CN102953106B - 一种用于金属表面的保护层及其制备 - Google Patents
一种用于金属表面的保护层及其制备 Download PDFInfo
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- CN102953106B CN102953106B CN201210471430.2A CN201210471430A CN102953106B CN 102953106 B CN102953106 B CN 102953106B CN 201210471430 A CN201210471430 A CN 201210471430A CN 102953106 B CN102953106 B CN 102953106B
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- Prior art keywords
- metallic surface
- protective layer
- metal
- preparation
- cleaned
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- 239000011241 protective layer Substances 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 238000004140 cleaning Methods 0.000 claims abstract description 19
- 239000003513 alkali Substances 0.000 claims abstract description 14
- 238000005554 pickling Methods 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 238000005498 polishing Methods 0.000 claims abstract description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 33
- 229910052751 metal Inorganic materials 0.000 claims description 32
- 239000002184 metal Substances 0.000 claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 11
- 239000010935 stainless steel Substances 0.000 claims description 9
- 238000007747 plating Methods 0.000 claims description 8
- 229910001220 stainless steel Inorganic materials 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 239000003792 electrolyte Substances 0.000 claims description 6
- 239000008151 electrolyte solution Substances 0.000 claims description 6
- 238000007654 immersion Methods 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 235000019353 potassium silicate Nutrition 0.000 claims description 6
- 238000009991 scouring Methods 0.000 claims description 6
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 6
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 6
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 abstract description 18
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 239000002699 waste material Substances 0.000 abstract description 4
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 238000005260 corrosion Methods 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 6
- 239000010408 film Substances 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000007769 metal material Substances 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 241001062472 Stokellia anisodon Species 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 2
- 239000006223 plastic coating Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- -1 enamel Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 238000007591 painting process Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
Landscapes
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
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CN201210471430.2A CN102953106B (zh) | 2012-11-20 | 2012-11-20 | 一种用于金属表面的保护层及其制备 |
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CN201210471430.2A CN102953106B (zh) | 2012-11-20 | 2012-11-20 | 一种用于金属表面的保护层及其制备 |
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CN102953106A CN102953106A (zh) | 2013-03-06 |
CN102953106B true CN102953106B (zh) | 2016-02-24 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103290448A (zh) * | 2013-05-07 | 2013-09-11 | 锡山区羊尖泓之盛五金厂 | 一种金属表面耐蚀处理方法 |
CN103540975B (zh) * | 2013-10-11 | 2016-08-10 | 上海大学 | 一种在铜表面电镀金属锰的方法 |
CN107475720A (zh) * | 2017-08-22 | 2017-12-15 | 苏州双金实业有限公司 | 一种使不锈钢表面清洁的处理方法 |
CN116970896B (zh) * | 2023-09-22 | 2024-02-02 | 成都先进金属材料产业技术研究院股份有限公司 | 一种提高Ni-Cr电热合金产品预氧化效果的方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08269757A (ja) * | 1995-03-29 | 1996-10-15 | Nissan Motor Co Ltd | アルミニウム合金部材の電解前処理方法 |
JPH1032146A (ja) * | 1996-07-16 | 1998-02-03 | Nichicon Corp | アルミニウム電解コンデンサ用電極箔の製造方法 |
CN101078114A (zh) * | 2006-05-26 | 2007-11-28 | 佛山市顺德区汉达精密电子科技有限公司 | 镁合金表面化学转化处理工艺 |
CN101311326A (zh) * | 2007-05-25 | 2008-11-26 | 比亚迪股份有限公司 | 一种用于轻金属微弧氧化的电解液及微弧氧化方法 |
CN101418461A (zh) * | 2008-11-13 | 2009-04-29 | 孙国云 | 模具的表面处理方法 |
CN101974774A (zh) * | 2010-11-01 | 2011-02-16 | 常熟市精艺玻璃模具制造有限公司 | 一种模具的表面处理方法 |
CN102021629A (zh) * | 2010-12-30 | 2011-04-20 | 南昌航空大学 | 一种钛合金表面微弧氧化减摩复合膜层的制备方法 |
-
2012
- 2012-11-20 CN CN201210471430.2A patent/CN102953106B/zh not_active Expired - Fee Related
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08269757A (ja) * | 1995-03-29 | 1996-10-15 | Nissan Motor Co Ltd | アルミニウム合金部材の電解前処理方法 |
JPH1032146A (ja) * | 1996-07-16 | 1998-02-03 | Nichicon Corp | アルミニウム電解コンデンサ用電極箔の製造方法 |
CN101078114A (zh) * | 2006-05-26 | 2007-11-28 | 佛山市顺德区汉达精密电子科技有限公司 | 镁合金表面化学转化处理工艺 |
CN101311326A (zh) * | 2007-05-25 | 2008-11-26 | 比亚迪股份有限公司 | 一种用于轻金属微弧氧化的电解液及微弧氧化方法 |
CN101418461A (zh) * | 2008-11-13 | 2009-04-29 | 孙国云 | 模具的表面处理方法 |
CN101974774A (zh) * | 2010-11-01 | 2011-02-16 | 常熟市精艺玻璃模具制造有限公司 | 一种模具的表面处理方法 |
CN102021629A (zh) * | 2010-12-30 | 2011-04-20 | 南昌航空大学 | 一种钛合金表面微弧氧化减摩复合膜层的制备方法 |
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Effective date of registration: 20160114 Address after: 214000 Xinhua Road, Wuxi province national high tech Industrial Development Zone, No. innovation Creative Industrial Park, building, room 109, B, China, Jiangsu Applicant after: Jiangsu Gaobo Zhirong Technology Co., Ltd. Address before: 214000, Jiangsu province Wuxi Huishan Economic Development Zone weir new road standard factory building A area Applicant before: Wuxi Chang'an General Metal Product Co., Ltd. |
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Inventor after: Wu Jun Inventor before: Gao Yihui |
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Effective date of registration: 20170511 Address after: 414000 Yueyang economic and Technological Development Zone, Hunan Shiling Road Patentee after: Yueyang Dongfang Automatic Control Engineering Equipment Co., Ltd. Address before: 214000 Xinhua Road, Wuxi province national high tech Industrial Development Zone, No. innovation Creative Industrial Park, building, room 109, B, China, Jiangsu Patentee before: Jiangsu Gaobo Zhirong Technology Co., Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160224 Termination date: 20181120 |