CN102953186B - A kind of superhigh molecular weight polyethylene fibers dyeing apparatus and method thereof - Google Patents
A kind of superhigh molecular weight polyethylene fibers dyeing apparatus and method thereof Download PDFInfo
- Publication number
- CN102953186B CN102953186B CN201210367822.4A CN201210367822A CN102953186B CN 102953186 B CN102953186 B CN 102953186B CN 201210367822 A CN201210367822 A CN 201210367822A CN 102953186 B CN102953186 B CN 102953186B
- Authority
- CN
- China
- Prior art keywords
- molecular weight
- weight polyethylene
- polyethylene fibers
- superhigh molecular
- dyeing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Coloring (AREA)
Abstract
The present invention is a kind of dyeing apparatus, particularly a kind of superhigh molecular weight polyethylene fibers dyeing apparatus and method thereof.Comprise untreatment fiber bobbin spindle and the rear fiber package spindle of process, described untreatment fiber bobbin spindle is wound with superhigh molecular weight polyethylene fibers yarn, described superhigh molecular weight polyethylene fibers yarn enter successively feeding jockey pulley, feeding three-axis friction processor and after exporting jockey pulley and with process after fiber package spindle be wound around mutually.Carry out surface treatment and two warm carrier dyeing process.A kind of superhigh molecular weight polyethylene fibers dyeing apparatus and method compact conformation thereof, improve the concentration gradient of dyestuff inside and outside fiber, accelerates dyestuff contaminates, there is plasticization, the macromolecular chain of amorphous region is more prone to movable, reduces dyeing temperature, improves the adsorbance of fiber surface.
Description
Technical field
The present invention is a kind of dyeing apparatus, particularly a kind of superhigh molecular weight polyethylene fibers dyeing apparatus and method thereof.
Background technology
The polyethylene of prior art middle-molecular-weihydroxyethyl more than 1,000,000 becomes ultra-high molecular weight polyethylene, the ultra high molecular polyethylene fiber obtained by gel or gel spinning method has higher intensity, modulus, rigidity, its stronger per mass unit is 15 times of steel wire, higher than aramid fiber, the density of fiber is 0.96g/cm
3, can bubble through the water column, energy absorption is good, can be used for making high strength hawser, shellproof, anti-cutting articles for use, is widely used in the fields such as military affairs, guard, space flight, naval vessel hawser.
Due to ultra-high molecular weight polyethylene, to have molecular structure regular, symmetrical, nonpolar chain structure and extended-chain configuration, the feature such as chemical inertness, hydrophobic and surface crystallinity are high, make superhigh molecular weight polyethylene fibers pole not easily react with other materials, and dyestuff can not be painted with fiber-reactive; Simultaneously, the ultimate-use (limiting service) temperature of this fibrid is 100-130 DEG C, and its strength and modulus reduces with the rising for the treatment of temperature, and 150 DEG C can melt, DISPERSE DYES high-temperature pressure dyeing technique is unsuitable for the dyeing of this fiber, weakens the high-intensity performance that it has as functional fiber.Therefore, the dyeing of superhigh molecular weight polyethylene fibers becomes international a difficult problem.
Fibre technology center, Aichi, Japan industrial technology research institute three river and the great achievement chamber of commerce develop jointly out a kind of colouring method of ultra-high molecular weight polyethylene, namely use on organic solvent-soluble dyestuff and ethanol medium and contaminate superhigh molecular weight polyethylene fibers.Although the method solves superhigh molecular weight polyethylene fibers colouring problem, production application is subject to great restriction, cannot carry out suitability for industrialized production.
Chinese patent 201210081172.7, disclose a kind of production method of ultra-high molecular weight polyethylene colored fibers, it is characterized in that: first dried superhigh molecular weight polyethylene fibers put into high pressure dyeing cabin and close, then the carbon dioxide in carbon dioxide storage tank is pressurized to non-pneumatic also aneroid supercriticality, then by pump, the carbon dioxide under supercriticality is squeezed in dyestuff groove, make Co 2 supercritical fluid dissolving dye, then deliver in high pressure dyeing cabin and contact with superhigh molecular weight polyethylene fibers, dye to superhigh molecular weight polyethylene fibers, superhigh molecular weight polyethylene fibers after dyeing carries out super times hot gas spring again, rolling, warehouse-in, described carbon dioxide enters separator with remaining dyestuff and is separated, collect reuse respectively.This structure dyeing effect is unoutstanding, and colouring method is relatively loaded down with trivial details simultaneously.
Summary of the invention
The present invention mainly solves the deficiencies in the prior art, compact conformation, on the basis of dispersion dyeing, adopt carrier dyeing method, to under superhigh molecular weight polyethylene fibers surface-treated prerequisite, use DISPERSE DYES upper superhigh molecular weight polyethylene fibers dyeing apparatus and the method thereof contaminating fiber at a lower temperature that molecular structure is less.
Above-mentioned technical problem of the present invention is mainly solved by following technical proposals:
A kind of superhigh molecular weight polyethylene fibers dyeing apparatus, comprise untreatment fiber bobbin spindle and the rear fiber package spindle of process, described untreatment fiber bobbin spindle is wound with superhigh molecular weight polyethylene fibers yarn, described superhigh molecular weight polyethylene fibers yarn enter successively feeding jockey pulley, feeding three-axis friction processor and after exporting jockey pulley and with process after fiber package spindle be wound around mutually.
A kind of superhigh molecular weight polyethylene fibers colouring method, carries out according to the following steps:
(1), surface treatment:
The method of high speed machine friction is adopted to carry out surface treatment to superhigh molecular weight polyethylene fibers, superhigh molecular weight polyethylene fibers is entered feeding three-axis friction processor, the friction rotating speed of feeding three-axis friction processor is 8000 ~ 12000 revs/min, the fraction time of feeding three-axis friction processor is 0.1 ~ 0.2 second, be 1.5 ~ 2.5mm with the spacing of superhigh molecular weight polyethylene fibers in feeding three-axis friction processor, superhigh molecular weight polyethylene fibers surface is unfavorable for that the high density crystallizing layer of dye diffusion is evenly peeled off by feeding three-axis friction processor, etching is produced to superhigh molecular weight polyethylene fibers surface simultaneously, the degree of depth of etching is about 2um ~ 5um, the area of etching accounts for 80% ~ 90% of fiber surface area, , to increase superhigh molecular weight polyethylene fibers dyeing contact area, for follow-up dyeing creates favorable conditions, the tension force of feeding jockey pulley controls at 100g ~ 250g, the tension force exporting jockey pulley is about 6g ~ 90g,
(2), dyeing carrier configuration:
By methyl naphthalene system and o-phenyl phenol system dyeing carrier, 9:1 is fully emulsified in water in proportion, and dyeing carrier total amount is 10g/L, and emulsification rotating speed controls as 2000r/min, and the time of normal temperature emulsification is 10 ~ 15min, until emulsion presents light blueness;
(3), two temperature carrier dyeing:
Get the dispersant NN0 of 1g/L and paregal O respectively as dyeing dispersant and levelling agent, be 5 ~ 6 by formic acid adjust ph, get the emulsion 1.5g/L configured in step (2), then add water, make dye bath ratio maintain 1:30, form mixing dye liquor; Mixing dye liquor and superhigh molecular weight polyethylene fibers cheese are put into yarn package dyeing machine, starts the dyeing that heats up, elevate the temperature to 95 DEG C with the heating rate of 2 DEG C/min, and be incubated 15 minutes; Elevate the temperature to 125 DEG C with the heating rate of 2 DEG C/min again, be incubated 30 minutes; Be down to room temperature with the rate of temperature fall of 2.5 DEG C/min, then take out superhigh molecular weight polyethylene fibers cheese, wash, the time of washing is 15min, then in the air dry oven of 90 DEG C, dries 2h.
Superhigh molecular weight polyethylene fibers yarn is drawn from untreated fiber package spindle, be introduced into feeding jockey pulley, then be fed to three-axis friction processor and carry out fiber surface friction treatment, then after delivering to process by output jockey pulley, silvalin bobbin spindle is wound into shape.By the speed difference regulating feeding jockey pulley and export between jockey pulley, the machine tensions needed for different size superhigh molecular weight polyethylene fibers can be met; Control superhigh molecular weight polyethylene fibers surface-treated intensity by regulating the friction rotating speed of three-axis friction processor.
The first step adopts the method for high speed machine friction to carry out surface treatment to superhigh molecular weight polyethylene fibers, fiber surface is unfavorable for the high density crystallizing layer of dye diffusion is evenly peeled off, slight etching is produced to fiber surface simultaneously, increased fiber dyeing contact area, for follow-up dyeing creates favorable conditions.Second step is in adopting, low temperature carrier dyeing method dyes, select middle low temperature disperse dyes, adopt the mixture of methyl naphthalene system and o-phenyl phenol class as dyeing carrier, add appropriate dispersant and levelling agent again, adopt specific dyeing temperature control method, superhigh molecular weight polyethylene fibers cheese is dyeed.After adding suitable carrier in dye liquor, carrier molecule is less, and diffusion rate is higher than dye molecule, and first carrier is combined with fiber; Dye molecule solubility in the carrier, higher than water, is therefore adsorbed on dye strength in fiber surface carrier layer higher than the concentration in dye bath, improves the concentration gradient of dyestuff inside and outside fiber, accelerates dyestuff contaminates.In addition, carrier also has plasticization to fiber, and the macromolecular chain of amorphous region is more prone to movable, reduces dyeing temperature, improves the adsorbance of fiber surface.
Therefore, a kind of superhigh molecular weight polyethylene fibers dyeing apparatus provided by the invention and method thereof, compact conformation, improve the concentration gradient of dyestuff inside and outside fiber, accelerate dyestuff contaminates, have plasticization, the macromolecular chain of amorphous region is more prone to movable, reduce dyeing temperature, improve the adsorbance of fiber surface.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
Detailed description of the invention
Below by embodiment, and by reference to the accompanying drawings, technical scheme of the present invention is described in further detail.
Embodiment 1: as shown in Figure 1, a kind of superhigh molecular weight polyethylene fibers dyeing apparatus, comprise untreatment fiber bobbin spindle 1 and the rear fiber package spindle 2 of process, described untreatment fiber bobbin spindle 1 is wound with superhigh molecular weight polyethylene fibers yarn 3, described superhigh molecular weight polyethylene fibers yarn 3 enter successively feeding jockey pulley 4, feeding three-axis friction processor 5 and after exporting jockey pulley 6 and with process after fiber package spindle 2 be wound around mutually.
A kind of superhigh molecular weight polyethylene fibers colouring method, carries out according to the following steps:
(1), surface treatment:
The method of high speed machine friction is adopted to carry out surface treatment to superhigh molecular weight polyethylene fibers, superhigh molecular weight polyethylene fibers is entered feeding three-axis friction processor 5, the friction rotating speed of feeding three-axis friction processor 5 is 8000 revs/min, the fraction time of feeding three-axis friction processor 5 is 0.1 second, be 1.5mm with the spacing of superhigh molecular weight polyethylene fibers in feeding three-axis friction processor 5, superhigh molecular weight polyethylene fibers surface is unfavorable for that the high density crystallizing layer of dye diffusion is evenly peeled off by feeding three-axis friction processor 5, etching is produced to superhigh molecular weight polyethylene fibers surface simultaneously, the degree of depth of etching is about 2um, the area of etching accounts for 80% of fiber surface area, , to increase superhigh molecular weight polyethylene fibers dyeing contact area, for follow-up dyeing creates favorable conditions, the tension force of feeding jockey pulley controls at 100g, the tension force exporting jockey pulley is about 6g,
(2), dyeing carrier configuration:
By methyl naphthalene system and o-phenyl phenol system dyeing carrier, 9:1 is fully emulsified in water in proportion, and dyeing carrier total amount is 10g/L, and emulsification rotating speed controls as 2000r/min, and the time of normal temperature emulsification is 10min, until emulsion presents light blueness;
(3), two temperature carrier dyeing:
Get the dispersant NN0 of 1g/L and paregal O respectively as dyeing dispersant and levelling agent, be 5 by formic acid adjust ph, get the emulsion 1.5g/L configured in step (2), then add water, make dye bath ratio maintain 1:30, form mixing dye liquor; Mixing dye liquor and superhigh molecular weight polyethylene fibers cheese are put into yarn package dyeing machine, starts the dyeing that heats up, elevate the temperature to 95 DEG C with the heating rate of 2 DEG C/min, and be incubated 15 minutes; Elevate the temperature to 125 DEG C with the heating rate of 2 DEG C/min again, be incubated 30 minutes; Be down to room temperature with the rate of temperature fall of 2.5 DEG C/min, then take out superhigh molecular weight polyethylene fibers cheese, wash, the time of washing is 15min, then in the air dry oven of 90 DEG C, dries 2h.
Embodiment 2: a kind of superhigh molecular weight polyethylene fibers colouring method, carry out according to the following steps:
(1), surface treatment:
The method of high speed machine friction is adopted to carry out surface treatment to superhigh molecular weight polyethylene fibers, superhigh molecular weight polyethylene fibers is entered feeding three-axis friction processor 5, the friction rotating speed of feeding three-axis friction processor 5 is 10000 revs/min, the fraction time of feeding three-axis friction processor 5 is 0.15 second, be 2mm with the spacing of superhigh molecular weight polyethylene fibers in feeding three-axis friction processor 5, superhigh molecular weight polyethylene fibers surface is unfavorable for that the high density crystallizing layer of dye diffusion is evenly peeled off by feeding three-axis friction processor 5, etching is produced to superhigh molecular weight polyethylene fibers surface simultaneously, the degree of depth of etching is about 4um, the area of etching accounts for 85% of fiber surface area, , to increase superhigh molecular weight polyethylene fibers dyeing contact area, for follow-up dyeing creates favorable conditions, the tension force of feeding jockey pulley controls at 150g, the tension force exporting jockey pulley is about 50g,
(2), dyeing carrier configuration:
By methyl naphthalene system and o-phenyl phenol system dyeing carrier, 9:1 is fully emulsified in water in proportion, and dyeing carrier total amount is 10g/L, and emulsification rotating speed controls as 2000r/min, and the time of normal temperature emulsification is 12min, until emulsion presents light blueness;
(3), two temperature carrier dyeing:
Get the dispersant NN0 of 1g/L and paregal O respectively as dyeing dispersant and levelling agent, be 5.5 by formic acid adjust ph, get the emulsion 1.5g/L configured in step (2), then add water, make dye bath ratio maintain 1:30, form mixing dye liquor; Mixing dye liquor and superhigh molecular weight polyethylene fibers cheese are put into yarn package dyeing machine, starts the dyeing that heats up, elevate the temperature to 95 DEG C with the heating rate of 2 DEG C/min, and be incubated 15 minutes; Elevate the temperature to 125 DEG C with the heating rate of 2 DEG C/min again, be incubated 30 minutes; Be down to room temperature with the rate of temperature fall of 2.5 DEG C/min, then take out superhigh molecular weight polyethylene fibers cheese, wash, the time of washing is 15min, then in the air dry oven of 90 DEG C, dries 2h.
Embodiment 3: a kind of superhigh molecular weight polyethylene fibers colouring method, carry out according to the following steps:
(1), surface treatment:
The method of high speed machine friction is adopted to carry out surface treatment to superhigh molecular weight polyethylene fibers, superhigh molecular weight polyethylene fibers is entered feeding three-axis friction processor 5, the friction rotating speed of feeding three-axis friction processor 5 is 12000 revs/min, the fraction time of feeding three-axis friction processor 5 is 0.2 second, be 2.5mm with the spacing of superhigh molecular weight polyethylene fibers in feeding three-axis friction processor 5, superhigh molecular weight polyethylene fibers surface is unfavorable for that the high density crystallizing layer of dye diffusion is evenly peeled off by feeding three-axis friction processor 5, etching is produced to superhigh molecular weight polyethylene fibers surface simultaneously, the degree of depth of etching is about 5um, the area of etching accounts for 90% of fiber surface area, , to increase superhigh molecular weight polyethylene fibers dyeing contact area, for follow-up dyeing creates favorable conditions, the tension force of feeding jockey pulley controls at 250g, the tension force exporting jockey pulley is about 90g,
(2), dyeing carrier configuration:
By methyl naphthalene system and o-phenyl phenol system dyeing carrier, 9:1 is fully emulsified in water in proportion, and dyeing carrier total amount is 10g/L, and emulsification rotating speed controls as 2000r/min, and the time of normal temperature emulsification is 15min, until emulsion presents light blueness;
(3), two temperature carrier dyeing:
Get the dispersant NN0 of 1g/L and paregal O respectively as dyeing dispersant and levelling agent, be 6 by formic acid adjust ph, get the emulsion 1.5g/L configured in step (2), then add water, make dye bath ratio maintain 1:30, form mixing dye liquor; Mixing dye liquor and superhigh molecular weight polyethylene fibers cheese are put into yarn package dyeing machine, starts the dyeing that heats up, elevate the temperature to 95 DEG C with the heating rate of 2 DEG C/min, and be incubated 15 minutes; Elevate the temperature to 125 DEG C with the heating rate of 2 DEG C/min again, be incubated 30 minutes; Be down to room temperature with the rate of temperature fall of 2.5 DEG C/min, then take out superhigh molecular weight polyethylene fibers cheese, wash, the time of washing is 15min, then in the air dry oven of 90 DEG C, dries 2h.
Claims (1)
1. apply the colouring method of superhigh molecular weight polyethylene fibers dyeing apparatus for one kind, comprise untreatment fiber bobbin spindle (1) and the rear fiber package spindle (2) of process, described untreatment fiber bobbin spindle (1) is wound with superhigh molecular weight polyethylene fibers yarn (3), described superhigh molecular weight polyethylene fibers yarn (3) enters feeding jockey pulley (4) successively, feeding three-axis friction processor (5) and export jockey pulley (6) afterwards and with process afterwards fiber package spindle (2) be wound around mutually, it is characterized in that carrying out according to the following steps:
(1), surface treatment:
The method of high speed machine friction is adopted to carry out surface treatment to superhigh molecular weight polyethylene fibers yarn, superhigh molecular weight polyethylene fibers yarn is entered feeding three-axis friction processor (5), the friction rotating speed of feeding three-axis friction processor (5) is 8000 ~ 12000 revs/min, the fraction time of feeding three-axis friction processor (5) is 0.1 ~ 0.2 second, be 1.5 ~ 2.5mm with the spacing of superhigh molecular weight polyethylene fibers yarn in feeding three-axis friction processor (5), superhigh molecular weight polyethylene fibers yam surface is unfavorable for that the high density crystallizing layer of dye diffusion is evenly peeled off by feeding three-axis friction processor (5), etching is produced to superhigh molecular weight polyethylene fibers yam surface simultaneously, the degree of depth of etching is 2um ~ 5um, the area of etching accounts for 80% ~ 90% of fiber surface area, to increase superhigh molecular weight polyethylene fibers yarn dyeing contact area, for follow-up dyeing creates favorable conditions, the tension force of feeding jockey pulley controls at 100g ~ 250g, the tension force exporting jockey pulley is 6g ~ 90g,
(2), dyeing carrier configuration:
By methyl naphthalene system and o-phenyl phenol system dyeing carrier, 9:1 is fully emulsified in water in proportion, and dyeing carrier total amount is 10g/L, and emulsification rotating speed controls as 2000r/min, and the time of normal temperature emulsification is 10 ~ 15min, until emulsion presents light blueness;
(3), two temperature carrier dyeing:
Get the dispersant NN0 of 1g/L and paregal O respectively as dyeing dispersant and levelling agent, be 5 ~ 6 by formic acid adjust ph, get the emulsion 1.5g/L configured in step (2), then add water, make dye bath ratio maintain 1:30, form mixing dye liquor; Mixing dye liquor and superhigh molecular weight polyethylene fibers yarn bobbin yarn are put into yarn package dyeing machine, starts the dyeing that heats up, elevate the temperature to 95 DEG C with the heating rate of 2 DEG C/min, and be incubated 15 minutes; Elevate the temperature to 125 DEG C with the heating rate of 2 DEG C/min again, be incubated 30 minutes; Be down to room temperature with the rate of temperature fall of 2.5 DEG C/min, then take out superhigh molecular weight polyethylene fibers yarn bobbin yarn, wash, the time of washing is 15min, then in the air dry oven of 90 DEG C, dries 2h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210367822.4A CN102953186B (en) | 2012-09-27 | 2012-09-27 | A kind of superhigh molecular weight polyethylene fibers dyeing apparatus and method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210367822.4A CN102953186B (en) | 2012-09-27 | 2012-09-27 | A kind of superhigh molecular weight polyethylene fibers dyeing apparatus and method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102953186A CN102953186A (en) | 2013-03-06 |
| CN102953186B true CN102953186B (en) | 2016-02-17 |
Family
ID=47762541
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210367822.4A Expired - Fee Related CN102953186B (en) | 2012-09-27 | 2012-09-27 | A kind of superhigh molecular weight polyethylene fibers dyeing apparatus and method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102953186B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103422195B (en) * | 2013-08-08 | 2015-06-17 | 黑龙江金源仑特种纤维有限公司 | Preparation method of colored ultrahigh molecular weight polyethylene fiber |
| CN106702773A (en) * | 2016-12-01 | 2017-05-24 | 西南大学 | Method for dyeing wool fabric with gardenin |
| CN111155334A (en) * | 2020-01-11 | 2020-05-15 | 长江纺织（浙江）有限公司 | Dyeing process of spandex/terylene/denim composite high-strength covered yarn |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0480776A1 (en) * | 1990-10-12 | 1992-04-15 | Milliken Research Corporation | Method and apparatus for modifying fibers and fabric by fatiguing |
| CN101570940A (en) * | 2009-05-18 | 2009-11-04 | 江南大学 | Method for modification, dyeing and multifunctional composite finishing of aramid fiber |
| CN101824757A (en) * | 2010-05-06 | 2010-09-08 | 四川大学 | Method for dyeing polyphenylene sulfide fiber or fabric |
| CN102182082A (en) * | 2011-04-06 | 2011-09-14 | 凯诺科技股份有限公司 | Strip dyeing method for corn fibers |
| EP2394671A1 (en) * | 2010-05-14 | 2011-12-14 | Tyco Healthcare Group LP | Method of producing colored high-strength fibers |
| CN102587060A (en) * | 2012-03-26 | 2012-07-18 | 江苏锵尼玛新材料有限公司 | Production method for ultra-high molecular weight colored polyethylene fibers |
| CN102660865A (en) * | 2012-04-24 | 2012-09-12 | 三元控股集团有限公司 | Environment-friendly processing method for improving polypropylene fiber dyeing property |
| CN202865483U (en) * | 2012-09-27 | 2013-04-10 | 杭州翔盛高强纤维材料股份有限公司 | Ultra high molecular weight polyethylene fiber dyeing device |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1254816B (en) * | 1958-03-24 | 1967-11-23 | Libuse Tlamicha Geb Peterkova | Process for roughening fully synthetic individual threads, in particular polyamide threads |
-
2012
- 2012-09-27 CN CN201210367822.4A patent/CN102953186B/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0480776A1 (en) * | 1990-10-12 | 1992-04-15 | Milliken Research Corporation | Method and apparatus for modifying fibers and fabric by fatiguing |
| CN101570940A (en) * | 2009-05-18 | 2009-11-04 | 江南大学 | Method for modification, dyeing and multifunctional composite finishing of aramid fiber |
| CN101824757A (en) * | 2010-05-06 | 2010-09-08 | 四川大学 | Method for dyeing polyphenylene sulfide fiber or fabric |
| EP2394671A1 (en) * | 2010-05-14 | 2011-12-14 | Tyco Healthcare Group LP | Method of producing colored high-strength fibers |
| CN102182082A (en) * | 2011-04-06 | 2011-09-14 | 凯诺科技股份有限公司 | Strip dyeing method for corn fibers |
| CN102587060A (en) * | 2012-03-26 | 2012-07-18 | 江苏锵尼玛新材料有限公司 | Production method for ultra-high molecular weight colored polyethylene fibers |
| CN102660865A (en) * | 2012-04-24 | 2012-09-12 | 三元控股集团有限公司 | Environment-friendly processing method for improving polypropylene fiber dyeing property |
| CN202865483U (en) * | 2012-09-27 | 2013-04-10 | 杭州翔盛高强纤维材料股份有限公司 | Ultra high molecular weight polyethylene fiber dyeing device |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102953186A (en) | 2013-03-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1059003C (en) | Process and device for treating textile substrates with supercritical fluid | |
| US10584433B2 (en) | Supercritical fluid dyeing and finishing system and method | |
| CN102953186B (en) | A kind of superhigh molecular weight polyethylene fibers dyeing apparatus and method thereof | |
| CN101824716B (en) | Device and method for fabric dyeing with supercritical carbon dioxide fluid | |
| CN202055028U (en) | Ultra-low bath ratio high-temperature pulsating current yarn dyeing machine | |
| CN105862474A (en) | Processing process of linen base yarn | |
| KR20050111982A (en) | Industrial supercritical fluid dye apparatus | |
| CN106835553A (en) | Cloth dyeing apparatus and colouring method under a kind of nearly vacuum state | |
| CN103628336A (en) | Printing and dyeing process | |
| CN105862451B (en) | A kind of fluorescent silk fiber based on BODIPY class dyestuffs and preparation method thereof | |
| CN110205762A (en) | A kind of dyeing of terylene cloth | |
| CN109267258A (en) | A kind of water-saving textile fabric dyeing apparatus and its dyeing | |
| CN102140743B (en) | High-temperature pulse flow yarn dyeing machine with ultra low bath ratio and control method thereof | |
| CN104195854A (en) | Dyeing and finishing process with zero emission | |
| CN113463308A (en) | Processing device and production method of cellulose fiber space-dyeing cheese | |
| CN106468026A (en) | For supercritical CO2The cotton fiber dyestuff of fluid dyeing and its colouring method | |
| JP2005273098A (en) | Dyeing method using supercritical fluid, dyed product dyed thereby and dyeing apparatus | |
| CN102978861B (en) | Counter-flow dye vat | |
| CN205775259U (en) | A kind of textile raw material Colour Difference device | |
| WO2015032020A1 (en) | Phase-transfer catalytic colour fixation processing method for textile | |
| CN202865483U (en) | Ultra high molecular weight polyethylene fiber dyeing device | |
| CN103046403B (en) | Method for preparing colored UHMW (ultra-high molecular weight) polyethylene fibers | |
| CN104963138B (en) | Rolling brush device of printing and dyeing vats | |
| CN101624765A (en) | Method for manufacturing color cheese | |
| CN209703028U (en) | A kind of yarn stretching dip dyeing apparatus |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20181217 Address after: 311245 Shanbei Village, Guali Town, Xiaoshan District, Hangzhou City, Zhejiang Province Patentee after: Hangzhou Xiangsheng New Materials Co., Ltd. Address before: 311245 Shanbei Village, Dangshan Town Industrial Park, Xiaoshan District, Hangzhou City, Zhejiang Province Patentee before: Hangzhou Xiangsheng High Strength Fiber Material Inc. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160217 Termination date: 20190927 |