CN102952478B - Filter adhesive film prepared by mixing neoprene and ethylene propylene diene monomer (EPDM) - Google Patents

Filter adhesive film prepared by mixing neoprene and ethylene propylene diene monomer (EPDM) Download PDF

Info

Publication number
CN102952478B
CN102952478B CN2012104164942A CN201210416494A CN102952478B CN 102952478 B CN102952478 B CN 102952478B CN 2012104164942 A CN2012104164942 A CN 2012104164942A CN 201210416494 A CN201210416494 A CN 201210416494A CN 102952478 B CN102952478 B CN 102952478B
Authority
CN
China
Prior art keywords
rubber
adhesive film
terpolymer
mixing
filter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN2012104164942A
Other languages
Chinese (zh)
Other versions
CN102952478A (en
Inventor
陈登宇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI PHOENIX FILTER CO., LTD.
Original Assignee
Bengbu Phoenix International Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bengbu Phoenix International Co Ltd filed Critical Bengbu Phoenix International Co Ltd
Priority to CN2012104164942A priority Critical patent/CN102952478B/en
Publication of CN102952478A publication Critical patent/CN102952478A/en
Application granted granted Critical
Publication of CN102952478B publication Critical patent/CN102952478B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention discloses filter adhesive film prepared by mixing neoprene and EPDM, which is prepared from the following raw materials: neoprene CR121, styrene, 2,4,6-tris(dimethylaminomethyl)phenol, polyvinyl alcohol, N-2-(aminoethyl)-3-aminopropyl trimethoxysilane, polyisobutylene, polytetrahydrofuran ether diol, modified tree ashes and the like. Through mixing neoprene and EPDM and adding compound powder as a filler, the filter adhesive film is good in heat resistance and high in adhesive strength, and excellent in electrical insulation and aging resistance. The adhesive film after curing is smooth in surface, good in toughness and good in anti-seismic effect.

Description

A kind of chloroprene rubber and terpolymer EP rubber mixing and adhesive film for filter
Technical field
The present invention relates to the purifier apparatus field, be exactly a kind of chloroprene rubber and terpolymer EP rubber mixing and adhesive film for filter.
Background technology
The selection of filter paper and complete processing, filter paper adhesion process are two crucial qualifying points in the purifier Production Flow Chart.Some producer, in order to reduce production costs, purchases more cheap underproof filter paper and tackiness agent, or the bonding time is short, brush coating is very few or inhomogeneous etc., all can cause filtration efficiency defective, thereby affect the work-ing life of purifier.
Especially for air filter, its tackiness agent that uses with epoxy resin as main raw material, the tackiness agent of the type is fluid binder, must fully stir before using, adopt again the methods such as pickling process, spraying method, spread coating, rolling method, transfer method to operate, therefore comparatively complicated on technique, be prone to adhesive distribution inhomogeneous and cause the phenomenon such as waste; And tackiness agent is very crisp, not shock-resistant after solidifying, and is easy to damage in following process, transportation and installation process, causes purifier short work-ing life.
In addition, develop rapidly along with rubber industry, rubber composite is widely used, in rubber and metal composite goods, the quality of tackiness agent is the key of composite product quality, along with increasing and the expansion of Application Areas of composite product kind, more and more harsher to the requirement of adhesive techniques.The technology such as traditional chlorinated rubber method, isocyanic ester method can not meet new requirement, need new tackiness agent to improve the quality of rubber composite product.
Traditional rubber cement can not meet new requirement, is badly in need of the better rubber adhesive of performance and improves the quality of purifier.
Summary of the invention
The object of the present invention is to provide a kind of chloroprene rubber with higher consolidation strength and toughness and terpolymer EP rubber mixing and adhesive film for filter.
Above-mentioned purpose realizes by following scheme:
a kind of chloroprene rubber and terpolymer EP rubber mixing and adhesive film for filter, it is characterized in that: it is that raw material by following weight parts makes: chloroprene rubber CR121 130-133, vinylbenzene 15-20, 2,4,6-three (dimethylamino methyl) phenol 1-2, polyvinyl alcohol 8-12, the N-2-(aminoethyl)-3-aminopropyl trimethoxysilane 2-3, polyisobutene 2-3, PTMG 2-3, terpolymer EP rubber 5-8, brominated butyl rubber BBK-232 8-12, Vanay 3-5, epoxy oleum lini 2-5, glycerol glycerinate 2-5, magnesium oxide 2-5, Imarcaptoacetate dioctyltin 1-2, attapulgite 15-20, nano barite powder 20-25, bauxitic clay powder 20-25, carbon black N339 10-15, 3-aminopropyl trimethoxysilane 1-2, irgasfos 168 1-2, phenyl triethoxysilane 1-2, silane coupling agent KH570 1-2, anti-aging agent ODA 1-2, anti-aging agent RD 1-2, 2-thiol group benzimidazolyl 1-2, accelerant CZ 1-2, accelerator CBS 0.5-1.5, ferrocene 1-2, modification trees ashes 1.3-2.1,
The preparation method of described modification trees ashes is:
(1), be the dioxygen bubble of 15-20% after 2-3 hour with the trees ashes with concentration, then with deionized water wash to neutral, oven dry;
(2), add 2 of the nano-sized carbon that is equivalent to its weight 2-3%, 1-2% in the trees ashes, 4, the α-cyanoacrylate of 6-three (dimethylamino methyl) phenol, 2-3%, the linking agent TAC of 1-2%, the aluminium hydroxide of 3-5%, after stirring 20-30 minute under 4500-4800 rev/min, ovendry power is broken into ultrafine powder and get final product.
Described a kind of chloroprene rubber and terpolymer EP rubber mixing and adhesive film for filter, it is characterized in that: the preparation method is: join by weight chloroprene rubber CR121 in vinylbenzene, be heated to 100-110 ℃, stir 10-15 minute, add by weight again 2,4,6-three (dimethylamino methyl) phenol, polyvinyl alcohol, N-2-(aminoethyl)-3-aminopropyl trimethoxysilane, polyisobutene, PTMG, stir reaction 1-2 hour; Add by weight again all the other raw materials, mixing to desired thickness, be trimmed to finally desired size and get final product.
Beneficial effect of the present invention is: the present invention is mixing by chloroprene rubber and terpolymer EP rubber, add composite powder as weighting agent, make heat resistance of the present invention good, have good electrical insulating property and ageing resistance when shearing resistance is high, and this adhesive film solidifies that rear surface is smooth, good toughness, anti seismic efficiency are good.
Embodiment
a kind of chloroprene rubber and terpolymer EP rubber mixing and adhesive film for filter, it is that raw material by following weight parts (kg) makes: chloroprene rubber CR121 133, vinylbenzene 20, 2, 4, 6-three (dimethylamino methyl) phenol 2, polyvinyl alcohol 12, the N-2-(aminoethyl)-3-aminopropyl trimethoxysilane 3, polyisobutene 2, PTMG 3, terpolymer EP rubber 5, brominated butyl rubber BBK-232 12, Vanay 3, epoxy oleum lini 5, glycerol glycerinate 2, magnesium oxide 5, Imarcaptoacetate dioctyltin 2, attapulgite 20, nano barite powder 25, bauxitic clay powder 25, carbon black N339 15, 3-aminopropyl trimethoxysilane 2, irgasfos 168 2, phenyl triethoxysilane 1, silane coupling agent KH570 2, anti-aging agent ODA 2, anti-aging agent RD 2, 2-thiol group benzimidazolyl 1, accelerant CZ 2, accelerator CBS 1.5, ferrocene 2, modification trees ashes 2.1,
The preparation method of described modification trees ashes is:
(1), be 15% dioxygen bubble after 3 hours with the trees ashes with concentration, then with deionized water wash to neutral, oven dry;
(2), add in the trees ashes nano-sized carbon that is equivalent to its weight 2%, 1% 2,4,6-three (dimethylamino methyl) phenol, 2% α-cyanoacrylate, 1% linking agent TAC, 4% aluminium hydroxide, after stirring 25 minutes under 4800 rev/mins, ovendry power is broken into ultrafine powder and get final product.
Described a kind of chloroprene rubber and terpolymer EP rubber mixing and adhesive film for filter, the preparation method is: join by weight chloroprene rubber CR121 in vinylbenzene, be heated to 105 ℃, stirred 15 minutes, add by weight again 2,4,6-three (dimethylamino methyl) phenol, polyvinyl alcohol, N-2-(aminoethyl)-3-aminopropyl trimethoxysilane, polyisobutene, PTMG, stir reaction 1-2 hour; Add by weight again all the other raw materials, mixing to desired thickness, be trimmed to finally desired size and get final product.
Chloroprene rubber of the present invention and terpolymer EP rubber mixing and adhesive film for filter have higher shearing resistance and toughness, after using, the normal temperature shearing resistance can reach 260 kilograms every square centimeter of 250-, the shearing resistance of 150 ℃ can reach 100-110 kilograms every square centimeter, and uneven pulling intensity can reach every square centimeter of 50-53 kilogram.
During use, film of the present invention is stained with filter paper of filter and end cap,, then in the sulfuration of heating, keeps sealed state, dust can not occur flow through in gap.Can greatly improve the bond strength of its toughness and rubber and filter paper, durable in use.

Claims (3)

  1. a chloroprene rubber and terpolymer EP rubber mixing and adhesive film for filter, it is characterized in that: it is that raw material by following weight parts makes: chloroprene rubber CR121 130-133, vinylbenzene 15-20, 2,4,6-three (dimethylamino methyl) phenol 1-2, polyvinyl alcohol 8-12, the N-2-(aminoethyl)-3-aminopropyl trimethoxysilane 2-3, polyisobutene 2-3, PTMG 2-3, terpolymer EP rubber 5-8, brominated butyl rubber BBK-232 8-12, Vanay 3-5, epoxy oleum lini 2-5, glycerol glycerinate 2-5, magnesium oxide 2-5, Imarcaptoacetate dioctyltin 1-2, attapulgite 15-20, nano barite powder 20-25, bauxitic clay powder 20-25, carbon black N339 10-15, 3-aminopropyl trimethoxysilane 1-2, irgasfos 168 1-2, phenyl triethoxysilane 1-2, silane coupling agent KH570 1-2, anti-aging agent ODA 1-2, anti-aging agent RD 1-2, 2-thiol group benzimidazolyl 1-2, accelerant CZ 1-2, accelerator CBS 0.5-1.5, ferrocene 1-2, modification trees ashes 1.3-2.1,
    The preparation method of described modification trees ashes is:
    (1), be the dioxygen bubble of 15-20% after 2-3 hour with the trees ashes with concentration, then with deionized water wash to neutral, oven dry;
    (2), add 2 of the nano-sized carbon that is equivalent to its weight 2-3%, 1-2% in the trees ashes, 4, the α-cyanoacrylate of 6-three (dimethylamino methyl) phenol, 2-3%, the linking agent TAC of 1-2%, the aluminium hydroxide of 3-5%, after stirring 20-30 minute under 4500-4800 rev/min, ovendry power is broken into ultrafine powder and get final product.
  2. A kind of chloroprene rubber according to claim 1 and terpolymer EP rubber mixing and adhesive film for filter, it is characterized in that: the preparation method is: join by weight chloroprene rubber CR121 in vinylbenzene, be heated to 100-110 ℃, stir 10-15 minute, add by weight 2 again, 4,6-three (dimethylamino methyl) phenol, polyvinyl alcohol, N-2-(aminoethyl)-3-aminopropyl trimethoxysilane, polyisobutene, PTMG, stir reaction 1-2 hour; Add by weight again all the other raw materials, mixing to desired thickness, be trimmed to finally desired size and get final product.
  3. A kind of chloroprene rubber according to claim 1 and terpolymer EP rubber mixing and adhesive film for filter, it is characterized in that: described terpolymer EP rubber is German bright Sheng 5962.
CN2012104164942A 2012-10-27 2012-10-27 Filter adhesive film prepared by mixing neoprene and ethylene propylene diene monomer (EPDM) Active CN102952478B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012104164942A CN102952478B (en) 2012-10-27 2012-10-27 Filter adhesive film prepared by mixing neoprene and ethylene propylene diene monomer (EPDM)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2012104164942A CN102952478B (en) 2012-10-27 2012-10-27 Filter adhesive film prepared by mixing neoprene and ethylene propylene diene monomer (EPDM)

Publications (2)

Publication Number Publication Date
CN102952478A CN102952478A (en) 2013-03-06
CN102952478B true CN102952478B (en) 2013-11-13

Family

ID=47761885

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2012104164942A Active CN102952478B (en) 2012-10-27 2012-10-27 Filter adhesive film prepared by mixing neoprene and ethylene propylene diene monomer (EPDM)

Country Status (1)

Country Link
CN (1) CN102952478B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103601991A (en) * 2013-10-28 2014-02-26 安徽东方金河精密机械制造有限公司 Novel environment protective sealing ring for capacitor and preparation method thereof
CN104086902B (en) * 2014-07-02 2016-04-27 合肥市再德高分子材料有限公司 A kind of automobile high-temperature resistant rubber sealing-ring

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101033298A (en) * 2006-03-09 2007-09-12 廊坊开发区深思博远新材料技术有限公司 Coiled material with environmental protection function and use thereof
CN102229785A (en) * 2011-05-13 2011-11-02 秦琪航 Adhesive film for filter
CN102277105A (en) * 2011-08-10 2011-12-14 佛山市豹王滤芯制造有限公司 High-temperature resistant adhesive for filter cleaner of automobile

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7589145B2 (en) * 2004-04-15 2009-09-15 Exxonmobil Chemical Patents Inc. Syndiotactic rich polyolefins

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101033298A (en) * 2006-03-09 2007-09-12 廊坊开发区深思博远新材料技术有限公司 Coiled material with environmental protection function and use thereof
CN102229785A (en) * 2011-05-13 2011-11-02 秦琪航 Adhesive film for filter
CN102277105A (en) * 2011-08-10 2011-12-14 佛山市豹王滤芯制造有限公司 High-temperature resistant adhesive for filter cleaner of automobile

Also Published As

Publication number Publication date
CN102952478A (en) 2013-03-06

Similar Documents

Publication Publication Date Title
CN103087431A (en) Chlorosulfonated polyethylene (CSM) rubber/butyl rubber gasket and preparation method thereof
CN102993517A (en) Chloroprene rubber gasket with high abrasion resistance and preparation method thereof
CN102977486B (en) Chlorosulfonated polyethylene rubber gasket of a kind of nanoclay modification and preparation method thereof
CN104961968A (en) Preparation technique for glass fiber composite material
CN102796289B (en) Preparation method for modified waste rubber powder/natural rubber composite material
CN103275625A (en) Adhesive for quickly mutually sticking vulcanized silicone rubbers and preparation method of adhesive
CN102952478B (en) Filter adhesive film prepared by mixing neoprene and ethylene propylene diene monomer (EPDM)
CN102993515A (en) Nano bentonite modified chloroprene rubber gasket and preparation method thereof
CN102952468B (en) Filter adhesive film prepared by mixing neoprene and brominated butyl rubber
CN102952486B (en) Adhesive film containing modified montmorillonite powder for filter
CN102952484B (en) Filter film adhesive compounded by neoprene and chlorosulfonated polyethylene rubber
CN105694239A (en) Waste PCB (printed circuit board) nonmetal powder/EPDM rubber composite material and preparation method thereof
CN102952480B (en) Filter adhesive film containing nano calcium carbonate
CN102952487B (en) Adhesive film containing modified nano diatomite for filter
CN102993682B (en) High-property epichlorohydrin rubber gasket and preparation method thereof
CN102942885B (en) A kind of alcohol type glue economic benefits and social benefits auxiliary agent and its preparation method and application
CN102952488B (en) Epoxy soybean oil modified adhesive film for filter
CN103938449A (en) Paint for train tarpaulin fabric
CN102977582B (en) Chlorohydrin rubber gasket of a kind of nano diatomite modification and preparation method thereof
CN102952469B (en) High-strength compound adhesive film for filter
CN108148534B (en) Double-component silane modified sealant for industrial buildings
CN102952479B (en) Film adhesive containing modified complex formulation powder used for filter
CN102952477B (en) Filter adhesive film containing nano barite powder
CN102952476B (en) Filter adhesive film containing nanometer attapulgite
CN102952485A (en) Adhesive film containing modified nano potassium feldspar powder for filter

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C56 Change in the name or address of the patentee

Owner name: ANHUI PHOENIX INTERNATIONAL CO., LTD.

Free format text: FORMER NAME: BENGBU FENGHUANG FILTERS CO., LTD.

CP01 Change in the name or title of a patent holder

Address after: 233000 Mount Huangshan Road, Bengbu high tech Zone, Anhui, No. 8028

Patentee after: ANHUI PHOENIX FILTER CO., LTD.

Address before: 233000 Mount Huangshan Road, Bengbu high tech Zone, Anhui, No. 8028

Patentee before: Bengbu Fenghuang Filters Co., Ltd.