CN102993865B - A kind of preparation method of multifunctional ecological negative ion paint - Google Patents
A kind of preparation method of multifunctional ecological negative ion paint Download PDFInfo
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- CN102993865B CN102993865B CN201210442969.5A CN201210442969A CN102993865B CN 102993865 B CN102993865 B CN 102993865B CN 201210442969 A CN201210442969 A CN 201210442969A CN 102993865 B CN102993865 B CN 102993865B
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- 239000003973 paint Substances 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 150000002500 ions Chemical class 0.000 claims abstract description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000001450 anions Chemical class 0.000 claims abstract description 13
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000011347 resin Substances 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 7
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 6
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
- 239000008367 deionised water Substances 0.000 claims abstract description 5
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 19
- 239000007788 liquid Substances 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229920002523 polyethylene Glycol 1000 Polymers 0.000 claims description 3
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 3
- 150000002910 rare earth metals Chemical class 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 229920002535 Polyethylene Glycol 1500 Polymers 0.000 claims description 2
- VUYXVWGKCKTUMF-UHFFFAOYSA-N tetratriacontaethylene glycol monomethyl ether Chemical compound COCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO VUYXVWGKCKTUMF-UHFFFAOYSA-N 0.000 claims description 2
- 239000001856 Ethyl cellulose Substances 0.000 claims 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims 1
- 229920001249 ethyl cellulose Polymers 0.000 claims 1
- 235000019325 ethyl cellulose Nutrition 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 4
- 235000021190 leftovers Nutrition 0.000 abstract description 4
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 3
- 230000002159 abnormal effect Effects 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract description 2
- 229910021529 ammonia Inorganic materials 0.000 abstract description 2
- 235000019504 cigarettes Nutrition 0.000 abstract description 2
- 239000000796 flavoring agent Substances 0.000 abstract description 2
- 235000019634 flavors Nutrition 0.000 abstract description 2
- -1 formaldehyde, ketone Chemical class 0.000 abstract description 2
- 230000006872 improvement Effects 0.000 abstract description 2
- 230000000622 irritating effect Effects 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 230000009967 tasteless effect Effects 0.000 abstract description 2
- 230000036541 health Effects 0.000 description 7
- 108090000623 proteins and genes Proteins 0.000 description 5
- 201000010099 disease Diseases 0.000 description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 4
- 102000004169 proteins and genes Human genes 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 201000011510 cancer Diseases 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 206010019233 Headaches Diseases 0.000 description 2
- 206010028980 Neoplasm Diseases 0.000 description 2
- 208000013738 Sleep Initiation and Maintenance disease Diseases 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 2
- 231100000315 carcinogenic Toxicity 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 231100000869 headache Toxicity 0.000 description 2
- 230000036039 immunity Effects 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 206010022437 insomnia Diseases 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000008520 organization Effects 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 208000024172 Cardiovascular disease Diseases 0.000 description 1
- 206010064571 Gene mutation Diseases 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229960004424 carbon dioxide Drugs 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 208000026106 cerebrovascular disease Diseases 0.000 description 1
- 231100000481 chemical toxicant Toxicity 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000002354 daily effect Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000002526 effect on cardiovascular system Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 210000000987 immune system Anatomy 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 208000001491 myopia Diseases 0.000 description 1
- 230000004379 myopia Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The present invention relates to negative ion paint technical field, the preparation method of a kind of multifunctional ecological negative ion paint, use the raw material of following ratio of weight and number to be prepared from: water-soluble resin 20 ~ 25 parts；PEG type emulsifying agent 5 ~ 10 parts；Nano titanium oxide 3 ~ 5 parts；Zinc oxide 0.05 ~ 0.06 part；Anion powder 5 ~ 15 parts；Deionized water 30 ~ 40 parts；Inserts 10 15 parts.The present invention is compared with prior art, multifunctional ecological negative ion paint can be prepared with simple reaction, reach to purify the purpose of air, effectively eliminated leftovers leftovers acid smell in benzene, formaldehyde, ketone, the irritative gas such as ammonia and the daily life that the art work used during interior decoration evaporates, the harmful abnormal flavour such as medicated cigarette.Human body is kept energetic and to human residential environment improvement to have great help by the present invention.The feature of these series of products be natural, tasteless, nontoxic, security performance is good.
Description
Technical field
The present invention relates to negative ion paint technical field, the preparation of a kind of multifunctional ecological negative ion paint
Method.
Background technology
It is said that in general, normal person needs about 13,000,000,000 anion every day, and our room, office, public place of entertainment etc.
Environment is only capable of furnishing us with hundred million anion oxygen of everyone about 2-20.Steeply rising especially directly to society of PM2.5 environmental pollution
Cause a certain degree of destructive power and negative effect power: magnetic produced by city Computer, mobile phone and other electronic goods
Electrical network makes city cation content constantly increase；Large-scale industrial decoration make the dangerous chemical toxicant of all kinds of band along with
Air sucks human body, thus seriously destroys human immune system, even causes various disease, such as: malignant tumor is occurred frequently,
Cardiovascular and cerebrovascular disease, hematopathy and adolescent myopia；The acidity two that the place of the public gathering of school, family and people is spued
Carbonoxide also makes the positive aeroion content of these occasions aggravate.Numerous medical researches and clinical trial certificate: human body cell
Electronics is by the source that plunder is ten thousand diseases, and active oxygen is a kind of material lacking electronics, fights for electronics everywhere, if taken by force after entering human body
Remove the electronics of cell protein molecule, make protein connect side chain generation alkylation, form the molecule of distortion and carcinogenic.This distortion divides
Son lacks electronics due to oneself, removes to capture the electronics of neighboring molecule again, makes again neighboring molecule also be distorted and carcinogenic.This
Sample, vicious cycle will form the protein molecular of a large amount of distortion.When the protein molecular breeding of these distortion replicates, gene mutation,
Form a large amount of cancerous cell, cancer finally occurs.And when free radical or distortion molecule have grabbed the electronics of gene, people will be direct
Obtain cancer.After human body obtains anion, owing to anion is electronegative, there is unnecessary electronics, it is possible to provide the electronics of Cells Depletion,
Thus blocking vicious cycle, cancerous cell is prevented from or is suppressed.
In the paper that Taiwan Zhongshan University delivers, the relation to negative ion concentration and human health degree has carried out comparison.
Negative ion concentration correspondence human health degree effect table
| Environment space concentration (individual/cm3) | With human health degree |
| Forest waterfall 10000-20000 | Human body has spontaneous recovery power |
| High mountain seashore 5000-10000 | Sterilization, minimizing disease propagation |
| Rural area field 1000-5000 | Increase body immunity, antimicrbial power |
| Urban Parks 400-600 | Maintain health reluctantly |
| Street greening area 200-400 | Reduce body immunity |
| Room, city 100 | Induction physiological barrier headache and insomnia etc. |
| Building office 40-50 | Induction physiological barrier headache and insomnia etc. |
| Industry Development Area 0-1000 | Easily send out disease various |
By upper table it is found that negative ion concentration has a very large relationship with human health degree.World Health Organization (WHO) advises
Fixed: the anion normal concentration of fresh air is to be not lower than 1000～1500 in every cc of air.Due to anion
The famine of oxygen, mankind itself will be unable to resist the serious consequence that air pollution is caused.
Summary of the invention
First technical problem to be solved by this invention be to provide a kind of by simple reaction with regard to getable generation
The negative ion paint of big negative ion concentration.
Second technical problem to be solved by this invention is to provide the preparation method of above-mentioned negative ion paint.
The technical solution adopted in the present invention
The preparation method of a kind of multifunctional ecological negative ion paint, it is characterised in that use the raw material of following ratio of weight and number
It is prepared from:
Water-soluble resin 20～25 parts
PEG type emulsifying agent 5～10 parts
Nano titanium oxide 3～5 parts
Zinc oxide 0.05～0.06 part
Anion powder 5～15 parts
Deionized water 30～40 parts
Inserts 10～15 parts.
Described water-soluble resin is acrylic resin.
Described PEG type emulsifying agent is the one in PEG-1000, PEG-1500.
Described nano titanium oxide is the one in VK-T05, VK-T60.
Described inserts is that Kaolin, titanium dioxide, nano rare earth breeze, ethyl knit dimension element and the mixing of methyl hydroxybenzoate
Thing.
The preparation method of above-mentioned a kind of multifunctional ecological negative ion paint, its preparation process is:
(1) water-soluble resin is poured in deionized water and stir 15 minutes, mixing speed 2000 revs/min；
(2) PEG type emulsifying agent is divided into four batches of equivalent be poured slowly into, 5 minutes, every a collection of interval, the most at the uniform velocity stirring 20 points
Clock, after all pouring into, is stirred for 10 minutes, and mixing speed is 2000 revs/min；
(3) adding nano titanium oxide and zinc oxide, at the uniform velocity stirring 15 minutes, mixing speed is 2000 revs/min；
(4) adding inserts, at the uniform velocity stirring 15 minutes, mixing speed is 2000 revs/min；
(5) take 20% step (4) gained liquid and pour in homogenizer, add anion powder and stir 15 minutes, mixing speed
It it is 4000 revs/min；
(6) being taken out from homogenizer by the liquid of step (5) gained, 80% liquid remaining with step (3) continues stirring 20 points
Clock, mixing speed is 2000 revs/min.
The present invention compared with prior art, can prepare multifunctional ecological negative ion paint with simple reaction, reaches to purify
The purpose of air, effectively eliminated during interior decoration use art work evaporate benzene, formaldehyde, ketone,
Leftovers leftovers acid smell in the irritative gass such as ammonia and daily life, the harmful abnormal flavour such as medicated cigarette.The present invention is to people
Body keeps energetic and to human residential environment improvement to have great help.The feature of these series of products is sky
So, tasteless, nontoxic, security performance is good.
Detailed description of the invention
Further illustrate how the present invention realizes below in conjunction with specific embodiment, but be not limiting as the present invention.
Embodiment 1
20 parts of water-soluble resins are poured in deionized water and stir 15 minutes, mixing speed 2000 revs/min；By 10 parts
PEG-1000 be divided into equivalent four batches are poured slowly into, 5 minutes, every a collection of interval, the most at the uniform velocity stirring 20 minutes, after all pouring into,
It is stirred for 10 minutes, mixing speed 2000 revs/min；Adding VK-T05 and the zinc oxide mix of 5 parts, mixing ratio is 5:1, even
Speed stirring 15 minutes, mixing speed is 2000 revs/min；Add Kaolin, the titanium dioxide of 10 parts, go out nanometer Rare Earth Mine powder, second
Base knits dimension element and the mixture of methyl hydroxybenzoate, and mixing ratio is 10:10:10:5:1, at the uniform velocity stirring 15 minutes, and mixing speed is
2000 revs/min；Take 20% coating modulated to pour into and add 15 parts of anion powder in homogenizer and stir 15 minutes, stirring speed
Spend 4000 revs/min；The coating modulated in homogenizer is taken out the coating continuation refunding dispersion machine and originally modulated
Stirring is in harmonious proportion 20 minutes, and mixing speed is 2000 revs/min.
After testing, above-mentioned raw materials proportioning and technique the multifunctional ecological negative ion paint prepared is after construction from metope 10
Centimeters records every cubic centimetre of anion concentration and reaches 15000, car load window ventilation time, indoor record every cubic centimetre bear from
Sub-content reaches 6000, far above the anion normal concentration standard value of the fresh air that World Health Organization (WHO) specifies.Through relevant
Detection, adds nano titanium oxide and zinc oxide can be by the humid control in air about 45%.
Above said content is only the basic explanation under present inventive concept, and according to appointing that technical scheme is made
What equivalent transformation, all should belong to protection scope of the present invention.
Claims (4)
1. the preparation method of a multifunctional ecological negative ion paint, it is characterised in that use the raw material system of following ratio of weight and number
For forming:
Described inserts is Kaolin, titanium dioxide, nano rare earth breeze, ethyl cellulose and the mixture of methyl hydroxybenzoate；
Preparation process is as follows:
(1) being poured into by water-soluble resin in deionized water and stir 15 minutes, mixing speed is 2000 revs/min；
(2) PEG type emulsifying agent is divided into four batches of equivalent be poured slowly into, 5 minutes, every a collection of interval, the most at the uniform velocity stirring 20 minutes,
After all pouring into, being stirred for 10 minutes, mixing speed is 2000 revs/min；
(3) nano titanium oxide and zinc oxide are added, at the uniform velocity stirring 15 minutes, mixing speed 2000 revs/min；
(4) adding inserts, at the uniform velocity stirring 15 minutes, mixing speed is 2000 revs/min；
(5) taking 20% step (4) gained liquid and pour in homogenizer, add anion powder and stir 15 minutes, mixing speed is
4000 revs/min；
(6) being taken out from homogenizer by the liquid of step (5) gained, 80% liquid remaining with step (4) continues stirring 20 minutes,
Mixing speed is 2000 revs/min.
The preparation method of a kind of multifunctional ecological negative ion paint the most according to claim 1, it is characterised in that:
Described water-soluble resin is acrylic resin.
The preparation method of a kind of multifunctional ecological negative ion paint the most according to claim 1, it is characterised in that:
Described PEG type emulsifying agent is the one in PEG-1000, PEG-1500.
The preparation method of a kind of multifunctional ecological negative ion paint the most according to claim 1, it is characterised in that:
Described nano titanium oxide is the one in VK-T05, VK-T60.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210442969.5A CN102993865B (en) | 2012-11-08 | 2012-11-08 | A kind of preparation method of multifunctional ecological negative ion paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210442969.5A CN102993865B (en) | 2012-11-08 | 2012-11-08 | A kind of preparation method of multifunctional ecological negative ion paint |
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| Publication Number | Publication Date |
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| CN102993865A CN102993865A (en) | 2013-03-27 |
| CN102993865B true CN102993865B (en) | 2016-10-05 |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694815A (en) * | 2013-12-06 | 2014-04-02 | 华阳新兴科技（天津）集团有限公司 | Scrapable formaldehyde closed film and preparation method thereof |
| CN105885643A (en) * | 2016-06-30 | 2016-08-24 | 合肥光聚财建筑装饰工程有限公司 | Water-based paint with functions of adsorbing formaldehyde and degrading formaldehyde |
| CN106752553A (en) * | 2017-03-23 | 2017-05-31 | 宁波百正新材料有限公司 | A kind of multifunctional ecological negative ion paint and preparation method thereof |
| CN107033700A (en) * | 2017-05-27 | 2017-08-11 | 宁波凯杜新材料科技有限公司 | A kind of furniture cleansing composition |
| CN107141917A (en) * | 2017-05-27 | 2017-09-08 | 宁波凯杜新材料科技有限公司 | A kind of automobile-used cleansing composition |
| CN107353738A (en) * | 2017-07-20 | 2017-11-17 | 郑州氧乐环境科技有限公司 | A kind of water oxygen ecologic coating and preparation method thereof |
| CN112502601A (en) * | 2020-10-26 | 2021-03-16 | 山东金冠网具有限公司 | New structure adsorptive window screen |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1386550A (en) * | 2002-07-08 | 2002-12-25 | 中国建筑材料科学研究院水泥科学与新型建筑材料研究所 | Composition tourmaline powder able to effectively generate negative ions in air and its preparing process |
| CN1607231A (en) * | 2003-10-15 | 2005-04-20 | 上海奥顿特种涂料厂 | Paint with sterilization and air-purifying function for internal wall |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101575473A (en) * | 2009-06-30 | 2009-11-11 | 许元铭 | Full effect negative ion furniture paint |
| CN102277043B (en) * | 2011-06-22 | 2013-05-08 | 嘉宝莉化工集团股份有限公司 | Algae-clay air purification coating and preparation method thereof |
-
2012
- 2012-11-08 CN CN201210442969.5A patent/CN102993865B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1386550A (en) * | 2002-07-08 | 2002-12-25 | 中国建筑材料科学研究院水泥科学与新型建筑材料研究所 | Composition tourmaline powder able to effectively generate negative ions in air and its preparing process |
| CN1607231A (en) * | 2003-10-15 | 2005-04-20 | 上海奥顿特种涂料厂 | Paint with sterilization and air-purifying function for internal wall |
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