonati extract aqueous solution, Rhizoma Polygonati extract used is the powder by extracting rear dry gained;
2) by Rhizoma Polygonati extract aqueous solution soaking sole, make the Rhizoma Polygonati extract aqueous solution penetrate in sole, add 20 grams of Rhizoma Polygonati extracts according to the sole of per kilogram;
3) to adopting the sole of Rhizoma Polygonati extract process to carry out electron beam irradiation grafting, the energy of the generation of the accelerator that irradiation is used is 5Mev, and radiation dose rate is 100Gy
4) moisture at the bottom of shoe drying, obtains antibacterial sole.
Made sole after testing, has inhibitory action in various degree to staphylococcus aureus, common causative fungi.
Embodiment 2
1) Baical Skullcap root P.E is mixed with the Baical Skullcap root P.E aqueous solution, Baical Skullcap root P.E used is the powder by extracting rear dry gained;
2) by Baical Skullcap root P.E aqueous solution soaking footwear inside, make the Baical Skullcap root P.E aqueous solution penetrate into footwear inside in, add 15 grams of Baical Skullcap root P.Es inside according to the footwear of per kilogram;
3) to adopting the footwear of Baical Skullcap root P.E process to carry out electron beam irradiation grafting inside, the energy of the generation of the accelerator that irradiation is used is 6Mev, and radiation dose rate is 80Gy;
4) shoe drying inside in moisture, obtain antibacterial footwear inside.
Made footwear after testing, have inhibitory action in various degree to staphylococcus aureus, common causative fungi inside.
Embodiment 3
1) forsythia suspense extraction is mixed with the forsythia suspense extraction aqueous solution, forsythia suspense extraction used is the powder by extracting rear dry gained;
2) by forsythia suspense extraction aqueous solution soaking shoe-pad, make the forsythia suspense extraction aqueous solution penetrate in shoe-pad, add 24 grams of forsythia suspense extractions according to the shoe-pad of per kilogram;
3) to adopting the shoe-pad of forsythia suspense extraction process to carry out electron beam irradiation grafting, the energy of the generation of the accelerator that irradiation is used is 7Mev, and radiation dose rate is 95Gy;
4) moisture in drying shoe-pads, obtains antibacterial shoe-pad.
Made shoe-pad after testing, has inhibitory action in various degree to staphylococcus aureus, common causative fungi.
Embodiment 4
1) Honegsukle flower P.E is mixed with the Honegsukle flower P.E aqueous solution, Honegsukle flower P.E used is the powder by extracting rear dry gained;
2) by Honegsukle flower P.E aqueous solution soaking sole, make the Honegsukle flower P.E aqueous solution penetrate in sole, add 25 grams of Honegsukle flower P.Es according to the sole of per kilogram;
3) to adopting the sole of Honegsukle flower P.E process to carry out electron beam irradiation grafting, the energy of the generation of the accelerator that irradiation is used is 8Mev, and radiation dose rate is 90Gy;
4) moisture at the bottom of shoe drying, obtains antibacterial sole.
Made sole after testing, has inhibitory action in various degree to staphylococcus aureus, common causative fungi.
Embodiment 5
1) coptis extract is mixed with the coptis extract aqueous solution, coptis extract used is the powder by extracting rear dry gained;
2) by coptis extract aqueous solution soaking shoe-pad, make the coptis extract aqueous solution penetrate in shoe-pad, add 30 grams of coptis extracts according to the shoe-pad of per kilogram;
3) cross shoe-pad to the process of employing coptis extract and carry out electron beam irradiation grafting, the energy of the generation of the accelerator that irradiation is used is 9Mev, and radiation dose rate is 85Gy;
4) moisture in drying shoe-pads, obtains antibacterial shoe-pad.
Made shoe-pad after testing, has inhibitory action in various degree to staphylococcus aureus, common causative fungi.
Embodiment 6
1) isatis root extract is mixed with the isatis root extract aqueous solution, isatis root extract used is the powder by extracting rear dry gained;
2) by isatis root extract aqueous solution soaking footwear inside, make the isatis root extract aqueous solution penetrate into footwear inside in, add 22 grams of isatis root extracts inside according to the footwear of per kilogram;
3) to adopting the footwear of isatis root extract process to carry out electron beam irradiation grafting inside, the energy of the generation of the accelerator that irradiation is used is 10Mev, and radiation dose rate is 80Gy;
4) shoe drying inside in moisture, obtain antibacterial footwear inside.
Made footwear after testing, have inhibitory action in various degree to staphylococcus aureus, common causative fungi inside.
Embodiment 7
1) pepper extract is mixed with the pepper extract aqueous solution, pepper extract used is the powder by extracting rear dry gained;
2) by pepper extract aqueous solution soaking footwear inside, make the pepper extract aqueous solution penetrate into footwear inside in, add 18 grams of pepper extracts inside according to the footwear of per kilogram;
3) to adopting the footwear of pepper extract process to carry out electron beam irradiation grafting inside, the energy of the generation of the accelerator that irradiation is used is 10Mev, and radiation dose rate is 80Gy;
4) shoe drying inside in moisture, obtain antibacterial footwear inside.
Made footwear after testing, have inhibitory action in various degree to staphylococcus aureus, dermatophyte inside.
Embodiment 8
1) bacteriostatic agent is mixed with the bacteriostatic agent aqueous solution, bacteriostatic agent used is the mixture of Honegsukle flower P.E and forsythia suspense extraction, and Honegsukle flower P.E used and forsythia suspense extraction are the powder by extracting rear dry gained;
2) by bacteriostatic agent aqueous solution soaking shoe-pad, make the bacteriostatic agent aqueous solution penetrate in shoe-pad, add 10 grams of bacteriostatic agents according to the shoe-pad of per kilogram;
3) to adopting the shoe-pad of bacteriostatic agent process to carry out electron beam irradiation grafting, the energy of the generation of the accelerator that irradiation is used is 7Mev, and radiation dose rate is 85Gy;
4) moisture in drying shoe-pads, obtains antibacterial shoe-pad.
Made shoe-pad after testing, has inhibitory action in various degree to staphylococcus aureus, common causative fungi.
Embodiment 9
1) bacteriostatic agent is mixed with the bacteriostatic agent aqueous solution, bacteriostatic agent used is the mixture of Honegsukle flower P.E, coptis extract and Baical Skullcap root P.E, and Honegsukle flower P.E used, coptis extract and Baical Skullcap root P.E are the powder by extracting rear dry gained;
2) by bacteriostatic agent aqueous solution soaking shoe-pad, make the bacteriostatic agent aqueous solution penetrate in shoe-pad, add 12 grams of bacteriostatic agents according to the shoe-pad of per kilogram;
3) to adopting the shoe-pad of bacteriostatic agent process to carry out electron beam irradiation grafting, the energy of the generation of the accelerator that irradiation is used is 7Mev, and radiation dose rate is 85Gy;
4) moisture in drying shoe-pads, obtains antibacterial shoe-pad.
Made shoe-pad after testing, has inhibitory action in various degree to staphylococcus aureus, common causative fungi.
Claims (1)
1. utilize bacteriostatic agent to manufacture a method for antibacterial sole, it is characterized in that, comprise the following steps:
1) Rhizoma Polygonati extract is mixed with the Rhizoma Polygonati extract aqueous solution, Rhizoma Polygonati extract used is the powder by extracting rear dry gained;
2) by Rhizoma Polygonati extract aqueous solution soaking sole, make the Rhizoma Polygonati extract aqueous solution penetrate in sole, add 20 grams of Rhizoma Polygonati extracts according to the sole of per kilogram;
3) to adopting the sole of Rhizoma Polygonati extract process to carry out electron beam irradiation grafting, the energy of the generation of the accelerator that irradiation is used is 5Mev, and radiation dose rate is 100Gy;
4) moisture at the bottom of shoe drying, obtains antibacterial sole.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210551269.XA CN103015160B (en) | 2012-12-18 | 2012-12-18 | Method for producing bacteriostatic sole, lining or insole by using bacteriostatic agent |
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| CN201210551269.XA CN103015160B (en) | 2012-12-18 | 2012-12-18 | Method for producing bacteriostatic sole, lining or insole by using bacteriostatic agent |
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| CN103015160B true CN103015160B (en) | 2015-06-03 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104358104B (en) * | 2014-11-07 | 2016-06-15 | 江南大学 | A kind of method utilizing electron radiation technology to prepare antibacterial fabric |
| CN107335286A (en) * | 2017-08-08 | 2017-11-10 | 成都漆彩之星环保科技有限公司 | A kind of composite air filter cotton |
| CN108823126B (en) * | 2018-04-12 | 2020-01-14 | 黄山学院 | Polygonatum sibiricum endophyte and application thereof |
| CN110760085A (en) * | 2019-10-15 | 2020-02-07 | 湖州健塑塑业科技有限公司 | Self-purification pipeline and preparation method and application thereof |
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| CN1224729A (en) * | 1998-11-02 | 1999-08-04 | 华南理工大学 | Chemical graft process for preparing pyridine salt polymer as antiseptic material |
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Family Cites Families (1)
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| FR2911883B1 (en) * | 2007-01-29 | 2009-05-01 | Intissel Soc Par Actions Simpl | IONIZING RADIATION GRAFTING PROCESS USING REACTIVE SURFACE MOLECULE, TEXTILE SUBSTRATE AND BATTERY SEPARATOR OBTAINED BY GRAFTING |
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| CN1224729A (en) * | 1998-11-02 | 1999-08-04 | 华南理工大学 | Chemical graft process for preparing pyridine salt polymer as antiseptic material |
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| CN101597860A (en) * | 2008-06-06 | 2009-12-09 | 王家君 | A kind of solvay-type anti-bacterial fibre, fabric and preparation method thereof |
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