CN102976497B - 一种利用芽孢杆菌处理高难度有机废水的方法 - Google Patents
一种利用芽孢杆菌处理高难度有机废水的方法 Download PDFInfo
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- CN102976497B CN102976497B CN201110258437.1A CN201110258437A CN102976497B CN 102976497 B CN102976497 B CN 102976497B CN 201110258437 A CN201110258437 A CN 201110258437A CN 102976497 B CN102976497 B CN 102976497B
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- waste water
- genus bacillus
- anoxic reacter
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- CVTZKFWZDBJAHE-UHFFFAOYSA-N [N].N Chemical compound 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Abstract
本发明涉及高难度有机废水的处理方法，属于污水处理领域。是一种利用芽孢杆菌处理高浓度有机废水的方法，利用芽孢杆菌在缺氧、好氧工艺的基础上，处理高难度有机废水。该方法具有耐受有机物负荷能力强，耐高盐，耐高氨氮，耐酸，耐碱，耐高温低温等优点。通过向处理工艺系统中，投加芽孢杆菌，投加芽孢杆菌激活剂、固化剂和促进剂，控制其生长条件、生长参数，达到处理高浓度有机废水的目的。
Description
一种利用芽孢杆菌处理高难度有机废水的方法
技术领域
[0001] 本发明涉及一种利用芽孢杆菌处理高难度有机废水的方法，属于污水处理领域。技术背景
[0002] 近年来，随着经济的发展，环境污染问题越来越凸显出来，尤其是水污染问题。各种高难度有机废水，如垃圾渗滤液、化工废水、石化废水、焦化废水、制药废水等。这些高难度有机废水具有COD含量高，有机物成分复杂，高盐分，高氨氮等特点。是一类非常难处理的有机废水。
[0003]目前，就处理方法而言，大多数是沿用城市生活污水的处理方法，如活性污泥法等，另外还有膜处理技术也越来越多的应用于这类废水的处理中。这些处理方法在处理这类高难度有机废水中都存在有一定的问题。活性污泥法这类传统的污水处理方法，在处理这些高难度有机废水中，因有机负荷高，氨氮高，盐分高，会使普通微生物难以生长，活性污泥难以培养，难以持续运行。膜处理方法，处理这些废水，只是物理过滤，会产生大量浓水，浓水更加难以处理。另外，膜处理中膜污染严重，膜清洗和定期更换，都会造成处理成本很闻。 [0004] 高难度有机废水的处理需要寻求一种更加合理有效的处理方法。本发明是一种利用芽孢杆菌处理高难度有机废水的方法。
发明内容
[0005] 本发明是一种利用芽孢杆菌处理高难度有机废水的方法。本发明中的芽孢杆菌具有耐盐、耐高氨氮、耐酸及耐碱的特点。本发明中涉及一种利用芽孢杆菌处理高难度有机废水的方法，芽孢杆菌是枯草芽孢杆菌、蜡样芽孢杆菌、地衣芽孢杆菌、巨大芽孢杆菌和纳豆芽孢杆菌的有效组合，对芽孢杆菌的生长条件，生长参数控制以及生长载体都做了说明。
[0006] 本发明的利用芽孢杆菌处理高难度有机废水的具体步骤如下。
[0007] 系统连续进水5-10天时，废水进入反应器量达到设计总量的30%，将芽孢杆菌9投加至高浓度有机废水缺氧反应器I和好氧反应器2内。缺氧反应器I内设置搅拌器5和生物反应器4，生物反应器4的材质为PVDC和PVDF的混合材质，耐腐蚀，耐氧化，为微生物生长提供载体，好氧反应器2内通过鼓风机6、曝气装置7向污水中充氧，采取闷曝方式。好氧反应器2内污水回流至缺氧反应器1，回流比为1:1-3:1 ;
[0008] 系统连续进水10-15天时，废水进入反应器量达到设计总量的50%，向缺氧反应器
I投加激活剂MgOlO (0.5-1.0mg/L),向好氧反应器2内投加固化剂SiO2Il (l_5mg/L)，激活剂MgOlO刺激芽孢杆菌9生长，固化剂SiO2Il为芽孢杆菌9形成颗粒污泥提供晶核。好氧反应器2内污泥浓度达到1500mg/L，其中芽孢杆菌9含量约15%_18%。好氧反应器2缺氧反应器I内存在回流，回流比为3:1-5:1 ;
[0009] 系统连续进水15-20天时，废水进入反应器量达到设计总量的80%时，分别向缺氧反应器I和好氧反应器2内投加促进剂果酸12 (l_5mg/L)，促进芽孢杆菌9形成多种水解酶，降解废水中污染物。芽孢杆菌9快速增殖，缺氧反应器I中，在生物反应器4上形成生物膜，在好氧反应器2内形成以固化剂SiO2Il为晶核的颗粒污泥，好氧反应器2缺氧反应器I内存在回流，回流比为3:1-5:1 ;
[0010] 系统连续进水20-25天时，废水进入反应器量达到设计总量的100%，系统满负荷运行。经缺氧反应器I好氧反应器2反应后，污水进入沉淀池3进行沉淀，系统开始正常出水。好氧反应器2和缺氧反应器I内存在回流，回流比为3:1-6:1。
[0011] 沉淀池3内的污泥1/2回流至缺氧反应器1，另外一部分剩余污泥排出。
[0012] 在废水进入到缺氧反应器I和好氧反应器2进行处理过程中，维持进水pH值、温度和C/N比，无需调节。
[0013] 本发明涉及的污水处理方法与传统污水处理方法相比，具有以下优点:
[0014] 1.几种芽孢杆菌9的有效组合，充分发挥了各个菌种的优点，此类芽孢杆菌9具有耐受有机物负荷能力强，耐高盐，耐高氨氮，耐酸，耐碱，耐高温低温等优点。并且这几种芽孢杆菌9能够共生互利，充分发挥各自优势；
[0015] 2.本发明中的芽孢杆菌9无需利用传统方法扩大培养，可直接投加至高浓度有机废水，直接进行生化污泥培养；
[0016] 3.本发明 中生物反应器4具有较强的耐腐蚀，耐氧化等特点，为微生物生长提供良好的载体，尤其是为芽孢杆菌9的生长提供良好载体，形成生物膜，防止高效芽孢杆菌9的在系统中流失；
[0017] 4.本发明中，在芽孢杆菌9处理污水过程中，投加固化剂SiO2I1、激活剂MgOlO和促进剂果酸12，利于芽孢杆菌9增殖，形成优势菌群，在好氧反应器2内形成颗粒污泥；
[0018] 5.本发明中高效芽孢杆菌9 一次性投加后培养后，无需重复投加，并且剩余污泥产量小；
[0019] 6.本发明中的芽孢杆菌9形成芽孢后，具有一定粘附性，污泥沉降性好，出水水质好；
[0020] 7.本发明中利用高效芽孢杆菌9处理的高浓度有机废水，有机废水无需调整pH、温度，C/N比等水质条件。
附图说明
[0021] 附图1为利用芽孢杆菌处理高难度有机废水的工艺流程图
[0022] 其中附图1中由缺氧反应器1、好氧反应器2、沉淀池3、生物反应器4、搅拌器5、鼓风机6、曝气装置7、回流泵8、芽孢杆菌9、激活剂MgOlO、固化剂Si0211、促进剂果酸12几部分组成
Claims (5)
1.一种利用芽孢杆菌处理高难度有机废水的方法，其特征在于:芽孢杆菌是枯草芽孢杆菌、蜡样芽孢杆菌、地衣芽孢杆菌、巨大芽孢杆菌和纳豆芽孢杆菌的有效组合，具体步骤如下:系统连续进水5-10天时，废水进入反应器量达到设计总量的30%，将芽孢杆菌(9)投加至高浓度有机废水缺氧反应器(I)和好氧反应器(2)内，缺氧反应器(I)内设置搅拌器(5)和生物反应器(4)，好氧反应器(2)内通过鼓风机(6)、曝气装置(7)向污水中充氧，采取闷曝方式，好氧反应器(2)内污水回流至缺氧反应器(1)，回流比为1:1-3:1 ;系统连续进水10-15天时，废水进入反应器量达到设计总量的50%，向缺氧反应器(I)投加激活剂MgO( 10)0.5-1.0mg/L，向好氧反应器(2)内投加固化剂SiO2 (11) l_5mg/L，好氧反应器(2)内污泥浓度达到1500mg/L，其中芽孢杆菌(9)含量15%_18%，好氧反应器(2)缺氧反应器(I)内存在回流，回流比为3:1-5:1 ;系统连续进水15-20天时，废水进入反应器量达到设计总量的80%时，分别向缺氧反应器(I)和好氧反应器(2)内投加促进剂果酸(12) l_5mg/L，芽孢杆菌(9)快速增殖，缺氧反应器(I)中，在生物反应器(4)上形成生物膜，在好氧反应器(2)内形成以固化剂SiO2 (11)为晶核的颗粒污泥，好氧反应器(2)缺氧反应器(I)内存在回流，回流比为3:1-5:1 ;系统连续进水20-25天时，废水进入反应器量达到设计总量的100%，系统满负荷运行，经缺氧反应器(I)好氧反应器(2 )反应后，污水进入沉淀池(3 )进行沉淀，系统开始正常出水，好氧反应器(2)和缺氧反应器(I)内存在回流，回流比为3:1-6:1 ;沉淀池 (3)内的污泥1/2回流至缺氧反应器(1)，另外一部分剩余污泥排出。
2.根据专利要求I所述的一种利用芽孢杆菌处理高难度有机废水的方法，其特征在于:所述缺氧反应器(I)中的生物反应器(4)，其材质为PVDC和PVDF的混合材质，耐腐蚀，耐氧化，为微生物生长提供载体。
3.根据权利要求1所述的一种利用芽孢杆菌处理高难度有机废水的方法，其特征在于:废水进入反应器量达到设计总量的50%，在缺氧反应器(I)投加激活剂MgO(IO),向好氧反应器(2)内投加固化剂SiO2 (11)，激活剂MgO (10)刺激芽孢杆菌(9)生长，固化剂SiO2(11)为芽孢杆菌(9 )形成颗粒污泥提供晶核。
4.根据权利要求1所述的一种利用芽孢杆菌处理高难度有机废水的方法，其特征在于:在缺氧反应器(I)和好氧反应器(2)中，在反应器进水量达到设计进水量的80%时，投加促进剂果酸(12)，促进芽孢杆菌(9)形成多种水解酶，降解废水中污染物。
5.根据权利要求1所述的一种利用芽孢杆菌处理高难度有机废水的方法，在废水进入到缺氧反应器(I)和好氧反应器(2)进行处理过程中，维持进水pH值、温度和C/N比，无需调节。
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| CN105948242B (zh) * | 2016-06-23 | 2019-05-14 | 浙江微技环境修复工程有限公司 | 一种培养用于抗生素废水厌氧处理的生物膜的方法 |
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