CN102986726A

CN102986726A - Acidic oxidation potential sterilizing preparation with certain viscosity and preparation method thereof

Info

Publication number: CN102986726A
Application number: CN2012103089198A
Authority: CN
Inventors: 邵鹏飞
Original assignee: Individual
Current assignee: Individual
Priority date: 2011-12-31
Filing date: 2012-08-27
Publication date: 2013-03-27
Also published as: CN102963963A; CN102963964A; CN102659217A; CN102633328A; CN102960365A; CN102659218A; CN102659216A; CN102963962A; CN102616895A

Abstract

The invention provides a preparation method of an acidic oxidation potential sterilizing preparation with certain viscosity, comprising the steps of (1) providing a unit A capable of generating hydrogen ions; (2) providing a unit B containing available chlorine or capable of generating available chlorine; (3) mixing the unit A with the unit B to form a unit C; and (4) adding a substance capable of increasing viscosity or consistence of the solution to at least one step of step (1), step (2) or step (3), so as to obtain an acidic strong-oxidization solution with certain viscosity, wherein the pH value of the acidic strong-oxidization solution is 2-7, the oxidation reduction potential is not lower than 700mV, the content of available chlorine is not lower than 3mg/L, and the viscosity is not lower than 1.1Pa.S. Compared with the prior art, the acidic oxidation potential sterilizing preparation with certain viscosity prepared by the preparation method provided by the invention can improve the adhesive force of a product, thereby being applicable to disinfecting a vertical plane, a spherical plane, a rough surface or a disinfected object with certain inclination angle.

Description

A kind of acid oxidation potential biocide preparation with certain viscosity and preparation method thereof

Technical field

The present invention relates to the sterilizing field, particularly a kind of acid oxidation potential biocide preparation with certain viscosity and preparation method thereof.

Background technology

The concept of introducing redox potential in the sterilization field is to come from the acidic oxidized electric potential water generation machine of Japanese 20th century development and production eighties and the acidic oxidized electric potential water that is produced by the generation machine.Acidic oxidized electric potential water (is called for short: the water of EOW) refer to have high redox potential (ORP), low pH value characteristic and low concentration available chlorine (ACC).

The mechanism of acidic oxidized electric potential water sterilization is as follows:

At first, because the microorganism of the most of kinds of occurring in nature lives in the environment of pH 4-9, and the pH value of acidic oxidized electric potential water can affect electric charge on the microbial biofilm and the absorption of nutriment, the activity of enzyme, and the toxicity of giving property or harmful substance of nutriment in the change environment, thereby reach the purpose of killing microorganisms.

Secondly, because the distributions inside and outside microbial biofilm such as hydrogen ion, potassium ion, sodium ion are different, so that the inside and outside current potential of film has certain potential difference when reaching dynamic equilibrium, generally be about-700～+ 900mV.The biomembrane of aerobic bacterium inside and outside potential difference be generally+200～+ 800mV, and the biomembrane of anaerobic bacteria inside and outside potential difference be generally-700～+ 200mV.The factors such as the oxidation in the acidic oxidized electric potential water, reduction material and pH make its ORP be higher than 1100mV, have exceeded the scope of microorganism.Having high ORP(is ORP〉1100mV) EOW contact microorganism after capture rapidly electronics, disturb the biomembrane balance, change biological transmembrane potential difference, the inside and outside osmotic pressure of film, the destruction that causes the enhancing of biomembrane permeability, cellular swelling and cellular metabolism enzyme, make intracellular organic matter overflow, dissolve, thereby reach the purpose of quick killing microorganisms.

At last, available chlorine can make the permeability of cell change, or biomembrane generation mechanicalness is broken, and impels the cell Dissolve things inside outwards to ooze out, and causes bacterium dead.And hypochlorous acid is neutral small-molecule substance, easily invades in the cell with protein generation oxidation or destroys its phosphate dehydrogenase, makes the glycometabolism imbalance cause bacterium dead, thereby reaches the purpose of killing microorganisms.

The sterilizing ability of EOW system is to take as the leading factor with ACC, and low pH value and high ORP are the synergistic result of three of important promotion.This systematic collaboration effect far above single ACC, low pH value and high ORP effect simply add and, its ACC is higher, the pH value is lower, ORP is higher, the effect that system synthesis is sterilized is just better.

But, the acidic oxidized electric potential water that existing acidic oxidized electric potential water generation machine generates has the easy mobility defective, be difficult to adhere to for vertical plane, sphere, male and fomale(M﹠F) or sterilization objects with certain angle of inclination, so that acidic oxidized electric potential water and pollutant are short time of contact, thereby cause Disinfection Effect poor.And the acidic oxidized electric potential water that existing acidic oxidized electric potential water generation machine generates has the volatile shortcoming of available chlorine, and the sterilization timeliness is unstable in the time of can causing using.

Summary of the invention

The object of the invention is to provide a kind of acid oxidation potential biocide preparation with certain viscosity, the acidic oxidized electric potential water tool easy mobility that generates to solve acidic oxidized electric potential water generation machine of the prior art, be difficult to adhere to for vertical plane, sphere, male and fomale(M﹠F) or sterilization objects with certain angle of inclination, so that acidic oxidized electric potential water and pollutant are short time of contact, thereby cause the poor technical matters of Disinfection Effect.

Another object of the present invention is to provide a kind of preparation method with acid oxidation potential biocide preparation of certain viscosity, the acidic oxidized electric potential water tool easy mobility that generates to solve acidic oxidized electric potential water generation machine of the prior art, be difficult to adhere to for vertical plane, sphere, male and fomale(M﹠F) or sterilization objects with certain angle of inclination, so that acidic oxidized electric potential water and pollutant are short time of contact, thereby cause the poor technical matters of Disinfection Effect.

The object of the invention is achieved through the following technical solutions:

A kind of preparation method with acid oxidation potential biocide preparation of certain viscosity may further comprise the steps:

(1) provides and to produce hydrionic A unit;

(2) provide the B unit that contains available chlorine or can produce available chlorine;

(3) described A unit is mixed formation C unit with described B unit;

(4) at least one step of step (1), step (2) or step (3), adding can increase the material of solution viscosity or consistence, obtain having the acid strong oxidizing property solution of certain viscosity, the pH value of described acid strong oxidizing property solution is between 2-7, its redox potential is not less than 700mV, its available chlorine content is not less than 3mg/L, and its viscosity is not less than 1.1PaS.

Preferably, the described material that can increase solution viscosity or consistence refers to and can dissolve in whole or in part or swelling in solution, the material that solution viscosity or consistence are strengthened.

Preferably, the described material that can increase solution viscosity or consistence is selected from one or more in inorganic thickening agent, cellulose thickener, natural polymer and derivative class thickener thereof, synthetic high polymer class thickener or the solvay-type organo-metallic compound class thickener.

Preferably, described A unit is acid reagent.

Preferably, the available chlorine of described B unit is selected from one or more of double salt, chlorite or available chlorine precursor substance of liquid chlorine, chlorine dioxide, hypochlorite, hypochlorite, and described available chlorine precursor substance refers to can generate with acid or water reaction the chlorine-bearing compound of available chlorine.

A kind of acid oxidation potential biocide preparation with certain viscosity, comprise A unit, B unit and D unit, described D unit can be mixed into the monobasic packing with described A unit or described B unit, separately packing also can be distinguished in described A unit, described B unit and described D unit, wherein, described A unit is for can produce hydrionic preparation, and described B unit is the preparation that contains available chlorine or can produce available chlorine, and described D contains the material that can increase solution viscosity or consistence in the unit.

Preferably, described A unit is acid reagent.

Preferably, after mixing, described A unit, described B unit and described D unit form the acid strong oxidizing property solution with certain viscosity, the pH value of described acid strong oxidizing property solution is between 2-7, its redox potential is not less than 700mV, its available chlorine content is not less than 3mg/L, and its viscosity is not less than 1.1PaS.

A kind of acid oxidation potential biocide preparation with certain viscosity, the pH value of described biocide preparation is between 2-7, and its redox potential is not less than 700mV, and its available chlorine content is not less than 3mg/L, and its viscosity is not less than 1.1PaS.

Preferably, contain one or several of inorganic acid, organic acid, strong acid weak base salt, strong base-weak acid salt, weak acid and weak base salt or strong acid and strong base salt in the described biocide preparation.

Preferably, available chlorine in the described biocide preparation is selected from one or more of double salt, chlorite or available chlorine precursor substance of liquid chlorine, chlorine dioxide, hypochlorite, hypochlorite, and described available chlorine precursor substance refers to can generate with acid or water reaction the chlorine-bearing compound of available chlorine.

Preferably, contain the material that can increase solution viscosity or consistence in the described biocide preparation, the described material that can increase solution viscosity or consistence refers to and can dissolve in whole or in part or swelling in solution, the material that solution viscosity or consistence are strengthened.

Compared with prior art, the present invention has following advantage:

1, the acid oxidation potential biocide preparation with certain viscosity that preparation method of the present invention makes can improve the adhesive force of product, thus the sterilization that is applicable to vertical plane, sphere, male and fomale(M﹠F) or has the sterilization objects at certain angle of inclination;

2, the flowability of the acid oxidation potential biocide preparation with certain viscosity of the present invention a little less than, thereby can sterilize to the appointed area, and do not affect non-designated zone;

3, the preparation method with acid oxidation potential biocide preparation of certain viscosity of the present invention can improve system to the constraint of free chlorine, the issuable harm thereby the free chlorine of reduction is escaped;

4, before use, A unit and B unit with acid oxidation potential biocide preparation of certain viscosity of the present invention deposited separately, in the time will using, A unit and B unit mixed again, solved the storage problem of the acid oxidation potential biocide preparation with certain viscosity, very easy to use;

5, in the process of the preparation acid oxidation potential biocide preparation with certain viscosity of the present invention, strengthen artificial controllability, can regulate according to the actual requirements pH value, available chlorine content and the redox potential of biocide preparation.

Description of drawings

Fig. 1 is the addition that improves thickener and the enhancing system schematic diagram that concerns at the thickening effect of non-best pH environment;

Fig. 2 produces the schematic diagram of the time of onset concentration available chlorine for addition and the shortening system that improves solid available chlorine;

Fig. 3 produces the schematic diagram of onset hydrionic time of concentration for addition and the shortening system that improves the solid acid thing.

Fig. 4 produces the schematic diagram of the time of minimum onset viscosity for addition and the shortening system that improves the solid thickener.

The schematic diagram of the relation of viscosity and bactericidal effect when Fig. 5 is the vertical plane sterilization.

Fig. 6 is that viscosity is on the schematic diagram that concerns of ORP impact.

Embodiment

Describe the present invention below in conjunction with drawings and Examples.

The bactericidal effect of bactericide depends on the sufficiently long time of sterilization factors effect of sufficient intensity, the range of viscosities of common rare electrolyte solution is between 0.001-0.01PaS, be not enough to resist the impact of gravity, be not enough to adhere to the sterilization factors of sufficient intensity on vertical plane, sphere, male and fomale(M﹠F) or inclined plane and act on the sufficiently long time.The present invention discusses the intensity of sterilization factors and the collaborative impact on the vertical plane bactericidal action of adhesion effect of the acid oxidation potential sterilized water under gravity effect, and the sufficiently long time of sterilization factors effect that whether reaches q.s by relatively weighing of bactericidal effect.Be the pH/ACC/ORP(sterilization factors of acid oxidation potential sterilized water) with effective combination of viscosity (adhesion amount with adhere to the time).

Preparation method with acid oxidation potential biocide preparation of certain viscosity of the present invention may further comprise the steps:

(1) provides and to produce hydrionic A unit;

(3) the A unit is mixed formation C unit with the B unit;

(4) at least one step of step (1), step (2) or step (3), adding can increase the material of solution viscosity or consistence, obtain having the acid strong oxidizing property solution of certain viscosity, the pH value of acid strong oxidizing property solution is between 2-7, its redox potential is not less than 700mV, its available chlorine content is not less than 3mg/L, and its viscosity is not less than 1.1PaS.Wherein, the material that can increase solution viscosity or consistence refers to and can dissolve in whole or in part or swelling in solution, the material that solution viscosity or consistence are strengthened.

The pH value of A unit is preferably between 0-6, is preferably again between 0-5, is preferably between 0-4 again, also is preferably between 0-3, most preferably is between 2-3.

The A unit can be selected from the precursor of inorganic acid, organic acid, strong acid weak base salt or acidic materials.Inorganic acid can be selected from hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, chloric acid, perchloric acid, bromic acid, hyperbromic acid, metaperiodic acid, metaphosphoric acid, permanganic acid, hydrogen borate, the acid of hydrogen astatine, hydrogen telluric acid, the folded acid iodide of hydrogen, fluosilicic acid, chlorine plumbic acid, osmic acid, selenic acid, ferric acid, fluosulfonic acid, cyanic acid, thiocyanic acid, phosphoric acid, niter cake, sulfurous acid or nitrous acid.Organic acid is optional from picric acid, Jiao's property picric acid, trifluoroacetic acid, trichloroacetic acid, acetic acid, formic acid, methanesulfonic acid, benzene sulfonic acid, KMD acid, 2-chloroethene mercaptan, ethanedioic acid, malonic acid, succinic acid, lactic acid, pyruvic acid, tartaric acid, malic acid, citric acid, benzoic acid, salicylic acid or caffeic acid.Common strong acid weak base salt is generally the strong acid salt of transition metal or the strong acid salt of amine substance, such as aluminium chloride, iron chloride, aluminum sulfate, iron sulfate, copper nitrate or ammonium chloride.The precursor of acidic materials refers to can be converted into the material of acidic materials in solution, such as the chloride derivative of acid, such as succinyl chloride.

The B unit can be selected from one or more of double salt, chlorite or available chlorine precursor substance of liquid chlorine, chlorine dioxide, hypochlorite, hypochlorite.Hypochlorite can be selected from one or more of clorox, calcium hypochlorite, bleaching powder, bleaching powder extraction, magnesium hypochlorite.The double salt of hypochlorite can be selected from Efficacious Disinfeitant (Na ₃PO ₄1/4NaOCl12H ₂O).Chlorite can be selected from sodium chlorite, calcium chlorite.The available chlorine precursor substance refers to can generate with acid or water reaction the chlorine-bearing compound of activated state available chlorine, and its stability in the B unit is higher than in the mixed liquor of A, B unit, and the available chlorine precursor substance can be selected from one or more of sodium dichloro cyanurate, dichlord isocyanurice acid, sym-closene, toluene-sodium-sulfonchloramide, chlorate, perchlorate.

The content of available chlorine should guarantee that the available chlorine content in A, the B unit mixed liquor is not less than 3mg/L in the B unit, wherein, available chlorine content in the mixed liquor is preferably 3-5000mg/L, be preferably again 30-4000mg/L, be preferably again 30-3000mg/L, more preferably 30-1000mg/L most preferably is 30-500mg/L.

The pH of B unit is neutral or alkaline, wherein, is preferably pH and is not less than 8, is preferably pH again and is not less than 9, also is preferably pH and is not less than 10, and more preferably pH is not less than 11, is preferably again pH and is not less than 12, most preferably is pH and is not less than 13.

The contained alkaline matter in B unit can be one or several of highly basic, middle highly basic, weak base or strong base-weak acid salt.The contained alkaline matter in B unit can be selected from alkali-metal hydroxide, such as sodium hydroxide, potassium hydroxide etc.; Also can be selected from the hydroxide of alkaline earth metal, such as slaked lime, barium hydroxide, magnesium hydroxide etc.; Also can be selected from the hydroxide of transition metal, such as zinc hydroxide, iron hydroxide etc.; Also can be selected from nitrogen substance, such as ammoniacal liquor, diethanol amine, triethylamine etc.; Also optional from the highly basic salt of weak acid, such as sodium carbonate, sodium acetate, sodium phosphate, sodium citrate etc.

The material that can increase solution viscosity or consistence is one or more in inorganic thickening agent, cellulose thickener, natural polymer and derivative class thickener thereof, synthetic high polymer class thickener or the solvay-type organo-metallic compound class thickener.

The mineral-type thickener can be selected imvite, bentonite, hectorite, attapulgite or the kaolin etc. take silicate as main component, and derivative, such as stearic ammonium imvite, quaternary ammonium salt-90 imvite, quaternary ammonium salt-18 imvite, sodium bentonite, calcium-base bentonite, magnesium base bentonite, hydrogen base bentonite, organobentonite, aluminium-magnesium silicate, lithium magnesium silicate, sodium magnesium silicate, lithium metasilicate magnesium sodium, stearic ammonium hectorite, quaternary ammonium salt-18 hectorite etc.

The cellulose ethers thickener can be selected from methylcellulose, ethyl cellulose, benzyl cellulose, benzylcellulose, cyanethyl cellulose, benzyl cyanide ethyl cellulose, spermaceti hydroxyethylcellulose, hydroxyethylcellulose, hydroxypropyl cellulose, methyl hydroxyethylcellulose, ethylhydroxyethylcellulose, methylhydroxypropylcellulose, sodium carboxymethylcellulose or carboxymethyl hydroxyethyl cellulose.

Natural polymer and derivative thickener thereof can be selected from starch, hydroxypropyl starch ether, pectin, agar, gelatin, alginic acid and alginate, carragheen, dextrin, bassora gum, xanthan gum, guar gum, cation guar gum, hydroxypropyl guar gum, gum Arabic, soybean protein glue, locust bean gum, trigonella bean gum, Artemisia Glue, the Chinese honey locust carbohydrate gum, tamarind seed polysaccharide glue, Sunset Abelmoschus Root glue, flaxseed gum, sesbania gum, konjac glucomannan, Chinese yam glue, lanolin, chitosan, sclerotium gum or casein.

Synthetic high polymer class thickener is optional from polyacrylamide, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol oxide, carbomer, polyacrylic acid, Sodium Polyacrylate, Polyacrylate Emulsion, polyurethane, modification polyureas, low-molecular polyethylene wax, polyquaternium or polyethylene glycol.

Solvay-type organo-metallic compound class thickener comprises amino alcohol solvay-type titanate esters.

Can increase the material of solution viscosity or consistence, should guarantee that the viscosity that A, B unit mixed liquor produce is not less than 1.1PaS, wherein, be preferably viscosity and be not less than 2, be preferably viscosity at 5-10000PaS again, also be preferably viscosity at 10-5000PaS, more preferably viscosity is at 15-2000PaS, be preferably again viscosity at 20-1000PaS, most preferably be viscosity at 25-500PaS.Its addition is preferably the 0.01%-50% into the quality sum of A unit and B unit, more preferably 1-15%.

Increase the material of viscosity, can make the A unit of specific acid have particular viscosity.

The thickener of common amount of calculation, heating or normal temperature are dissolved in the water liquid of amount of calculation, are configured to the solution of particular viscosity, transfer to specific acidity again, make the A unit of particular viscosity and specific acidity; Perhaps the thickener of amount of calculation heating or normal temperature are dissolved in the solution of specific acidity of amount of calculation, make the A unit of particular viscosity and specific acidity.

When can in water, dissolving fast under the thickener normal temperature or during swelling, can adopt the solid thickener of amount of calculation and amount of calculation can to produce acid solid matter hybrid packed, composition can produce particular viscosity and acid A unit.

Increase the material of viscosity, can make the B unit that contains specific available chlorine have particular viscosity.

The thickener of common amount of calculation, heating or normal temperature are dissolved in the water liquid of amount of calculation, are configured to the solution of particular viscosity, add quantitative available chlorine and alkaline matter again, make the B unit of particular viscosity and specific effective chlorine density; Perhaps the thickener normal temperature of amount of calculation is dissolved in the solution of specific available chlorine of amount of calculation, makes the B unit of particular viscosity and specific effective chlorine density.

When can in water, dissolving fast under the thickener normal temperature or during swelling, can adopt the solid matter that can discharge available chlorine of the solid thickener of amount of calculation and amount of calculation hybrid packed, composition can produce the B unit of particular viscosity and available chlorine.

Increase the material of viscosity, in water, can be partly dissolved under the normal temperature or during swelling, independent packing that also can amount of calculation adds in the mixed liquor of A, B unit during use, makes the acid oxidation potential solution of particular viscosity and specific effective chlorine density and specific acidity; Perhaps the solid thickener of amount of calculation is hybrid packed with the solid matter that produces acid solid matter and release available chlorine, is dissolved in during use in the gauge water, makes the acid oxidation potential solution of particular viscosity and specific effective chlorine density and specific acidity.

Nonionic thickener is such as nonionic cellulose thickener, nonionic natural polymer, nonionic synthesising macromolecule copolymer, because the unionized characteristic has good resistance to acids and bases and salt resistance usually.The mineral-type thickener if you would take off stone, hectorite etc., and working range is at pH2-13, to the salt amount without significant discomfort.Therefore, this method preferentially adopts above-mentioned thickener.

In mixed system, there is different chemical particle, such as the acid ion of A unit introducing, the cation that the B unit is introduced, cation or the anion that thickener may be introduced.Unexpected side reaction may occur between the above-mentioned particle.

The first kind, the cation that the acid ion that the A unit is introduced and the available chlorine of B unit or alkaline conditioner or thickener are introduced produces precipitation, as sulfate ion and calcium ion (as, slaked lime, calcium hypochlorite, calcium-base bentonite) precipitation, this type of side reaction neither can affect the pH/ACC/ORP of mixed system, also can not affect the viscosity of system, only make to have insoluble granule in the system.

Equations of The Second Kind generates insoluble hypochlorite or more weak acid after system is mixed, and selects the lithium magnesium silicate thickener such as clorox, produces poorly soluble magnesium hypochlorite.Perhaps highly acid A unit runs into the strong base-weak acid salt of B unit or the carboxylate groups in the thickener structure, produces weak acid.Usually can increase to amount of calculation the addition of acid or available chlorine, to guarantee that acid or available chlorine are in the scope of effective dose.

The 3rd class, some ionic or have carboxyl or amino thickener can have intolerance to soda acid in the system.It should be understood that described intolerance is not the degraded of material, and refer to that the Morphological Transitions (molecule-type-ionic) of special groups in acid or alkali environment in the thickener changes viscosity, i.e. so-called viscosity reduction effect.As, carbomer has low viscosity in molecular state, has high viscosity in ionic condition, can adjust the structural form of carbomer by soda acid, as shown in Figure 1.Therefore, use this type of thickener, suitably increase the amount of thickener, perhaps preferentially prepare the nearly neutrality of pH5-7/ACC3-500mg/L, the acid oxidation potential biocide preparation of less salt amount, perhaps change the other types thickener.Known thickener has good thickening effect near neutrality at present.

The 4th class, some ionic thickening material can have intolerance to the salt in the system.As reduce viscosity or generate insoluble matter since system viscosity value can bring into play in very low scope effect should be arranged, therefore suitably increase amount or the salt content in the reduction system of thickening material or change the kind of thickening material, usually can solve.

Because form and the dissolubility difference of A, B unit and thickener, mixed system may produce certain proterties difference.

The acid A unit of solution state mixes with the available chlorine B unit of solution state, and is even in order to be conducive to rapid mixing, guaranteeing under the stable prerequisite, and the preferential and large volume unit of thickener is made into the independent packing of certain viscosity in advance.

The available chlorine B unit of solid state mixes with the acid A unit with certain viscosity of solution state, and the form with powder adds usually, and stirs, and makes powder particle evenly be suspended in the A unit, can use through swelling, the decomposition of certain hour.The uniformity of its particle is higher, particle diameter is less, more be conducive to the even and release of available chlorine in the system, the content that suitably increases available chlorine is enough with the content of the active available chlorine that guarantees to produce in the short time, as shown in Figure 2, system more is conducive to the release of available chlorine from solid when rare viscosity of 1.1-30PaS.

Same, the solid acid unit mixes with the available chlorine B unit with certain viscosity of solution state, and the form with powder adds usually, and stirs, and when mixed system becomes acidity, can use.The uniformity of its particle is higher, particle diameter is less, more be conducive to hydrionic release, utilization, uniformity in the system, the addition that can suitably increase acid simultaneously transfers the acid time to shorten mixed system, as shown in Figure 3, system more is conducive to the release of hydrogen ion from solid when rare viscosity of 1.1-30PaS.

The material of some thickening power (particularly under normal temperature) in the aqueous solution can not dissolve or swelling fully, makes to have block insoluble matter in the system.Such as polyethylene glycol, the PEG300 of low polymerization degree～400 are transparency liquid, can mix arbitrarily with water, and can dissolve many water-soluble inorganic salts and water-insoluble organic matter, and along with the rising of the degree of polymerization, PEG solvability in water descends.Starch and for example, the solvability that is degraded to the starch of small-molecular weight is higher than undegradable starch.Same as long as guaranteeing to dissolve partly to make the viscosity number of system be not less than 1.1PaS, just can guarantee bactericidal effect.Therefore, this type of situation, no matter be to appear at A unit or B unit or AB mixed cell, the amount that suitably increases thickener guarantees that the part of swelling in the short time produces enough viscosity, as shown in Figure 4, perhaps changes the kind of thickening material, usually can solve.

Because the powerful killing microorganisms ability of acid oxidation potential bactericide, therefore the adhesive ability for system requires not high, the viscosity produce an effect that is not less than 1.1PaS is enough, even so non-optimum state, the acid or alkali environment of preserving such as packing is not suitable for or mixes rear acid or alkali environment being not suitable for or having insoluble substance or available chlorine to discharge fully, as long as system viscosity is not less than 1.1PaS after mixing, available chlorine content is not less than 3mg/L, the pH value is between 2-7, redox potential is not less than 700mV, it can bring into play enough effects, as shown in Figure 5.

In the present invention, one group of index ORP/pH/ACC is decomposed into two groups of index: A group index control pH values, B group index control ACC, A group unit guarantees the pH value, B group unit guarantees ACC, produces stable pH/ORP/ACC after AB merges.

In the present invention, viscosity by control A unit and B unit mixed liquor, increased the adhesion amount of mixed liquor on pollutant of A, B unit, and A, the mixed liquor of B unit and the time of contact of pollutant have been prolonged, reduce simultaneously the mixed liquor active available chlorine escape that forms and the speed of decomposing of A, B unit, as shown in Figure 6, thus improve bactericidal property, prolong the sterilization timeliness.

Trace chlorine on the one hand as previously mentioned, has strengthened oxidisability for the effect major embodiment of acidic oxidized electric potential water both ways.On the other hand, micro-chlorine soluble in water as hypochlorous donor, along with hypochlorous degraded, continues to be converted into hypochlorous acid, replenishes it and reduces the oxidation timeliness that has prolonged acidic oxidized electric potential water.

Among the present invention, a kind of acid oxidation potential biocide preparation with certain viscosity also is provided, comprise A unit, B unit and D unit, the D unit can be mixed into the monobasic packing with A unit or B unit, separately packing also can be distinguished in described A unit, B unit and D unit, and wherein, the A unit is for can produce hydrionic preparation, the B unit is the preparation that contains available chlorine or can produce available chlorine, and D contains the unit material that can increase solution viscosity or consistence.Wherein, the material that can increase solution viscosity or consistence refers to and can dissolve in whole or in part or swelling in solution, the material that solution viscosity or consistence are strengthened.

The B unit be for can discharging one or several materials of available chlorine under certain condition, and the B unit is selected from one or more of double salt, chlorite or available chlorine precursor substance of liquid chlorine, chlorine dioxide, hypochlorite, hypochlorite.Hypochlorite is selected from one or more of clorox, calcium hypochlorite, bleaching powder, bleaching powder extraction, magnesium hypochlorite, and the double salt of hypochlorite can be Efficacious Disinfeitant (Na ₃PO ₄1/4NaOCl12H ₂O), chlorite can be selected from sodium chlorite, calcium chlorite, this available chlorine precursor substance be for can generating the material of activated state available chlorine with the reaction of acid or water, and the available chlorine precursor substance is selected from one or more of sodium dichloro cyanurate, dichlord isocyanurice acid, sym-closene, toluene-sodium-sulfonchloramide, chlorate, perchlorate.The available chlorine of B unit is the stable form of available chlorine.The available chlorine stable form refers to have better stability in the B unit, can generate activated state available chlorine with acid or water reaction.Available chlorine content should guarantee that the available chlorine content in A, the B unit mixed liquor is not less than 3mg/L in the B unit.

The pH of B unit is alkalescence, wherein, is preferably pH and is not less than 8, is preferably pH again and is not less than 9, also is preferably pH and is not less than 10, is preferably again pH and is not less than 11, and more preferably pH is not less than 12, most preferably is pH and is not less than 13.

The contained alkaline matter in B unit can be one or several of highly basic, middle highly basic, weak base or strong base-weak acid salt.The contained alkaline matter in B unit can be selected from alkali-metal hydroxide, such as sodium hydroxide, potassium hydroxide etc., also can be selected from the hydroxide of alkaline earth metal, such as slaked lime, barium hydroxide, magnesium hydroxide etc., also can be selected from the hydroxide of transition metal, such as zinc hydroxide, iron hydroxide etc., also can be selected from nitrogen substance, such as ammoniacal liquor, diethanol amine, triethylamine etc., also optional from the highly basic salt of weak acid, such as sodium carbonate, sodium acetate, sodium phosphate, sodium citrate etc.

The mineral-type thickener can be selected imvite, bentonite, hectorite, attapulgite, kaolin take silicate as main component etc., and derivative, such as stearic ammonium imvite, quaternary ammonium salt-90 imvite, quaternary ammonium salt-18 imvite, sodium bentonite, calcium-base bentonite, magnesium base bentonite, hydrogen base bentonite, organobentonite, aluminium-magnesium silicate, lithium magnesium silicate, sodium magnesium silicate, lithium metasilicate magnesium sodium, stearic ammonium hectorite, quaternary ammonium salt-18 hectorite etc.

The A unit can produce acidity, after the B unit mixes, guarantees that mixed liquor is the acidity of pH value between pH2-7.The quality of capable of regulating A, B unit or volume and soda acid scope and inherent component prepare the acid oxidation potential bactericide of different available chlorine contents.The A unit is with after the B unit mixes, and mixed liquor generates the strong oxidizing property material, produces high redox potential (ORP 〉=700mV).The B unit is the reagent that can discharge available chlorine, after the A unit mixes, and available chlorine content 〉=3mg/L that mixed liquor produces.Available chlorine content scope with acid oxidation potential biocide preparation of certain viscosity of the present invention can be regulated by the amount that adds the B unit, and domestic consumer uses and can be 30-100mg/L.The viscosity that A, B unit mixed liquor produce is not less than 1.1PaS, wherein, is preferably viscosity and is not less than 2, be preferably viscosity again and be not less than 5, also be preferably viscosity and be not less than 10, more preferably viscosity is not less than 15, be preferably again viscosity and be not less than 20, most preferably be viscosity and be not less than 25.

Among the present invention, also provide a kind of acid oxidation potential biocide preparation with certain viscosity, the pH value of biocide preparation is between 2-7, and its redox potential is not less than 700mV, and its available chlorine content is not less than 3mg/L, and its viscosity is not less than 1.1PaS.

Contain one or several of inorganic acid, organic acid, strong acid weak base salt, strong base-weak acid salt, weak acid and weak base salt or strong acid and strong base salt in the biocide preparation.

Available chlorine in the biocide preparation is selected from one or more of double salt, chlorite or available chlorine precursor substance of liquid chlorine, chlorine dioxide, hypochlorite, hypochlorite, and the available chlorine precursor substance refers to can generate with acid or water reaction the chlorine-bearing compound of available chlorine.

Contain the material that can increase solution viscosity or consistence in the biocide preparation, the material that can increase solution viscosity or consistence refers to and can dissolve in whole or in part or swelling in solution, the material that solution viscosity or consistence are strengthened.

The EOW that the similar electrolysis of acid oxidation potential biocide preparation with certain viscosity of the present invention generates, have high redox potential (〉=700mV), between low pH(pH2-7), low concentration various ways available chlorine (〉=3mg/l), have powerful killing microorganisms effect.

Acid oxidation potential biocide preparation with certain viscosity of the present invention can improve the adhesive force of product, thus the sterilization that is applicable to vertical plane, sphere, male and fomale(M﹠F) or has the sterilization objects at certain angle of inclination; And flowability a little less than, thereby can sterilize to the appointed area, and do not affect non-designated zone.Preparation method with acid oxidation potential biocide preparation of certain viscosity of the present invention can also improve system to the constraint of free chlorine, the issuable harm thereby the free chlorine of reduction is escaped.

Before use, A unit and the B unit with acid oxidation potential biocide preparation of certain viscosity of the present invention deposited separately, in the time will using, A unit and B unit mixed again, and solved the storage problem of acid oxidation potential sterilized water, and be very easy to use.And, in the process of the preparation acid oxidation potential biocide preparation with certain viscosity of the present invention, strengthened artificial controllability, can regulate according to the actual requirements pH value, available chlorine content and the redox potential of sterilized water.

Embodiment 1: configuration 10L highly acid oxidizing potential biocide preparation (available chlorine content is 3mg/L)

Raw material A: get 18 parts of aqueous hydrochloric acid solutions (pH2-3), add respectively thickener D _X, stir swelling, measure respectively 9.99L, can, sealing gets the A1-A18 unit.

D wherein _XTake from respectively following raw material: D1 imvite, the stearic ammonium imvite of D2, D3 quaternary ammonium salt-90 imvite, D4 quaternary ammonium salt-18 imvite, D5 bentonite, D6 sodium bentonite, D7 calcium-base bentonite, D8 magnesium base bentonite, D9 hydrogen base bentonite, D10 organobentonite, D11 aluminium-magnesium silicate, D12 lithium magnesium silicate, D13 sodium magnesium silicate, D14 lithium metasilicate magnesium sodium, the stearic ammonium hectorite of D15, D16 quaternary ammonium salt-18 hectorite, D17 attapulgite, D18 kaolin.

Raw material B: liquor natrii hypochloritis (available chlorine 3mg/ml, pH=11-12), measure 10ml, can, sealing gets B unit (available chlorine 30mg), prepares altogether 18 parts of B unit.

During use, each mixes the 10L acid oxidation potential biocide preparation 1-18(pH2-3 of system, ORP1050-1150mV, ACC3mg/L, viscosity 1.1-2PaS the A1-A18 unit with a B unit), thickener D _XQuality be A, B unit the quality sum 0.01%.

Embodiment 2: configuration 10L faintly acid oxidizing potential biocide preparation (available chlorine content is 50mg/L)

Raw material A: get 18 parts of aqueous solution of nitric acid (pH2-3), add respectively thickener D _X, stir swelling, measure respectively 9.9L, can, sealing gets the A1-A18 unit.

Raw material B: liquor natrii hypochloritis (available chlorine 5mg/ml, pH=13-13.5), measure 100ml, can, sealing gets B unit (available chlorine 500mg), prepares altogether 18 parts of B unit.

During use, each mixes the 10L acid oxidation potential biocide preparation 1-18(pH3-5 of system, ORP1000-1100mV, ACC50mg/L, viscosity 50-100PaS the A1-A18 unit with a B unit), thickener D _XQuality be A, B unit the quality sum 5%.

Embodiment 3: configuration 10L subacidity oxidizing potential biocide preparation (available chlorine content is 5000mg/L)

Raw material A: get 18 parts of aqueous sulfuric acids (pH=1-1.5), add respectively thickener D _X, stir swelling, measure 9.9L, can, sealing gets the A1-A18 unit.

Raw material B: calcium hypochlorite solution (available chlorine 500mg/ml, pH=12-13), measure 100ml, can, sealing gets B unit (available chlorine 50000mg), prepares altogether 18 parts of B unit.

During use, each mixes the 10L subacidity oxidizing potential biocide preparation 1-18(pH5-7 of system, ORP1000-1300mV, ACC5000mg/L, viscosity 100-500PaS the A1-A18 unit with a B unit), thickener D _XQuality be A, B unit the quality sum 15%.Because calcium hypochlorite is poorly soluble, so there is insoluble matter to suspend in the system, still do not affect the characteristic of its tack and available chlorine, pH, ORP.

Embodiment 4: configuration 10L subacidity oxidizing potential biocide preparation (available chlorine content is 4000mg/L)

Raw material A: get 14 parts of hydriodic acid aqueous solutions (pH=1-1.5), add respectively thickener D _X, stir swelling, measure respectively 9.9L, can, sealing gets the A1-A14 unit.

D wherein _XTake from respectively following raw material: D1 methylcellulose, D2 ethyl cellulose, D3 benzyl cellulose, D4 benzylcellulose, D5 cyanethyl cellulose, D6 benzyl cyanide ethyl cellulose, D7 hydroxyethylcellulose, D8 hydroxypropyl cellulose, D9 methyl hydroxyethylcellulose, D10 ethylhydroxyethylcellulose, D11 spermaceti hydroxyethylcellulose, D12 methylhydroxypropylcellulose, D13 sodium carboxymethylcellulose, D14 carboxymethyl hydroxyethyl cellulose.

Raw material B: calcium hypochlorite solution (available chlorine 400mg/ml, pH=12-13), measure 100ml, can, sealing gets B unit (available chlorine 40000mg), prepares altogether 14 parts of B unit.

During use, each mixes the 10L subacidity oxidizing potential biocide preparation 1-14(pH5-7 of system, ORP1000-1300mV, ACC4000mg/L, viscosity 20-80PaS the A1-A14 unit with a B unit), thickener D _XQuality be A, B unit the quality sum 5%.

Embodiment 5: configuration 10L highly acid oxidizing potential biocide preparation (available chlorine content is 150mg/L)

Raw material A: get 28 parts of aqueous citric acid solutions (pH=2-2.5), add respectively thickener D _X, stir swelling, measure 9.9L, can, sealing gets the A1-A28 unit.

D wherein _XTake from respectively following raw material: D1 starch, the D2 hydroxypropyl starch ether, D3 pectin, D4 agar, the D5 gelatin, the D6 algin, the D7 sodium alginate, the D8 carragheen, the D9 dextrin, the D10 bassora gum, the D11 xanthan gum, the D12 guar gum, the D13 cation guar gum, the D14 hydroxypropyl guar gum, the D15 gum Arabic, D16 soybean protein glue, the D17 locust bean gum, the D18 trigonella bean gum, the D19 Artemisia Glue, D20 Chinese honey locust carbohydrate gum, D21 tamarind seed polysaccharide glue, D22 Sunset Abelmoschus Root glue, the D23 flaxseed gum, the D24 sesbania gum, D25 lanolin, the D26 chitosan, the D27 sclerotium gum, the D28 casein.

Raw material B: liquor natrii hypochloritis (available chlorine 15mg/ml, pH=11-12), measure 100ml, can, sealing gets B unit (available chlorine 1500mg), prepares altogether 28 parts of B unit.

During use, the A1-A28 unit mixes with the B unit respectively, the 10L highly acid oxidizing potential biocide preparation 1-28(pH2-3 of system, ORP1150-1250mV, ACC150mg/L, viscosity 35-100PaS), thickener D _XQuality be A, B unit the quality sum 5%.

Embodiment 6: configuration 10L subacidity oxidizing potential biocide preparation (available chlorine content is 3000mg/L)

Raw material A: get 15 parts of acetic acid aqueous solutions (pH=1-1.5), add respectively 5% thickener D _X, stir swelling, measure respectively 9.9L, can, sealing gets the A1-A15 unit.

D wherein _XTake from respectively following raw material: D1 PAMA (Mr100 ten thousand-5,000,000), D2 PAMC (Mr200 ten thousand-5,000,000), D3 non-ionic polyacrylamide (Mr500 ten thousand-8,000,000), D4 polyvinyl alcohol (Mr16000-20000), D5 polyvinylpyrrolidone (Mr40000-50000), D6 polyethylene glycol oxide (Mr50 ten thousand-800,000), D7 carbomer (C-940), D8 polyacrylic acid (Mr＜10000), the D9 Sodium Polyacrylate (Mr〉2,000,000), D10 acrylate/cetyl ethyoxyl (20) methacrylate copolymer, D11 polyurethane (RM-8W), D12 modification polyureas, D13 polyquaternium (Polyquaternium-10), D14 polyethylene glycol (Mr1000-8000), D15 amino alcohol solvay-type titanate esters.

Raw material B: calcium hypochlorite solution (available chlorine 300mg/ml, pH=12-13), measure 100ml, can, sealing gets B unit (available chlorine 30000mg), prepares altogether 15 parts of B unit.

During use, the A1-A15 unit mixes with the B unit respectively, the 10L subacidity oxidizing potential biocide preparation 1-15(pH5-7 of system, ORP1000-1300mV, ACC3000mg/L, viscosity 15-150PaS), thickener D _XQuality be A, B unit the quality sum 5%.

Embodiment 7: configuration 10L acid oxidation potential biocide preparation (available chlorine content is 2000mg/L)

Raw material A: liquor alumini chloridi (pH=1-2), add hydroxyethylcellulose, stir swelling, measure 9.5L, can, sealing gets the A unit.

Raw material B: liquor natrii hypochloritis (available chlorine 40mg/ml, pH=13.1), take by weighing 500ml, packing gets B unit (available chlorine 20g).

During use, A unit and B unit mix, the 10L acid oxidation potential biocide preparation (pH2-3, ORP1200-1400mV, ACC2000mg/L, viscosity 46PaS) of system, the quality of hydroxyethylcellulose be A, B unit the quality sum 1%.

Embodiment 8: configuration 10L acid oxidation potential biocide preparation (available chlorine content is 30-200mg/L)

Raw material A: hydrochloric acid solution (pH=2-2.5), measure 9.8L, can, sealing gets the A unit.

Raw material B: By Solution of Stabilized Chlorine Dioxide (available chlorine 10mg/ml, pH=11-12), add lithium magnesium silicate, stir swelling, take by weighing 200ml, packing gets B unit (available chlorine 2000mg).

During use, A unit and B unit mix, the 10L acid oxidation potential biocide preparation (pH2-3, ORP1100-1200mV, ACC30-200mg/L, viscosity 55PaS) of system, the quality of lithium magnesium silicate be A, B unit the quality sum 3%.

Because the available chlorine Partial Conversion is the magnesium hypochlorite of poor activity, increase the loss that excessive available chlorine can remedy available chlorine.

Embodiment 9: configuration 10L highly acid oxidizing potential biocide preparation (available chlorine 30-100mg/L)

Raw material A: aqueous sulfuric acid (pH2-3), add algin, stir swelling, measure 10L, can, sealing gets the A unit.

Raw material B: solid type chlorine dioxide powder (available chlorine 0.2g/g), take by weighing 5g, packing gets B unit (the about 1000mg of available chlorine).

During use, the A unit mixes with the B unit, stir to make it even, the 10L highly acid oxidizing potential biocide preparation (pH2-3, ORP1100-1200mV, ACC30-100mg/L, viscosity 1.1PaS) of system, the quality of algin be A, B unit the quality sum 0.01%.

When the available chlorine in the system does not dissolve fully, can only partly discharge Active Chlorine, release portion not can be used as slowly-releasing available chlorine, prolongs the sterilization timeliness.

Embodiment 10: configuration 10L faintly acid oxidizing potential biocide preparation (available chlorine 30-500mg/L)

Raw material A: ferric chloride in aqueous solution (pH3-5), add lithium magnesium silicate, stir swelling, measure 10L, can, sealing gets the A unit.

Raw material B: sym-closene superfine powder (available chlorine 0.2g/g), take by weighing 25g, packing gets B unit (the about 5000mg of available chlorine).

During use, the A unit mixes with the B unit, stir to make it even, the 10L faintly acid oxidizing potential biocide preparation (pH3-5, ORP1000-1150mV, ACC30-500mg/L, viscosity 15PaS) of system, the quality of lithium magnesium silicate be A, B unit the quality sum 2%.

Embodiment 11: configuration 10L subacidity oxidizing potential biocide preparation (available chlorine 30-1000mg/L)

Raw material A: the succinic acid aqueous solution (pH5-7), add the card ripple, stir swelling, measure 10L, can, sealing gets the A unit.

Raw material B: sodium trichloro-isocyanurate fine powder (available chlorine 0.2g/g), claim 50g, packing gets B unit (the about 10000mg of available chlorine).

During use, the A unit mixes with the B unit, stir to make it even, the 10L subacidity oxidizing potential biocide preparation (pH3-7, ORP800-1300mV, ACC30-1000mg/L, viscosity 30PaS) of system, the quality of card ripple be A, B unit the quality sum 0.1%.

Embodiment 12: configuration 10L highly acid oxidizing potential biocide preparation (available chlorine 30-100mg/L)

Raw material A: aqueous hydrochloric acid solution (pH2-3), measure 10L, can, sealing gets the A unit.

Raw material B: sodium dichloro cyanurate powder (available chlorine 0.2g/g), take by weighing 5g, add the solid algin, hybrid packed, get B unit (the about 1000mg of available chlorine).

When the available chlorine in the system and thickener do not dissolve fully, can only partly discharge Active Chlorine and display part viscosity, release portion not can be used as slowly-releasing available chlorine, prolongs the sterilization timeliness.

Embodiment 13: configuration 1L acid oxidation potential biocide preparation (available chlorine content is 30mg/L)

Raw material A: the malonic acid powder, take by weighing 1mol, packing, sealing gets the A unit.

Raw material B: liquor natrii hypochloritis (pH=10-11), add bentonite, stir swelling, measure 1L(available chlorine 30mg), can, sealing gets B unit (available chlorine 30mg).

During use, the A unit mixes with the B unit, stirs, become acidity to system, make 1L acid oxidation potential biocide preparation (pH2-7, ORP800-1200mV, ACC30mg/L, viscosity 1.5PaS), bentonitic quality be A unit and B unit the quality sum 0.01%.

May exist undissolved solid acid particles in the system this moment.

Embodiment 14: configuration 1L acid oxidation potential biocide preparation (available chlorine content is 100mg/L)

Raw material A: the malic acid fine powder, take by weighing 1mol, add the carboxymethyl cellulose powder, hybrid packed, sealing gets the A unit.

Raw material B: liquor natrii hypochloritis (pH=10-11), measure 1L(available chlorine 100mg), can, sealing gets B unit (available chlorine 100mg).

During use, the A unit mixes with the B unit, stirs, become acidity to system, make 1L acid oxidation potential biocide preparation (pH2-7, ORP800-1200mV, ACC100mg/L, viscosity 25PaS), the quality of carboxymethyl cellulose be A, B unit the quality sum 10%.

May exist undissolved solid acid particles or undissolved solid thickener in the system this moment.

Embodiment 15: configuration 1L acid oxidation potential biocide preparation (available chlorine content is 1000mg/L)

Raw material A: the iron chloride superfine powder, take by weighing 1mol, packing, sealing gets the A unit.

Raw material B: liquor natrii hypochloritis (pH=10-11), add trigonella bean gum, stir swelling, measure 1L(available chlorine 1g), can, sealing gets B unit (available chlorine 1g).

During use, the A unit mixes with the B unit, stirs, become acidity to system, make 1L acid oxidation potential biocide preparation (pH2-7, ORP800-1400mV, ACC1000mg/L, viscosity 20PaS), the quality of trigonella bean gum be A, B unit the quality sum 2%.

May exist undissolved solid acid particles in the system this moment.

Embodiment 16: configuration 1L acid oxidation potential biocide preparation (available chlorine content is 200mg/L)

Raw material A: aluminum chloride powder, take by weighing 1mol, add Polyacrylamide Powder, hybrid packed, sealing gets the A unit.

Raw material B: liquor natrii hypochloritis (pH=11), measure 1L(available chlorine 200mg), can, sealing gets B unit (available chlorine 200mg).

During use, the A unit mixes with the B unit, stirs, become acidity to system, make 1L acid oxidation potential biocide preparation (pH2-7, ORP800-1200mV, ACC200mg/L, viscosity 40PaS), the quality of polyacrylamide be A, B unit the quality sum 3%.

May exist undissolved A unit grain in the system this moment.

Embodiment 17: configuration 1L acid oxidation potential biocide preparation (available chlorine content is 500mg/L)

Raw material A: succinyl chloride, take by weighing 1mol, packing, sealing gets the A unit.

Raw material B: liquor natrii hypochloritis (pH=11), add 3% Sodium Polyacrylate, stir swelling, measure 1L(available chlorine 500mg), can, sealing gets B unit (available chlorine 500mg).

During use, the A unit mixes with the B unit, stirs, become acidity to system, make 1L acid oxidation potential biocide preparation (pH2-7, ORP800-1300mV, ACC500mg/L, viscosity 85PaS), the quality of Sodium Polyacrylate be A, B unit the quality sum 3%.

May exist the A unit grain that not change in the system this moment.

Embodiment 18: configuration 1L acid oxidation potential biocide preparation (available chlorine content is 30mg/L)

Raw material A: succinyl chloride, take by weighing 0.1mol, add bentonite, hybrid packed, get the A unit.

Raw material B: liquor natrii hypochloritis (pH=10-11), measure 1L(available chlorine 30mg), can, sealing gets B unit (available chlorine 30mg).

During use, the A unit mixes with the B unit, stirs, and becomes acidity to system, makes 1L acid oxidation potential biocide preparation (pH2-7, ORP800-1200mV, ACC30mg/L, viscosity 10PaS), bentonitic quality be A, B unit the quality sum 1%.

May exist the acidic materials precursor and the undissolved solid bentonite that not change in the system this moment.

Embodiment 19: configuration 10L acid oxidation potential biocide preparation (available chlorine content is 90mg/L)

Raw material A: hydrochloric acid solution (pH=2-3), measure 9.2L, can, sealing gets the A unit.

Raw material B: liquor natrii hypochloritis (available chlorine 3mg/ml, pH=13), take by weighing 300ml, packing gets B unit (available chlorine 900mg).

Raw material D:PEG300-400,500 grams, packing gets the D unit.

During use, A, B, D unit mix, and stir swelling, the 10L acid oxidation potential biocide preparation (pH2-3, ORP1050-1250mV, ACC90mg/L, viscosity 50PaS) of system.

PEG300-400 has good water-soluble, can increase fast the viscosity of mixed system.

Embodiment 20: configuration 10L acid oxidation potential biocide preparation (available chlorine content is 90mg/L)

Raw material B: calcium hypochlorite powder (available chlorine 30%), take by weighing 8g, packing gets B unit (available chlorine 240mg).

Raw material D: polyurethane solutions 0.8L (3%), viscosity 50PaS, can gets the D unit.

During use, A, B, D unit mix, and stir the 10L acid oxidation potential biocide preparation (pH2-3, ORP1050-1250mV, ACC90mg/L, viscosity 45PaS) of system.

The solid particle that may have available chlorine in the system.

Embodiment 21: configuration 10L acid oxidation potential biocide preparation (available chlorine content is 150mg/L)

Raw material A: the citric acid powder, take by weighing 1mol, packing gets the A unit.

Raw material B: liquor natrii hypochloritis (available chlorine 1.5mg/ml, pH=11), take by weighing 1L, packing gets B unit (available chlorine 1500mg).

Raw material D: polyacrylic acid solution 9L(15%), packing gets the D unit.

During use, A, B, D unit mix, stir, and when the system for the treatment of transfers acidity to, the 10L acid oxidation potential biocide preparation (pH2-7, ORP800-1250mV, ACC150mg/L, viscosity 46PaS) of system.

Embodiment 22: configuration 10L acid oxidation potential biocide preparation (available chlorine content is 3-90mg/L)

Raw material A: hydrochloric acid solution (pH=2-3), measure 10L, can, sealing gets the A unit.

Raw material B: calcium hypochlorite powder (available chlorine 30%), take by weighing 3g, packing gets B unit (available chlorine 900mg).

Raw material D: cold-water-soluble sesbania gum, 500 grams.

During use, A, B, D unit mix, and stir swelling, the 10L acid oxidation potential biocide preparation (pH2-7, ORP900-1250mV, ACC3-90mg/L, viscosity 162PaS) of system.

The cold-water-soluble sesbania gum has good water-soluble, can increase fast the viscosity of mixed system.

Embodiment 23: configuration 1L acid oxidation potential biocide preparation (available chlorine content is 1000mg/L)

Raw material A: the citric acid powder, take by weighing 0.1mol, packing gets the A unit.

Raw material B: liquor natrii hypochloritis (available chlorine 1mg/ml, pH=11), take by weighing 1L, packing gets B unit (available chlorine 1000mg).

Raw material D: sesbania gum, 500 grams.

During use, A, B, D unit mix, and stir swelling, the 1L acid oxidation potential biocide preparation (pH2-7, ORP900-1250mV, ACC1000mg/L, viscosity 35PaS) of system.

The cold-water-soluble composition has good water-solublely in the sesbania gum, can increase fast the viscosity of mixed system.The hot water soluble composition is poorly soluble.The short-and-medium time memory of mixed liquor is at the undissolved sesbania gum of part.

Embodiment 24: configuration 1L acid oxidation potential biocide preparation (available chlorine content is 300mg/L)

Raw material B: the sodium dichloro cyanurate powder takes by weighing 0.6g(available chlorine 300mg), packing gets B unit (available chlorine 300mg).

Raw material D: ethylhydroxyethylcellulose solution 1L(20%, viscosity 300PaS).

During use, A, B, D unit mix, the 1L acid oxidation potential biocide preparation (pH2-7, ORP700-1250mV, ACC3-300mg/L, viscosity 300PaS) of system.

The dissolving of solid acid and solid available chlorine needs process, and when system transfers acidity to, available chlorine discharges greater than 3mg/L, both can bring into play bactericidal effect.

Embodiment 25: configuration 15L acid oxidation potential biocide preparation (available chlorine content is 100mg/L)

Raw material A: hydrochloric acid solution (pH=2-3), measure 0.97L, can, sealing gets the A unit.

Raw material B: liquor natrii hypochloritis (available chlorine 50mg/ml, pH=12), take by weighing 30ml, packing gets B unit (available chlorine 1500mg).

Raw material D: Macrogol 200, measure 5000ml, be dissolved in the 9L water, get the D unit.

During use, A, B, D unit mix, and stir swelling, the 15L acid oxidation potential biocide preparation (pH2-3, ORP1100-1250mV, ACC100mg/L, viscosity 500PaS) of system.

PEG200 has good water-soluble, can increase fast the viscosity of mixed system.

Embodiment 26: configuration 1L acid oxidation potential biocide preparation (available chlorine content is 500mg/L)

Raw material A: citric acid powder 0.1mol.

Raw material B: sodium dichloro cyanurate powder 1g(available chlorine 500mg).

Raw material D: gum Arabic 500g.

Before the use, A, B, the independent packing of D raw material or A, B, the D raw material is hybrid packed or A, the B raw material is hybrid packed or A, the D raw material is hybrid packed or B, D raw material are hybrid packed.

During use, with the above-mentioned unit that contains A, B, D raw material, be dissolved in the 1L water, mix, stir swelling, the 1L acid oxidation potential biocide preparation (pH2-7, ORP800-1300mV, ACC500mg/L, viscosity 10000PaS) of system.

Gum Arabic has good water-soluble, can increase fast the viscosity of mixed system.

Embodiment 27: configuration 1L acid oxidation potential sterilized water (available chlorine content is 10mg/L)

Raw material A: hydrochloric acid viscosity solution (pH2-3, viscosity 5000PaS, 30% Chinese yam glue), measure 1L, independent packaging.

Raw material B: chlorine/nitrogen mixture, can amount 9ml, available chlorine 10mg, independent high sealing packing.

During use, under the airtight condition, the A unit is mixed with the B unit, make 1L acid oxidation potential sterilized water (pH2-3, ORP1100-1200mV, ACC10mg/L, viscosity 5000PaS).

Embodiment 28: configuration 10L acid oxidation potential sterilized water (available chlorine content is 500mg/L)

Raw material A: hydrochloric acid solution (3M), measure 15ml, independent corrosion-proof packing.

Raw material B: sodium chlorate solution (2.5M, pH8), measure 10ml, independent corrosion-proof packing.

The viscosity water independent packaging of raw material D:9.975L (viscosity 2000PaS, 20% konjac glucomannan).

During use, the A unit with after the B unit mixes, is mixed with the D unit again, make 10L acid oxidation potential sterilized water (pH2.5-3.5, ORP1150-1300mV, ACC500mg/L, viscosity 2000PaS).

Embodiment 29: configuration 10L acid oxidation potential sterilized water (available chlorine content is 150mg/L)

Raw material A: hydrochloric acid solution (4M), measure 10ml, independent corrosion-proof packing.

Raw material B: sodium perchlorate solution (0.5M, pH8), measure 10ml, independent corrosion-proof packing.

The viscosity water independent packaging of raw material D:9.98L (viscosity 1000PaS, 10% locust bean gum).

During use, the A unit with after the B unit mixes, is mixed with the D unit again, make 10L acid oxidation potential sterilized water (pH3-7, ORP900-1100mV, ACC150mg/L, viscosity 1000PaS).

Disinfection effect test: following experiment all (adds 0.3% organic chaff interference) and carries out under clean conditions.

With the representative of staphylococcus aureus ATCC 6538 as pyococcus in the bacterial propagule; Escherichia coli 8099 are as the representative of enteron aisle bacterium in the bacterial propagule; Pseudomonas aeruginosa ATCC 15442 is as the representative of the bacterial propagule of normal separation in the hospital infection; Staphylococcus albus 8032 is as the representative of bacterium in the air; Mycobacterium chelonei abscess subspecies ATCC 93326 is as bacillus tuberculosis typus humanus's representative; Bacillus subtilis black variety gemma ATCC 9372 is as the representative of bacterial spore; Candida albicans ATCC 10231 and black-koji mould ATCC 16404 are as the representative of pathogenic fungus; Polyovirus-I type vaccine strain (Poliovirus-I) is as the representative of virus; With the representative as drug-fast bacteria of the staphylococcus aureus (MRSA) of methicillin-resistant and vancomycin-resistant enterococcus (VRE).

Contrast bactericidal assay 1, gravity is on the impact of vertical plane killing effect

Trial target 1:ACC3mg/L, pH6.8, ORP730mV, viscosity 0.001PaS

Trial target 2:ACC3mg/L, pH2.0, ORP1050mV, viscosity 0.001PaS

Under table 1 gravity effect, act on the logarithm of killing of 10min

Experimental result shows: after only possessing the sterilization factors of some strength and acting on certain hour, just can reach certain bactericidal effect.If with the theory sterilization value that the quantitative result of the test of suspension makes up as this pH/ACC/ORP, action of gravitation makes being combined on the vertical plane of identical pH/ACC/ORP can not form effective killing effect so.

Contrast bactericidal assay 2, viscosity is on the impact of faintly acid EOW at the vertical plane killing effect

Reference substance, ACC3mg/L, pH6.8, ORP730mV, viscosity 0.001PaS

Trial target 1, ACC3mg/L, pH6.8, ORP730mV, viscosity 0.1PaS

Trial target 2, ACC3mg/L, pH6.8, ORP730mV, viscosity 1.0PaS

Trial target 3, ACC3mg/L, pH6.8, ORP730mV, viscosity 1.1PaS

Trial target 4, ACC3mg/L, pH6.8, ORP730mV, viscosity 5000PaS

Trial target 5, ACC3mg/L, pH6.8, ORP730mV, viscosity 10000PaS

Under table 2 viscosity influence, act on the logarithm of killing of 10min

Experimental result shows: be not less than each experimental group of 1.1PaS viscosity and suspension test group (theoretical value) relatively, difference does not have statistical significance (P〉0.05).The Main Function of the viscosity of test fluid is to strengthen adhesive ability, the viscosity that is not less than 1.1PaS can make being combined in of this pH/ACC/ORP form effective killing effect on the vertical plane, has namely adhered to the sterilization factors of necessary intensity and can be attached to necessary time at vertical plane.

Contrast bactericidal assay 3, viscosity is on the impact of highly acid EOW at the vertical plane killing effect

Reference substance, ACC3mg/L, pH2.0, ORP1050mV, viscosity 0.001PaS

Trial target 1, ACC3mg/L, pH2.0, ORP1050mV, viscosity 0.5PaS

Trial target 2, ACC3mg/L, pH2.0, ORP1050mV, viscosity 1.0PaS

Trial target 3, ACC3mg/L, pH2.0, ORP1050mV, viscosity 1.1PaS

Trial target 4, ACC3mg/L, pH2.0, ORP1050mV, viscosity 6000PaS

Trial target 5, ACC3mg/L, pH2.0, ORP1050mV, viscosity 12000PaS

Under table 3 viscosity influence, act on the logarithm of killing of 10min

The contrast bactericidal assay 4, viscosity to faintly acid EOW at the plane of different directions killing effect

Trial target: ACC3mg/L, pH6.8, ORP730mV, viscosity 1.1PaS

Reference substance: ACC3mg/L, pH6.8, ORP730mV, viscosity ≈ 0.001PaS

Table 4 effect was killed logarithm after 10 minutes

Experimental result shows: 1.1PaS viscosity makes identical pH/ACC/ORP combination, the killing effect that produces on the plane of different directions, difference does not have statistical significance (P〉0.05), the viscosity that shows 1.1PaS makes EOW have enough adhesive force, the sterilization factors that all can adhere to sufficient intensity on the plane of all directions, and continue enough action time, can reach the effect identical with theoretical value (suspension group).

The contrast bactericidal assay 5, viscosity to highly acid EOW at the plane of different directions killing effect

Trial target: ACC3mg/L, pH2.0, ORP1050mV, viscosity 1.1PaS

Reference substance: ACC3mg/L.PH2.0, ORP1050mV, viscosity ≈ 0.001PaS

Table 5 effect was killed logarithm after 10 minutes

Contrast bactericidal assay 6

Trial target 1:ACC20mg/L, pH6.8, ORP860mV, viscosity 1.1PaS

Reference substance 1:ACC20mg/L, pH6.8, ORP860mV, viscosity ≈ 0.001PaS

Trial target 2:ACC2000mg/L, pH6.8, ORP1250mV, viscosity 1.1PaS

Reference substance 2:ACC2000mg/L, pH6.8, ORP1250mV, viscosity ≈ 0.001PaS

Trial target 3:ACC5000mg/L, pH6.8, ORP1450mV, viscosity 1.1PaS

Reference substance 3:ACC5000mg/L, pH6.8, ORP1450mV, viscosity ≈ 0.001PaS

Table 6 gemma is killed logarithm

Act on after 40 minutes	Vertical plane	To lower plane	The plane makes progress	Suspension is quantitative
					Trial target
1	>5.00	>5.00	>5.00	>5.00
					Reference substance 1	<1	<1	<1	>5.00
Act on after 10 minutes	Vertical plane	To lower plane	The plane makes progress	Suspension is quantitative
					Trial target
2	>5.00	>5.00	>5.00	>5.00
					Reference substance 2	<1	<1	<1	>5.00
Act on after 5 minutes	Vertical plane	To lower plane	The plane makes progress	Suspension is quantitative
					Trial target
3	>5.00	>5.00	>5.00	>5.00
					Reference substance 3	<1	<1	<2	>5.00

Experimental result shows: for the germicidal solution of 1.1PaS viscosity, and identical pH/ACC/ORP combination, vertical plane group and set of planes and the comparison of suspension group, difference do not have statistical significance (P〉0.05).Trial target group and reference substance group compare at the killing effect that needs overcome under the gravity effect, and difference has statistical significance (P＜0.01).The viscosity that shows 1.1PaS makes biocide preparation have enough adhesive force, can overcome gravity effect, adheres to the sterilization factors of sufficient intensity, and continues enough action time, can reach the effect identical with theoretical value (suspension group).

Contrast bactericidal assay 7

Trial target 1:ACC20mg/L, pH2.0, ORP1130mV, viscosity 1.1PaS

Reference substance 1:ACC20mg/L, pH2.0, ORP1130mV, viscosity ≈ 0.001PaS

Trial target 2:ACC3000mg/L, pH2.0, ORP1300mV, viscosity 1.1PaS

Reference substance 2:ACC3000mg/L, pH2.0, ORP1300mV, viscosity ≈ 0.001PaS

Trial target 3:ACC6000mg/L, pH2.0, ORP1500mV, viscosity 1.1PaS

Reference substance 3:ACC6000mg/L, pH2.0, ORP1500mV, viscosity ≈ 0.001PaS

Table 7 gemma is killed logarithm

Contrast bactericidal assay 8(vertical plane)

Trial target 1, ACC500mg/L, pH6.8, ORP975mV, viscosity 1.1PaS

Reference substance 1, ACC3mg/L, pH6.8, ORP730mV, viscosity 1.1PaS

Trial target 2, ACC500mg/L, pH2.0, ORP1205mV, viscosity 1.1PaS

Reference substance 2, ACC3mg/L, pH2.0, ORP1050mV, viscosity 1.1PaS

Table 8 vertical plane, pH/ACC/ORP and viscosity are on killing the impact of logarithm

Test organisms	Trial target	1	Reference substance 1	Trial target 2	Reference substance 2
							Effect 5min	Effect 10min	Effect 5min	Effect 10min
Staphylococcus aureus	>5.00	>5.00	>5.00	>5.00
					MRSA	>5.00	>5.00	>5.00	>5.00
Escherichia coli	>5.00	>5.00	>5.00	>5.00
					VRE	>5.00	>5.00	>5.00	>5.00
Pseudomonas aeruginosa	>5.00	>5.00	>5.00	>5.00

Candida albicans	>5.00	>5.00	>5.00	>5.00
					Black-koji mould	>5.00	>5.00	>5.00	>5.00
Staphylococcus albus	>5.00	>5.00	>5.00	>5.00
					Bacillus subtilis black variety gemma	>5.00	>1.00	>5.00	>1.00
Poliovirus-Ⅰ	>5.00	>5.00	>5.00	>5.00
					Mycobacterium chelonei abscess subspecies	>5.00	>5.00	>5.00	>5.00

Experimental result shows: during 1.1PaS viscosity, the enhancing of pH/ACC/ORP combination makes sterilization factors increase in the adhesive strength of vertical plane, thereby has shortened the time that reaches identical killing effect.

Contrast bactericidal assay 9

Kill bacterial classification, bacillus subtilis black variety gemma

Reference substance 1, ACC3mg/L, pH6.8, ORP730mV, ≈ 0.001PaS

Trial target 1-7, different viscosities reference substance 1

Reference substance 2, ACC65mg/L, pH2.5, ORP11340mV, machine preparation do not add thickener

Table 945min, gemma killing rate %

Sticky parameter	Vertical plane	Suspension is quantitative
			Reference substance 1: ≈ 0.001PaS	4.25	65.52
Trial target 1:1.1PaS	90.23	90.56
			Trial target 2:2PaS	92.62	92.50
Trial target 3:5PaS	97.39	98.39
			Trial target 4:10PaS	99.05	99.23
Trial target 5:15PaS	99.94	99.99
			Trial target 6:20PaS	99.99	99.99
Trial target 7:25PaS	99.99	99.99
			Reference substance 2: ≈ 0.001PaS	11.96	99.99

Experimental result shows: for the sterilization of vertical plane, and acid oxidation potential sterilization viscosity preparation, during viscosity 〉=1.1PaS, bactericidal effect obviously is better than substantially noncohesive water formulation, and along with viscosity increases, bactericidal effect strengthens.For the suspension quantitative method killing effect, acid oxidation potential sterilization viscosity preparation, during viscosity 〉=1.1PaS, sterilization is significantly better than substantially noncohesive water formulation, and along with viscosity increases, bactericidal effect strengthens.During low content available chlorine, difference is more remarkable.

Contrast bactericidal assay 10

Trial target S, the acidic oxidized electric potential water of pH6.8 (≈ 0.001PaS)

Trial target 1, trial target S, 1.1PaS, ACC3mg/L

Trial target X, trial target S, ≈ 0.001PaS, different ACC content

Table 10 vertical plane, effect kill behind the 10min logarithm can 5.00 available chlorine content

Experimental result shows: for the sterilization of vertical plane, when reaching identical bactericidal effect, substantially noncohesive acid oxidation potential sterilized water preparation need to use stronger pH/ACC/ORP combination.

Contrast bactericidal assay 11(vertical plane)

Trial target 1,1.1PaS, ACC3mg/L, pH6.8, ORP730mV

Reference substance 1,0.001PaS, ACC500mg/L, pH6.8, ORP830mV

Reference substance 2,0.001PaS, ACC500mg/L, pH4.0, ORP1030mV

Reference substance 3,0.001PaS, ACC500mg/L, pH2.0, ORP1180mV

Table 11 vertical plane, effect are killed logarithm behind the 10min

	Trial target 1	Reference substance 1	Reference substance 2	Reference substance 3
					Staphylococcus aureus	>5.00	<3.00	<3.00	<3.00
MRSA	>5.00	<3.00	<3.00	<3.00
					Escherichia coli	>5.00	<3.00	<3.00	<3.00

VRE	>5.00	<3.00	<3.00	<3.00
					Pseudomonas aeruginosa	>5.00	<3.00	<3.00	<3.00
Candida albicans	>5.00	<3.00	<3.00	<3.00
					Black-koji mould	>5.00	<3.00	<3.00	<3.00
Staphylococcus albus	>5.00	<3.00	<3.00	<3.00
					Poliovirus-Ⅰ	>5.00	<3.00	<3.00	<3.00
Mycobacterium chelonei abscess subspecies	>5.00	<3.00	<3.00	<3.00

Experimental result shows: for vertical plane, the bactericidal effect of substantially noncohesive acid oxidation potential sterilized water preparation obviously is weaker than the biocide preparation with certain viscosity (1.1PaS).

Contrast bactericidal assay 12(vertical plane)

Kill bacterial classification, staphylococcus aureus.

Time is after 10 minutes.

Trial target X, 1.1PaS, ACC3mg/L, pH6.8, ORP730mV.

Thickening thing Dx, D1 imvite, D2 bentonite, D3 hectorite, D4 polyanion cellulose, D5 cationic cellulose, D6 ethyl cellulose, D7 hydroxypropyl cellulose, D8 xanthans, D9 cation guar gum, D10 soybean protein glue, D11 gelatin, D12 Macrogol 600, D13 PAMC 300, D14 Acritamer 940, D15 amino alcohol solvay-type titanate esters.

X1-X15 kills number average〉5, and group difference does not have statistical significance (P〉0.05)

Experimental result shows: for vertical plane, the bactericidal effect of acid oxidation potential sterilized water preparation depends on the adhesion amount of sterilization parameter (pH, ACC, ORP) and Fungicidal substance and adheres to the time.The adhesion amount of Fungicidal substance depends on viscosity number, rather than the kind of thickening material.

Contrast bactericidal assay 13(vertical plane)

Kill bacterial classification, select respectively Escherichia coli, pseudomonas aeruginosa, staphylococcus albus, Mycobacterium chelonei abscess subspecies, Candida albicans, black-koji mould, polyovirus-I type vaccine strain, the staphylococcus aureus of methicillin-resistant, vancomycin-resistant enterococcus.

Repeat to contrast bactericidal assay 4, X1-X15 kills number average〉5, and group difference does not have statistical significance (P〉0.05).

Experimental result shows: the bactericidal effect for vertical plane depends on pH, ACC, ORP and viscosity.

Contrast bactericidal assay 14(vertical plane)

Kill bacterial classification, bacillus subtilis black variety gemma

Trial target X, ACC3mg/L, pH6.8, ORP730mV

Thickening material, 15% tamarind gum.

15% tamarind gum adds in the trial target 1.The slow swelling of tamarind gum is got the mixed liquor of different time.

Table 14

Dissolution time minute	Sticky parameter	Effect 45min, gemma killing rate %
			0.5	Trial target 1: ≈ 0.001PaS	7.52
5	Trial target 2:0.6PaS	28.65
			10	Trial target 3:1.1PaS	90.05
15	Trial target 4:2.3PaS	93.55
			20	Trial target 5:6.2PaS	98.45
30	Trial target 6:17PaS	99.97
			40	Trial target 7:25PaS	99.99
50	Trial target 8:30PaS	99.99

Experimental result shows: after 50 minutes, and the thickener complete swelling, system reaches stable viscosity.Reach between the 30PaS to complete swelling but produce certain viscosity (1.1PaS) in the part swelling, system has the significantly property killed equally because have enough pH, ACC, ORP and viscosity.

More than disclosed only be several specific embodiments of the application, but the application is not limited thereto, the changes that any person skilled in the art can think of all should drop in the application's the protection domain.

Claims

1. the preparation method with acid oxidation potential biocide preparation of certain viscosity is characterized in that, may further comprise the steps:

(1) provides and to produce hydrionic A unit;

(3) described A unit is mixed formation C unit with described B unit;

2. the preparation method with acid oxidation potential biocide preparation of certain viscosity as claimed in claim 1, it is characterized in that, the described material that can increase solution viscosity or consistence refers to and can dissolve in whole or in part or swelling in solution, the material that solution viscosity or consistence are strengthened.

3. the preparation method with acid oxidation potential biocide preparation of certain viscosity as claimed in claim 1 or 2, it is characterized in that the described material that can increase solution viscosity or consistence is selected from one or more in inorganic thickening agent, cellulose thickener, natural polymer and derivative class thickener thereof, synthetic high polymer class thickener or the solvay-type organo-metallic compound class thickener.

4. the preparation method with acid oxidation potential biocide preparation of certain viscosity as claimed in claim 1 is characterized in that, described A unit is acid reagent.

5. the preparation method with acid oxidation potential biocide preparation of certain viscosity as claimed in claim 1, it is characterized in that, the available chlorine of described B unit is selected from one or more of double salt, chlorite or available chlorine precursor substance of liquid chlorine, chlorine dioxide, hypochlorite, hypochlorite, and described available chlorine precursor substance refers to can generate with acid or water reaction the chlorine-bearing compound of available chlorine.

6. acid oxidation potential biocide preparation with certain viscosity, it is characterized in that, comprise A unit, B unit and D unit, described D unit can be mixed into the monobasic packing with described A unit or described B unit, separately packing also can be distinguished in described A unit, described B unit and described D unit, wherein, described A unit is for can produce hydrionic preparation, described B unit is the preparation that contains available chlorine or can produce available chlorine, and described D contains the material that can increase solution viscosity or consistence in the unit.

7. the acid oxidation potential biocide preparation with certain viscosity as claimed in claim 6, it is characterized in that, the described material that can increase solution viscosity or consistence refers to and can dissolve in whole or in part or swelling in solution, the material that solution viscosity or consistence are strengthened.

8. the acid oxidation potential biocide preparation with certain viscosity as claimed in claim 6, it is characterized in that the described material that can increase solution viscosity or consistence is selected from one or more in inorganic thickening agent, cellulose thickener, natural polymer and derivative class thickener thereof, synthetic high polymer class thickener or the solvay-type organo-metallic compound class thickener.

9. the acid oxidation potential biocide preparation with certain viscosity as claimed in claim 6 is characterized in that, described A unit is acid reagent.

10. the acid oxidation potential biocide preparation with certain viscosity as claimed in claim 6, it is characterized in that, the available chlorine of described B unit is selected from one or more of double salt, chlorite or available chlorine precursor substance of liquid chlorine, chlorine dioxide, hypochlorite, hypochlorite, and described available chlorine precursor substance refers to can generate with acid or water reaction the chlorine-bearing compound of available chlorine.

11. such as the described acid oxidation potential biocide preparation with certain viscosity of any one among the claim 6-10, it is characterized in that, after mixing, described A unit, described B unit and described D unit form the acid strong oxidizing property solution with certain viscosity, the pH value of described acid strong oxidizing property solution is between 2-7, its redox potential is not less than 700mV, its available chlorine content is not less than 3mg/L, and its viscosity is not less than 1.1PaS.

12. the acid oxidation potential biocide preparation with certain viscosity is characterized in that the pH value of described biocide preparation is between 2-7, its redox potential is not less than 700mV, and its available chlorine content is not less than 3mg/L, and its viscosity is not less than 1.1PaS.

13. the acid oxidation potential biocide preparation with certain viscosity as claimed in claim 12, it is characterized in that, contain one or several of inorganic acid, organic acid, strong acid weak base salt, strong base-weak acid salt, weak acid and weak base salt or strong acid and strong base salt in the described biocide preparation.

14. the acid oxidation potential biocide preparation with certain viscosity as claimed in claim 12, it is characterized in that, available chlorine in the described biocide preparation is selected from one or more of double salt, chlorite or available chlorine precursor substance of liquid chlorine, chlorine dioxide, hypochlorite, hypochlorite, and described available chlorine precursor substance refers to can generate with acid or water reaction the chlorine-bearing compound of available chlorine.

15. the acid oxidation potential biocide preparation with certain viscosity as claimed in claim 12, it is characterized in that, contain the material that can increase solution viscosity or consistence in the described biocide preparation, the described material that can increase solution viscosity or consistence refers to and can dissolve in whole or in part or swelling in solution, the material that solution viscosity or consistence are strengthened.