CN102924124B - Ceramic tile with embossed textures - Google Patents
Ceramic tile with embossed textures Download PDFInfo
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- CN102924124B CN102924124B CN201210388434.4A CN201210388434A CN102924124B CN 102924124 B CN102924124 B CN 102924124B CN 201210388434 A CN201210388434 A CN 201210388434A CN 102924124 B CN102924124 B CN 102924124B
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Abstract
The invention relates to the technical field of construction ceramics, and in particular discloses a ceramic tile with embossed textures, which is formed by processing a blank and glaze. The ceramic tile is characterized in that: the glaze is prepared from the following basic components in percentage by weight: 5 to 20 percent of frit, 5 to 15 percent of magnesium oxide, 5 to 15 percent of alumina, 10 to 30 percent of camwood segments, and 20 to 50 percent of bentonite. The invention also discloses a method for manufacturing the ceramic tile with embossed texture, which comprises the following steps of: preparing the blank and glaze; forming a tile blank; applying the glaze; firing; and cooling to a normal temperature. According to the ceramic tile with embossed textures disclosed by the invention, the formation of embossed textures does not require an embossed die, and a natural smooth, continuously changing and non-repeated embossed texture surface decorating effect is represented on the manufactured ceramic tile without artificial trace by virtue of the glaze prescription and process parameter design.
Description
Technical field
The present invention relates to architectural pottery technical field, specifically relate to a kind of Z-Correct bump mapping Z-correct ceramic tile that has.
Background technology
Ceramic tile is by clay and other inorganic non-metallic raw materials, through the tabular or block ceramic of the explained hereafter such as moulding, sintering, for decorating and metope and the ground of protecting buildings, structures, is one of main material of current interior decoration.Along with the raising of people's living standard, for the constantly new requirement of proposition of decorative effect of ceramic tile, increasing people wishes that ceramic tile can present the Z-Correct bump mapping Z-correct of imitative natural dermatoglyph, wood grain etc.
CN102029644A discloses a kind of production technique of wood grain antique brick, comprises the steps: that (1) prepare blank, cover-coat enamel and fancy glaze; (2) blank moulding in mould brick forms base brick, and mould brick is provided with rough lines, and the degree of depth of rough lines is in the scope of 1.0mm-2.0mm, and the pressure of blank moulding is 3300MPa/cm
2-3700MPa/cm
2; (3) the base brick sintering after moulding is dry, and sintering temperature is 1170 ℃-1200 ℃; (4) dry body drenches glaze, and the mobility of glaze slip is 30S/100M1-40S/100M1, fluctuates as 0S-5S, and glaze slip proportion is 170g/cm
2-190g/cm
2, glaze amount is 0.01g/cm
2-0.08g/cm
2; (5) screen printing fancy glaze, the tension degree of silk screen is 20MPa/cm
2-24MPa/cm
2; (6) enter klining; (7) edging.
CN1843735A discloses a kind of manufacturing process with the ceramic tile of fine raised grain, by pressing brick shaping mould to suppress surface, there is the concave surface that numerous irregular distributions and shape do not advise, the adobe of convex surface, the degree of depth between each concave surface and convex surface is all below 1mm and deep mixed, and the area of each concave surface and convex surface is all at 15mm
2below and not of uniform size; After brick bat drying, stamp, glazing, high-temperature firing; Adopt Spring grinding head to carry out micro-polishing grinding to the adobe of burning till, the degree of depth of each concave surface of adobe surface is reduced to below 0.7mm, and polished area accounts for the 40-70% of full brick area, and account for the 60-30% of full brick area because of the not polished area of depression, obtain finished product, this technique can make brick face form polishing glaze, the fine raised grain of the various forms such as polishing glaze, polishing base face not, makes ceramic brick surface have gentle soft gloss and is rich in the visual effect of leather texture.
CN101157571A discloses a kind of production method of ceramic tile and ceramic tile of production thereof with convex-concave surface, the method comprise preparation have convex-concave surface base substrate, billet surface glazing, polish glaze, then printing ornament, finally burn till, it is characterized by: through described in polish after, the area of the glaze that is not ground to surface concave surface is compared the area of base substrate concave surface before not glazing and has been reduced more than 50%.The production method of the ceramic tile with convex-concave surface so has not only overcome the scarce colored defect at concave surface place, can also realize color or the different effect of texture of concave surface and convex surface or plane, and, have advantages of that compared to existing technology cost is low.
Aforesaid method is all by adopting male and female mold to make billet surface form texture, but because mould is inevitably with artificial trace, do not there is natural random decorative effect, therefore cause produced ceramic tile decorative effect stiff, stiff, unnatural; Meanwhile, if will obtain different textured patterns, need more mold exchange, cause production cost to increase; Also can not combine with other decorative pattern well.
Summary of the invention
The object of the invention is for the deficiencies in the prior art, a kind of Z-Correct bump mapping Z-correct ceramic tile that has is provided, the formation of the Z-Correct bump mapping Z-correct of described ceramic tile is without utilizing male and female mold, but by special glaze formula and simple technological process, utilize lower cost to create, this ceramic tile can't have the naturally continuous Z-Correct bump mapping Z-correct decorative effect of artificial trace.
For achieving the above object, the present invention adopts following technical scheme:
A kind of have a Z-Correct bump mapping Z-correct ceramic tile, by blank and glaze, processed, described glaze is by comprising that the basal component according to following weight percent is formulated: pre-fusion thing 5-20wt%, magnesium oxide 5-15wt%, aluminum oxide 5-15wt%, camwood knag 10-30wt%, wilkinite 20-50wt%.
Described pre-fusion thing refers to the molten mixture of stannic oxide, sodium carbonate, raw talcum and zinc oxide.
Preferably, in described pre-fusion thing, the weight ratio of stannic oxide, sodium carbonate, raw talcum and zinc oxide is 1:2:2:1.
Preferably, the melt temperature of described pre-fusion thing is 1150-1450 ℃.
Described stannic oxide is tindioxide, and its strong adhesion can reach 20MPa with ceramic bonding force, and Mohs' hardness is 7-8, and chemical stability is good, can stand chemical etching, because its specific refractory power to light is high, plays good milkiness effect in glaze formula.
Described sodium carbonate is one of important industrial chemicals, has fluxing action.
Described raw talcum refers to the talcum powder that does not pass through pyroprocessing, its main component is the moisture Magnesium Silicate q-agent of talcum, good physics, the chemical property such as have that surface tension sticks, helps that stream, fire-resistant, antiacid, insulation, fusing point are high greatly, lubricated, anti-, chemical property torpescence, opacifying power are good, good luster, adsorptive power are strong, with its manufacture ceramic product there is whiteness enhancing, even density after high temperature nondiscoloration, calcination, glossiness is good and surface smoothing.In glaze drying process, large because giving birth to talcum surface tension, as excessive in the add-on in formula, easily cause glaze season cracking degree to cross dark and cause kiln-made product glaze became uneven, when affecting glaze decorating effect, also easily produce the phenomenon of glaze cracking, this is also the reason place that raw talcum is made to frit.
Described zinc oxide is commonly called as zinc white, is a kind of conventional chemical additives in field such as plastics, silicate product, synthetic rubber, lubricating oil, paint, is often used to the element of the salt facile hydrolysiss such as precipitated iron, chromium, vanadium, titanium and zirconium.At ceramic field, zinc oxide mainly plays the effect of fusing assistant, and because being subject to the impact of smelting and extraction process, zinc oxide is larger for glaze slip performance impact, easily causes glaze slip thixotroping, therefore be processed into frit.
The weight percent of described pre-fusion thing in described glaze is 5-20wt%, for example, can be 5-14wt%, 6.4-13wt%, 7.5-12.5wt%, 10-18wt%, 11-20wt%, 5wt%, 7wt%, 8.3wt%, 9wt%, 95wt%, 102wt%, 12wt%, 137wt%, 15wt%, 16wt%, 17wt%, 171wt%, 18.6wt%, 19wt%, 19.8wt%, 20wt%; Be preferably 8-18wt%; Most preferably be 10-15wt%.
Described magnesium oxide has extremely fireproof insulating property, for one of conventional stupalith, its weight percent in described glaze is 5-15wt%, for example, can be 5-8.4wt%, 6-11.3wt%, 8.5-12.5wt%, 7-14.6wt%, 9-15wt%, 5wt%, 5.1wt%, 6.6wt%, 7wt%, 7.7wt%, 8wt%, 9.3wt%, 9.9wt%, 10wt%, 11wt%, 12wt%, 13wt%, 13.5wt%, 14wt%, 14.8wt%, 15wt%; Be preferably 6-14wt%; Most preferably be 8-12wt%.
Described aluminum oxide is aluminium sesquioxide, it is high-temperature refractory conventional while making ceramic, its weight percent in described glaze is 5-15wt%, for example, can be 5.5-9wt%, 7-12.2wt%, 11-13.5wt%, 8-14.6wt%, 10-15wt%, 5wt%, 5.3wt%, 6.6wt%, 6.7wt%, 7.4wt%, 8.9wt%, 9.1wt%, 9.5wt%, 10.7wt%, 11.5wt%, 12wt%, 13wt%, 13.8wt%, 14wt%, 14.2wt%, 15wt%; Be preferably 6-14wt%; Most preferably be 8-12wt%.
Described camwood knag is the fireclay that a kind of plasticity-is good, its weight percent in described glaze is 10-30wt%, for example, can be 10-18wt%, 12.2-20wt%, 15-23.5wt%, 14-26wt%, 25-30wt%, 10wt%, 10.3wt%, 11wt%, 11.5wt%, 13.4wt%, 15.6wt%, 16.7wt%, 17wt%, 18.9wt%, 19wt%, 20.7wt%, 21wt%, 22.4wt%, 24wt%, 25.2wt%, 27.5wt%, 28wt%, 29.3wt%, 30wt%; Be preferably 15-25wt%; Most preferably be 18-22wt%.
Described wilkinite is to take the moisture clay that montmorillonite is main component, there are good sticking power, opacifying power, water tolerance, abrasion resistance etc., its weight percent in described glaze is 20-50wt%, for example, can be 20-37wt%, 25-40wt%, 35-45wt%, 30-44wt%, 23-30wt%, 20wt%, 20.7wt%, 22.4wt%, 26wt%, 28.5wt%, 30wt%, 33.4wt%, 35.1wt%, 36.7wt%, 38wt%, 39.3wt%, 40wt%, 41.5wt%, 45.6wt%, 48.9wt%, 50wt%; Be preferably 25-45wt%; Most preferably be 30-40wt%.
Further, in described glaze, can also comprise coloring oxide.
Described coloring oxide is Fe
2o
3, FeO, MnO, CuO, Cu
2o, TiO
2, CoO, Cr
2o
3, Nd
2o
3, Bi
2o
3in a kind of or mixture of at least two kinds, adding of coloring oxide can meet people as required for the demand of different colours and pattern.
The weight percent of described coloring oxide in described glaze is 0-5wt%, for example, can be 0.3-2wt%, 0.75-3wt%, 1-2.5wt%, 1.4-4wt%, 3.5-5wt%, 0,0.2wt%, 0.5wt%, 0.64wt%, 0.9wt%, 1.1wt%, 1.26wt%, 1.5wt%, 1.7wt%, 1.87wt%, 2.2wt%, 2.34wt%, 2.65wt%, 2.9wt%, 3.05wt%, 3.18wt%, 3.4wt%, 3.59wt%, 3.8wt%, 4.25wt%, 4.4wt%, 4.5wt%, 4.7wt%, 5wt%; Be preferably 1-4wt%; Most preferably be 2-3wt%.The weight percent of described coloring oxide in described glaze is 0, refers to and in glaze, do not contain coloring oxide.
Preferably, the fineness of described glaze is 250-500 order, for example, can be 250-385 order, 281-410 order, 350-436 order, 405-450 order, 305-500 order, 250 orders, 275 orders, 293 orders, 300 orders, 319 orders, 342 orders, 360 orders, 374 orders, 390 orders, 400 orders, 427 orders, 440 orders, 452 orders, 468 orders, 475 orders, 480 orders, 492 orders, 500 orders; 250-450 order more preferably; Most preferably be 250-325 order.
Preferably, the glaze layer thickness that described glaze is made is 0.5-3mm, for example, can be 0.5-1.5mm, 0.6-2.3mm, 1.7-2mm, 1.4-2.8mm, 2.5-3mm, 0.5mm, 0.6mm, 07mm, 0.8mm, 0.9mm, 1mm, 1.23mm, 1.35mm, 1.6mm, 1.8mm, 1.96mm, 2.1mm, 2.25mm, 2.4mm, 2.57mm, 2.6mm, 2.7mm, 2.9mm, 3mm; 1-2.5mm more preferably; Most preferably be 1.2-1.8mm.
" comprising " of the present invention, mean it except described component, described glaze can also contain other components, and these other components are given described glaze and described Z-Correct bump mapping Z-correct ceramic tile with different characteristics.No matter which kind of composition glaze of the present invention comprises, the weight percent sum of described glaze is 100%.In addition, " comprising " of the present invention, can also replace with enclosed " being " or " by ... make ".
It is above-mentioned that to have Z-Correct bump mapping Z-correct ceramic tile be produced according to following processing step:
(1) prepare blank, glaze.
(2) moulding adobe.
Blank, through brick pressing machine compression moulding automatically, is controlled green brick forming pressure at 5-7Kn/cm
2between.
(3) glazing.
Preferably, the mode of described glazing for drenching glaze, glaze spraying, the combination of getting rid of a kind of in glaze or dry powder cloth glaze or at least two kinds, most preferably be glaze spraying.
Preferably, after described glazing, the thickness of glaze layer is 0.5-3mm, and more preferably 1-2.5mm, most preferably is 1.2-1.8mm.
(4) fire.
Preferably, described in fire in roller kiln or shuttle kiln and carry out, most preferably be roller kiln.
Preferably, described in, fire in oxidizing atmosphere and carry out.Described oxidizing atmosphere, a kind of flame atmosphere that refers to that when firing furnace air is supplied with fully, produces complete combustion of fuel in the situation that.
Preferably, the described temperature of firing is normal temperature to 1200 ℃, can be for example normal temperature to 100 ℃, normal temperature to 500 ℃, 200-650 ℃, 305-900 ℃, 800-1100 ℃, 750-1200 ℃, normal temperature, 30 ℃, 64 ℃, 99 ℃, 118 ℃, 150 ℃, 210 ℃, 273 ℃, 300 ℃, 336 ℃, 400 ℃, 450 ℃, 500 ℃, 524 ℃, 600 ℃, 700 ℃, 850 ℃, 987 ℃, 1000 ℃, 1070 ℃, 1135 ℃, 1160 ℃, 1200 ℃.
Preferably, the described time of firing is 1-3h, for example, can be 1-1.6h, 1.2-1.8h, 1.45-2.4h, 1.5-2.7h, 2-3h, 1h, 1.1h, 1.3h, 1.79h, 1.9h, 2h, 2.06h, 2.1h, 2.25h, 2.3h, 2.5h, 2.62h, 2.8h, 2.95h, 3h; 1.2-2.8h more preferably; Most preferably be 1.5-2.5h.
In sintering procedure, magnesium oxide in formula, aluminum oxide play the capillary effect that increases glaze, when surface tension acquires a certain degree, glaze at high temperature forms reticulate pattern cracking, and simultaneously again because glaze is under high temperature fused state, its viscosity is large, so make the surrounding of reticulate pattern cracking as the island of protuberance, concavo-convex fluctuating, in picturesque disorder, thus make whole glaze self-assembling formation there is the decorative effect of Z-Correct bump mapping Z-correct outward appearance.
(5) be cooled to normal temperature.
In this technique, do not carry out polishing step, the ceramic tile obtaining is the Antique Imitation Tiles with dumb light texture.
Technical scheme after above-mentioned processing step optimization is:
(1) prepare blank, glaze;
(2) blank, through brick pressing machine compression moulding automatically, is controlled green brick forming pressure at 5-7Kn/cm
2between;
(3) with the array mode a kind of or at least two kinds of drenching glaze, glaze spraying, get rid of in glaze or dry powder cloth glaze, carry out glazing, making glaze layer thickness is 0.5-3mm;
(4), in oxidizing atmosphere, at the temperature of normal temperature to 1200 ℃, fire 1-3h;
(5) be cooled to normal temperature.
Technical scheme after above-mentioned processing step is further optimized is:
(1) prepare blank, glaze;
(2) blank, through brick pressing machine compression moulding automatically, is controlled green brick forming pressure at 5-7Kn/cm
2between;
(3) with the array mode a kind of or at least two kinds of drenching glaze, glaze spraying, get rid of in glaze or dry powder cloth glaze, carry out glazing, making glaze layer thickness is 1-2.5mm;
(4), in the oxidizing atmosphere of roller kiln or shuttle kiln, at the temperature of normal temperature to 1200 ℃, fire 1.2-2.8h;
(5) be cooled to normal temperature.
The optimized technical scheme of above-mentioned processing step is:
(1) prepare blank, glaze;
(2) blank, through brick pressing machine compression moulding automatically, is controlled green brick forming pressure at 5-7Kn/cm
2between;
(3) in the mode of glaze spraying, carry out glazing, making glaze layer thickness is 1.2-1.8mm;
(4), in the oxidizing atmosphere of roller kiln, at the temperature of normal temperature to 1200 ℃, fire 1.5-2.5h;
(5) be cooled to normal temperature.
As an optional technical scheme, of the present invention have Z-Correct bump mapping Z-correct ceramic tile and can also create according to following processing step:
(1) prepare blank, glaze;
(2) blank, through brick pressing machine compression moulding automatically, is controlled green brick forming pressure at 5-7Kn/cm
2between;
(3) with the array mode a kind of or at least two kinds of drenching glaze, glaze spraying, get rid of in glaze or dry powder cloth glaze, carry out glazing.
(4) on the glaze with Z-Correct bump mapping Z-correct, add and cover printing screen, carry out printing ornament.
Preferably, it is that 1-4 opens that the adding of described printing screen covered number, for example, can be 1,2,3,4.
The effect selection multiple patterns that described printing screen can obtain as required, for example, with reference to famous and precious animal skin line, wood grain, goes out the patterns such as leather texture imitation texture, imitative wood texture by computer photograph, thereby obtains that color is more abundant, the more natural product of texture.
(5), in oxidizing atmosphere, at the temperature of normal temperature to 1200 ℃, fire 1-3h.
(6) be cooled to normal temperature.
As another optional technical scheme, of the present invention have Z-Correct bump mapping Z-correct ceramic tile and can also create according to following processing step:
(1) prepare blank, glaze.
(2) blank, through brick pressing machine compression moulding automatically, is controlled green brick forming pressure at 5-7Kn/cm
2between.
(3) with the array mode a kind of or at least two kinds of drenching glaze, glaze spraying, get rid of in glaze or dry powder cloth glaze, carry out glazing.
(4), in oxidizing atmosphere, at the temperature of normal temperature to 1200 ℃, fire 1-3h.
(5) be cooled to normal temperature;
(6) polishing.Increase after polishing step, the Z-Correct bump mapping Z-correct ceramic brick surface that has of gained has more gloss, and product is more rich in modern sense.
The all expression processing parameters that use in specification sheets and claims, component concentration, reaction conditions etc. are all appreciated that the modification that adds term " about " in all cases.Therefore, unless point out on the contrary, in specification sheets and claims given numerical value can be according to the present invention the desired character obtaining difference and change.At bottom line, and be not used in the scope that the application of Equivalent principle is defined as to claim, each numerical value should be at least according to the value of reported significant figure by using common rounding method to make an explanation.And all scopes in this announcement are all appreciated that starting point and the end point values that comprises scope, comprise arbitrarily and all being included in wherein among a small circle.For example, certain scope " 1-10 " should be considered to comprise any and among a small circle all of (being included) between minimum value 1 and maximum value 10; All initial to be more than or equal to 1 minimum value, and to be less than or equal among a small circle all that 10 maximum value finishes, 2-10 for example, 3.5-8.5, or 6-9.8.
Compared with prior art, of the present invention have a Z-Correct bump mapping Z-correct ceramic tile, and the formation of its Z-Correct bump mapping Z-correct is without utilizing male and female mold, but by special glaze formula and process parameters design.Magnesium oxide in formula, aluminum oxide, in sintering procedure, play the capillary effect that increases glaze, make glaze at high temperature form reticulate pattern cracking, around as the island swelling; A large amount of camwood knag, wilkinite in formula because dry shrinkage just starts to have produced crackle, thereby fired the concavo-convex fluctuating of rear whole glaze, in picturesque disorder before entering klining and becoming, and self-assembling formation has the decorative effect of Z-Correct bump mapping Z-correct outward appearance.As required, also can in glaze, add multiple painted colorant and design the patterns such as multiple leather texture imitation texture, imitative wood texture, enrich product pattern.In technique, pass through to control glaze layer thickness and dry, firing temperature, under certain technic index is controlled, make the product made not artificial trace present natural and tripping, change continuously, without repeated Z-Correct bump mapping Z-correct surface decoration effect, meet the consumers demand of different crowd.The present invention is simultaneously with low cost, raw material sources abundant, and product is unique.
Below in conjunction with embodiment, the present invention is described in further detail.But following embodiment is only simple and easy example of the present invention, does not represent or limit the scope of the present invention, and interest field of the present invention is as the criterion with claims.
Embodiment
For the present invention is described better, be convenient to understand technical scheme of the present invention, typical but non-limiting embodiment of the present invention is as follows:
Embodiment 1:
A kind of have a Z-Correct bump mapping Z-correct ceramic tile, by blank and glaze, processed, described glaze is by comprising that the basal component according to following weight percent is formulated: pre-fusion thing 15wt%, magnesium oxide 8wt%, aluminum oxide 12wt%, camwood knag 18wt%, wilkinite 47wt%.
Described pre-fusion thing refers to the molten mixture that stannic oxide, sodium carbonate, raw talcum and zinc oxide form according to the weight ratio of 1:2:2:1.
Above-mentioned have Z-Correct bump mapping Z-correct ceramic tile and manufacture and form in accordance with the following steps:
(1) prepare blank, glaze;
(2) blank, through brick pressing machine compression moulding automatically, is controlled green brick forming pressure at 5-7Kn/cm
2between;
(3) in the mode of glaze spraying, carry out glazing, making glaze layer thickness is 1.5mm;
(4), in the oxidizing atmosphere of shuttle kiln, at the temperature of normal temperature to 1200 ℃, fire 1.5h;
(5) be cooled to normal temperature.
Embodiment 2:
A kind of have a Z-Correct bump mapping Z-correct ceramic tile, by blank and glaze, processed, described glaze is by comprising that the basal component according to following weight percent is formulated: pre-fusion thing 10wt%, magnesium oxide 12wt%, aluminum oxide 8wt%, camwood knag 22wt%, wilkinite 48wt%.
Described pre-fusion thing refers to the molten mixture that stannic oxide, sodium carbonate, raw talcum and zinc oxide form according to the weight ratio of 1:2:2:1.
Above-mentioned have Z-Correct bump mapping Z-correct ceramic tile and manufacture and form in accordance with the following steps:
(1) prepare blank, glaze;
(2) blank, through brick pressing machine compression moulding automatically, is controlled green brick forming pressure at 5-7Kn/cm
2between;
(3) in the mode of glaze spraying, carry out glazing, making glaze layer thickness is 2mm;
(4), in the oxidizing atmosphere of shuttle kiln, at the temperature of normal temperature to 1200 ℃, fire 2.5h;
(5) be cooled to normal temperature.
Embodiment 3:
A kind of have a Z-Correct bump mapping Z-correct ceramic tile, by blank and glaze, processed, described glaze is by comprising that the basal component according to following weight percent is formulated: pre-fusion thing 18wt%, magnesium oxide 6wt%, aluminum oxide 14wt%, camwood knag 15wt%, wilkinite 45wt%, cobalt black 2wt%.
Described pre-fusion thing refers to the molten mixture that stannic oxide, sodium carbonate, raw talcum and zinc oxide form according to the weight ratio of 1:2:2:2.
Above-mentioned have Z-Correct bump mapping Z-correct ceramic tile and manufacture and form in accordance with the following steps:
(1) prepare blank, glaze;
(2) blank, through brick pressing machine compression moulding automatically, is controlled green brick forming pressure at 5-7Kn/cm
2between;
(3) to drench the mode of glaze, carry out glazing, making glaze layer thickness is 1mm;
(4), in the oxidizing atmosphere of shuttle kiln, at the temperature of normal temperature to 1200 ℃, fire 1.8h;
(5) be cooled to normal temperature.
Embodiment 4:
A kind of have a Z-Correct bump mapping Z-correct ceramic tile, by blank and glaze, processed, described glaze is by comprising that the basal component according to following weight percent is formulated: pre-fusion thing 8wt%, magnesium oxide 14wt%, aluminum oxide 6wt%, camwood knag 25wt%, wilkinite 43wt%, praseodymium yellow 4wt%.
Described pre-fusion thing refers to the molten mixture that stannic oxide, sodium carbonate, raw talcum and zinc oxide form according to the weight ratio of 2:1:2:1.
Above-mentioned have Z-Correct bump mapping Z-correct ceramic tile and manufacture and form in accordance with the following steps:
(1) prepare blank, glaze;
(2) blank, through brick pressing machine compression moulding automatically, is controlled green brick forming pressure at 5-7Kn/cm
2between;
(3) to drench the mode of glaze, carry out glazing, making glaze layer thickness is 2.5mm;
(4), in the oxidizing atmosphere of shuttle kiln, at the temperature of normal temperature to 1200 ℃, fire 2.2h;
(5) be cooled to normal temperature.
Embodiment 5:
A kind of have a Z-Correct bump mapping Z-correct ceramic tile, by blank and glaze, processed, described glaze is by comprising that the basal component according to following weight percent is formulated: pre-fusion thing 20wt%, magnesium oxide 5wt%, aluminum oxide 15wt%, camwood knag 10wt%, wilkinite 49wt%, cobalt black 1wt%.
Described pre-fusion thing refers to the molten mixture that stannic oxide, sodium carbonate, raw talcum and zinc oxide form according to the weight ratio of 1:2:3:4.
Above-mentioned have Z-Correct bump mapping Z-correct ceramic tile and manufacture and form in accordance with the following steps:
(1) prepare blank, glaze;
(2) blank, through brick pressing machine compression moulding automatically, is controlled green brick forming pressure at 5-7Kn/cm
2between;
(3) to get rid of the mode of glaze, carry out glazing, making glaze layer thickness is 0.5mm;
(4), in the oxidizing atmosphere of roller kiln, at the temperature of normal temperature to 1200 ℃, fire 1.2h;
(5) be cooled to normal temperature.
Embodiment 6:
A kind of have a Z-Correct bump mapping Z-correct ceramic tile, by blank and glaze, processed, described glaze is by comprising that the basal component according to following weight percent is formulated: pre-fusion thing 5wt%, magnesium oxide 15wt%, aluminum oxide 5wt%, camwood knag 30wt%, wilkinite 40.5wt%, praseodymium yellow 4.5wt%.
Described pre-fusion thing refers to the molten mixture that stannic oxide, sodium carbonate, raw talcum and zinc oxide form according to the weight ratio of 4:3:2:1.
Above-mentioned have Z-Correct bump mapping Z-correct ceramic tile and manufacture and form in accordance with the following steps:
(1) prepare blank, glaze;
(2) blank, through brick pressing machine compression moulding automatically, is controlled green brick forming pressure at 5-7Kn/cm
2between;
(3) to get rid of the mode of glaze, carry out glazing, the thickness that makes glaze layer is 3mm;
(4) on the glaze with Z-Correct bump mapping Z-correct, add and cover 1 imitative wood grain printing screen, carry out printing ornament;
(5), in the oxidizing atmosphere of roller kiln, at the temperature of 1200 ℃, fire 2.8h;
(6) be cooled to normal temperature.
Embodiment 7:
A kind of have a Z-Correct bump mapping Z-correct ceramic tile, by blank and glaze, processed, described glaze is by comprising that the basal component according to following weight percent is formulated: pre-fusion thing 15wt%, magnesium oxide 12wt%, aluminum oxide 5wt%, camwood knag 20wt%, wilkinite 45wt%, cobalt black 3wt%.
Described pre-fusion thing refers to the molten mixture that stannic oxide, sodium carbonate, raw talcum and zinc oxide form according to the weight ratio of 1:3:5:7.
Above-mentioned have Z-Correct bump mapping Z-correct ceramic tile and manufacture and form in accordance with the following steps:
(1) prepare blank, glaze;
(2) blank, through brick pressing machine compression moulding automatically, is controlled green brick forming pressure at 5-7Kn/cm
2between;
(3) in the mode of dry powder cloth glaze, carry out glazing, the thickness of gained glaze layer is 1.6mm;
(4) exist
in the oxidizing atmosphere of roller kiln, at the temperature of 1200 ℃, fire 1h;
(5) be cooled to normal temperature;
(6) polishing.
Embodiment 8:
A kind of have a Z-Correct bump mapping Z-correct ceramic tile, by blank and glaze, processed, described glaze is by comprising that the basal component according to following weight percent is formulated: pre-fusion thing 15wt%, magnesium oxide 10wt%, aluminum oxide 5wt%, camwood knag 20wt%, wilkinite 45wt%, praseodymium yellow 5wt%
Described pre-fusion thing refers to the molten mixture that stannic oxide, sodium carbonate, raw talcum and zinc oxide form according to the weight ratio of 7:5:3:1.
Above-mentioned have Z-Correct bump mapping Z-correct ceramic tile and manufacture and form in accordance with the following steps:
(1) prepare blank, glaze;
(2) blank, through brick pressing machine compression moulding automatically, is controlled green brick forming pressure at 5-7Kn/cm
2between;
(3) in the mode of dry powder cloth glaze, carry out glazing, the thickness of gained glaze layer is 1.8mm;
(4) on the glaze with Z-Correct bump mapping Z-correct, add and cover 4 leather texture imitation printing screens, carry out printing ornament;
(5), in the oxidizing atmosphere of roller kiln, at the temperature of 1200 ℃, fire 3h;
(6) be cooled to normal temperature;
(7) polishing.
Should be noted that and understand, in the situation that not departing from the desired the spirit and scope of the present invention of accompanying claim, can make various modifications and improvement to the present invention of foregoing detailed description.Therefore, the scope of claimed technical scheme is not subject to the restriction of given any specific exemplary teachings.
Applicant's statement, above content is in conjunction with concrete preferred implementation further description made for the present invention, can not assert that specific embodiment of the invention is confined to these explanations.For general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, can also make some simple deduction or replace, all should be considered as belonging to protection scope of the present invention.
Claims (9)
1. one kind has Z-Correct bump mapping Z-correct ceramic tile, by blank and glaze, processed, it is characterized in that, described glaze comprises the basal component according to following weight percent: pre-fusion thing 5-20wt%, magnesium oxide 5-15wt%, aluminum oxide 5-15wt%, camwood knag 10-30wt%, wilkinite 20-50wt%;
Described have Z-Correct bump mapping Z-correct ceramic tile and prepare by following technique:
(1) prepare blank, glaze;
(2) blank, through brick pressing machine compression moulding automatically, is controlled green brick forming pressure at 5-7 kN/cm
2between;
(3) with the array mode a kind of or at least two kinds of drenching glaze, glaze spraying, get rid of in glaze or dry powder cloth glaze, carry out glazing, making glaze layer thickness is 0.5-3mm;
(4), in oxidizing atmosphere, at the temperature of normal temperature to 1200 ℃, fire 1-3h;
(5) be cooled to normal temperature.
2. according to claim 1 have a Z-Correct bump mapping Z-correct ceramic tile, it is characterized in that, described pre-fusion thing refers to the molten mixture of stannic oxide, sodium carbonate, raw talcum and zinc oxide.
3. according to claim 1 and 2 have a Z-Correct bump mapping Z-correct ceramic tile, it is characterized in that, in described pre-fusion thing, the weight ratio of stannic oxide, sodium carbonate, raw talcum and zinc oxide is 1:2:2:1.
4. according to claim 1 and 2 have a Z-Correct bump mapping Z-correct ceramic tile, it is characterized in that, the melt temperature of described pre-fusion thing is 1150-1450 ℃.
5. according to claim 1 and 2 have a Z-Correct bump mapping Z-correct ceramic tile, it is characterized in that, also comprises coloring oxide in described glaze.
6. according to claim 5 have a Z-Correct bump mapping Z-correct ceramic tile, it is characterized in that, the weight percent of described coloring oxide in glaze is 0.3-5wt%.
7. according to claim 5 have a Z-Correct bump mapping Z-correct ceramic tile, it is characterized in that, described coloring oxide is Fe
2o
3, FeO, MnO, CuO, Cu
2o, TiO
2, CoO, Cr
2o
3, Nd
2o
3, Bi
2o
3in a kind of or mixture of at least two kinds.
8. according to claim 1 and 2 have a Z-Correct bump mapping Z-correct ceramic tile, it is characterized in that, the fineness of described glaze is 250-325 order.
9. according to claim 1 and 2 have a Z-Correct bump mapping Z-correct ceramic tile, it is characterized in that, the glaze layer thickness that described glaze is made is 1-2.5mm.
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| CN201210388434.4A CN102924124B (en) | 2012-10-12 | 2012-10-12 | Ceramic tile with embossed textures |
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|---|---|---|---|
| CN201210388434.4A CN102924124B (en) | 2012-10-12 | 2012-10-12 | Ceramic tile with embossed textures |
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| CN102924124A CN102924124A (en) | 2013-02-13 |
| CN102924124B true CN102924124B (en) | 2014-04-09 |
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| CN104193383A (en) * | 2014-08-23 | 2014-12-10 | 济南大学 | Method for preparing coloured ceramsite |
| CN106145896B (en) * | 2015-04-16 | 2019-01-22 | 佛山市东鹏陶瓷有限公司 | A kind of manufacturing process with decoration texture Imitation Rock Porcelain Tiles |
| CN106242294B (en) * | 2016-08-05 | 2018-09-21 | 佛山市凯撒大道陶瓷有限公司 | A kind of Antiskid ceramic tile and preparation method thereof |
| CN108002702A (en) * | 2017-12-18 | 2018-05-08 | 黄岳娇 | A kind of decorative pattern Ceramic Tiles |
| CN108101371B (en) * | 2017-12-18 | 2021-02-05 | 广东永航新材料实业股份有限公司 | Preparation method of non-mold water ripple type glazed ceramic tile |
| CN113105225B (en) * | 2021-03-30 | 2022-07-22 | 广东欧文莱陶瓷有限公司 | Dermatoglyph ceramic and preparation method thereof |
| CN112939466B (en) * | 2021-03-30 | 2022-02-22 | 广东欧文莱陶瓷有限公司 | Leather grain ceramic glaze |
| CN113105114A (en) * | 2021-04-06 | 2021-07-13 | 广东欧文莱陶瓷有限公司 | Crystalline dry grain face rock plate and preparation method thereof |
| CN113087491A (en) * | 2021-04-06 | 2021-07-09 | 广东欧文莱陶瓷有限公司 | Matte dry grain surface rock plate and preparation method thereof |
| CN115594526B (en) * | 2022-12-14 | 2023-03-31 | 佛山市道氏科技有限公司 | Glaze combination and ceramic tile with latticed concave-convex grain effect |
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| CN1245294C (en) * | 2003-06-16 | 2006-03-15 | 佛山欧神诺陶瓷有限公司 | Production method for ceramic brick with natural concave-convex surface |
| CN100584802C (en) * | 2007-11-14 | 2010-01-27 | 陈继棉 | Production method with ceramic tile of convex-concave surface |
| CN101905965B (en) * | 2009-06-03 | 2012-07-25 | 佛山市简一陶瓷有限公司 | Ceramic brick manufacturing process with concave-convex polished in-glaze decoration |
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Effective date of registration: 20130725 Address after: 528031 Chancheng, Foshan, Jiangwan District, No. three, No. 8, No. layer on the first floor, No. 1 Applicant after: Guangdong Dongpeng Ceramic Co., Ltd. Applicant after: Lixian Xinpeng Ceramic Co., Ltd. Applicant after: Guangdong Dongpeng Holdings Co., Ltd. Applicant after: Foshan Dongpeng Ceramic Co., Ltd. Applicant after: Foshan Huashengchang Ceramic Co., Ltd. Address before: 511533 Qingyuan high tech Development Zone Ceramic Industrial City Dongpeng ceramic Qingyuan Co., Ltd. Applicant before: Guangdong Dongpeng Holdings Co., Ltd. Applicant before: Lixian Xinpeng Ceramic Co., Ltd. Applicant before: Foshan Dongpeng Ceramic Co., Ltd. Applicant before: Guangdong Dongpeng Ceramic Co., Ltd. |
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Effective date of registration: 20170508 Address after: 528031 Chancheng, Foshan District, Jiangwan, No. three, No., layer 8, layer two Co-patentee after: Guangdong Dongpeng Holdings Co., Ltd. Patentee after: Foshan Dongpeng Ceramic Co., Ltd. Co-patentee after: Lixian Xinpeng Ceramic Co., Ltd. Co-patentee after: Donghua Foshan New Material Co., Ltd. Address before: 528031 Chancheng, Foshan, Jiangwan District, No. three, No. 8, No. layer on the first floor, No. 1 Co-patentee before: Lixian Xinpeng Ceramic Co., Ltd. Patentee before: Guangdong Dongpeng Ceramic Co., Ltd. Co-patentee before: Guangdong Dongpeng Holdings Co., Ltd. Co-patentee before: Foshan Dongpeng Ceramic Co., Ltd. Co-patentee before: Foshan Huashengchang Ceramic Co., Ltd. |
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