CN102942875B - A kind of concentrated solution for the preparation of polishing leather care products and purposes - Google Patents
A kind of concentrated solution for the preparation of polishing leather care products and purposes Download PDFInfo
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Abstract
The invention discloses a kind of concentrated solution for the preparation of polishing leather care products and purposes.This concentrated solution in cold water can rapid solution, stablize not stratified, still there is after within dilution thirtyfold number excellent glazing and nursing effect, be very suitable for the production application of the leather nursing glazing products such as functional wipes, convenient interpolation, without the need to emulsification process.
Description
Technical field
The present invention relates to a kind of concentrated solution and purposes of polishing leather care products, be mainly used in the preparation of polishing leather care products.
Background technology
Polishing leather care products mainly comprises in the market: one is polishing leather nursing sprays, is mainly used in the glossing care of fur clothing, leather sofa and automotive leather interior trim; One is polishing leather conditioning liquid, adopts the cotton of nursing brush or other softness to carry out wiping leatherware; Also have one to be polishing leather nursing wet tissue, main employing has the steeping fluid of glossing care effect, and with non-woven fabrics as carrier, wiping leatherware is disposable product.Leather nursing glazing spray and glazing liquid, owing to carrying inconvenience, limit its use range.Wet tissue as one-time consumption product in recent years growth and develop rapidly.Its functional product, as kitchen cleaning wet tissue, polishing leather nursing wet tissue, cleaning glass wet tissue etc., is more and more subject to the favor of consumers in general.
Polishing leather nursing generally all adopts the organic composition with nursing and glazing, such as vegetable wax, animal wax, mineral wax, synthesis modification wax, organosilicon etc.As the steeping fluid of wet tissue, generally all adopt the form of emulsion to give the function of nursing glazing.But for wet tissue manufacturing enterprise, a large amount of production emulsion is cumbersome thing.Show as: first is power consumption, preparation emulsion needs more than heated aqueous to 80 DEG C, again the oil phases such as various solid wax are heated to more than fusing point, being stirred to solid wax is dissolved completely in oil phase, aqueous phase is slowly joined in oil phase, Keep agitation carries out mixing and emulsifying, and this needs considerable heat energy; Even if adopt low-energy emulsification method, because turnout is large, also consume energy very much, lower the temperature after emulsification again, heat energy major part all lost, and does not meet the mode of production of current environmental protection.Second is consuming time, and in whole emulsion process, heat-up time of aqueous phase and oil phase, mixing and emulsifying time and temperature fall time, need the time longer, be unfavorable for scale operation.3rd is need special equipment, and traditional stirred autoclave can not reach the function demand of emulsification, and preparation emulsion needs emulsion tank, and this occupies very large cost in production.Therefore, the leather nursing glazing wet tissue concentrated solution that preparation a kind of (cold water is prepared, rapid solution) easy to use, diluent good stability, use (can carry out allotment of filling a prescription) flexibly is as required necessary.
To nurse special wet tissue concentrated solution fewer for polishing leather in the market.This concentrated solution not only will ensure stability and the glossing care function of diluting rear solution, also will ensure that glossing care active component content is enough high, the glossing care function of diluent after such guarantee dilution.China Patent Publication No. CN101802117A, publication date on 08 11st, 2008, invention and created name " not containing the polish product of volatile constituent ", this application case discloses a kind of polish product, comprises the wax component of 20-60%, the non-aqueous non-volatile liquid component of 20-60%, and the lipid fraction of 1-40%, preferably 5-15%, preferred fatty acid, mainly with the small pieces of solid that thickener form exists, is not suitable for preparation wet tissue.
China Patent Publication No. CN1297012A, 05 month 30 days publication date calendar year 2001, invention and created name " a kind of general fur clothing, leather nursing glazing liquid formula and working method thereof ", comprise brightening agent, mould inhibitor, antioxidant etc., brightening agent have employed the materials such as Ka Nabala, has the functions such as nursing glazing.China Patent Publication No. CN1167798A, publication date on December 17th, 1997, invention and created name " spray leahter care polishing agent ", comprise with Nitrocellulose is brightening agent main body, add that acrylic resin is protected light and protected look, and allocate ethyl acetate, silicone oil, dibutyl phthalate, positive alcohol etc. into.Prior art is all generally the nursing being directly used in leatherware, use as wet tissue concentrated solution, mainly contain 2 disadvantages: one is fill a prescription not consider dilution problem, may produce breakdown of emulsion, precipitation in the process of application, two is that after dilution, polishing effect is not very desirable.
Summary of the invention
The invention provides one to can be used for preparing polishing leather care products, as the concentrated solution of wet tissue, cloth for cleaning, cotton etc., its objective is in order to provide a kind of can the polishing leather nursing concentrated solution of rapid solution dispersion in cold water (general 10 ~ 15 DEG C), and the emulsion-stabilizing formed is not stratified.Concentrated solution of the present invention, optimizes the formula of polishing leather nursing activeconstituents, still has excellent stability after within dilution thirtyfold number; Find simultaneously, after adding emulsifying animal grease, can significantly improve the polishing effect of diluent, be very suitable for the production application of the leather nursing glazing products such as functional wipes in concentrated solution, convenient interpolation, without the need to emulsification process.
According to the present invention, described concentrated solution comprises:
A) oil phase component of 0.5 ~ 50 % by weight;
B) emulsifier component of 0.15 ~ 30 % by weight;
C) water phase components of 40 ~ 98 % by weight;
D) binder component of 0.05 ~ 5 % by weight.
Described A) oil phase component comprises animal grease, and they are mixtures of a kind of in lard, butter, sheep oil or at least two kinds, also containing the lustering agent component playing glossiness-giving effect;
A in described concentrated solution) lustering agent is at least one in glossing care wax, silicone oil in oil phase.
A in described concentrated solution) oil phase weight % is preferably 2.0 ~ 40, is more preferably 3.0 ~ 35;
B in described concentrated solution) emulsifying agent % by weight is preferably 0.8 ~ 25, is more preferably 1.0 ~ 20;
C in described concentrated solution) aqueous phase % by weight is preferably 45 ~ 95, is more preferably 50 ~ 90;
D in described concentrated solution) weight of additive % is preferably 0.2 ~ 4.5, is more preferably 0.5 ~ 2.
The present invention also comprises the purposes of described concentrated solution for the preparation of leather nursing glazing product (as wet tissue, cloth for cleaning, cotton), the nursing that described product is specifically excellent and glazing effect.
The present invention also comprises described concentrated solution can also for the preparation of leather sprays, glossing care liquid product.
The present invention also comprises a kind of leather nursing glazing product (as wet tissue, cloth for cleaning, cotton, sprays, glossing care liquid) containing concentrated solution, the nursing that this product is specifically excellent and glazing effect.Described concentrated solution comprises:
A) oil phase component of 0.5 ~ 50 % by weight; % by weight is preferably 2.0 ~ 40, is more preferably 3.0 ~ 35;
B) emulsifier component of 0.15 ~ 30 % by weight; % by weight is preferably 0.8 ~ 25, is more preferably 1.0 ~ 20;
C) water phase components of 40 ~ 98 % by weight; % by weight is preferably 45 ~ 95, is more preferably 50 ~ 90;
D) binder component of 0.05 ~ 5 % by weight; % by weight is preferably 0.2 ~ 4.5, is more preferably 0.5 ~ 2.
Described A) oil phase component comprises animal grease, and they are mixtures of a kind of in lard, butter, sheep oil or at least two kinds, also containing the lustering agent component playing glossiness-giving effect;
A in described concentrated solution) lustering agent is at least one in glossing care wax, silicone oil in oil phase.
The present invention also comprises a kind of preparation method of the leather nursing glazing product (as wet tissue, cloth for cleaning, cotton) containing concentrated solution, comprising: a) get leather nursing glazing product material ready; B) apply after described concentrated solution dilution 20 ~ 300 times or be soaked on material; C) leather nursing glazing product is prepared into; Leather nursing glazing product prepared by the method has excellent nursing and polishing effect.Described concentrated solution comprises:
A) oil phase component of 0.5 ~ 50 % by weight; % by weight is preferably 2.0 ~ 40, is more preferably 3.0 ~ 35;
B) emulsifier component of 0.15 ~ 30 % by weight; % by weight is preferably 0.8 ~ 25, is more preferably 1.0 ~ 20;
C) water phase components of 40 ~ 98 % by weight; % by weight is preferably 45 ~ 95, is more preferably 50 ~ 90;
D) binder component of 0.05 ~ 5 % by weight; % by weight is preferably 0.2 ~ 4.5, is more preferably 0.5 ~ 2.
Described A) oil phase component comprises animal grease, and they are mixtures of a kind of in lard, butter, sheep oil or at least two kinds, also containing the lustering agent component playing glossiness-giving effect;
In described concentrated solution, in A oil phase, lustering agent is at least one in glossing care wax, silicone oil.
In described concentrated solution, in A oil phase component, glossing care wax is animal wax, vegetable wax, mineral wax or synthetic wax; Be specially: animal wax is the mixture of a kind of in beeswax, Insect Wax, spermaceti, shellac wax or at least two kinds; Vegetable wax is the mixture of a kind of in rice bran wax, carnauba wax, gama wax, Chinese haze tallow or at least two kinds; Mineral wax is the mixture of a kind of in paraffin, Microcrystalline Wax, montanin wax or at least two kinds; Synthetic wax is the mixture of a kind of in polyethylene wax, oxidized polyethlene wax, hydrogenated castor oil wax, S wax, E wax or at least two kinds.
In described concentrated solution, in A oil phase component, silicone oil specifically comprises the silicone oil of following structure:
In formula, R is alkyl, aryl, and R' is alkyl, aryl, hydrogen, carbon functional group and polyether chain etc.; X is alkyl, aryl, alkenyl, hydrogen, hydroxyl, alkoxyl group, acetoxyl group, chlorine, carbon functional group and polyether chain etc.; N, m=0,1,2,3 Such as, methyl-silicone oil, dimethyl silicone oil, ethyl silicon oil, phenyl silicone oil etc.
In described concentrated solution, B emulsifier component has the Compositional type emulsifying agent of HLB value (i.e. hydrophile-lipophile balance value) between 6 ~ 20, composite by different emulsifying agents, not only can regulate HLB value, more can coordinate the emulsification property of each emulsifying agent, make final emulsion more stable.Specifically contain the mixture of in following four class emulsifying agents two kinds or at least three kinds, Ta Menshi:
1) emulsifying agent containing following structure:
In formula, R is alkyl; N=3,8,9,10,15,20,25,30,35;
2) emulsifying agent containing following structure:
In formula, R is alkyl; N > 6;
3) sorbitan fatty acid ester, commodity are called sapn, are selected from the mixture of a kind of in Arlacel-20, Arlacel-40, Arlacel-60, Arlacel-80 or at least two kinds.
4) polyoxyethylene sorbitan fatty acid ester, commodity are called tween, are selected from the mixture of a kind of in tween 20, Tween-40, Tween-60, tween-80 or at least two kinds.
In described concentrated solution, B emulsifier component also comprises the mixture of a kind of in the condenses of the condenses of Sodium dodecylbenzene sulfonate, palmityl trimethyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride, cetalkonium chloride, dodecyl benzyl dimethyl ammonium chloride, oxyethane and Viscotrol C, hydrogenated castor oil and oxyethane, ethoxylated alkyl sulfate or at least two kinds.
In described concentrated solution, C water phase components is water-soluble component, is specifically selected from the mixture of a kind of in butyleneglycol, propylene glycol, C16 ~ 18 alcohol, pentanediol, propyl carbinol, primary isoamyl alcohol or at least two kinds and water.
In described concentrated solution, D binder component is trolamine, sodium cellulose glycolate, Walocel MT 20.000PV, Natvosol, sodium hydroxyethyl cellulose, methylisothiazolinone, methylchloroisothiazandnone, BIT, bronopol, diazonium Imidurea, Imidurea, DMDMH (namely 1, two (methylol)-5 of 3-, 5-methylimidazole quinoline-2,4-diketone), the mixture of in methylol glycine sodium two kinds or at least three kinds.
Concentrated solution of the present invention can adopt this area ordinary method preparation; Or preparation method is: 1. by A) and B) component mixing post-heating to melted state, be incubated 20 ~ 60 minutes, use as oil phase; 2. by C) be heated to 80 ~ 90 DEG C, be incubated 20 ~ 60 minutes, use as aqueous phase; 3. after emulsion tank is heated to 80 DEG C, oil phase is added emulsion tank, then 1/3 aqueous phase is slowly added in emulsion tank, again by remaining aqueous phase suction, high-speed stirring, homogeneous 10 ~ 40 minutes, emulsification is complete, be incubated 20 ~ 60 minutes, be cooled to 40 DEG C after add D) component, continuation stirring 5 ~ 10 minutes.
Polishing leather care products of the present invention includes but not limited to wet tissue, cloth for cleaning, cotton etc.
The present invention is advantageously: concentrated solution both can dilute at cold water, and the diluent formed is stablized not stratified, to leather, there is excellent nursing and the effect of glazing simultaneously, be very suitable for the production application of polishing leather care products, convenient interpolation, without the need to a large amount of emulsification process, existing extraordinary economic benefit, has again good environment-friendly production process.
Embodiment
The following stated embodiment describes the present invention in detail.In these embodiments, all consumptions all be weight %.
Embodiment 1
The preparation method of numbering 1 to No. 12 concentrated solution is: 1. by A) and B) component mixing post-heating to melted state, be incubated 20 ~ 60 minutes, use as oil phase; 2. by C) be heated to 80 ~ 90 DEG C, be incubated 20 ~ 60 minutes, use as aqueous phase; 3. after emulsion tank is heated to 80 DEG C, oil phase is added emulsion tank, then 1/3 aqueous phase is slowly added in emulsion tank, again by remaining aqueous phase suction, high-speed stirring, homogeneous 10 ~ 40 minutes, emulsification is complete, insulation half an hour, be cooled to 40 DEG C after add D) component, continue stirring 5 ~ 10 minutes.
Table 1. is respectively filled a prescription charging capacity
Note:
AEO-n, n=10,15,20 are fatty alcohol-polyoxyethylene ether, and S-40 is Arlacel-40, S-60 Arlacel-60, S-80 Arlacel-80, T-60 is Tween-60, T-40 is Tween-40, and EL-10 is the condenses of oxyethane and Viscotrol C, and HEL-20 is the condenses of oxyethane and hydrogenated castor oil.
Embodiment 2
Diluent stability, by numbering 1 to No. 12 concentrated solution in embodiment 1 with after cold water (11 DEG C) dilution 5 ~ 30 times, within 24 hours, observe whether layering, the results are shown in Table 2, the diluent of visible concentrated solution of the present invention does not have demixing phenomenon, has good stability.
The stability of table 2. diluent
The evaluation of embodiment 3 glossing care
Evaluate and adopt sensory evaluation method, respectively by after 1 to No. 12 contracting liquid dilution of numbering in dense embodiment 15,10 and 20 times, with spunlace non-woven cloth (cotton content 60%) dipping, water content control is at the 300%-400% of non-woven weight, for subsequent use.
With this wet tissue wiping designated area on leather sofa, area is 10cm × 10cm, and evaluation score is 25,50,75 and 100, is expressed as glossing care poor effect, general, better, very well successively.Evaluation number is 5 people, averages after test, and its result is as shown in table 3.
Table 3. glossing care evaluation result
As can be seen from Table 3, concentrated solution of the present invention, after dilution 20 times, evaluation score, more than 50, still has certain glossing care effect, after dilution 5 and 10 times, has preferably glossing care effect.Wherein formulation examples 11 and 12 contrasts, and on identical basic components, adds the formula after butter 11, has significant polishing effect.
Claims (16)
1. for the preparation of a concentrated solution for polishing leather care products, it is characterized in that, described concentrated solution is composed of the following components:
A) oil phase component of 0.5 ~ 50 % by weight;
B) emulsifier component of 0.15 ~ 30 % by weight;
C) water phase components of 40 ~ 98 % by weight;
D) binder component of 0.05 ~ 5 % by weight;
Described A) oil phase component comprises animal grease, and they are mixtures of a kind of in lard, butter, sheep oil or at least two kinds, also containing the lustering agent component playing glossiness-giving effect;
Described D) binder component is the mixture of a kind of in a kind of or at least two kinds of mixtures in trolamine, sodium cellulose glycolate, Walocel MT 20.000PV, Natvosol, sodium hydroxyethyl cellulose and methylisothiazolinone, methylchloroisothiazandnone, BIT, bronopol, diazonium Imidurea, Imidurea, DMDMH, Sodium hydroxymethyl glycinate or at least two kinds.
2. concentrated solution according to claim 1, is characterized in that, A in described concentrated solution) lustering agent is at least one in glossing care wax, silicone oil in oil phase.
3. concentrated solution according to claim 2, is characterized in that, in described lustering agent component, glossing care wax is animal wax, vegetable wax, mineral wax or synthetic wax.
4. concentrated solution according to claim 3, is characterized in that, described animal wax is the mixture of a kind of in beeswax, Insect Wax, spermaceti, wool wax or at least two kinds; Vegetable wax is the mixture of a kind of in rice bran wax, carnauba wax, gama wax, Chinese haze tallow, sugar-cane wax, laurel wax or at least two kinds; Mineral wax is the mixture of a kind of in paraffin, Microcrystalline Wax, montanin wax or at least two kinds; Synthetic wax is the mixture of a kind of in polyethylene wax, oxidized polyethlene wax, hydrogenated castor oil wax, S wax, E wax or at least two kinds.
5. concentrated solution according to claim 2, is characterized in that, in described lustering agent component, silicone oil is the silicone oil comprising following structure:
In formula, R is alkyl, aryl, and R' is alkyl, aryl, hydrogen, carbon functional group and polyether chain; X is alkyl, aryl, alkenyl, hydrogen, hydroxyl, alkoxyl group, acetoxyl group, chlorine, carbon functional group and polyether chain; N, m=0,1,2,3 ...
6. concentrated solution according to claim 1, is characterized in that, B in described concentrated solution) emulsifier component comprises the mixture of in following four class emulsifying agents two kinds or at least three kinds, Ta Menshi:
1) emulsifying agent containing following structure:
In formula, R is alkyl; N=3,8,9,10,15,20,25,30,35;
2) emulsifying agent containing following structure:
In formula, R is alkyl; N > 6;
3) sorbitan fatty acid ester;
4) polyoxyethylene sorbitan fatty acid ester.
7. concentrated solution according to claim 6, is characterized in that, described sorbitan fatty acid ester is the mixture of a kind of in Arlacel-20, Arlacel-40, Arlacel-60, Arlacel-80 or at least two kinds; Described polyoxyethylene sorbitan fatty acid ester is the mixture of a kind of in tween 20, Tween-40, Tween-60, tween-80 or at least two kinds.
8. concentrated solution according to claim 6, wherein also includes the mixture of a kind of in the condenses of the condenses of Sodium dodecylbenzene sulfonate, palmityl trimethyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride, cetalkonium chloride, dodecyl benzyl dimethyl ammonium chloride, oxyethane and Viscotrol C, hydrogenated castor oil and oxyethane, ethoxylated alkyl sulfate or at least two kinds.
9. concentrated solution according to claim 1, is characterized in that, C in described concentrated solution) water phase components is a kind of in butyleneglycol, propylene glycol, C16 ~ 18 alcohol, pentanediol, propyl carbinol, primary isoamyl alcohol or at least two kinds and the mixture of water.
10., according to the arbitrary described concentrated solution of claim 1 ~ 9, it is characterized in that,
A in described concentrated solution) oil phase weight % is 2.0 ~ 40;
B in described concentrated solution) emulsifying agent % by weight is 0.8 ~ 25;
C in described concentrated solution) aqueous phase % by weight is 45 ~ 95;
D in described concentrated solution) weight of additive % is 0.2 ~ 4.5;
Described A) oil phase component comprises animal grease, and they are mixtures of a kind of in lard, butter, sheep oil or at least two kinds, also containing the lustering agent component playing glossiness-giving effect.
11. concentrated solutions according to claim 10, is characterized in that,
A in described concentrated solution) oil phase weight % is 3.0 ~ 35;
B in described concentrated solution) emulsifying agent % by weight is 1.0 ~ 20;
C in described concentrated solution) aqueous phase % by weight is 50 ~ 90;
D in described concentrated solution) weight of additive % is 0.5 ~ 2;
Described A) oil phase component comprises animal grease, and they are mixtures of a kind of in lard, butter, sheep oil or at least two kinds, also containing the lustering agent component playing glossiness-giving effect.
12. according to the purposes of the arbitrary described concentrated solution of claim 1 ~ 11, for the preparation of leather nursing glazing product.
13. 1 kinds of leather nursing glazing products containing concentrated solution, is characterized in that, described concentrated solution is the arbitrary described concentrated solution of claim 1 ~ 11.
The preparation method of 14. 1 kinds of leather nursing glazing products containing concentrated solution, comprising: a) get leather nursing glazing product material ready; B) apply after described concentrated solution dilution 20 ~ 300 times or be soaked on material; C) leather nursing glazing product is prepared into; Leather nursing glazing product prepared by the method has excellent nursing and polishing effect; Described concentrated solution is the arbitrary described concentrated solution of claim 1 ~ 11.
15., according to the preparation method of the arbitrary described concentrated solution of claim 1 ~ 11, is characterized in that, 1. by A) and B) component mixing post-heating is to melted state, insulation 20-60 minute, uses as oil phase; 2. by C) be heated to 80 ~ 90 DEG C, insulation 20-60 minute, uses as aqueous phase; 3. after emulsion tank is heated to 80 DEG C, oil phase is added emulsion tank, then 1/3 aqueous phase is slowly added in emulsion tank, again by remaining aqueous phase suction, high-speed stirring, homogeneous 10 ~ 40 minutes, emulsification is complete, be incubated 20-60 minute, be cooled to 40 DEG C after add D) component, continue stirring 5 ~ 10 minutes.
16. according to the purposes of the arbitrary described concentrated solution of claim 1 ~ 11, for the preparation of leather sprays and polishing leather conditioning liquid product.
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| CN103666281A (en) * | 2013-11-22 | 2014-03-26 | 南通信一服饰有限公司 | Stain removal and leather softening shoe polish |
| CN103667549A (en) * | 2013-11-22 | 2014-03-26 | 南通信一服饰有限公司 | Caring brightener for leather clothing |
| CN103669002A (en) * | 2013-11-27 | 2014-03-26 | 南通市通州区川姜镇盛世王朝家用纺织品设计工作室 | Leather softener |
| CN103642954A (en) * | 2013-12-12 | 2014-03-19 | 诺斯贝尔(中山)无纺日化有限公司 | Care wet tissue for cleaning and polishing leather |
| CN105342945A (en) * | 2015-08-06 | 2016-02-24 | 铜陵百锐设备配件有限公司 | Fleece care solution |
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| CN105623529A (en) * | 2016-01-11 | 2016-06-01 | 上海馨臣家化有限公司 | Silicon-oil-containing leather cleaning glazing caring wet tissue |
| CN105950023A (en) * | 2016-06-29 | 2016-09-21 | 宋春燕 | Leather polishing agent |
| CN106047181A (en) * | 2016-06-29 | 2016-10-26 | 宋雁群 | Leather glazing agent |
| CN107663424A (en) * | 2016-07-28 | 2018-02-06 | 金猴集团威海鞋业有限公司 | A kind of New-type leather glazing moistening cleaning tissue |
| CN108587193B (en) * | 2018-04-16 | 2021-05-11 | 江南大学 | Double-dispersion type composite wax emulsion and preparation method thereof |
| CN110129148A (en) * | 2019-06-18 | 2019-08-16 | 黄婷 | A kind of efficient cleaner for automobile interiors |
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