CN103027074A

CN103027074A - Low-corrosivity oxidation potential sterilization water and preparation method thereof

Info

Publication number: CN103027074A
Application number: CN2013100066108A
Authority: CN
Inventors: 邵鹏飞
Original assignee: Individual
Current assignee: Individual
Priority date: 2013-01-08
Filing date: 2013-01-08
Publication date: 2013-04-10

Abstract

The invention relates to the field of sterilization and disinfection and particularly relates to low-corrosivity oxidation potential sterilization water and a preparation method of the low-corrosivity oxidation potential sterilization water. The preparation method of the low-corrosivity oxidation potential sterilization water comprises the following steps: (1), providing an available chlorine providing unit containing available chlorine or capable of producing the available chlorine; (2), providing a pH regulating unit; and (3) mixing the pH regulating unit and the available chlorine providing unit to obtain a solution having a strong oxidizing property, wherein the pH value of the solution having the strong oxidizing property is between 2 and 8, the redox potential of the solution having the strong oxidizing property is not lower than 600mV, the content of the available chlorine of the solution having the strong oxidizing property is not lower than 3mg/L, and the total content of chlorate of the solution having the strong oxidizing property is not higher than 0.5mol/L. Compared with the existing acid oxidation potential sterilization water, the sterilization water prepared by the oxidation potential sterilization water preparation method can reduce the corrosivity on metal, so that the application range is expanded.

Description

Oxidizing potential sterilized water of a kind of low-corrosiveness and preparation method thereof

Technical field

The present invention relates to the sterilizing field, particularly oxidizing potential sterilized water of a kind of low-corrosiveness and preparation method thereof.

Background technology

The concept of introducing redox potential in the sterilization field is to come from the acidic oxidized electric potential water generation machine of Japanese 20th century development and production eighties and the acidic oxidized electric potential water that is produced by the generation machine.Acidic oxidized electric potential water (is called for short: the water of EOW) refer to have high redox potential (ORP), low pH value characteristic and low concentration available chlorine (ACC).

The mechanism of acidic oxidized electric potential water sterilization is as follows:

At first, the microorganism of the most of kinds of occurring in nature lives in the environment of pH4-9, and the pH value of acidic oxidized electric potential water can affect electric charge on the microbial biofilm and the absorption of nutriment, the activity of enzyme, and the toxicity of giving property or harmful substance of nutriment in the change environment, thereby quick killing microorganisms.

Secondly, because the distributions inside and outside microbial biofilm such as hydrogen ion, potassium ion, sodium ion are different, so that the inside and outside current potential of film has certain potential difference when reaching dynamic equilibrium, generally be about-700～+ 900mV.The inside and outside potential difference of the biomembrane of aerobic bacterium is generally+200～+ 800mV, and the inside and outside potential difference of the biomembrane of anaerobic bacteria is generally-700～+ 200mV.The factors such as the oxidation in the acidic oxidized electric potential water, reduction material and pH make its ORP be higher than 1100mV, have exceeded the scope of microorganism.Having high ORP(is ORP〉1100mV) EOW contact microorganism after capture rapidly electronics, disturb the biomembrane balance, change biological transmembrane potential difference, the inside and outside osmotic pressure of film, the destruction that causes the enhancing of biomembrane permeability, cellular swelling and biotransferase, make the interior material of film overflow, dissolve, thus quick killing microorganisms.

At last, available chlorine can make the permeability of cell change, or biomembrane generation mechanicalness is broken, and impels the interior material of film outwards to ooze out, and causes microbial death.And hypochlorous acid is neutral small-molecule substance, easily invades in the cell with protein generation oxidation or destroys its phosphate dehydrogenase, makes the glycometabolism imbalance cause microbial death, thus quick killing microorganisms.

The sterilizing ability of EOW system is to take as the leading factor with ACC, and low pH value and high ORP are the synergistic result of three of important promotion.This systematic collaboration effect far above single ACC, low pH value and high ORP effect simply add and, its ACC is higher, the pH value is lower, ORP is higher, the system synthesis sterilization effect is just better.

But existing acid oxidation potential sterilized water has general metal protection.

Summary of the invention

The first purpose of the present invention is to provide a kind of preparation method of oxidizing potential sterilized water of low-corrosiveness, has the technical matters of general metal protection to solve acid oxidation potential sterilized water of the prior art.

The second purpose of the present invention is to provide a kind of oxidizing potential sterilized water of low-corrosiveness, has the technical matters of general metal protection to solve acid oxidation potential sterilized water of the prior art.

The object of the invention is achieved through the following technical solutions:

A kind of preparation method of oxidizing potential sterilized water of low-corrosiveness may further comprise the steps:

(1) provide the available chlorine that contains available chlorine or can produce available chlorine that the unit is provided;

(2) provide pH value regulon;

(3) provide the unit to mix with described available chlorine described pH value regulon, obtain strong oxidizing property solution, the pH value of described strong oxidizing property solution is between 2-8, its redox potential is not less than 600mV, its available chlorine content is not less than 3mg/L, and the total content of its halo acid ion is not higher than 0.5mol/L.

Preferably, the pH value of described strong oxidizing property solution is between 5-7, and its redox potential is 600-1100mV, and its available chlorine content is 3-1000mg/L, and the total content of its halo acid ion is not higher than 0.01mol/L.

Preferably, described halo acid ion be chloranion, bromate ion, iodate ion wherein one or more.

Preferably, in step (1), also comprise: provide the unit to reduce the preliminary treatment of the total content of halo acid ion to described available chlorine.

Preferably, in step (2), also comprise: described pH value regulon is reduced the preliminary treatment of the total content of halo acid ion.

Preferably, in step (3), also comprise: provide the mixed mixed liquor in unit to reduce the post processing of the total content of halo acid ion to described pH value regulon and described available chlorine.

Preferably, the processing method of the total content of described reduction halo acid ion can be selected from one or several in adding halo acid ion deactivator, membrane separation process, electrochemical process, chromatography, absorption method or the ion-exchange.

Preferably, described available chlorine provides one or more in double salt, chlorite or the available chlorine precursor substance that the unit contains liquid chlorine, chlorine dioxide, hypochlorite, hypochlorite, and described available chlorine precursor substance refers to can generate with acid or water reaction the chlorine-bearing compound of available chlorine.

Preferably, the unit is provided is neutral or alkaline to described available chlorine.

Preferably, described pH value regulon comprises the combination of acidic materials, alkaline matter or acidic materials and alkaline matter.

A kind of oxidizing potential sterilized water of low-corrosiveness comprises that pH value regulon and the available chlorine of independent packing provides the unit before using; It is the preparation that contains available chlorine or can produce available chlorine that described available chlorine provides the unit, described pH value regulon with obtain strong oxidizing property solution after described available chlorine provides the unit to mix, the pH value of described strong oxidizing property solution is between 2-8, its redox potential is not less than 600mV, its available chlorine content is not less than 3mg/L, and the total content of its halo acid ion is not higher than 0.5mol/L.

A kind of oxidizing potential sterilized water of low-corrosiveness, the pH value of described sterilized water is between 2-8, and its redox potential is not less than 600mV, and its available chlorine content is not less than 3mg/L, and the total content of its halo acid ion is not higher than 0.5mol/L.

Preferably, the pH value of described sterilized water is between 5-7, and its redox potential is 600-1100mV, and its available chlorine content is 3-1000mg/L, and the total content of its halo acid ion is not higher than 0.01mol/L.

Preferably, available chlorine in the described sterilized water is by one or more generations in double salt, chlorite or the available chlorine precursor substance of liquid chlorine, chlorine dioxide, hypochlorite, hypochlorite, and described available chlorine precursor substance refers to can generate with acid or water reaction the chlorine-bearing compound of available chlorine.

Compare with existing acid oxidation potential sterilized water, the present invention has following advantage:

1, the sterilized water of the preparation method of oxidizing potential sterilized water of the present invention preparation can reduce corrosion of metal, thereby has enlarged range of application;

2, before use, pH value regulon and the available chlorine of oxidizing potential sterilized water of the present invention provide the unit to deposit separately, in the time will using, provide the unit to mix pH value regulon and available chlorine again, solved the storage problem of oxidizing potential sterilized water, very easy to use;

3, in the process of preparation oxidizing potential sterilized water of the present invention, strengthen artificial controllability, can regulate according to the actual requirements pH value, ACC content and the ORP value of sterilized water.

Description of drawings

Fig. 1 is in the environment of pH=2-8, XO ₃ ^-To copper corrosion effect schematic diagram;

Fig. 2-Fig. 3 is in the oxidative environment of pH=2-8, available chlorine and XO ₃ ^-Schematic diagram to the copper corrosion effect;

Fig. 4-Fig. 5 is in the oxidative environment of pH=2-8, pH and XO ₃ ^-Schematic diagram to the copper corrosion effect;

Fig. 6-Fig. 7 is in the oxidative environment of pH=2, pH/ACC/XO ₃ ^-Schematic diagram to the copper corrosion effect;

Fig. 8-Fig. 9 is in the oxidative environment of pH=8, pH/ACC/XO ₃ ^-Schematic diagram to the copper corrosion effect.

Embodiment

Below describe the present invention.

Known at present, available chlorine has three kinds of basic existence forms, comprises chlorine, hypochlorous acid molecule and hypochlorite ion, and wherein chlorine and the bactericidal property of hypochlorous acid molecule in solution are far longer than the hypochlorite ion.Because the hypochlorite ion needs slowly hydrolysis, change the hypochlorous acid molecular conformation into after, just have microbe killing properties can, so control the pH value of available chlorine solution, available chlorine is existed with the form of hypochlorous acid molecule and chlorine, can guarantee bactericidal property.

Hypochlorous ionized acidic constant is approximately pKa=7.6, so during the pH value＜pKa (7.6) of available chlorine solution, the ratio of molecule-type available chlorine is greater than ionic available chlorine in the available chlorine of solution.The pH value of available chlorine solution≤8.0 o'clock can be brought into play the activity of q.s (＞30%) molecule-type available chlorine.The pH value of available chlorine solution 〉=9.0 o'clock, the ratio less than 4% of molecule-type available chlorine.

At present, the acid oxidation potential sterilized water has launched Primary Study to corrosion of metal, and the result who has announced shows that acidic oxidized electric potential water has general metal protection.But its corrosive research on mechanism is not carried out, and its corrosivity is considered to usually that peracid acidity (pH2-3) causes, even thinks that nearly neutral electrolyzed oxidizing water can avoid metal protection.The result who has announced shows acidic oxidized electric potential water, to stainless steel substantially without corroding to mild corrosion, to carbon steel, copper, aluminium moderate to heavy corrosion, its conclusion widely different.

Electrolyzed oxidizing water mainly is that three aspect factor causes to corrosion of metal, the one, and the acidity of system, as, the replacing hydrogen reaction of hydrogen ion and active metal (iron, magnesium, zinc, aluminium etc.), or the reaction of hydrogen ion and metal oxide etc.; The 2nd, the available chlorine of system (oxidisability); The 3rd, the impact of other ion in the system.But pH and oxidisability are the physics and chemistry speciality of electrolyzed oxidizing water, also are the decisive factors of bactericidal property, and therefore, in a sense, bactericidal property and corrosion of metal are the paradox of coexistence.

Compare with electrolysis, chemical method prepares oxidizing potential solution, and by calculating the constituent content that can control in the solution, its pH value regulon, available chlorine provide the Material Source of unit wider general.But also caused the source of the impurity of introducing in the solution more complicated.

Halate has strong oxidizing property, and in sour environment, the existence of halate can be kept, the oxidisability of fortification system especially, is conducive to the killing effect of oxidation potential germicidal water, but has also promoted corrosion of metal simultaneously.Discuss in the present invention chloranion, bromate ion, iodate ion between pH=2-8 in the oxidative environment to copper corrosion.Because copper and simple hydrogen ion do not react, thus with copper as research object, can more effective embodiment pH/ACC/XO ₃ ^-Comprehensive corrosive effect.Annotate, with XO ₃ ^-(X=Cl, Br or I) represents chloranion, bromate ion or iodate ion, with [XO ₃ ^-] expression ion total content of material.

In the oxidizing potential sterilization system, XO ₃ ^-The introducing of (X=Cl, Br, I) mainly contains four kinds of approach, one, and the raw material employing itself contains or produces XO ₃ ^-Material, such as chloric acid, bromic acid, acid iodide and corresponding salt thereof etc.; Its two, raw material adopts XO ₃ ^-Precursor substance, described XO ₃ ^-Precursor substance refer in the oxidizing potential sterilized water of pH2-8, can change XO into ₃ ^-Material; Its three, use to carry secretly in the raw material and contain XO ₃ ^-Or the impurity of its precursor substance; Its four, contain XO ₃ ^-The perhaps component of other effects of its precursor substance is such as thickener, stabilizing agent, hardening agent, desiccant etc.

Usually metal has certain diaphragm or can produce certain passivating film, makes the isolation of interior metal and the external corrosion factor, has stoped the continuation of corrosion.The existence of aggressivity anion in the solution, under diffusion or electric field or oxidation, be adsorbed on passivating film surface or enter in the film by the aperture in the passivating film or defective, changed the structure of passivating film, promoted the dissolving of passivating film, made metal inside that further corrosion occur.The radius of anion is less, and the activity of pierce through the protection film is stronger.

As from the foregoing, contain XO ₃ ^-The electrolyzed oxidizing water of (X=Cl, Br, I), XO ₃ ^-Aggressivity and oxidisability affected system to corrosion of metal.And in electrolyzed oxidizing water, its rodent impact is greater than the impact of oxidisability.Its ionic radius from little to large order be ClO ₃ ^-＜BrO ₃ ^-＜IO ₃ ^-, its corrosion activity is ClO from large extremely little order ₃ ^-＞BrO ₃ ^-＞IO ₃ ^-

See also Fig. 1, show among the figure: in the pH=2-8 system, [XO ₃ ^-] increase of content, strengthened system to corrosion of metal.Simultaneously as can be known, hydrogen ion and XO ₃ ^-Synergy, strengthened system to corrosion of metal.

See also Fig. 2, Fig. 3, show among the figure: in the system of pH=2-8 oxidisability (containing ACC), XO ₃ ^-With the available chlorine synergy, the system that affected makes system to corrosion of metal generation hop to corrosion of metal.Wherein, during available chlorine content 〉=3ppm, [XO ₃ ^-] concentration increase (＞0.5M), all can produce the hop to corrosion of metal.Simultaneously as can be known, the reduction of available chlorine makes system to the corrosion of metal reduction, and has reduced the significance of hop.

See also Fig. 4, Fig. 5, show among the figure: in the system of pH=2-8 oxidisability (containing ACC), XO ₃ ^-With the hydrogen ion synergy, the system that affected makes system to corrosion of metal generation hop to corrosion of metal.Wherein, the environment of pH2-8, [XO ₃ ^-] concentration increase (＞0.5M), all can produce the hop to corrosion of metal.Simultaneously as can be known, acid reduction makes system to the corrosion of metal reduction, and has reduced the significance of hop.

Comparison diagram 1-Fig. 5 controls [XO as can be known ₃ ^-] content≤0.5M, can control or reduce the metal protection of oxidizing potential sterilized water.

See also Fig. 6-Fig. 9, show among the figure: in the system of the oxidisability of pH=2-8 (containing ACC), available chlorine (〉=3ppm) with different types of XO ₃ ^-(X=Cl, Br, I) synergy is to the similar characteristic of the active generation of corrosion of metal.[XO ₃ ^-] increase of ion concentration, make system produce hop to metal protection.Its corrosion activity is ClO from large extremely little order ₃ ^-＞BrO ₃ ^-＞IO ₃ ^-Wherein, ClO ₃ ^-The ionic reaction activity is the strongest, and it produces the concentration minimum (0.5M) of corrosion hop.Other XO ₃ ^-Ion, along with ion activity reduces, the concentration increase that corrosion activity reduces or hop is required (＞0.5M).

See also Fig. 6-Fig. 9, show among the figure: in the system of the oxidisability of pH=2-8 (containing ACC), the available chlorine (〉=XO that 3ppm) forms with different proportion ₃ ^-(X=Cl, Br, I) synergy is to the similar characteristic of the active generation of corrosion of metal.The different XO that form ₃ ^-Has different corrosion activities.Wherein, ClO ₃ ^-The ionic reaction activity is the strongest, therefore fully by ClO ₃ ^-The XO that ion forms ₃ ^-The concentration minimum (0.5M) of corrosivity hop.Under the same amount, its corrosivity is greater than containing BrO ₃ ^-Ion or IO ₃ ^-Total XO of ion ₃ ^-Ion.

Comparison diagram 6-Fig. 9 controls the XO of variety classes, different proportion composition as can be known ₃ ^-Total content≤the 0.5M of (X=Cl, Br, I) can control or reduce the metal protection of oxidizing potential sterilized water.

As from the foregoing, contain XO ₃ ^-The oxidizing potential sterilized water of (X=Cl, Br, I), XO ₃ ^-Interact with hydrogen ion and available chlorine, the system that greatly affected is to corrosion of metal.

Therefore, the invention provides a kind of preparation method of oxidizing potential sterilized water of low-corrosiveness, may further comprise the steps:

(2) provide pH value regulon;

(3) provide the unit to mix with described available chlorine described pH value regulon, obtain strong oxidizing property solution, the pH value of described strong oxidizing property solution is between 2-8, its redox potential is not less than 600mV, its available chlorine content is not less than 3mg/L, and the total content of its halo acid ion is not higher than 0.5mol/L.Wherein, described halo acid ion be chloranion, bromate ion, iodate ion wherein one or more.

The present invention also provides a kind of oxidizing potential sterilized water of low-corrosiveness, comprises that pH value regulon and the available chlorine of independent packing provides the unit before using; It is the preparation that contains available chlorine or can produce available chlorine that described available chlorine provides the unit, described pH value regulon with obtain strong oxidizing property solution after described available chlorine provides the unit to mix, the pH value of described strong oxidizing property solution is between 2-8, its redox potential is not less than 600mV, its available chlorine content is not less than 3mg/L, and the total content of its halo acid ion is not higher than 0.5mol/L.Wherein, described halo acid ion be chloranion, bromate ion, iodate ion wherein one or more.

PH value regulon is acid or weakly alkaline solid or liquid, and wherein the pH value of liquid is preferably between 0-8, is preferably again between 1-8, is preferably between 1-7 again, also is preferably between 1-5, most preferably is between 1-3.

PH value regulon comprises the combination of acidic materials, alkaline matter or acidic materials and alkaline matter.Optional in the precursor of inorganic acid, organic acid, strong acid weak base salt, weak acid and weak base salt or acidic materials one or several of its middle acid substance.Inorganic acid can be selected from hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, chloric acid, perchloric acid, bromic acid, hyperbromic acid, acid iodide, periodic acid, permanganic acid, hydrogen borate, the acid of hydrogen astatine, hydrogen telluric acid, the folded acid iodide of hydrogen, fluosilicic acid, chlorine plumbic acid, osmic acid, selenic acid, ferric acid, fluosulfonic acid, cyanic acid, thiocyanic acid, phosphoric acid, metaphosphoric acid, niter cake, sulfurous acid or nitrous acid.Organic acid is optional from picric acid, Jiao's property picric acid, trifluoroacetic acid, trichloroacetic acid, acetic acid, formic acid, methanesulfonic acid, benzene sulfonic acid, KMD acid, 2-chloroethene mercaptan, ethanedioic acid, malonic acid, succinic acid, lactic acid, pyruvic acid, tartaric acid, malic acid, citric acid, benzoic acid, salicylic acid or caffeic acid.Common strong acid weak base salt is generally the strong acid salt of transition metal or the strong acid salt of amine substance, such as aluminium chloride, iron chloride, aluminum sulfate, iron sulfate, copper nitrate or ammonium chloride.The common weak acid and weak base salt that is acidity is such as ammonium formate, zinc acetate, Schweinfurt green.The precursor of acidic materials refers to can be converted into the material of acidic materials in solution, such as the chloride derivative of acid, such as succinyl chloride.Wherein alkaline matter can be selected from one or several in inorganic base, organic base, strong base-weak acid salt or the weak acid and weak base salt.Inorganic base can be selected from alkali-metal hydroxide, such as sodium hydroxide, potassium hydroxide etc., also can be selected from the hydroxide of alkaline earth metal, such as slaked lime, barium hydroxide, magnesium hydroxide etc., also can be selected from the hydroxide of transition metal, such as zinc hydroxide, iron hydroxide etc.Organic base is optional from nitrogen substance, such as ammoniacal liquor, diethanol amine, triethylamine, natural alkaloid etc.Common strong base-weak acid salt is such as sodium carbonate, sodium acetate, tertiary sodium phosphate, sodium citrate etc.The common weak acid and weak base salt that is alkalescence is such as carbonic hydroammonium, ammonium sulfite, triammonium phosphate.The combined optional of its middle acid substance and alkaline matter is from the combination of combination, weak acid and its conjugate base of weak acid and weak base salt such as ammonium citrate, strong acid weak base salt and strong base-weak acid salt.

Available chlorine provides one or more in double salt, chlorite or the available chlorine precursor substance that the unit can contain liquid chlorine, chlorine dioxide, hypochlorite, hypochlorite.Hypochlorite can be selected from one or more of clorox, calcium hypochlorite, bleaching powder, bleaching powder extraction, magnesium hypochlorite.The double salt of hypochlorite is such as Efficacious Disinfeitant (Na ₃PO ₄1/4NaOCl12H ₂O).Chlorite can be selected from sodium chlorite, calcium chlorite.The available chlorine precursor substance refers to can generate with acid or water reaction the chlorine-bearing compound of activated state available chlorine, and it provides stability in the unit to be higher than at pH value regulon, available chlorine at available chlorine and provides in the mixed liquor of unit, and the available chlorine precursor substance can be selected from one or more of sodium dichloro cyanurate, dichlord isocyanurice acid, sym-closene, toluene-sodium-sulfonchloramide, chlorate, perchlorate.

Available chlorine provides the unit to contain the available chlorine of stable form.The available chlorine of stable form refers to provide at available chlorine has better stability in the unit, can generate the chlorine-bearing compound of activated state available chlorine with acid or water reaction.Available chlorine provides that available chlorine content should guarantee that pH value regulon and available chlorine provide the available chlorine content in the unit mixed liquor to be not less than 3mg/L in the unit.

PH value regulon and available chlorine provide that available chlorine content is not less than 3mg/L in the unit mixed liquor, wherein are preferably 3-15000mg/L, are preferably 3-10000mg/L again, be preferably again 3-8000mg/L, more preferably 3-4000mg/L also is preferably 3-2000mg/L, most preferably is 3-1000mg/L.

It is neutral or alkaline solid or liquid that available chlorine provides the unit, and wherein the pH of liquid is preferably and is not less than 8, is preferably and is not less than 9, also is preferably and is not less than 10, is preferably again and is not less than 11, more preferably is not less than 12, most preferably is and is not less than 13.

Available chlorine provides the pH value of unit can pass through one or several controls of highly basic, middle highly basic, weak base or strong base-weak acid salt.Available chlorine provides the contained alkaline matter in unit can be selected from alkali-metal hydroxide, such as sodium hydroxide, potassium hydroxide etc., also can be selected from the hydroxide of alkaline earth metal, such as slaked lime, barium hydroxide, magnesium hydroxide etc., also can be selected from the hydroxide of transition metal, such as zinc hydroxide, iron hydroxide etc., also optional from nitrogen substance, such as ammoniacal liquor, diethanol amine, triethylamine etc., also optional from the highly basic salt of weak acid, such as sodium carbonate, sodium acetate, tertiary sodium phosphate, sodium citrate etc.

PH value regulon and available chlorine provide the pH value of unit mixed liquor between 2-8, wherein are preferably between 3-8, are preferably again between 4-8, are preferably between 5-8 again, most preferably are between 5-7.

PH value regulon and available chlorine provide the redox potential value of unit mixed liquor to be not less than 600mV, wherein are preferably 600-1500mV, are preferably 600-1300mV again, are preferably again 600-1200mV, most preferably are 600-1100mV.

PH value regulon and available chlorine provide the total content of halo acid ion in the unit mixed liquor not to be higher than 0.5mol/L, wherein be preferably and be not higher than 0.4mol/L, be preferably again and be not higher than 0.3mol/L, be preferably again and be not higher than 0.2mol/L, also be preferably and be not higher than 0.1mol/L, most preferably be and be not higher than 0.01mol/L.

Control XO ₃ ^-The method of (X=Cl, Br, I) content, one provides by adjusting pH value regulon, available chlorine that the volume of unit and inherent component are controlled pH value regulon, available chlorine provides the content of material in the unit mixed liquor; Its two, provide the preliminary treatment of unit by pH value regulon or (reaching) available chlorine, remove part XO ₃ ^-Ion; Its three, provide the post processing of unit mixed liquor by pH value regulon, available chlorine, remove part XO ₃ ^-Ion.

Described removal XO ₃ ^-The method of (X=Cl, Br, I) can be selected one or several of following method, to remove or masked segment XO ₃ ^-Ion.Can add XO ₃ ^-The ion deactivator is such as precipitating reagent-water-soluble silver ion, with XO ₃ ^-Ion forms the indissoluble thing, such as reductant-ferrous ion, with XO ₃ ^-Ion generation redox reaction; Also can utilize membrane separation process, such as reverse osmosis membrane, ion-selective membrane, filtration, ultrafiltration, nanofiltration; Also can utilize electrochemical process, such as electroosmose process, electrolysis; Also can utilize chromatography, absorption method or ion-exchange.Described electroosmose process refers to carry out dialysis under electric field action, utilizes the otherness of the charged solute particles (such as ion) in the solution to make the method for content of predetermined substance enrichment or reduction by film.

The solution that contains available chlorine is being removed part XO by said method ₃ ^-During ion, available chlorine has certain loss usually, and its content need to redeterminate.In order to reduce the loss of available chlorine, can select the fast processing mode; Also can select to process under the cryogenic conditions; Also ionic available chlorine can be transferred to molecule-type available chlorine (acidity), make it and ionic species (XO ₃ ^-) distinguish; Also can be with XO ₃ ^-Ion transfers water-insoluble derivative to, makes it with ionic active ingredient (such as, ClO ^-) distinguish.Remove purpose impurity (XO ₃ ^-) after, return to again the stable form of available chlorine or activate form.

Equally, the post processing meeting of sterilized water loss part available chlorine, but as long as suitably increase amount and the control percent of loss of available chlorine, the sterilized water that guarantees to process is at pH2-8, ORP 〉=600mV in the scope of ACC 〉=3mg/L, all can produce enough bactericidal effects.

The present invention is a kind of oxidizing potential sterilized water of low-corrosiveness also, the pH value of described sterilized water is between 2-8, its redox potential is not less than 600mV, its available chlorine content is not less than 3mg/L, the total content of its halo acid ion is not higher than 0.5mol/L, described halo acid ion be chloranion, bromate ion, iodate ion wherein one or more.

The pH value of sterilized water is 2-8, wherein is preferably between 3-8, is preferably again between 4-8, is preferably between 5-8 again, most preferably is between 5-7.

The control of its pH value, can be separately by acidic materials, alkaline matter control or by acidic materials and alkaline matter co-controlling, make the oxidizing potential sterilized water of low-corrosiveness contain one or several of inorganic acid, organic acid, inorganic base, organic base, strong acid weak base salt, strong base-weak acid salt, weak acid and weak base salt or strong acid and strong base salt.

Described acidic materials can be selected from one or several of precursor of inorganic acid, organic acid, strong acid weak base salt, weak acid and weak base salt or acidic materials.Inorganic acid can be selected from hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, chloric acid, perchloric acid, bromic acid, hyperbromic acid, acid iodide, periodic acid, permanganic acid, hydrogen borate, the acid of hydrogen astatine, hydrogen telluric acid, the folded acid iodide of hydrogen, fluosilicic acid, chlorine plumbic acid, osmic acid, selenic acid, ferric acid, fluosulfonic acid, cyanic acid, thiocyanic acid, phosphoric acid, metaphosphoric acid, niter cake, sulfurous acid or nitrous acid.Organic acid is optional from picric acid, Jiao's property picric acid, trifluoroacetic acid, trichloroacetic acid, acetic acid, formic acid, methanesulfonic acid, benzene sulfonic acid, KMD acid, 2-chloroethene mercaptan, ethanedioic acid, malonic acid, succinic acid, lactic acid, pyruvic acid, tartaric acid, malic acid, citric acid, benzoic acid, salicylic acid or caffeic acid.Common strong acid weak base salt is generally the strong acid salt of transition metal or the strong acid salt of amine substance, such as aluminium chloride, iron chloride, aluminum sulfate, iron sulfate, copper nitrate or ammonium chloride.The common weak acid and weak base salt that is acidity is such as ammonium formate, zinc acetate, Schweinfurt green.The precursor of acidic materials refers to can be converted into the material of acidic materials in solution, such as the chloride derivative of acid, such as succinyl chloride.

Described alkaline matter can be one or several of highly basic, middle highly basic, weak base, strong base-weak acid salt or weak acid and weak base salt.Described alkaline matter can be selected from alkali-metal hydroxide, such as sodium hydroxide, potassium hydroxide etc., also can be selected from the hydroxide of alkaline earth metal, such as slaked lime, barium hydroxide, magnesium hydroxide etc., also can be selected from the hydroxide of transition metal, such as zinc hydroxide, iron hydroxide etc., also optional from nitrogen substance, such as ammoniacal liquor, diethanol amine, triethylamine, natural alkaloid etc., also optional from the highly basic salt of weak acid, such as sodium carbonate, sodium acetate, tertiary sodium phosphate, sodium citrates etc. also can be selected from the weak acid and weak base salt that is alkalescence, such as carbonic hydroammonium, ammonium sulfite, triammonium phosphate.

Contained available chlorine can be by one or more generations of double salt, chlorite or the available chlorine precursor substance of liquid chlorine, chlorine dioxide, hypochlorite, hypochlorite.Hypochlorite can be selected from one or more of clorox, calcium hypochlorite, bleaching powder, bleaching powder extraction, magnesium hypochlorite.The double salt of hypochlorite can be selected from Efficacious Disinfeitant (Na ₃PO ₄1/4NaOCl12H ₂O).Chlorite can be selected from sodium chlorite, calcium chlorite.The available chlorine precursor substance refers to can generate with the reaction of acid or water the chlorine-bearing compound of activated state available chlorine, and the available chlorine precursor substance can be selected from one or more of sodium dichloro cyanurate, dichlord isocyanurice acid, sym-closene, toluene-sodium-sulfonchloramide, chlorate, perchlorate.

The available chlorine content of sterilized water is not less than 3mg/L, wherein is preferably 3-15000mg/L, is preferably 3-10000mg/L again, is preferably again 3-8000mg/L, and more preferably 3-4000mg/L also is preferably 3-2000mg/L, most preferably is 3-1000mg/L.

The redox potential value of sterilized water is not less than 600mV, wherein is preferably 600-1500mV, is preferably 600-1300mV again, is preferably again 600-1200mV, most preferably is 600-1100mV.

The total content of the halo acid ion of sterilized water is not higher than 0.5mol/L, wherein be preferably and be not higher than 0.4mol/L, be preferably again and be not higher than 0.3mol/L, be preferably again and be not higher than 0.2mol/L, also be preferably and be not higher than 0.1mol/L, most preferably be and be not higher than 0.01mol/L.

Describe the present invention in detail below in conjunction with embodiment, XO ₃ ^-Represent halo acid ion, ClO ₃ ^-Represent chloranion, BrO ₃ ^-Represent bromate ion, IO ₃ ^-Represent iodate ion.

First kind embodiment, pH value conditioning agent unit and nearly neutral available chlorine provide the unit:

Step 1, the preparation that configuration has certain acidity makes raw material A; Raw material A is measured an amount of volume or quality, and packing makes pH value regulon.

Step 2 prepares nearly neutral available chlorine preparation, makes raw material B, contains certain density available chlorine; Raw material B is measured a certain amount of, and packing makes available chlorine the unit is provided.

Step 3 during use, provides the unit to mix pH value regulon and available chlorine, makes the oxidizing potential sterilized water.

Embodiment 1: configuration 10L oxidizing potential sterilized water contains single halo acid ion.

Prepare different pH value regulons, (solution contains [XO in the A1-A4 unit ₃ ^-]=0mol/L):

Configuration phosphoric acid-buffer solution of sodium phosphate (pH7-8) is measured 10L, and can makes the A1 unit;

Configuration acetic acid-sodium acetate buffer solution (pH5-7) is measured 10L, and can makes the A2 unit;

Configuration lactic acid-sodium lactate buffer solution (pH3-5) is measured 10L, and can makes the A3 unit;

Configuration citric acid-sodium citrate buffer (pH2-3) is got 10L, and can makes the A4 unit.

Raw material B(sodium dichloro cyanurate, available chlorine 0.25g/g), preparing different available chlorine provides the unit, and (solid pharmaceutical preparation contains XO in the B1-B4 unit ₃ ^-〉=0mol):

Raw material B, weighing 0.12g, packing makes B1 unit (containing available chlorine 30mg);

Raw material B, weighing 1g adds 0.1mol sodium chlorate, fully disperses to mix, and packing makes B2 unit (containing available chlorine 0.25g);

Raw material B, weighing 2g adds the 0.5mol sodium bromate, fully disperses to mix, and packing makes B3 unit (containing available chlorine 0.5g);

Raw material B, weighing 3g adds the 1mol sodium iodate, fully disperses to mix, and packing makes B4 unit (containing available chlorine 0.75g).

Provide the unit to mix with available chlorine pH value regulon, make available chlorine that the unit dissolving is provided, make following 10L oxidizing potential sterilized water:

Electrolyzed oxidizing water	pH	ORP	ACC(mg/L)	[XO ₃ ^-]（mol/L）
					A1+B1	7.0-8.0	600-800	3	[XO ₃ ^-]=0
A2+B2	5.0-7.0	800-1000	25	[XO ₃ ^-]=[ClO ₃ ^-]=0.01
					A3+B3	3.0-5.0	1000-1100	50	[XO ₃ ^-]=[BrO ₃ ^-]=0.05
A4+B4	2.0-3.0	1100-1200	75	[XO ₃ ^-]=[IO ₃ ^-]=0.1

Embodiment 2: configuration 10L oxidizing potential sterilized water contains single halo acid ion.

Prepare different pH value regulons, (solution contains [XO in the A1-A3 unit ₃ ^-]＞0mol/L):

Configuration sodium hydroxide-sodium chlorate aqueous solution (pH7-7.5) is measured 10L, and can makes the A1 unit, wherein [ClO ₃ ^-] total content 0.2mol/L;

Configuration bromic acid-sodium bromate aqueous solution (pH4-7) is measured 10L, and can makes the A2 unit, wherein [BrO ₃ ^-] total content 0.3mol/L;

Configuration acid iodide-sodium iodate aqueous solution (pH2-4) is measured 10L,, can makes the A3 unit, wherein [IO ₃ ^-] total content 0.4mol/L.

Preparing different available chlorine provides the unit, and (solid pharmaceutical preparation contains [XO in the B1-B3 unit ₃ ^-]=0mol):

Sodium dichloro cyanurate 2g(available chlorine 0.5g), calcium hypochlorite 2.5g(available chlorine 0.5g), hybrid packed, make B1 unit (total available chlorine 1g);

Sodium dichloro cyanurate 4g(available chlorine 1g), Efficacious Disinfeitant 5g(available chlorine 0.5g), hybrid packed, make B2 unit (total available chlorine 1.5g);

Sodium dichloro cyanurate 6g(available chlorine 1.5g), calcium chlorite 2.5g(available chlorine 0.5g), hybrid packed, make B3 unit (total available chlorine 2g).

Electrolyzed oxidizing water	pH	ORP	ACC(mg/L)	[XO ₃ ^-]（mol/L）
					A1+B1	7-8	700-900	100	[XO ₃ ^-]=[ClO ₃ ^-]=0.2
A2+B2	4-7	900-1050	150	[XO ₃ ^-]=[BrO ₃ ^-]=0.3
					A3+B3	2-4	1050-1200	200	[XO ₃ ^-]=[IO ₃ ^-]=0.4

Embodiment 3: configuration 10L oxidizing potential sterilized water contains single halo acid ion.

Configuration sodium hydrate aqueous solution (0.8M) is measured 5L, and configuration chloric acid aqueous solution (0.8M) is measured 5L, and two kinds of solution mix, and make A1 unit (pH6-8), wherein [ClO ₃ ^-] total content 0.4mol/L;

Configuration aqueous sodium carbonate (0.44M) is measured 5L, and the configuration bromic acid aqueous solution (0.8M) is measured 5L, and two kinds of solution mix, and make A2 unit (pH5.0), wherein [BrO ₃ ^-] total content 0.4mol/L;

The configuration acid iodide aqueous solution (0.4M) adds sodium hydroxide and transfers to pH=3.0, measures 10L, and can makes A3 unit (pH3.0), wherein [IO ₃ ^-] total content 0.4mol/L.

Preparing different available chlorine provides the unit, and (solid pharmaceutical preparation contains XO in the B1-B3 unit ₃ ^-＞0mol):

Sodium dichloro cyanurate 2g(available chlorine 0.5g), sym-closene 5g(available chlorine 2g), potassium chlorate 1mol mixes, and packing makes B1 unit (total available chlorine 2.5g);

Sodium dichloro cyanurate 8g(available chlorine 2g), toluene-sodium-sulfonchloramide 4g(available chlorine 1g), potassium bromate 1mol mixes, and packing makes B2 unit (total available chlorine 3g);

Sodium dichloro cyanurate 8g(available chlorine 2g), dichlord isocyanurice acid 6g(available chlorine 1.5g), Potassiumiodate 1mol mixes, and packing makes B3 unit (total available chlorine 3.5g).

Electrolyzed oxidizing water	pH	ORP	ACC(mg/L)	[XO ₃ ^-]（mol/L）
					A1+B1	6-8	700-950	250	[XO ₃ ^-]=[ClO ₃ ^-]=0.5
A2+B2	4-6	900-1050	300	[XO ₃ ^-]=[BrO ₃ ^-]=0.5
					A3+B3	2-4	1050-1200	350	[XO ₃ ^-]=[IO ₃ ^-]=0.5

[0129]Embodiment 4: configuration 10L oxidizing potential sterilized water, contain 2 kinds of halo acid ions

Prepare different pH value regulons, the A1-A3 unit (contains [XO ₃ ^-]=0mol/L, A2-A8 are mixed acid solution):

Configuration aqueous sodium carbonate (pH7-7.5) is measured 9L, makes the A1 unit, contains [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH6-6.5) is measured 5L, and configuration aqueous sulfuric acid (pH6-6.5) is measured 4L, and two kinds of acid solutions are mixed, and make A2 unit (pH6-6.5), contain [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH=5) is measured 5L, and configuration aqueous citric acid solution (pH=6) is measured 4L, and two kinds of acid solutions are mixed, and make A3 unit (pH5-6), contain [XO ₃ ^-] 0mol/L.

Preparing different available chlorine provides the unit, and (High-pH solution contains [XO in the B1-B3 unit ₃ ^-]＞0mol/L):

Aqueous sodium hypochlorite solution (pH8.2, available chlorine 4g/L) is measured 1L, can, and sealing makes the B1 unit, contains [ClO ₃ ^-] 0.005mol/L, [BrO ₃ ^-] 0.005mol/L;

Aqueous sodium hypochlorite solution (pH8.2, available chlorine 4.5g/L) is measured 1L, can, and sealing makes the B2 unit, contains [ClO ₃ ^-] 0.025mol/L, [IO ₃ ^-] 0.025mol/L;

Aqueous sodium hypochlorite solution (pH8.2, available chlorine 5g/L) is measured 1L, can, and sealing makes the B3 unit, contains [BrO ₃ ^-] 0.05mol/L, [IO ₃ ^-] 0.05mol/L.

Provide the unit to mix with available chlorine pH value regulon, make following 10L oxidizing potential sterilized water:

Electrolyzed oxidizing water	pH	ORP：mV	ACC(mg/L)	[XO ₃ ^-]（mol/L）
					A1+B1	7-8	800-950	400	ClO ₃ ^-+BrO ₃ ^-=0.001
A2+B2	6-7	900-1000	450	ClO ₃ ^-+IO ₃ ^-=0.005
					A3+B3	5-6	950-1050	500	BrO ₃ ^-+IO ₃ ^-=0.01

Embodiment 5: configuration 10L oxidizing potential sterilized water, contain 2 kinds of halo acid ions

Prepare different pH value regulons, (mixed acid solution contains [XO in the A1-A3 unit ₃ ^-]＞0mol/L):

Configuration chloric acid aqueous solution (pH=4) is measured 5L, and the configuration zinc bromate aqueous solution (pH=5) is measured 5L, and two kinds of acid solutions are mixed, and make A1 unit (pH4-5), wherein [ClO ₃ ^-] total content 0.03mol/L, [BrO ₃ ^-] total content 0.02mol/L;

Configuration acetic acid aqueous solution (pH=4) is measured 5L, and configuration oxalic acid aqueous solution (pH=3.5) is measured 5L, and two kinds of acid solutions are mixed, and make A2 unit (pH3-4), wherein [ClO ₃ ^-] total content 0.02mol/L, [IO ₃ ^-] total content 0.08mol/L;

Configuration aqueous citric acid solution (pH=3) is measured 5L, and the configuration aluminium bromate aqueous solution (pH=2.5) is measured 5L, and two kinds of acid solutions are mixed, and make A3 unit (pH2-3), wherein [BrO ₃ ^-] total content 0.075mol/L, [IO ₃ ^-] total content 0.075mol/L.

Preparing different available chlorine provides the unit, and (solid pharmaceutical preparation contains XO in the B1-B3 unit ₃ ^-0mol):

Sym-closene, weighing 13.75g, packing makes B1 unit (total available chlorine 5.5g);

Sym-closene 10g(available chlorine 4g), calcium hypochlorite 10g(available chlorine 2g), to mix, packing makes B2 unit (total available chlorine 6g);

Sym-closene 10g(available chlorine 4g), Efficacious Disinfeitant 30g(available chlorine 3g), to mix, packing makes B3 unit (total available chlorine 7g).

Electrolyzed oxidizing water	pH	ORP：mV	ACC(mg/L)	[XO ₃ ^-]（mol/L）
					A1+B1	4-5	1000-1100	550	ClO ₃ ^-+BrO ₃ ^-=0.05
A2+B2	3-4	1050-1150	600	ClO ₃ ^-+IO ₃ ^-=0.1
					A3+B3	2-3	1100-1200	700	BrO ₃ ^-+IO ₃ ^-=0.15

Embodiment 6: configuration 10L oxidizing potential sterilized water, contain 2 kinds of halo acid ions

Prepare different pH value conditioning agents, (solution contains [XO in the A1-A3 unit ₃ ^-]＞0mol/L):

Configuration aluminium chlorate solution (pH=6-7) is measured 9.5L, makes A1 unit (pH=6-7), wherein [ClO ₃ ^-] total content 0.2mol/L;

Configuration acid iodide aluminum solutions (pH=5-6) is measured 5L, and configuration zinc iodate solution (pH=5) is measured 4.5L, and two kinds of acid solutions are mixed, and make A2 unit (pH=4-6), wherein [IO ₃ ^-] total content 0.3mol/L;

Configuration bromic acid solution (pH2-3) is measured 3L, and configuration citric acid solution (pH=3) is measured 2L, and configuration bromic acid ferrous solution (pH=2.5) is measured 4.5L, and three kinds of acid solutions are mixed, and make A3 unit (pH=3), wherein [BrO ₃ ^-] total content 0.4mol/L;

Preparing different available chlorine provides the unit, and (solution contains [XO in the B1-B3 unit ₃ ^-]＞0mol/L):

Liquor natrii hypochloritis (available chlorine 16g/L, pH8.2) is measured 0.5L, can, and sealing makes the B1 unit, wherein [BrO ₃ ^-] total content 0.2mol/L;

Liquor natrii hypochloritis (available chlorine 18g/L, pH8.2) is measured 0.5L, can, and sealing makes the B2 unit, wherein [ClO ₃ ^-] total content 0.3mol/L;

Liquor natrii hypochloritis (available chlorine 20g/L, pH8.2) is measured 0.5L, can, and sealing makes the B3 unit, wherein [IO ₃ ^-] total content 0.4mol/L.

Electrolyzed oxidizing water

pH

ORP：mV

ACC(mg/L)

[XO ₃ ^-]（mol/L）

[0162]?

A1+B1	6-8	800-1000	800	ClO ₃ ^-+BrO ₃ ^-=0.2
					A2+B2	4-6	950-1100	900	ClO ₃ ^-+IO ₃ ^-=0.3
A3+B3	2-4	1050-1200	1000	BrO ₃ ^-+IO ₃ ^-=0.4

Embodiment 7: configuration 10L oxidizing potential sterilized water, contain 2 kinds of halo acid ions

Configuration solution chlorate (pH6-7) is measured 5L, and configuration aluminium bromate solution (pH6-7) is measured 5L, and two kinds of solution mix, and make A1 unit (pH5-7), wherein [ClO ₃ ^-] total content 0.1mol/L, [BrO ₃ ^-] total content 0.1mol/L;

Configuration iodic acid solution (pH3-4) is measured 5L, and configuration zinc iodate solution (pH4-5) is measured 5L, and two kinds of solution mix, and make A2 unit (pH3-5), wherein [IO ₃ ^-] total content 0.3mol/L;

Configuration bromic acid-sodium iodide solution (pH2-2.5) is measured 10L, makes A3 unit (pH2-2.5), wherein [BrO ₃ ^-] total content 0.2mol/L, [IO ₃ ^-] total content 0.1mol/L.

Sym-closene 10g(available chlorine 4g), calcium chlorite 80g(available chlorine 16g), sodium bromate 3mol mixes, and packing makes B1 unit (total available chlorine 20g);

Sym-closene 25g(available chlorine 10g), toluene-sodium-sulfonchloramide 80g(available chlorine 20g), sodium chlorate 1mol, Potassiumiodate 1mol mixes, and packing makes B2 unit (total available chlorine 30g);

Sym-closene 50g(available chlorine 20g), dichlord isocyanurice acid 80g(available chlorine 20g), sodium bromate 1mol, Potassiumiodate 1mol mixes, and packing makes the B3 unit, (total available chlorine 40g).

Electrolyzed oxidizing water	pH	ORP：mV	ACC(mg/L)	[XO ₃ ^-]（mol/L）
					A1+B1	5-8	900-1100	2000	ClO ₃ ^-+BrO ₃ ^-=0.5
A2+B2	3-5	1100-1200	3000	ClO ₃ ^-+IO ₃ ^-=0.5
					A3+B3	2-3	1150-1250	4000	BrO ₃ ^-+IO ₃ ^-=0.5

Embodiment 8: configuration 10L oxidizing potential sterilized water, contain 3 kinds of halo acid ions

Dispose the aqueous solution of different pH, prepare different pH value conditioning agents, the A1-A8 unit:

Configuration diethylamine aqueous solution (pH7-7.5) is got 9L, makes the A1 unit, contains [XO ₃ ^-] 0mol/L;

Configuration hydracid-hydracid sodium solution (pH6-6.5) is got 9L, makes the A2 unit, wherein [ClO ₃ ^-] total content 0.02mol/L, [BrO ₃ ^-] total content 0.022mol/L, [IO ₃ ^-] total content 0.0135mol/L;

Configuration chloric acid-sodium chlorate solution (pH5-5.5) gets 9L, makes the A3 unit, contains [ClO ₃ ^-] 0.1mol/L;

Configuration hydracid-hydracid sodium solution (pH4-4.5) is got 10L, makes the A4 unit, wherein [ClO ₃ ^-] total content 0.1mol/L, [BrO ₃ ^-] total content 0.04mol/L, [IO ₃ ^-] total content 0.02mol/L;

Configuration hydracid-hydracid sodium solution (pH3-3.5) is got 10L, makes the A5 unit, wherein [ClO ₃ ^-] total content 0.1mol/L, [BrO ₃ ^-] total content 0.05mol/L, [IO ₃ ^-] total content 0.05mol/L;

Configuration hydracid-hydracid sodium solution (pH2-2.5) is got 10L, makes the A6 unit, wherein [ClO ₃ ^-] total content 0.1mol/L, [BrO ₃ ^-] total content 0.1mol/L, [IO ₃ ^-] total content 0.1mol/L;

Configuration hydracid-hydracid sodium solution (pH2-7) is got 10L, makes the A7 unit, wherein [BrO ₃ ^-] total content 0.2mol/L, [IO ₃ ^-] total content 0.1mol/L;

Configuration hydracid-hydracid sodium solution (pH2-7) is got 9L, makes the A8 unit, wherein [ClO ₃ ^-] total content 0.3mol/L, [IO ₃ ^-] total content 0.2mol/L.

Prepare different available chlorine unit B 1-B8 be provided:

Liquor natrii hypochloritis (available chlorine 50g/L, pH8.2) gets 1L,, can gets the B1 unit, wherein [ClO ₃ ^-] total content 0.05mol/L, [BrO ₃ ^-] total content 0.03mol/L, [IO ₃ ^-] total content 0.02mol/L;

Liquor natrii hypochloritis (available chlorine 60g/L, pH8.2) gets 1L, and can gets the B2 unit, contains [XO ₃ ^-] 0mol/L;

Liquor natrii hypochloritis (available chlorine 70g/L, pH8.2) gets 1L, and can gets the B3 unit, wherein [BrO ₃ ^-] total content 0.05mol/L, [IO ₃ ^-] total content 0.05mol/L;

Calcium hypochlorite 400g, potassium bromate 0.4mol, hybrid packed, get B4 unit (total available chlorine 80g);

Magnesium hypochlorite 450g, potassium chlorate 0.5mol, sodium iodate 0.5mol, hybrid packed, get B5 unit (total available chlorine 90g);

Bleaching powder, weighing 2kg adds sodium chlorate 0.5mol, potassium bromate 0.3mol, Potassiumiodate 0.2mol, mixes, and packing makes B6 unit (total available chlorine 100g);

Bleaching powder extraction, weighing 1.5kg adds sodium chlorate 1mol, potassium bromate 1mol, mixes, and packing makes B7 unit (total available chlorine 150g);

Liquor natrii hypochloritis (available chlorine 30mg/L, pH8.2) gets 1L, and can makes the B8 unit, wherein [BrO ₃ ^-] total content 0.5mol/L.

Provide the unit to mix with available chlorine pH value regulon, make available chlorine that the unit dissolving is provided, make following oxidizing potential sterilized water:

Electrolyzed oxidizing water	pH	ORP(mV)	ACC(mg/L)	[XO ₃ ^-]（mol/L）
					A1+B1	7-8	900-1000	5000	ClO ₃ ^-+BrO ₃ ^-+IO ₃ ^-=0.01

[0195]?

A2+B2	6-7	1000-1100	6000	ClO ₃ ^-+BrO ₃ ^-+IO ₃ ^-=0.05
					A3+B3	5-6	1050-1150	7000	ClO ₃ ^-+BrO ₃ ^-+IO ₃ ^-=0.1
A4+B4	4-5	1100-1200	8000	ClO ₃ ^-+BrO ₃ ^-+IO ₃ ^-=0.2
					A5+B5	3-4	1200-1300	9000	ClO ₃ ^-+BrO ₃ ^-+IO ₃ ^-=0.3
A6+B6	2-3	1300-1400	10000	ClO ₃ ^-+BrO ₃ ^-+IO ₃ ^-=0.4
					A7+B7	2-8	800-1400	15000	ClO ₃ ^-+BrO ₃ ^-+IO ₃ ^-=0.5
A8+B8	2-8	600-1100	3	ClO ₃ ^-+BrO ₃ ^-+IO ₃ ^-=0.5

Equations of The Second Kind embodiment, pH value regulon and alkaline available chlorine provide the unit:

Step 1, the certain acid preparation of configuration makes raw material A; Raw material A is measured an amount of volume or quality, and packing makes pH value regulon;

Step 2 prepares effective chlorinated product, makes raw material B, contains certain available chlorine; Raw material B is measured a certain amount of, adds an amount of alkaline matter, mixes, and packing makes available chlorine the unit is provided;

Embodiment 9: configuration 100L acid oxidation potential sterilized water (pH=2.0)

Dispose the aqueous hydrochloric acid solution of different pH, prepare different pH value regulons, the A1-A4 unit:

Configuration aqueous hydrochloric acid solution (pH=0) is measured 100L, makes the A1 unit, contains [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH=1) is measured 100L, makes the A2 unit, contains [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH=2) is measured 100L, makes the A3 unit, contains [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH=2) is measured 100L, makes the A4 unit, contains [XO ₃ ^-] 0mol/L.

Different solid available chlorine preparations, preparing different available chlorine provides the unit, the B1-B4 unit:

Calcium hypochlorite 1g(available chlorine 0.2g), Efficacious Disinfeitant 1g(available chlorine 0.1g), sodium hydroxide 99mol and hydracid potassium 50mol, hybrid packed, make B1 unit (total available chlorine 0.3g);

Calcium hypochlorite 5kg(available chlorine 1kg), calcium chlorite 2.5kg(available chlorine 0.5kg), sodium hydroxide 9mol and hydracid sodium 50mol mix, and packing makes B2 unit (total available chlorine 1500g);

Calcium hypochlorite 1g(available chlorine 0.2g), toluene-sodium-sulfonchloramide 0.4g(available chlorine 0.1g), to mix, packing makes B3 unit (total available chlorine 0.3g);

Calcium hypochlorite 2kg(available chlorine 0.4kg), dichlord isocyanurice acid 2.4kg(available chlorine 0.6kg), to mix, packing makes B4 unit (total available chlorine 1000g).

Electrolyzed oxidizing water	pH	ORP：mV	ACC(mg/L)	[XO ₃ ^-]
					A1+B1	2.0	1050	3	0.5mol/L
A2+B2	2.0	1400	15000	0.5mol/L
					A3+B3	2.0	1050	3	0mol/L
A4+B4	2.0	1350	10000	0mol/L

Embodiment 10: configuration 100L acid oxidation potential sterilized water (pH=4.0)

Dispose the aqueous hydrochloric acid solution of different pH, prepare different pH value regulons, the A1-A5 unit:

Configuration aqueous hydrochloric acid solution (pH=3) is measured 100L, makes the A4 unit, contains [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH=4) is measured 100L, makes the A5 unit, contains [XO ₃ ^-] 0mol/L.

Different solid available chlorine preparations, preparing different available chlorine provides the unit, the B1-B5 unit:

The calcium chlorite, weighing 1.5g adds sodium hydroxide 99.99mol and hydracid sodium 50mol, mixes, and packing makes B1 unit (total available chlorine 0.3g);

Calcium chlorite 2kg(available chlorine 400g), Efficacious Disinfeitant 5kg(available chlorine 500g), sodium hydroxide 9.99mol and hydracid sodium 50mol mix, and packing makes B2 unit (total available chlorine 900g);

Calcium chlorite 1g(available chlorine 0.2g), toluene-sodium-sulfonchloramide 0.4g(available chlorine 0.1g), sodium hydroxide 0.99mol mixes, and packing makes B3 unit (total available chlorine 0.3g);

Calcium chlorite 2kg(available chlorine 400g), dichlord isocyanurice acid 1.6kg(available chlorine 400g), sodium hydroxide 0.09mol mixes, and packing makes B4 unit (total available chlorine 800g);

Efficacious Disinfeitant, weighing 650g, the hydracid sodium of interpolation 5mol mixes, and packing makes B5 unit (total available chlorine 65g).

Electrolyzed oxidizing water	pH	ORP：mV	ACC(mg/L)	[XO ₃ ^-]
					A1+B1	4.0	990	3	0.5mol/L
A2+B2	4.0	1250	9000	0.5mol/L

[0228]?

A3+B3	4.0	990	3	0mol/L
					A4+B4	4.0	1250	8000	0mol/L
A5+B5	4.0	1080	650	0.05mol/L

Embodiment 11: configuration 100L acid oxidation potential sterilized water (pH=5-7)

Dispose the aqueous hydrochloric acid solution of different pH, prepare different pH value regulons, the A1-A6 unit:

Configuration aqueous hydrochloric acid solution (pH=4) is measured 100L, makes the A5 unit, contains [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH=5-6) is measured 100L, makes the A6 unit, contains [XO ₃ ^-] 0mol/L.

Different solid available chlorine preparations, preparing different available chlorine provides the unit, the B1-B6 unit:

Efficacious Disinfeitant 2g(available chlorine 0.2g), toluene-sodium-sulfonchloramide 0.4g(available chlorine 0.1g), sodium carbonate 57mol and hydracid potassium 50mol, hybrid packed, make B1 unit (total available chlorine 0.3g);

Efficacious Disinfeitant 3kg(available chlorine 0.3kg), dichlord isocyanurice acid 1.6kg(available chlorine 0.4kg), sodium carbonate 5.7mol and hydracid potassium 50mol mix, and packing makes B2 unit (total available chlorine 700g);

Toluene-sodium-sulfonchloramide, weighing 1.2g(available chlorine 0.3g), add sodium carbonate 0.57mol, to mix, packing makes B3 unit (total available chlorine 0.3g);

Toluene-sodium-sulfonchloramide 1.6kg(available chlorine 400g), dichlord isocyanurice acid 0.8kg(available chlorine 200g), sodium carbonate 0.057mol mixes, and packing makes B4 unit (total available chlorine 600g);

Dichlord isocyanurice acid, weighing 300g adds sodium carbonate 0.0057mol and hydracid potassium 0.1mol, mixes, and packing makes B5 unit (total available chlorine 75g);

Calcium hypochlorite 250g(available chlorine 50g), magnesium hypochlorite 100g(available chlorine 20g), barium hypochlorite 75g(available chlorine 15g), hydracid potassium 0.5mol mixes, and packing makes B6 unit (total available chlorine 85g).

Electrolyzed oxidizing water	pH	ORP：mV	ACC(mg/L)	[XO ₃ ^-]
					A1+B1	5-7	700-800	3	0.5mol/L

[0246]?

A2+B2	5-7	1100-1200	7000	0.5mol/L
					A3+B3	5-7	700-800	3	0mol/L
A4+B4	5-7	1100-1200	6000	0mol/L
					A5+B5	5-7	800-1000	750	0.001mol/L
A6+B6	5-7	800-1000	850	0.005mol/L

Embodiment 12: configuration 100L alkalescence oxidizing potential sterilized water (pH=7-8)

Dispose the aqueous solution of different pH, prepare different pH value regulons, the A1-A5 unit:

Configuration aqueous hydrochloric acid solution (pH=2) is measured 100L, makes the A2 unit, contains [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH=4) is measured 100L, makes the A3 unit, contains [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH=6) is measured 100L, makes the A4 unit, contains [XO ₃ ^-] 0mol/L;

Configuration diethylamine aqueous solution (pH=7-7.5) is got 100L, makes the A5 unit, contains [XO ₃ ^-] 0mol/L.

Calcium hypochlorite 0.5g(available chlorine 0.1g), Efficacious Disinfeitant 1g(available chlorine 0.1g), calcium chlorite 0.5g(available chlorine 0.1g), sodium carbonate 60mol and hydracid sodium 50mol mix, and packing makes B1 unit (total available chlorine 0.3g);

Calcium hypochlorite 1kg(available chlorine 0.2kg), Efficacious Disinfeitant 1kg(available chlorine 0.1kg), sodium dichloro cyanurate 0.8kg(available chlorine 0.2kg), sodium carbonate 0.6mol and hydracid sodium 50mol mix, and packing makes B2 unit (total available chlorine 500g);

Calcium hypochlorite 0.5g(available chlorine 0.1g), calcium chlorite 0.5g(available chlorine 0.1g), sym-closene 0.25g(available chlorine 0.1g), sodium carbonate 0.006mol mixes, and packing makes B3 unit (total available chlorine 0.3g);

Calcium hypochlorite 1kg(available chlorine 0.2kg), toluene-sodium-sulfonchloramide 0.4kg(available chlorine 0.1kg), dichlord isocyanurice acid 0.4kg(available chlorine 0.1kg), sodium carbonate 0.00006mol mixes, and packing makes B4 unit (containing available chlorine 400g);

Efficacious Disinfeitant 500g(available chlorine 50g), calcium chlorite 200g(available chlorine 40g), toluene-sodium-sulfonchloramide 20g(available chlorine 5g), hydracid sodium 10mol mixes, and packing makes B5 unit (total available chlorine 95g).

Electrolyzed oxidizing water	pH	ORP：mV	ACC(mg/L)	[XO ₃ ^-]
					A1+B1	7-8	600-700	3	0.5mol/L
A2+B2	7-8	1000-1100	5000	0.5mol/L
					A3+B3	7-8	600-700	3	0mol/L
A4+B4	7-8	1000-1100	4000	0mol/L
					A5+B5	7-8	700-1000	950	0.1mol/L

Embodiment 13: configuration 100L alkalescence oxidizing potential sterilized water (pH=8.0)

Configuration chloric acid aqueous solution (0.2M) gets 100L, makes pH value regulon.Prepare identical two parts, the A1-A2 unit.

Configuration aqueous hydrochloric acid solution (0.2M) is got 100L, makes pH value regulon.Prepare identical two parts, the A3-A4 unit.

Different solid available chlorine raw materials, preparing different available chlorine provides the unit, the B1-B4 unit:

Efficacious Disinfeitant 1g(available chlorine 0.1g), sodium dichloro cyanurate 0.4g(available chlorine 0.1g), sym-closene 0.25g(available chlorine 0.1g), sodium carbonate 13mol and hydracid potassium 30mol mix, and packing makes B1 unit (total available chlorine 0.3g);

Calcium chlorite 2.5kg(available chlorine 0.5kg), sodium dichloro cyanurate 2kg(available chlorine 0.5kg), toluene-sodium-sulfonchloramide 2kg(available chlorine 0.5kg), sodium carbonate 13mol and hydracid potassium 30mol mix, and packing makes B2 unit (total available chlorine 1.5kg);

Sym-closene 0.25g(available chlorine 0.1g), toluene-sodium-sulfonchloramide 0.4g(available chlorine 0.1g), dichlord isocyanurice acid 0.4g(available chlorine 0.1g), sodium carbonate 13mol mixes, and packing makes B3 unit (total available chlorine 0.3g);

Calcium hypochlorite 2kg(available chlorine 0.4kg), Efficacious Disinfeitant 5kg(available chlorine 0.5kg), calcium chlorite 2kg(available chlorine 0.4kg), sodium dichloro cyanurate 0.8kg(available chlorine 0.2kg), sodium carbonate 13mol mixes, packing makes B4 unit (total available chlorine 1.5kg).

Electrolyzed oxidizing water	pH	ORP：mV	ACC(mg/L)	[XO ₃ ^-]
					A1+B1	8.0	600	3	0.5mol/L
A2+B2	8.0	1090	15000	0.5mol/L
					A3+B3	8.0	600	3	0mol/L

[0272]?

A4+B4

8.0

1090

15000

0mol/L

Embodiment 14: configuration 10L acid oxidation potential sterilized water (pH=2.0)

Configuration aqueous hydrochloric acid solution (pH=1.7) is measured 5L, makes the A1 unit, contains [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH=1.7) is measured 5L, makes the A2 unit, contains [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH=1.0) is measured 5L, makes the A3 unit, contains [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH=0) is measured 5L, makes the A4 unit, contains [XO ₃ ^-] 0mol/L.

Prepare different available chlorine and provide the unit, the B1-B4 unit:

The liquor natrii hypochloritis, sodium carbonate is adjusted to pH8.1, measures 5L, can, sealing makes the B1 unit, contains available chlorine 6mg/L, [XO ₃ ^-] 1mol/L;

The liquor natrii hypochloritis, diethylamine is adjusted to pH8.1, measures 5L, can, sealing makes the B2 unit, contains available chlorine 6g/L, [XO ₃ ^-] 1mol/L;

The liquor natrii hypochloritis is measured 5L, adds sodium hydroxide 0.4mol(pH ≈ 12.90), can, sealing makes the B3 unit, contains available chlorine 6mg/L, [XO ₃ ^-] 0mol/L;

The liquor natrii hypochloritis is measured 5L, adds potassium hydroxide 4.9mol(pH ≈ 13.99), can, sealing makes the B4 unit, contains available chlorine 4g/L, [XO ₃ ^-] 0mol/L.

Electrolyzed oxidizing water	pH	ORP：mV	ACC(mg/L)	[XO ₃ ^-]
					A1+B1	2.0	1050	3	0.5mol/L
A2+B2	2.0	1255	3000	0.5mol/L
					A3+B3	2.0	1050	3	0mol/L
A4+B4	2.0	1235	2000	0mol/L

Embodiment 15: configuration 10L acid oxidation potential sterilized water (pH=5.0-7.0)

Dispose the hydrochloric acid solution of different pH, prepare different pH value regulons, the A1-A4 unit:

Configuration aqueous hydrochloric acid solution (pH=5-5.5) is measured 5L, makes the A1 unit, contains [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH=5-5.5) is measured 5L, makes the A2 unit, contains [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH=4) is measured 5L, makes the A3 unit, contains [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH=2) is measured 5L, makes the A4 unit, contains [XO ₃ ^-] 0mol/L.

Prepare different available chlorine and provide the unit, the B1-B4 unit:

The liquor natrii hypochloritis, sodium bicarbonate is adjusted to pH8.1, measures 5L, can, sealing makes the B1 unit, contains available chlorine 6mg/L, [XO ₃ ^-] 1mol/L;

The liquor natrii hypochloritis, sodium acetate is adjusted to pH8.1, measures 5L, can, sealing makes the B2 unit, contains available chlorine 2g/L, [XO ₃ ^-] 1mol/L;

The liquor natrii hypochloritis is measured 5L, adds sodium hydroxide 0.49mmol(pH ≈ 9.99), can, sealing makes the B3 unit, contains available chlorine 6mg/L, [XO ₃ ^-] 0mol/L;

The liquor natrii hypochloritis is measured 5L, adds sodium carbonate 0.0286mol, can, and sealing makes the B4 unit, contains available chlorine 1g/L, [XO ₃ ^-] 0mol/L.

Electrolyzed oxidizing water	pH	ORP：mV	ACC(mg/L)	[XO ₃ ^-]
					A1+B1	5-7	700-800	3	0.5mol/L
A2+B2	5-7	950-1050	1000	0.5mol/L
					A3+B3	5-7	700-800	3	0mol/L
A4+B4	5-7	900-1000	500	0mol/L

Embodiment 16: configuration 10L alkalescence oxidizing potential sterilized water (pH=7.0-8.0)

Dispose the aqueous solution of different pH, prepare different pH value regulons, the A1-A9 unit:

Configuration sodium hydroxide solution (pH=7-7.5) is got 5L, and configuration potassium hydroxide solution (pH=7-7.5) is got 4L, and two kinds of alkali lye mix, and make A1 unit (pH=7-7.5), contain [XO ₃ ^-] 0mol/L;

Configuration sodium hydroxide solution (pH=7-7.5) is got 5L, and configuration diethylamine solution (pH=7-7.5) is got 4L, and two kinds of alkali lye mix, and make A2 unit (pH=7-7.5), contain [XO ₃ ^-] 0mol/L;

Configuration sodium hydroxide solution (pH=7-7.5) is got 5L, and configuration sodium acetate solution (pH=7-7.5) is got 4L, and two kinds of alkali lye mix, and make A3 unit (pH=7-7.5), contain [XO ₃ ^-] 0mol/L;

Configuration triethylamine solution (pH=7-7.5) is got 5L, and configuration triethanolamine solution (pH=7-7.5) is got 4L, and two kinds of alkali lye mix, and make A4 unit (pH=7-7.5), contain [XO ₃ ^-] 0mol/L;

Configuration triethylamine solution (pH=7-7.5) is got 5L, and configuration sodium bicarbonate solution (pH=7-7.5) is got 4L, and two kinds of alkali lye mix, and make A5 unit (pH=7-7.5), contain [XO ₃ ^-] 0mol/L;

Configuration sodium carbonate liquor (pH=7-7.5) is got 5L, and configuration sodium acetate solution (pH=7-7.5) is got 4L, and two kinds of alkali lye mix, and make A6 unit (pH=7-7.5), contain [XO ₃ ^-] 0mol/L;

Configuration sodium hydroxide solution (pH=7-7.5) is got 4L, and configuration triethylamine solution (pH=7-7.5) is got 3L, and configuration sodium acetate solution (pH=7-7.5) is got 2L, and three kinds of alkali lye mix, and make A7 unit (pH=7-7.5), contain [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH=4) is measured 5L, makes the A8 unit, contains [XO ₃ ^-] 0mol/L;

Configuration aqueous hydrochloric acid solution (pH=2) is measured 5L, makes the A9 unit, contains [XO ₃ ^-] 0mol/L.

Prepare different available chlorine and provide the unit, the B1-B9 unit:

The liquor natrii hypochloritis, pH8.1 is measured 1L, can, sealing makes the B1 unit, contains available chlorine 30mg/L, [XO ₃ ^-] 1mol/L;

The liquor natrii hypochloritis, pH8.1 is measured 1L, can, sealing makes the B2 unit, contains available chlorine 300mg/L, [XO ₃ ^-] 0.1mol/L;

The liquor natrii hypochloritis, pH8.1 is measured 1L, can, sealing makes the B3 unit, contains available chlorine 35g/L, [XO ₃ ^-] 0.01mol/L;

The liquor natrii hypochloritis, pH8.1 is measured 1L, can, sealing makes the B4 unit, contains available chlorine 45g/L, [XO ₃ ^-] 1mmol/L;

The liquor natrii hypochloritis, pH8.1 is measured 1L, can, sealing makes the B5 unit, contains available chlorine 55g/L, [XO ₃ ^-] 0.1mmol/L;

The liquor natrii hypochloritis, pH8.1 is measured 1L, can, sealing makes the B6 unit, contains available chlorine 65g/L, [XO ₃ ^-] 0.01mmol/L;

The liquor natrii hypochloritis, pH8.1 is measured 1L, can, sealing makes the B7 unit, contains available chlorine 75g/L, [XO ₃ ^-] 0.001mmol/L;

The liquor natrii hypochloritis is measured 5L, adds sodium carbonate 0.0003mol, can, and sealing makes the B8 unit, contains available chlorine 17g/L, [XO ₃ ^-] 0mol/L;

The liquor natrii hypochloritis is measured 5L, adds sodium carbonate 0.03mol, can, and sealing makes the B9 unit, contains available chlorine 19g/L, [XO ₃ ^-] 1mol/L.

Electrolyzed oxidizing water	pH	ORP：mV	ACC(mg/L)	[XO ₃ ^-]
					A1+B1	7-8	600-700	3	100mmol/L
A2+B2	7-8	750-850	30	10mmol/L
					A3+B3	7-8	900-1000	3500	1mmol/L
A4+B4	7-8	900-1000	4500	0.1mmol/L
					A5+B5	7-8	1000-1100	5500	0.01mmol/L
A6+B6	7-8	1000-1100	6500	0.001mmol/L
					A7+B7	7-8	1000-1100	7500	0.0001mmol/L

[0322]?

A8+B8	7-8	1000-1100	8500	0mol/L
					A9+B9	7-8	1000-1100	9500	0.5mol/L

Embodiment 17: configuration 10L oxidizing potential sterilized water (pH=2.0-8.0)

Configuration chloric acid aqueous solution (0.02M) is measured 5L, can, and sealing makes pH value regulon, contains [ClO ₃ ^-] 0.02mol/L.Prepare 8 parts of identical pH value regulons.

Prepare different available chlorine and provide the unit, the B1-B8 unit:

The liquor natrii hypochloritis, sodium hydroxide is adjusted to pH=8.0, measures 5L, can, sealing makes the B1 unit, contains available chlorine 2.2g/L, [XO ₃ ^-] 0mol/L;

The sodium chlorite solution, sodium hydroxide is adjusted to pH=12.26, measures 5L, can, sealing makes the B2 unit, contains available chlorine 2.4g/L, [XO ₃ ^-] 0.08mol/L;

Stable ClO 2 solution, sodium hydroxide is adjusted to pH=12.30, measures 5L, can, sealing makes the B3 unit, contains available chlorine 2.6g/L, [XO ₃ ^-] 0.18mol/L;

Liquor natrii hypochloritis (available chlorine 2.8g/L) is measured 2.5L, and sodium chlorite (available chlorine 2.8g/L) is measured 2.5L, and both mix, and adds sodium carbonate 0.056mol, can, and sealing makes the B4 unit, contains available chlorine 2.8g/L, [XO ₃ ^-] 0.38mol/L;

Liquor natrii hypochloritis (available chlorine 3g/L) is measured 4L, and ClO 2 solution (available chlorine 3g/L) is measured 1L, and both mix, and adds sodium carbonate 0.058mol, can, and sealing makes the B5 unit, contains available chlorine 3g/L, [XO ₃ ^-] 0.58mol/L;

Sodium chlorite solution (available chlorine 3.2g/L) is measured 3L, and ClO 2 solution (available chlorine 3.2g/L) is measured 2L, and both mix, and adds sodium carbonate 0.06mol, can, and sealing makes the B6 unit, contains available chlorine 3.2g/L, [XO ₃ ^-] 0.78mol/L;

Liquor natrii hypochloritis (available chlorine 5g/L) is measured 2L, and sodium chlorite solution (available chlorine 3g/L) is measured 2L, ClO 2 solution (available chlorine 1g/L) is measured 1L, and the three mixes, and adds sodium carbonate 0.066mol, can, sealing makes the B7 unit, contains available chlorine 3.4g/L, [XO ₃ ^-] 0.98mol/L;

The liquor natrii hypochloritis, sodium hydroxide is adjusted to pH=7.0-12.30, measures 5L, can, sealing makes the B8 unit, contains available chlorine 30g/L, [XO ₃ ^-] 0.98mol/L.

Provide the unit to mix in every part of pH value regulon and different available chlorine, make following 10L oxidizing potential sterilized water:

Electrolyzed oxidizing water	pH	ORP：mV	ACC(mg/L)	[XO ₃ ^-]
					A+B1	2.0	1170	1100	0.01mol/L

[0336]?

A+B2	3.0	1130	1200	0.05mol/L
					A+B3	4.0	1080	1300	0.1mol/L
A+B4	5.0	1005	1400	0.2mol/L
					A+B5	6.0	980	1500	0.3mol/L
A+B6	7.0	955	1600	0.4mol/L
					A+B7	8.0	940	1700	0.5mol/L
A+B8	2.0-8.0	1050-1400	15000	0.5mol/L

Embodiment 18: configuration 10L oxidizing potential sterilized water

Organic acid is raw material, prepares different pH value regulons, the A1-A5 unit:

Citric acid solution (0.1M) is measured 9.5L, can, and sealing makes the A1 unit, contains [XO ₃ ^-] 0mol/L;

The tartaric acid powder takes by weighing 0.46mol, and the succinyl chloride solid takes by weighing 0.12mol, and hydracid sodium takes by weighing 1mol, mixes, and packing makes the A2 unit, contains XO ₃ ^-1mol;

Succinic acid solution (0.4M) is measured 10L, can, and sealing makes the A3 unit, contains [XO ₃ ^-] 0mol/L;

The citric acid powder takes by weighing 1mol, adds 3mol hydracid sodium, mixes, and packing makes the A4 unit, contains XO ₃ ^-3mol;

Acetic acid solution (pH2.0-3.0) is measured 9L, can, and sealing makes the A5 unit, contains [XO ₃ ^-] 0mol/L.

Different available chlorine are raw material, and preparing different available chlorine provides the unit, the B1-B5 unit:

The liquor natrii hypochloritis is measured 0.5L, adds sodium carbonate 0.6mol, can, and sealing makes the B1 unit, contains available chlorine 60mg/L, [XO ₃ ^-] 0mol/L;

The sodium chlorite solution, sodium hydroxide transfers to pH=13, measures 10L, can, sealing makes the B2 unit, contains available chlorine 30mg/L, [XO ₃ ^-] 0mol/L;

Calcium hypochlorite 5g(available chlorine 1g), Efficacious Disinfeitant 80g(available chlorine 8g), sodium dichloro cyanurate 20g(available chlorine 5g), sym-closene 10g(available chlorine 4g), sodium hydroxide 2mol and hydracid sodium 3mol, hybrid packed, make B3 unit (total available chlorine 18g);

Calcium hypochlorite 25g(available chlorine 5g), calcium chlorite 25g(available chlorine 5g), sym-closene 10g(available chlorine 4g) and, toluene-sodium-sulfonchloramide 20g(available chlorine 5g), hydracid sodium 2mol mixes, and packing makes B4 unit (total available chlorine 19g);

Liquor natrii hypochloritis (pH8.1) is measured 1L, can, and sealing makes the B5 unit, contains available chlorine 21g/L, [XO ₃ ^-] 0mol/L.

Provide the unit to mix with available chlorine pH value regulon, dissolving makes following 10L oxidizing potential sterilized water, and wherein A4 and B4 mixing monobasic are packed, perhaps independent packing, and A4/B4 is dissolved in the 10L water before using.

Electrolyzed oxidizing water	pH	ORP：mV	ACC(mg/L)	[XO ₃ ^-]
					A1+B1	7-8	600-700	3	0mol/L
A2+B2	5-7	800-1000	30	0.1mol/L
					A3+B3	3-5	1100-1200	1800	0.3mol/L
A4+B4	2-3	1150-1250	1900	0.5mol/L
					A5+B5	2-3	1150-1250	2100	0mol/L

Embodiment 19: the configuration nearly neutral oxidizing potential sterilized water of 10L (available chlorine content is 2200mg/L)

Acid solution (0.1M acetic acid, 0.02M bromic acid) is measured 9.8L, and can makes pH value conditioning agent unit: [XO ₃ ^-] 0.02mol/L.

Liquor natrii hypochloritis's (triethanolamine-sodium carbonate is adjusted to pH=12.51) is measured 0.2L, and packing makes available chlorine unit (available chlorine 110mg/ml, [XO are provided ₃ ^-] 0mol/L).

During use, provide the unit to mix with available chlorine pH value regulon, make 10L nearly neutral oxidizing potential sterilized water (pH6.97, ORP1070mV, ACC2200mg/L, [XO ₃ ^-] 0.0196mol/L).

Embodiment 20: configuration 1L oxidizing potential sterilized water

Strong acid weak base salt or acidic precursor are raw material, prepare different pH value regulons, the A1-A6 unit:

Ferric chloride solution (0.015M) is measured 0.9L, and can makes the A1 unit, contains [XO ₃ ^-] 0mol/L;

Aluminum chloride powder takes by weighing 0.005mol, and the succinyl chloride powder takes by weighing 0.0045mol, and sodium chlorate takes by weighing 0.05mol, and the three mixes, and packing makes the A2 unit, contains XO ₃ ^-0.05mol;

Solution of zinc sulfate (0.1M) is measured 1L, and can makes the A3 unit, contains [XO ₃ ^-] 0mol/L;

The copper chlorate powder takes by weighing 0.1mol, adds 0.1mol hydracid sodium, mixes, and packing makes the A4 unit, contains XO ₃ ^-0.3mol;

The succinyl chloride powder takes by weighing 0.05mol, and packing makes the A5 unit, contains XO ₃ ^-0mol;

The succinyl chloride powder takes by weighing 0.01mol, and the zinc chloride powder takes by weighing 0.02mol, and the citric acid powder takes by weighing 0.04mol, and sodium bromate takes by weighing 0.2mol, mixing, and packing makes the A6 unit, contains XO ₃ ^-0.2mol.

Different available chlorine are raw material, and preparing different available chlorine provides the unit, the B1-B6 unit:

The liquor natrii hypochloritis, sodium hydroxide transfers to pH=9, measures 0.1L, can, sealing makes the B1 unit, contains available chlorine 23g/L, [XO ₃ ^-] 0mol/L;

Sodium chlorite solution (pH=8.1) is measured 1L, can, and sealing makes the B2 unit, contains available chlorine 2.4g/L, [XO ₃ ^-] 0mol/L;

Calcium hypochlorite 5g(available chlorine 1g), sodium dichloro cyanurate 2g(available chlorine 0.5g), toluene-sodium-sulfonchloramide 2g(available chlorine 0.5g), dichlord isocyanurice acid 2g(available chlorine 0.5g), sodium carbonate 0.099mol and sodium chlorate 0.2mol mix, packing makes B3 unit (total available chlorine 2.5g);

Efficacious Disinfeitant 6g(available chlorine 0.6g), calcium chlorite 5g(available chlorine 1g), sodium dichloro cyanurate 2g(available chlorine 0.5g), toluene-sodium-sulfonchloramide 2g(available chlorine 0.5g), sodium carbonate 0.1mol and sodium iodate 0.2mol mix, packing makes B4 unit (total available chlorine 2.6g);

The liquor natrii hypochloritis, sodium hydroxide transfers to pH=11, measures 1L, can, sealing makes the B5 unit, total available chlorine 2.7g/L, [XO ₃ ^-] 0mol/L;

Efficacious Disinfeitant 9g(available chlorine 0.9g), sodium dichloro cyanurate 4g(available chlorine 1g), sym-closene 1g(available chlorine 0.4g), toluene-sodium-sulfonchloramide 2g(available chlorine 0.5g), sodium bromate 0.3mol mixes, packing makes B6 unit (total available chlorine 2.8g).

Provide the unit to mix with available chlorine pH value regulon, dissolving makes following oxidizing potential sterilized water.Wherein A4 and B4 mixing monobasic are packed, and perhaps independent packing is dissolved in A4/B4 in the 1L water during use; A6 and B6 mixing monobasic packing, perhaps independent packing is dissolved in A6/B6 in the 1L water during use.

Electrolyzed oxidizing water	pH	ORP：mV	ACC(mg/L)	[XO ₃ ^-]
					A1+B1	2-3	1150-1250	2300	0mol/L
A2+B2	3-5	1050-1150	2400	0.05mol/L
					A3+B3	5-7	1000-1100	2500	0.2mol/L
A4+B4	7-8	950-1050	2600	0.5mol/L
					A5+B5	2-8	800-1300	2700	0mol/L
A6+B6	2-8	800-1300	2800	0.5mol/L

The insoluble matters such as carbonate that calcium sulphate, transition metal are arranged in the system, but the characteristic of its available chlorine, pH, ORP do not affected.Because hydrionic generation is step-by-step procedure in the mixed liquor, so the pH of system is a process that changes, after system transfers pH2-8 to, bactericidal property that can guarantee system.

Embodiment 21: preparation 10L oxidizing potential sterilized water

The zinc citrate pressed powder, weighing 1mol makes pH value regulon;

Calcium chlorite 30mg(available chlorine 6mg), sym-closene 10mg(available chlorine 4mg), toluene-sodium-sulfonchloramide 40mg(available chlorine 10mg) and, dichlord isocyanurice acid 40mg(available chlorine 10mg), mix, make available chlorine unit (total available chlorine 30mg) is provided;

PH value regulon provides unit mixing monobasic packing or independent binary packing with available chlorine.

Before the use, above-mentioned substance is dissolved in 10L water, behind the pH of solution≤8.0, makes oxidizing potential sterilized water (pH2-8, ORP 〉=600mV, ACC3mg/L, [XO ₃ ^-] 0mol/L).

Embodiment 22: preparation 10L oxidizing potential sterilized water

The zinc chlorate powder, weighing 0.5mol makes pH value regulon;

Sodium dichloro cyanurate 40g(available chlorine 10g), sym-closene 10g(available chlorine 4g), toluene-sodium-sulfonchloramide 40g(available chlorine 10g), dichlord isocyanurice acid 20g(available chlorine 5g), sodium acetate 1mol mixes, and makes available chlorine unit (total available chlorine 29g) is provided;

Before the use, above-mentioned substance is dissolved in 10L water, behind the pH of solution≤8.0, makes oxidizing potential sterilized water (pH2-8, ORP 〉=900mV, ACC2900mg/L, [XO ₃ ^-] 0.1mol/L).

Embodiment 23: preparation 10L oxidizing potential sterilized water

Zinc bromate powder 2mol, sodium acetate powder 4mol mixes, and makes pH value regulon;

Calcium hypochlorite 100g(available chlorine 20g), Efficacious Disinfeitant 200g(available chlorine 20g), calcium chlorite 100g(available chlorine 20g), sodium dichloro cyanurate 80g(available chlorine 20g), sym-closene 50g(available chlorine 20g), potassium bromate 1mol mixes, and makes available chlorine unit (total available chlorine 100g) is provided;

Before the use, above-mentioned substance is dissolved in 10L water, behind the pH of solution≤8.0, makes oxidizing potential sterilized water (pH2-8, ORP 〉=1000mV, ACC10000mg/L, [XO ₃ ^-] 0.5mol/L).

Embodiment 24: configuration 10L oxidizing potential sterilized water (available chlorine content is 3100mg/L)

Raw material A, the niter cake powder takes by weighing 0.2mol.

Raw material B, calcium hypochlorite 25g(available chlorine 5g), Efficacious Disinfeitant 70g(available chlorine 7g), calcium chlorite 25g(available chlorine 5g), sodium dichloro cyanurate 20g(available chlorine 5g), sym-closene 10g(available chlorine 4g), toluene-sodium-sulfonchloramide 20g(available chlorine 5g), mix (total available chlorine 31g).

After above-mentioned substance and 1mol anhydrous sodium sulfate, 3mol Potassiumiodate fully mixed, packing.

During use, above-mentioned composition is dissolved in the 10L water, dissolving behind the pH of solution≤8.0, makes 10L oxidizing potential sterilized water (pH2-8, ORP900-1300mV, ACC3100mg/L, [XO ₃ ^-] 0.3mol/L).

Embodiment 25: configuration 10L acid oxidation potential sterilized water (available chlorine content is 3200mg/L)

Raw material A: nitrous acid aqueous solution (pH=3.0), measure 10L, can, sealing gets pH value regulon, [XO ₃ ^-] 0mol/L.

Raw material B, calcium hypochlorite 35g(available chlorine 7g), calcium chlorite 30g(available chlorine 6g), sodium dichloro cyanurate 20g(available chlorine 5g), sym-closene 10g(available chlorine 4g), toluene-sodium-sulfonchloramide 20g(available chlorine 5g), dichlord isocyanurice acid 20g(available chlorine 5g), ammonium chlorate 3mol, above-mentioned substance is hybrid packed, make available chlorine unit (total available chlorine 32g, XO are provided ₃ ^-3mol).

During use, provide the unit to mix with available chlorine pH value regulon, make 10L oxidizing potential sterilized water (pH3-7, ORP900-1250mV, ACC3200mg/L, [XO ₃ ^-] 0.3mol/L).

Embodiment 26: configuration 1000L highly acid oxidizing potential sterilized water (available chlorine content is 3300mg/L)

Raw material A, electrolysis produces acidic oxidized electric potential water (pH2-3, ACC decomposes rapidly), measures 1000L, can, sealing makes pH value regulon, [XO ₃ ^-] 0mol/L.

Raw material B, calcium hypochlorite 3kg(available chlorine 0.6kg), Efficacious Disinfeitant 2kg(available chlorine 0.2kg), calcium chlorite 3kg(available chlorine 0.6kg), sodium dichloro cyanurate 2kg(available chlorine 0.5kg), sym-closene 1kg(available chlorine 0.4kg), toluene-sodium-sulfonchloramide 2kg(available chlorine 0.5kg), dichlord isocyanurice acid 2kg(available chlorine 0.5kg), sodium chlorate 400mol, above-mentioned substance is hybrid packed, makes available chlorine unit (total available chlorine 3.3kg) is provided.

During use, provide the unit to mix with available chlorine pH value regulon, make 1000L oxidizing potential sterilized water (pH2-3, ORP1100-1300mV, ACC3300mg/L, [XO ₃ ^-] 0.4mol/L).

Embodiment 27: configuration 1L acid oxidation potential sterilized water (available chlorine content is 50mg/L)

Raw material A: hydrochloric acid solution (pH2-3), measure 1L, independent packaging.

Raw material B: chlorine/nitrogen mixture, can amount 5ml, available chlorine 50mg, independent high sealing packing.

During use, under the airtight condition, raw material B is added raw material A mix, make 1L acid oxidation potential sterilized water (pH2-3, ORP1100-1200mV, ACC50mg/L, [XO ₃ ^-] 0mol/L).

Embodiment 28: configuration 10L acid oxidation potential sterilized water (available chlorine content is 500mg/L)

Raw material A: hydrochloric acid solution (3M), measure 15ml, independent corrosion-proof packing.

Raw material B: sodium chlorate solution (2.5M, sodium carbonate is adjusted to pH=8), measure 10ml, independent corrosion-proof packing, [XO ₃ ^-] 2.5mol/L.

During use, after A, the mixing of B raw material, with the water dilution of 9.975L, make 10L acid oxidation potential sterilized water (pH2.5-3.5, ORP1100-1200mV, ACC500mg/L, [XO again ₃ ^-]＜0.5mol/L).

Embodiment 29: configuration 10L acid oxidation potential sterilized water (available chlorine content is 15000mg/L)

Raw material A: hydrochloric acid solution (4M), measure 1L, independent corrosion-proof packing.

Raw material B: the sodium perchlorate powder, take by weighing 0.6mol, add 1mol potassium nitrate, fully disperse to mix, independent corrosion-proof packing contains XO ₃ ^-0mol.

During use, after A, the mixing of B raw material, with the water dilution of 9L, make 10L acid oxidation potential sterilized water (pH2-8, ORP1000-1400mV, ACC15000mg/L, [XO again ₃ ^-] 0mol/L).

Embodiment 30: configuration 1L acid oxidation potential sterilized water (available chlorine content is 850mg/L)

Raw material A: hydrochloric acid solution (pH=0), measure 10ml, independent packaging.

Raw material B: liquor natrii hypochloritis's (potassium hydroxide is adjusted to pH=12.5), measure 10ml, independent packaging (available chlorine 85g/L, [XO ₃ ^-] 0mol/L).

A, B raw material are placed 0.98L water ([XO ₃ ^-] 1.02mmol/L) in, make 1L oxidizing potential sterilized water (pH2-3, ORP1100-1200mV, ACC850mg/L, [XO ₃ ^-] 0.001mol/L).

Embodiment 31: configuration 1000L highly acid oxidizing potential sterilized water (available chlorine content is 1000mg/L)

Raw material A: acidic aqueous solution 2000L(pH2-3, [XO ₃ ^-] 1mol/L).

The raw material A preliminary treatment

Method 1, raw material A adds water-soluble silver ion (2005mol), forms hydracid silver indissoluble thing, and filtrate is got in ultrafiltration, adjusts pH, obtains raw material A 1(pH2-3, [XO ₃ ^-]＜0.1mmol/L).

Method 2, raw material A add water-soluble ferrous ion (2000mol), and the reduction halo acid ion is adjusted pH, obtains raw material A 2(pH2-3, [XO ₃ ^-]＜0.1mol/L).

Method 3, raw material A is analysed post by resinbed, and efflux by ion-selective membrane, is removed part XO under certain electric field ₃ ^-, adjust pH, obtain raw material A 3(pH2-3, [XO ₃ ^-]＜0.05mol/L).

Method 4, raw material A is analysed post by active carbon adsorption column and resinbed, removes part XO ₃ ^-, adjust pH, obtain raw material A 4(pH2-3, [XO ₃ ^-]＜0.5mmol/L).

Method 5, raw material A are by NF membrane, and controlled condition is removed part XO ₃ ^-, filtrate is adjusted pH, obtains raw material A 5(pH2-3, [XO ₃ ^-]＜0.3mol/L).

Method 6, raw material A by ion-selective membrane, are removed part XO through electrodialysis under certain electric field ₃ ^-, adjust pH, obtain raw material A 6(pH2-3, [XO ₃ ^-]＜0.5mol/L).

Measure respectively each 1000L of raw material A 1-A6, can gets pH value regulon A1-A6.

Raw material B: sodium dichloro cyanurate powder (available chlorine 0.25g/g), take by weighing 4kg, packing gets available chlorine unit B (available chlorine 1000g) is provided.Prepare identical available chlorine 6 parts of unit B are provided.

During use, provide unit B to mix with a available chlorine respectively pH value regulon A1-A6, make following 1000L acid oxidation potential sterilized water.

Electrolyzed oxidizing water	pH	ORP：mV	ACC(mg/L)	[XO ₃ ^-]
					A1+B	2-3	1150-1250	1000	0.0001mol/L
A2+B	2-3	1150-1250	1000	0.1mol/L
					A3+B	2-3	1150-1250	1000	0.05mol/L
A4+B	2-3	1150-1250	1000	0.0005mol/L
					A5+B	2-3	1150-1250	1000	0.3mol/L
A6+B	2-3	1150-1250	1000	0.5mol/L

Above-mentioned acid oxidation potential sterilized water (A6+B) continues post processing

Method 1, sterilized water (A6+B) add gauge water dissolubility silver ion, make Ag ⁺: XO ₃ ^-Mol ratio be not less than 1:1, form precipitation, (5-10 ℃) nanofiltration obtains sterilized water 7(pH2-3, ORP1150-1250mV, ACC900mg/L, [XO under the low temperature ₃ ^-]＜0.1mmol/L).

Method 2, sterilized water (A6+B) is analysed post by charcoal absorption chromatography post and resinbed fast, removes part XO ₃ ^-, obtain sterilized water 8(pH2-3, ORP1150-1250mV, ACC800mg/L, [XO ₃ ^-]＜0.5mmol/L).

Method 3, (5-10 ℃) analyses post and NF membrane by resinbed fast under sterilized water (A6+B) low temperature, removes part XO ₃ ^-, obtain sterilized water 9(pH2-3, ORP1150-1250mV, ACC700mg/L, [XO ₃ ^-]＜1mmol/L).

Method 4, sterilized water (A6+B) by ion-selective membrane, are removed part XO through electrodialysis under certain electric field ₃ ^-, obtain sterilized water 10(pH2-3, ORP1150-1250mV, ACC700mg/L, [XO ₃ ^-]＜0.2mol/L).

The post processing meeting of sterilized water makes the available chlorine partial loss, but at pH2-8, ORP 〉=600mV in the scope of ACC 〉=3mg/L, all can produce enough bactericidal effects.

Embodiment 32: configuration 10L highly acid oxidizing potential sterilized water (available chlorine 500-1000mg/L)

Raw material A: the citric acid powder, weighing 1mol, packing gets pH value regulon A.Prepare identical pH value regulon A5 part.

Raw material B: available chlorine solution 100L(pH8.1, [ClO ₃ ^-] 0.8mol/L).

Raw material B preliminary treatment

Method 1, raw material B adds gauge water dissolubility silver ion, makes Ag ⁺: ClO ₃ ^-Mol ratio be not less than 1:1, form precipitation, (5-10 ℃) ultrafiltration under the low temperature, filtrate is adjusted pH again, obtains raw material B1(pH8.1, ACC950mg/L, [ClO ₃ ^-]＜0.1mmol/L).

Method 2, raw material B analyses post by resinbed fast, removes part ClO ₃ ^-, adjust pH, obtain raw material B2(pH8.1, ACC900mg/L, [ClO ₃ ^-]＜0.2mol/L).

Method 3, raw material B is (5-10 ℃) fast operating at low temperatures, adds first acticarbon, absorbed portion ClO ₃ ^-, active carbon is removed in then coarse filtration, again by NF membrane, and filtering part ClO ₃ ^-, obtain raw material B3(pH8.1, ACC700mg/L, [ClO ₃ ^-]＜1mmol/L).

Method 4, raw material B is fast by NF membrane, and controlled condition is removed part ClO ₃ ^-, adjust pH, obtain raw material B4(pH8.1, ACC800mg/L, [ClO ₃ ^-]＜0.2mol/L).

Method 5, the pH of raw material B is adjusted to 5.0-7.0, makes available chlorine be converted into molecular conformation, fast by ion-selective membrane, removes part ClO under certain electric field ₃ ^-, filtrate is adjusted pH again, obtains raw material B4(pH8.1, ACC700mg/L, [ClO ₃ ^-]＜0.5mol/L).

Through above-mentioned processing, available chlorine has certain loss, and its content need to redeterminate.

Raw material B1-B5 is respectively measured 10L, can, and sealing makes available chlorine unit B 1-B5 is provided.

During use, provide unit B 1-B5 to mix with a pH value regulon A respectively in available chlorine, make following 10L acid oxidation potential sterilized water.

Electrolyzed oxidizing water	pH	ORP：mV	ACC(mg/L)	[ClO ₃ ^-]
					A+B1	2-3	1150-1250	950	0.0001mol/L
A+B2	2-3	1150-1250	900	0.2mol/L
					A+B3	2-3	1150-1250	700	0.001mol/L
A+B4	2-3	1150-1250	800	0.2mol/L
					A+B5	2-3	1150-1250	700	0.5mol/L

Above-mentioned acid oxidation potential sterilized water (A+B5) continues post processing

Method 1, sterilized water (A+B5) add gauge water dissolubility silver ion, make Ag ⁺: ClO ₃ ^-Mol ratio be not less than 1:1, form precipitation, (5-10 ℃) fast nanofiltration obtains sterilized water 6(pH2-3, ORP1150-1250mV, ACC650mg/L, [ClO under the low temperature ₃ ^-]＜0.1mmol/L).

Method 2, sterilized water (A+B5) is analysed post by resinbed fast, removes part ClO ₃ ^-, efflux recovers the pH value, obtains sterilized water 7(pH2-3, ORP1150-1250mV, ACC600mg/L, [ClO ₃ ^-]＜0.1mol/L).

Method 3, (5-10 ℃) removes part ClO fast by NF membrane under sterilized water (A+B5) low temperature ₃ ^-, obtain sterilized water 8(pH2-3, ORP1150-1250mV, ACC600mg/L, [ClO ₃ ^-]＜0.15mol/L).

Method 4, sterilized water (A+B5) are removed part ClO fast by active carbon adsorption column ₃ ^-, obtain sterilized water 9(pH2-3, ORP1150-1250mV, ACC600mg/L, [ClO ₃ ^-]＜0.2mol/L).

Embodiment 33: configuration 100L acid oxidation potential sterilized water (available chlorine content 1000mg/L)

Raw material A: acid solution 100L(pH2-3, [BrO ₃ ^-] 0.55mol/L).

The raw material A preliminary treatment

Raw material A adds 56mol water-soluble silver ion, forms precipitation, and ultrafiltration membrance filter obtains raw material A 1(pH2-3, [BrO ₃ ^-] 1mmol/L).Measure 99L, can, sealing makes pH value regulon A, [BrO ₃ ^-] 1mmol/L.

Raw material B: liquor natrii hypochloritis 10L(pH8.1, [BrO ₃ ^-] 0.6mol/L).

Raw material B analyses post and active carbon adsorption column by resinbed fast, removes part BrO ₃ ^-, obtain raw material B1(pH8.1, ACC100mg/ml, [BrO ₃ ^-] 1mmol/L).Measure 1L, can, sealing makes available chlorine unit B is provided, [BrO ₃ ^-] 1mmol/L.

During use, provide unit B to mix with available chlorine pH value regulon A, make 100L oxidizing potential sterilized water (pH2-3, ORP1150-1250mV, ACC1g/L, [BrO ₃ ^-] 1mmol/L).

Embodiment 34: configuration 10L acid oxidation potential sterilized water (available chlorine content 1000mg/L)

Raw material A: aqueous acid (pH5-6), measure 9L, make pH value regulon, contain [IO ₃ ^-] 1mol/L.

Raw material B: liquor natrii hypochloritis (pH8.1, ACC10g/L, [IO ₃ ^-] 0.5mol/L), take by weighing 1L, make available chlorine the unit is provided, contain [IO ₃ ^-] 0.5mol/L.

During use, provide the unit to mix with available chlorine pH value regulon, make 10L height [IO ₃ ^-] oxidizing potential sterilized water (pH5-7, ACC1000mg/L, the ORP1000-1100mV, [IO of content ₃ ^-] 0.95mol/L).(5-10 ℃) removes part IO fast by ion-selective membrane and active carbon adsorption column under the above-mentioned sterilized water low temperature ₃ ^-, obtain low [IO ₃ ^-] sterilized water (pH5-7, ACC950mg/L, ORP1000-1100mV, [IO ₃ ^-] 2mmol/L).

Disinfection effect test: annotate, below experiment all (adds 0.3% organic chaff interference) and carries out under clean conditions.

Represent pyococcus in the bacterial propagule with staphylococcus aureus; Escherichia coli represent enteron aisle bacterium in the bacterial propagule; Pseudomonas aeruginosa represents in the hospital infection the bacterial propagule of normal separation; Staphylococcus albus represents airborne bacterium; Mycobacterium chelonei abscess subspecies representative Much's bacillus; Bacillus subtilis black variety gemma represents bacterial spore; Candida albicans and black-koji mould represent pathogenic fungus; Polyovirus-I type vaccine strain (Poliovirus-I) represents virus; Staphylococcus aureus (MRSA) and vancomycin-resistant enterococcus (VRE) with methicillin-resistant represent drug-fast bacteria; Vibrio parahemolyticus, Listeria monocytogenes represent the pathogenic bacteria in the aquatic products; The white diarrhea salmonella represents the bird pathogenic bacteria; Wheat stripe rust represents agriculture pathogenic bacteria.

Bactericidal assay 1 (suspension is quantitative), the oxidizing potential sterilized water is killed logarithm and time

Trial target 1, ACC3mg/L, pH8.0, ORP600mV, [ClO ₃ ^-] 0.5mol/L

Trial target 2, ACC3mg/L, pH8.0, ORP600mV, [BrO ₃ ^-] 0.5mol/L

Trial target 3, ACC3mg/L, pH8.0, ORP600mV, [IO ₃ ^-] 0.5mol/L

Trial target 4, ACC3mg/L, pH8.0, ORP600mV, [XO ₃ ^-] 0mol/L

Trial target 5, ACC3mg/L, pH7.0, ORP700mV, [XO ₃ ^-] 0mol/L

Trial target 6, ACC3mg/L, pH2.0, ORP1050mV, [ClO ₃ ^-] 0.5mol/L

Trial target 7, ACC3mg/L, pH2.0, ORP1050mV, [BrO ₃ ^-] 0.5mol/L

Trial target 8, ACC3mg/L, pH2.0, ORP1050mV, [IO ₃ ^-] 0.5mol/L

Trial target 9, ACC3mg/L, pH2.0, ORP1050mV, [XO ₃ ^-] 0mol/L

Kill logarithm referring to table 1 behind the trial target 1-9 effect 15min.

Kill logarithm behind table 1 15min action time

Bactericidal assay 2 (suspension is quantitative), the oxidizing potential sterilized water is killed logarithm and time

Trial target 1, ACC8000mg/L, pH8.0, ORP1050mV, [ClO ₃ ^-] 0.5mol/L

Trial target 2, ACC8000mg/L, pH8.0, ORP1050mV, [BrO ₃ ^-] 0.5mol/L

Trial target 3, ACC8000mg/L, pH8.0, ORP1050mV, [IO ₃ ^-] 0.5mol/L

Trial target 4, ACC8000mg/L, pH8.0, ORP1050mV, [XO ₃ ^-] 0mol/L

Trial target 5, ACC8000mg/L, pH7.0, ORP1100mV, [XO ₃ ^-] 0mol/L

Trial target 6, ACC8000mg/L, pH2.0, ORP1350mV, [ClO ₃ ^-] 0.5mol/L

Trial target 7, ACC8000mg/L, pH2.0, ORP1350mV, [BrO ₃ ^-] 0.5mol/L

Trial target 8, ACC8000mg/L, pH2.0, ORP1350mV, [IO ₃ ^-] 0.5mol/L

Trial target 9, ACC8000mg/L, pH2.0, ORP1350mV, [XO ₃ ^-] 0mol/L

Kill logarithm referring to table 2 behind the trial target 1-9 effect 0.5min.

Kill logarithm behind table 2 0.5min action time

Stability test

" disinfection technology standard (version in 2008) " middle three kinds of term of validity detection methods stipulating that the product of embodiment 1-3,9-13 is promulgated according to the Ministry of Public Health, the result shows that the term of validity surpasses 2 years.

The metal protection test, (with reference to " version disinfection technology standard in 2008 ")

Test material 1, copper, circle, diameter 24.00mm, thick 1.0mm, wearing a diameter is the 2.0mm aperture, the surface area total value is about 9.80cm ²Fineness is 6.

Test material 2, thimerosal, different [XO ₃ ^-] the oxidizing potential sterilized water of content.

Experimental group, test material 1 are removed attachment (fully deoil, fully the deoxidation layer is cleaned); Measure diameter, thickness, the aperture of sheet; 50 ℃ of dry 1h, weigh (as weight before the test); Hang in the 200ml test material 2, continue 72 hours, and regularly change thimerosal; Take out sheet metal, remove corrosion product, clean, 50 ℃ of dry 1h weigh.

The blank group, test material 1 repeats by above-mentioned steps, but soaks without disinfectant.And calculate its average weightless value.

According to following formula Calculation of corrosion rate:

R = \frac{8.76 \times 10^{7} \times (m - m_{t} - m_{k})}{S \times t \times d}

Wherein, R is corrosion rate, mm/a(millimeter/year); M is the front sheet metal weight of test, g; m _tFor testing rear sheet metal weight, g; m _kRemove the weightless value of corrosion product print for chemical treatment, g does not carry out the chemical scavenging processor in the test, leave out m during calculating in formula _kValue; S is the surface area total value of sheet metal, cm ²T is test period, h; D is metal material density, kg/m ³

Corrosion test 1 carries out corrosion test according to above-mentioned steps, the rate of corrosion data as shown in Figure 1, comparison diagram 1 data can be learnt: the solution system of pH=2-8, pH/[XO ₃ ^-] copper is had corrosivity.

Corrosion test 2 carries out corrosion test according to above-mentioned steps, the rate of corrosion data as shown in Figure 2, comparison diagram 2 data can be learnt: during pH=2.0, with the solution that does not contain available chlorine (ACC=0ppm) relatively, the introducing of available chlorine is with [XO ₃ ^-] synergy, affected solution to the copper corrosion characteristic.Simultaneously as can be known, at pH/ACC/[XO ₃ ^-] in the system, the ACC/[XO of different content during pH=2.0 ₃ ^-], metal is had similar etching characteristic, i.e. pH=2.0/[XO ₃ ^-During]＞0.5mol/L, the ACC system of different content all produces hop to corrosion of metal.

Corrosion test 3 carries out corrosion test according to above-mentioned steps, the rate of corrosion data as shown in Figure 3, comparison diagram 3 data can be learnt: during pH=8.0, with the solution that does not contain available chlorine (ACC=0ppm) relatively, the introducing of available chlorine is with [XO ₃ ^-] synergy, affected solution to the copper corrosion characteristic.Simultaneously as can be known, at pH/ACC/[XO ₃ ^-] in the system, the ACC/[XO of different content during pH=8.0 ₃ ^-], equally metal is had similar etching characteristic, i.e. pH=8.0/[XO ₃ ^-During]＞0.5mol/L, the ACC system of different content all produces hop to corrosion of metal.

Comparison diagram 2,3 as can be known, at pH/ACC/[XO ₃ ^-] in the system, during pH=2.0-8.0, the reduction of available chlorine reduces the corrosivity of system, and reduced the significance of hop.

Corrosion test 4 carries out corrosion test according to above-mentioned steps, the rate of corrosion data as shown in Figure 4, comparison diagram 4 data can be learnt: at pH/ACC/[XO ₃ ^-] in the system, during ACC=15000ppm, pH has similar etching characteristic, i.e. ACC=15000ppm/[XO at 2.0-8.0 to metal ₃ ^-During]＞0.5mol/L, pH all produces hop in the system of 2.0-8.0 to corrosion of metal.

Corrosion test 5 carries out corrosion test according to above-mentioned steps, the rate of corrosion data as shown in Figure 5, comparison diagram 5 data can be learnt: at pH/ACC/[XO ₃ ^-] in the system, during ACC=3ppm, pH has similar etching characteristic, i.e. ACC=3ppm/[XO to metal equally at 2.0-8.0 ₃ ^-During]＞0.5mol/L, pH all produces hop in the system of 2.0-8.0 to corrosion of metal.

Comparison diagram 4,5 as can be known, at pH/ACC/[XO ₃ ^-] in the system, during ACC 〉=3ppm, acid reduction reduces the corrosivity of system, and reduced the significance of hop.

Corrosion test 6-9 carries out corrosion test according to above-mentioned steps, rate of corrosion data such as Fig. 6-shown in Figure 9, and comparison diagram 6-Fig. 9 data can be learnt: (among the ACC 〉=3ppm), the order of corrosion activity is: ClO in the oxidisability system of pH=2-8 ₃ ^-＞BrO ₃ ^-＞IO ₃ ^-So different total XO that consist of of same amount ₃ ^-The corrosivity of ion, 100%ClO ₃ ^-The XO that consists of ₃ ^-＞100%BrO ₃ ^-The XO that consists of ₃ ^-＞100%IO ₃ ^-The XO that consists of ₃ ^-, 100%ClO ₃ ^-The XO that consists of ₃ ^-The ClO of＞different proportion ₃ ^-/ BrO ₃ ^-The XO that consists of ₃ ^-＞100%BrO ₃ ^-The XO that consists of ₃ ^-The BrO of＞different proportion ₃ ^-/ IO ₃ ^-The XO that consists of ₃ ^-＞100%IO ₃ ^-The XO that consists of ₃ ^-, 100%ClO ₃ ^-The XO that consists of ₃ ^-The ClO of＞different proportion ₃ ^-/ BrO ₃ ^-/ IO ₃ ^-The XO that consists of ₃ ^-＞100%IO ₃ ^-The XO that consists of ₃ ^-

Comparison diagram 6-9 as can be known, pH/ACC/[XO ₃ ^-] in the system, [the XO of same concentrations ₃ ^-], the difference of its composition and ratio makes system have different metal protections.[XO wherein ₃ ^-] fully by ClO ₃ ^-During composition, corrosivity is the strongest; [XO ₃ ^-] fully by IO ₃ ^-During composition, corrosivity is the most weak; [XO ₃ ^-] by the ClO of different proportion ₃ ^-/ BrO ₃ ^-/ IO ₃ ^-During composition, corrosivity is between between the above two.

Oxidizing potential sterilized water of the present invention can reduce corrosion of metal, thereby has enlarged range of application.Before use, pH value regulon and the available chlorine of oxidizing potential solution of the present invention provide the unit to deposit separately, in the time will using, provide the unit to mix pH value regulon and available chlorine again, solved the storage problem of oxidizing potential sterilized water, very easy to use.In the process of preparation oxidizing potential solution of the present invention, strengthened artificial controllability, can regulate according to the actual requirements pH value, available chlorine content and the redox potential of sterilized water.

More than disclosed only be several specific embodiments of the application, but the application is not limited thereto, the changes that any person skilled in the art can think of all should drop in the application's the protection domain.

Claims

1. the preparation method of the oxidizing potential sterilized water of a low-corrosiveness is characterized in that, may further comprise the steps:

(2) provide pH value regulon;

2. the preparation method of the oxidizing potential sterilized water of low-corrosiveness as claimed in claim 1, it is characterized in that, the pH value of described strong oxidizing property solution is between 5-7, its redox potential is 600-1100mV, its available chlorine content is 3-1000mg/L, and the total content of its halo acid ion is not higher than 0.01mol/L.

3. the preparation method of the oxidizing potential sterilized water of low-corrosiveness as claimed in claim 1 or 2 is characterized in that, described halo acid ion be chloranion, bromate ion, iodate ion wherein one or more.

4. the preparation method of the oxidizing potential sterilized water of low-corrosiveness as claimed in claim 1 is characterized in that, also comprises in step (1): provide the unit to reduce the preliminary treatment of the total content of halo acid ion to described available chlorine.

5. the preparation method of the oxidizing potential sterilized water of low-corrosiveness as claimed in claim 1 is characterized in that, also comprises in step (2): described pH value regulon is reduced the preliminary treatment of the total content of halo acid ion.

6. the preparation method of the oxidizing potential sterilized water of low-corrosiveness as claimed in claim 1, it is characterized in that, in step (3), also comprise: provide the mixed mixed liquor in unit to reduce the post processing of the total content of halo acid ion to described pH value regulon and described available chlorine.

7. such as the preparation method of the oxidizing potential sterilized water of claim 4 or 5 or 6 described low-corrosiveness, it is characterized in that the processing method of the total content of described reduction halo acid ion can be selected from one or several in adding halo acid ion deactivator, membrane separation process, electrochemical process, chromatography, absorption method or the ion-exchange.

8. the preparation method of the oxidizing potential sterilized water of low-corrosiveness as claimed in claim 1, it is characterized in that, described available chlorine provides one or more in double salt, chlorite or the available chlorine precursor substance that the unit contains liquid chlorine, chlorine dioxide, hypochlorite, hypochlorite, and described available chlorine precursor substance refers to can generate with acid or water reaction the chlorine-bearing compound of available chlorine.

9. the preparation method of the oxidizing potential sterilized water of low-corrosiveness as claimed in claim 1 is characterized in that, it is neutral or alkaline that described available chlorine provides the unit.

10. the preparation method of the oxidizing potential sterilized water of low-corrosiveness as claimed in claim 1 is characterized in that, described pH value regulon comprises the combination of acidic materials, alkaline matter or acidic materials and alkaline matter.

11. the oxidizing potential sterilized water of a low-corrosiveness is characterized in that, comprises that pH value regulon and the available chlorine of independent packing provides the unit before using; It is the preparation that contains available chlorine or can produce available chlorine that described available chlorine provides the unit, described pH value regulon with obtain strong oxidizing property solution after described available chlorine provides the unit to mix, the pH value of described strong oxidizing property solution is between 2-8, its redox potential is not less than 600mV, its available chlorine content is not less than 3mg/L, and the total content of its halo acid ion is not higher than 0.5mol/L.

12. the oxidizing potential sterilized water of low-corrosiveness as claimed in claim 11, it is characterized in that the pH value of described strong oxidizing property solution is between 5-7, its redox potential is 600-1100mV, its available chlorine content is 3-1000mg/L, and the total content of its halo acid ion is not higher than 0.01mol/L.

13. the oxidizing potential sterilized water such as claim 11 or 12 described low-corrosiveness is characterized in that, described halo acid ion be chloranion, bromate ion, iodate ion wherein one or more.

14. the oxidizing potential sterilized water of low-corrosiveness as claimed in claim 11, it is characterized in that, described available chlorine provides one or more in double salt, chlorite or the available chlorine precursor substance that the unit contains liquid chlorine, chlorine dioxide, hypochlorite, hypochlorite, and described available chlorine precursor substance refers to can generate with acid or water reaction the chlorine-bearing compound of available chlorine.

15. the oxidizing potential sterilized water of low-corrosiveness as claimed in claim 11 is characterized in that, it is neutral or alkaline that described available chlorine provides the unit.

16. the oxidizing potential sterilized water of a low-corrosiveness is characterized in that, the pH value of described sterilized water is between 2-8, and its redox potential is not less than 600mV, and its available chlorine content is not less than 3mg/L, and the total content of its halo acid ion is not higher than 0.5mol/L.

17. the oxidizing potential sterilized water of low-corrosiveness as claimed in claim 16, it is characterized in that the pH value of described sterilized water is between 5-7, its redox potential is 600-1100mV, its available chlorine content is 3-1000mg/L, and the total content of its halo acid ion is not higher than 0.01mol/L.

18. the oxidizing potential sterilized water such as claim 16 or 17 described low-corrosiveness is characterized in that, described halo acid ion be chloranion, bromate ion, iodate ion wherein one or more.

19. the oxidizing potential sterilized water of low-corrosiveness as claimed in claim 16, it is characterized in that, available chlorine in the described sterilized water is by one or more generations in double salt, chlorite or the available chlorine precursor substance of liquid chlorine, chlorine dioxide, hypochlorite, hypochlorite, and described available chlorine precursor substance refers to can generate with acid or water reaction the chlorine-bearing compound of available chlorine.