CN102952469B - High-strength compound adhesive film for filter - Google Patents
High-strength compound adhesive film for filter Download PDFInfo
- Publication number
- CN102952469B CN102952469B CN2012104165080A CN201210416508A CN102952469B CN 102952469 B CN102952469 B CN 102952469B CN 2012104165080 A CN2012104165080 A CN 2012104165080A CN 201210416508 A CN201210416508 A CN 201210416508A CN 102952469 B CN102952469 B CN 102952469B
- Authority
- CN
- China
- Prior art keywords
- adhesive film
- phenol
- clay
- trees ashes
- high strength
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a high-strength compound adhesive film for filter. The adhesive film is prepared from raw materials comprising chloroprene rubber CR121, styrene, 2,4,6-tri(dimethylaminomethyl)phenol, polyvinyl alcohol, N-2-(aminoethyl)-3-amino propyl trimethoxy silane, polyisobutylene, polytetramethylene ether glycol (PTMEG), modified nano clay and modified wood ash. The prepared adhesive film has advantages of good temperature tolerance, high shear strength, excellent electric insulation property and ageing resistance; the cured adhesive film gains smooth surface, good toughness and good shockproof effect; and the modified nano clay and modified wood ash can improve the strength of the adhesive film provided by the invention.
Description
Technical field
The present invention relates to the purifier apparatus field, is exactly the composite purifier film cement of a kind of high strength.
Background technology
The selection of filter paper and complete processing, filter paper adhesion process are two crucial qualifying points in the purifier Production Flow Chart.Some producer, in order to reduce production costs, purchases more cheap underproof filter paper and tackiness agent, or the bonding time is short, brush coating is very few or inhomogeneous etc., all can cause filtration efficiency defective.
Especially for air filter, its tackiness agent that uses with epoxy resin as main raw material, the tackiness agent of the type is fluid binder, must fully stir before using, adopt again the methods such as pickling process, spraying method, spread coating, rolling method, transfer method to operate, therefore comparatively complicated on technique, be prone to adhesive distribution inhomogeneous and cause the phenomenon such as waste; And tackiness agent is very crisp, not shock-resistant after solidifying, and is easy to damage in following process, transportation and installation process, causes purifier short work-ing life.
In addition, develop rapidly along with rubber industry, rubber composite is widely used, in rubber and metal composite goods, the quality of tackiness agent is the key of composite product quality, along with increasing and the expansion of Application Areas of composite product kind, more and more harsher to the requirement of adhesive techniques.The technology such as traditional chlorinated rubber method, isocyanic ester method can not meet new requirement, need new tackiness agent to improve the quality of rubber composite product.
Traditional rubber cement can not meet new requirement, is badly in need of the better rubber adhesive of performance and improves the quality of purifier.
Summary of the invention
The object of the present invention is to provide the composite purifier film cement of a kind of high strength.
Above-mentioned purpose realizes by following scheme:
the composite purifier film cement of a kind of high strength is characterized in that: it is that raw material by following weight parts makes: chloroprene rubber CR121 135-145, isoprene-isobutylene rubber 7-9, epoxy resin modification polyamide hot 10-12, vinylbenzene 15-20, three 2.4.6-(dimethylamino methyl) phenol 1-2, polyvinyl alcohol 8-12, the N-2-(aminoethyl)-3-aminopropyl trimethoxysilane 2-3, polyisobutene 2-3, PTMG 2-3, glycol ether benzoic ether 2-5, Vanay 3-5, magnesium oxide 2-3, epoxyoleic acid butyl ester 2-5, dibutyl maleate 2-5, modified Nano potter's clay 40-45, carbon black N220 15-20, nano diatomite 30-35, sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanic acid ester 1-2, antioxidant 1010 1-2, silane coupling agent kh560 3-4, anti-aging agent TPPD 1-2, antioxidant NBC 1-2, accelerant CZ 1-2, accelerator CBS 0.5-1.5, ferrocene 1-2, modification trees ashes 2-3,
The preparation method of described modified Nano potter's clay is: it is in the sodium hydroxide solution of 10-12% that potter's clay is added concentration, after stirring 20-30 minute under 3700-4200 rev/min, more extremely neutral with deionized water wash, oven dry, grind to form nanometer powder, gets final product;
The preparation method of described modification trees ashes is:
(1), be the dioxygen bubble of 15-20% after 2-3 hour with the trees ashes with concentration, then with deionized water wash to neutral, oven dry;
(2), add the nano-sized carbon that is equivalent to its weight 2-3%, 2.4.6-three (dimethylamino methyl) phenol of 1-2%, the a-cyanoacrylate of 2-3%, the linking agent TAC of 1-2%, the aluminium hydroxide of 3-5% in the trees ashes, after stirring 20-30 minute under 4500-4800 rev/min, ovendry power is broken into ultrafine powder and get final product.
The composite purifier film cement of described a kind of high strength, it is characterized in that: the preparation method is: join by weight chloroprene rubber CR121 in vinylbenzene, be heated to 100-110 ℃, stir 10-15 minute, add by weight again 2.4.6-three (dimethylamino methyl) phenol, polyvinyl alcohol, N-2-(aminoethyl)-3-aminopropyl trimethoxysilane, polyisobutene, PTMG, stir reaction 1-2 hour; Add by weight again all the other raw materials, mixing to desired thickness, be trimmed to finally desired size and get final product.
Described isoprene-isobutylene rubber model is CBK139.
Beneficial effect of the present invention is: heat resistance of the present invention is good, have good electrical insulating property and ageing resistance when shearing resistance is high, and this adhesive film solidifies that rear surface is smooth, good toughness, anti seismic efficiency are good.The use of modified Nano potter's clay and modification trees ashes, increased intensity of the present invention.
Embodiment
the composite purifier film cement of a kind of high strength, it is that raw material by following weight parts (kg) makes: chloroprene rubber CR121 139, isoprene-isobutylene rubber 9, epoxy resin modification polyamide hot 12, vinylbenzene 20, three 2.4.6-(dimethylamino methyl) phenol 2, polyvinyl alcohol 12, the N-2-(aminoethyl)-3-aminopropyl trimethoxysilane 2.3, polyisobutene 3, PTMG 2.5, glycol ether benzoic ether 3, Vanay 5, magnesium oxide 3, epoxyoleic acid butyl ester 5, dibutyl maleate 2, modified Nano potter's clay 40, carbon black N220 20, nano diatomite 35, sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanic acid ester 2, antioxidant 1010 2, silane coupling agent kh560 4, anti-aging agent TPPD 2, antioxidant NBC 2, accelerant CZ 2, accelerator CBS 1.3, ferrocene 1.7, modification trees ashes 3,
The preparation method of described modified Nano potter's clay is: it is in 12% sodium hydroxide solution that potter's clay is added concentration, after stirring 20 minutes under 4000 rev/mins, then with deionized water wash to neutral, oven dry, grind to form nanometer powder, gets final product;
The preparation method of described modification trees ashes is:
(1), be 20% dioxygen bubble after 3 hours with the trees ashes with concentration, then with deionized water wash to neutral, oven dry;
(2), add the nano-sized carbon that is equivalent to its weight 3%, 1% 2.4.6-three (dimethylamino methyl) phenol, 2% a-cyanoacrylate, 1% linking agent TAC, 3% aluminium hydroxide in the trees ashes, after stirring 30 minutes under 4500 rev/mins, ovendry power is broken into ultrafine powder and get final product.
The composite purifier film cement of described a kind of high strength, the preparation method is: join by weight chloroprene rubber CR121 in vinylbenzene, be heated to 110 ℃, stirred 12 minutes, add by weight again 2.4.6-three (dimethylamino methyl) phenol, polyvinyl alcohol, N-2-(aminoethyl)-3-aminopropyl trimethoxysilane, polyisobutene, PTMG, stir, reacted 1.5 hours; Add by weight again all the other raw materials, mixing to desired thickness, be trimmed to finally desired size and get final product.
The composite purifier of high strength of the present invention has higher shearing resistance and toughness with film cement, after using, the normal temperature shearing resistance can reach every square centimeter of 261-270 kilogram, the shearing resistance of 150 ℃ can reach every square centimeter of 100-116 kilogram, and uneven pulling intensity can reach every square centimeter of 52-54 kilogram.
During use, film of the present invention is stained with filter paper of filter and end cap,, then in the sulfuration of heating, can greatly improves the bond strength of its toughness and end cap and filter paper, durable in use.Keep sealed state, dust can not occur flow through in gap.
Claims (3)
1. composite purifier film cement of high strength is characterized in that: it is that raw material by following weight parts makes: chloroprene rubber CR121 135-145, isoprene-isobutylene rubber 7-9, epoxy resin modification polyamide hot 10-12, vinylbenzene 15-20, 2,4,6-three (dimethylamino methyl) phenol 1-2, polyvinyl alcohol 8-12, the N-2-(aminoethyl)-3-aminopropyl trimethoxysilane 2-3, polyisobutene 2-3, PTMG 2-3, glycol ether benzoic ether 2-5, Vanay 3-5, magnesium oxide 2-3, epoxyoleic acid butyl ester 2-5, dibutyl maleate 2-5, modified Nano potter's clay 40-45, carbon black N220 15-20, nano diatomite 30-35, sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanic acid ester 1-2, antioxidant 1010 1-2, silane coupling agent KH-560 3-4, anti-aging agent TPPD 1-2, antioxidant NBC 1-2, accelerant CZ 1-2, accelerator CBS 0.5-1.5, ferrocene 1-2, modification trees ashes 2-3,
The preparation method of described modified Nano potter's clay is: it is in the sodium hydroxide solution of 10-12% that potter's clay is added concentration, after stirring 20-30 minute under 3700-4200 rev/min, more extremely neutral with deionized water wash, oven dry, grind to form nanometer powder, gets final product;
The preparation method of described modification trees ashes is:
(1), be the dioxygen bubble of 15-20% after 2-3 hour with the trees ashes with concentration, then with deionized water wash to neutral, oven dry;
(2), add 2 of the nano-sized carbon that is equivalent to its weight 2-3%, 1-2% in the trees ashes, 4, the α-cyanoacrylate of 6-three (dimethylamino methyl) phenol, 2-3%, the linking agent TAC of 1-2%, the aluminium hydroxide of 3-5%, after stirring 20-30 minute under 4500-4800 rev/min, ovendry power is broken into ultrafine powder and get final product.
2. the composite purifier film cement of a kind of high strength according to claim 1, it is characterized in that: the preparation method is: join by weight chloroprene rubber CR121 in vinylbenzene, be heated to 100-110 ℃, stir 10-15 minute, add by weight again 2,4,6-three (dimethylamino methyl) phenol, polyvinyl alcohol, N-2-(aminoethyl)-3-aminopropyl trimethoxysilane, polyisobutene, PTMG, stir reaction 1-2 hour; Add by weight again all the other raw materials, mixing to desired thickness, be trimmed to finally desired size and get final product.
3. the composite purifier film cement of a kind of high strength according to claim 1, it is characterized in that: described isoprene-isobutylene rubber model is CBK139.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104165080A CN102952469B (en) | 2012-10-27 | 2012-10-27 | High-strength compound adhesive film for filter |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104165080A CN102952469B (en) | 2012-10-27 | 2012-10-27 | High-strength compound adhesive film for filter |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102952469A CN102952469A (en) | 2013-03-06 |
| CN102952469B true CN102952469B (en) | 2013-11-13 |
Family
ID=47761876
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012104165080A Active CN102952469B (en) | 2012-10-27 | 2012-10-27 | High-strength compound adhesive film for filter |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102952469B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103626573B (en) * | 2013-10-24 | 2015-02-18 | 安徽久久肥业有限公司 | Water-retention coated nitrogen phosphorus potassium compound fertilizer and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004051957A1 (en) * | 2004-10-26 | 2006-04-27 | Pelzer Acoustic Products Gmbh | Adhesive tape e.g. useful for making airtight seals and soundproofing comprises an adhesive layer and a heavy backing layer |
| CN102153966A (en) * | 2011-02-24 | 2011-08-17 | 中科英华湖州工程技术研究中心有限公司 | Special hot melt adhesive for mating 1E-grade K1-type cable accessories for nuclear power station |
| CN102229785A (en) * | 2011-05-13 | 2011-11-02 | 秦琪航 | Adhesive film for filter |
| CN102277105A (en) * | 2011-08-10 | 2011-12-14 | 佛山市豹王滤芯制造有限公司 | High-temperature resistant adhesive for filter cleaner of automobile |
| CN102453458A (en) * | 2010-10-28 | 2012-05-16 | 长沙把兄弟胶粘剂有限公司 | Nano rubber modified room temperature cured high temperature resistant structure adhesive |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100918914B1 (en) * | 2007-10-04 | 2009-09-23 | 도레이새한 주식회사 | Non-halogen type adhesive composition using polymer layered silicate nanocomposites for coverlay film |
| JP2010126698A (en) * | 2008-11-28 | 2010-06-10 | Furukawa Electric Co Ltd:The | Releasable adhesive tape for masking |
-
2012
- 2012-10-27 CN CN2012104165080A patent/CN102952469B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004051957A1 (en) * | 2004-10-26 | 2006-04-27 | Pelzer Acoustic Products Gmbh | Adhesive tape e.g. useful for making airtight seals and soundproofing comprises an adhesive layer and a heavy backing layer |
| CN102453458A (en) * | 2010-10-28 | 2012-05-16 | 长沙把兄弟胶粘剂有限公司 | Nano rubber modified room temperature cured high temperature resistant structure adhesive |
| CN102153966A (en) * | 2011-02-24 | 2011-08-17 | 中科英华湖州工程技术研究中心有限公司 | Special hot melt adhesive for mating 1E-grade K1-type cable accessories for nuclear power station |
| CN102229785A (en) * | 2011-05-13 | 2011-11-02 | 秦琪航 | Adhesive film for filter |
| CN102277105A (en) * | 2011-08-10 | 2011-12-14 | 佛山市豹王滤芯制造有限公司 | High-temperature resistant adhesive for filter cleaner of automobile |
Non-Patent Citations (1)
| Title |
|---|
| JP特开2010-126698A 2010.06.10 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102952469A (en) | 2013-03-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104961968A (en) | Preparation technique for glass fiber composite material | |
| CN102153775A (en) | Surface treatment method for enhancing adhesive property of vulcanized natural rubber | |
| CN102169744B (en) | Laminated magnetic conducting plate and manufacturing method thereof | |
| CN103756157A (en) | Automobile environmental-friendly brake rubber pipe material | |
| CN102796289B (en) | Preparation method for modified waste rubber powder/natural rubber composite material | |
| CN102952486B (en) | Adhesive film containing modified montmorillonite powder for filter | |
| CN102952487B (en) | Adhesive film containing modified nano diatomite for filter | |
| CN102952469B (en) | High-strength compound adhesive film for filter | |
| CN102952480B (en) | Filter adhesive film containing nano calcium carbonate | |
| CN102952488B (en) | Epoxy soybean oil modified adhesive film for filter | |
| CN102952484B (en) | Filter film adhesive compounded by neoprene and chlorosulfonated polyethylene rubber | |
| CN102952478B (en) | Filter adhesive film prepared by mixing neoprene and ethylene propylene diene monomer (EPDM) | |
| CN102952468B (en) | Filter adhesive film prepared by mixing neoprene and brominated butyl rubber | |
| CN102952485B (en) | Adhesive film containing modified nano potassium feldspar powder for filter | |
| CN102952479B (en) | Film adhesive containing modified complex formulation powder used for filter | |
| CN102850828A (en) | Active nano silica composition and preparation method thereof | |
| CN102952477B (en) | Filter adhesive film containing nano barite powder | |
| CN102952476B (en) | Filter adhesive film containing nanometer attapulgite | |
| CN103938449A (en) | Paint for train tarpaulin fabric | |
| CN102952483B (en) | Filter adhesive film | |
| CN102952481B (en) | Filter adhesive film containing nano-silica | |
| CN102163497B (en) | Preparation method and the magnetic sheet that ripple extrudes rubber and plastic magnetic sheet is inhaled in high-performance broadband electromagnetic radiation | |
| CN103509435B (en) | A kind of anti-corrosion antirust powder paint | |
| CN103571388A (en) | High-temperature-resistant hot melt adhesive | |
| CN101880513A (en) | Manufacturing method of organic ceramic body binder and organic ceramic body binding method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: ANHUI PHOENIX INTERNATIONAL CO., LTD. Free format text: FORMER NAME: BENGBU FENGHUANG FILTERS CO., LTD. |
|
| CP01 | Change in the name or title of a patent holder |
Address after: 233000 Mount Huangshan Road, Bengbu high tech Zone, Anhui, No. 8028 Patentee after: ANHUI PHOENIX FILTER CO., LTD. Address before: 233000 Mount Huangshan Road, Bengbu high tech Zone, Anhui, No. 8028 Patentee before: Bengbu Fenghuang Filters Co., Ltd. |