CN102921942A - Guider of damper and preparation method of guider - Google Patents
Guider of damper and preparation method of guider Download PDFInfo
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- CN102921942A CN102921942A CN2012104151976A CN201210415197A CN102921942A CN 102921942 A CN102921942 A CN 102921942A CN 2012104151976 A CN2012104151976 A CN 2012104151976A CN 201210415197 A CN201210415197 A CN 201210415197A CN 102921942 A CN102921942 A CN 102921942A
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Abstract
The invention provides a guider of a damper, belonging to the field of automobile accessories and solving the problem of low density of the conventional guider of the damper. The guider of the damper comprises the following components in parts by weight: 40-60 parts of reducing iron powder, 0.2-0.5 part of electrolytic copper powder, 0.1-0.3 part of graphite, 0.25-0.35 part of lubricant and 0.15-0.25 part of manganese sulfide. The invention also provides a preparation method of the guider of the damper. By means of rationally selecting ingredients for preparing the guider of the damper and utilizing a powder metallurgy method, the cost can be reduced, the product density can be improved, the dimensional tolerance of a product can be reduced, and the hardness of the product can be improved. Further, the dimensional tolerance of the product is reduced by using shaping, and the product density is further improved through water atomization steam treatment, so that the product density of the guider of the damper can reach 6.3-6.5 g/cm<3>.
Description
Technical field
The present invention relates to field of powder metallurgy, relate in particular to a kind of guider of shock absorber and preparation method thereof.
Background technology
Damper all is installed in the automobile suspension system usually, and damper can make automobile reduce in the process of moving fluctuation when travelling, and the damping, buffering effect by damper reaches and improves comfortableness by bus and the purpose of security.Damper is converted to fixedly elasticity connection with the parts of rigid connection.Guider is fitted on the damper, mainly be that the piston rod that is slidingly mounted in the damper working cylinder is play the guiding role, guarantee the ride comfort of piston in running, and the oil-through hole by guider is transported to unnecessary shock absorber fluid in the oil storage cylinder in the piston movement process, and the assurance working cylinder is communicated with oil storage cylinder.
Because guider of shock absorber needs repeatedly back and forth movement, therefore preferably product density and air tightness need to be arranged.Existing publication number is that CN102335744 discloses a kind of automobile absorber production process of guider, its by batch mixing, compacting, sintering, finishing, turn blue to obtain guider of shock absorber, this technique is by adopting the integrated mode of powder metallurgy to prepare guider of shock absorber, can increase work efficiency, yet but not solve the problem of air tightness.Publication number is the manufacture method that CN101386073 discloses a kind of powder metallurgy guide device, and it improves product density by increase reduced iron powder in prescription, and this kind mode has not only increased the cost of product and the powder metallurgical technique of routine is not done improvement.
Summary of the invention
The object of the present invention is to provide the guider of shock absorber that a kind of product density is high, air-tightness is good.
Another object of the present invention is to provide the preparation method of the guider of shock absorber that reduces manufacturing cost, improves the quality of products.
The technical solution used in the present invention is, proposes a kind of guider of shock absorber, and the component of this guider of shock absorber and parts by weight are:
Reduced iron powder: 40-60 part;
Electrolytic copper powder: 0.2-0.5 part;
Graphite: 0.1-0.3 part;
Lubricant: 0.25-0.35 part;
Manganese sulfide: 0.15-0.25 part.
Iron powder, copper powder and graphite are elements commonly used in the powder metallurgy process.Copper powder is more soft than iron powder, has better plasticity, and copper powder and iron powder can have preferably briquettability in pressing process, and copper powder has certain solubility in iron powder, has solution strengthening effect after adding copper powder.And graphite mainly is because it can form this high rigidity of cementite mutually with iron powder, and the mechanical property that improves final workpiece is had good effect, so the graphite component that is absolutely necessary in the preparation process of all kinds of powder metallurgy workpieces.
The increase of copper powder content can directly improve the bending strength of product, but because its plasticity is relatively poor, can reduce the Rockwell hardness of product; The increase of content of graphite is then opposite with copper powder on the impact of product mechanical performance, its Rockwell hardness that can significantly increase product but reduces bending strength, the present invention is by the proportioning of reasonable disposition copper powder and graphite, so that the Rockwell hardness of product and bending strength remain on than poised state.
In addition, the content of copper powder also can affect the density of product, this is because copper is different from the scattering nature of iron, diffusion ratio iron the diffusion in copper of copper in iron is fast, copper dissolution forms substitution solid solution in iron, the volume of substitution solid solution is larger, and therefore the increase along with copper content also can be so that the volume of product increases, and product density reduces.The proportioning that need consider copper powder, graphite when selecting copper powder content is on the impact on product density of the impact of product mechanical performance and copper powder.
Common powder metallurgical technique adopts straight iron powder or atomized iron powder usually, iron powder needs to carry out first the powder reduction step in powder metallurgy process, the present invention directly selects reduced iron powder, has saved the powder reduction step of conventional powder metallurgy process, has improved operating efficiency.
Lubricant mainly plays and reduces between powder and the mould and the frictional force between powder and the powder, makes in the powder compaction process, and transmission of pressure better strengthens the filling capacity of powder particle.The parts by weight of lubricant select with the product pressing process in pressure closely related, and product is suppressed the shaping press of common employing standard, therefore can obtain the parts by weight of lubricant by the compacting tonnage of determining the product shaping press.
Among the present invention, lubricant is preferably zinc stearate, paraffin or polytetrafluoroethylene (PTFE).
During choosing, the raw material of guider of shock absorber of the present invention also chooses the manganese sulfide that the 0.15-0.25 weight fraction is arranged.Manganese sulfide adds as cutting agent in powder metallurgy process usually, is used for improving the cutting ability of product, even has experiment to show, also can reduce product density when manganese sulfide content is low.Yet the present invention found through experiments, the content increase of manganese sulfide is during to certain proportion, because manganese sulfide is more crisp, plasticity is fine, a certain proportion of manganese sulfide can be scattered in the iron powder surface preferably when compacting, so that iron powder can change liquid into from solid under relatively low pressure and temperature, can bring into play to greatest extent the compressibility of metal dust, thereby improve the density of product, the changes of contents of manganese sulfide also can not exert an influence to hardness and the dimensional accuracy of product simultaneously.Yet but can reduce the corrosion resistance of product during the too high levels of manganese sulfide, reduce life of product.The weight ratio of the manganese sulfide that the present invention chooses has been broken the conventional interpolation manganese sulfide of thinking can reduce the prejudice of product density, and can take into account and reduce its harmful effect to life of product.
Preferably, the reduced iron powder particle diameter is the 100-150 order, and the electrolytic copper powder particle diameter is the 180-250 order.
In the preferred embodiment for the present invention, the reduced iron powder particle diameter is different from the electrolytic copper powder particle diameter, so that thereby small particle powder can be mixed with the bulky grain powder so that the gap between the bulky grain powder is occupied by small particle powder, improving the apparent density of powder so that product when compressing density and the intensity of product all increase.
Another technical scheme that the present invention adopts is, proposes a kind of preparation method of above-mentioned guider of shock absorber, and it comprises step:
S1: batching is mixed;
S2: compacting: the compacting tonnage is the 30-50 ton;
S3: sintering: 750 ℃ to 800 ℃ of calcined temperatures, 30 minutes to 60 minutes pre-burning time; Sintering temperature is 1100 ℃ to 1150 ℃, sintering time 3 to 4 hours; Be filled with 30 to 40 cubic metres of protective gas during sintering.
When compressing, pressing pressure fundamental sum final products density is directly proportional.When pressure had just begun to increase, so that the arch bridge in the body of powder is broken soon, powder particle is subjected to displacement filled the space each other, and rearranging the position increases contact, and product density sharply increases.After pressure sharply increased to critical pressure above powder particle, powder particle began distortion, and product density continues to increase.After pressure surpasses the powder critical pressure, continue to improve pressure the product density improved effect is reduced.For saving cost, save equipment acquisition expense usefulness, the compacting tonnage that the present invention chooses is the 30-50 ton.
In sintering process, the main purpose of pre-burning is the lubricant when removing step S1 and S2.When sintering temperature rose, the sintering neck enlarged, and grain spacing reduces, and forms continuous space grid, and sintered body shrinks to be separated, to improve product density and can improve intensity.When sintering temperature was too high, product grains too increased, so that the sintering space is distorted fully, caused deformation of products and cracking, and is undesirable.
In the sintering process, be filled with protective gas, prevent from occuring in the sintering process redox reaction, reduce properties of product.
Preferably, among the step S1, after choosing first the reduced iron powder of half weight portion and electrolytic copper powder, graphite, lubricant and manganese sulfide and mixing, again add the reduced iron powder of second half weight portion, again mix.
Preferably, also comprise the shaping step, shaping pressure is the 80-90 ton.To improve Product Precision, reduce dimensional tolerance by secondary compacting shaping.
Preferably, also comprise steam atomizing treatment step: it is 550-600 ℃ steam heating 5 hours that product is put into temperature, so that product surface forms the diaphragm of 0.005mm to 0.006mm.
The steam atomizing is processed and can be formed the tri-iron tetroxide diaphragm at product surface, can improve wearability and the high pressure compactness of product, so that product has certain rust-proof effect.
The present invention prepares the batching of guider of shock absorber by Rational choice, and utilizes the powder metallurgy process preparation, can reduce cost, improves product density, and the shorten product sizes tolerance improves product hardness.Further, the present invention further improves product density by utilizing shaping further to reduce the product size tolerance by the water atomization steam treatment, so that the product density of guider of shock absorber of the present invention can reach 6.3-6.5g/cm
3
The specific embodiment
Below be specific embodiments of the invention, technical scheme of the present invention is further described, but the present invention is not limited to these embodiment.
Embodiment 1
The present embodiment prepares guider of shock absorber in the following way:
(1) batching
Choosing average grain diameter is that 100 purpose reduced iron powders, 25 weight portions, average grain diameter are 250 purpose electrolytic copper powders, 0.5 weight portion, graphite 0.2 weight portion, zinc stearate 0.35 weight portion, manganese sulfide 0.25 weight portion, puts into the mixed powder machine of taper and fully mixes; Then again adding average grain diameter in the mixed powder machine of taper is 100 purpose reduced iron powders, 25 weight portions.Incorporation time 40 minutes reaches abundant mixed effect and gets final product.
(2) compacting
It is that 50 tons automatic moulding machine is suppressed that the powder that mixes is put into the compacting tonnage.
(3) sintering
In meshbeltfurnace, carry out sintering step; 750 ℃ of calcined temperatures, 45 minutes pre-burning time; 1125 ℃ of sintering temperatures, sintering time 3 hours.Meshbeltfurnace is in sintering process, and the flow of burning gases hydrogen is 20 cubic metres, and the flow of protective gas helium is 40 cubic metres.
(4) shaping
Adopt 80 tons of trimmer Shape corrections.
Test its density, dimensional tolerance behind the product that obtains, Rockwell hardness, crushing force radially, the test result that obtains sees Table one.
Wherein, Rockwell hardness adopts the Rockwell apparatus test, and density adopts drainage (GB/T5163-1985) test, and dimensional tolerance adopts conventional universl tester to get final product with crushing force radially.
Embodiment 2
(1) batching
Choosing average grain diameter is that 130 purpose reduced iron powders, 40 weight portions, average grain diameter are 200 purpose electrolytic copper powders, 0.3 weight portion, graphite 0.3 weight portion, paraffin 0.3 weight portion, manganese sulfide 0.2 weight portion, puts into the mixed powder machine of taper and fully mixes.
(2) compacting
It is that 30 tons automatic moulding machine is suppressed that the powder that mixes is put into the compacting tonnage.
(3) sintering
In meshbeltfurnace, carry out sintering step; 800 ℃ of calcined temperatures, 30 minutes pre-burning time; 1150 ℃ of sintering temperatures, sintering time 3 hours.Meshbeltfurnace is in sintering process, and the flow of burning gases hydrogen is 30 cubic metres, and the flow of protective gas helium is 30 cubic metres.
(4) the steam atomizing is processed
It is 550 ℃ steam heating 5 hours that product behind the sintering is put into temperature, so that product surface forms the diaphragm of 0.005mm to 0.006mm.
Test its density, dimensional tolerance, Rockwell hardness behind the product that obtains, radially press stain power, the test result that obtains sees Table one.
Wherein, Rockwell hardness adopts the Rockwell apparatus test, and density adopts drainage (GB/T5163-1985) test, and dimensional tolerance adopts conventional universl tester to get final product with crushing force radially.
Embodiment 3
One) batching
Choosing average grain diameter is that 100 purpose reduced iron powders, 60 weight portions, average grain diameter are 180 purpose electrolytic copper powders, 0.2 weight portion, graphite 0.1 weight portion, PVC emulsifying liquid 0.25 weight portion, manganese sulfide 0.15 weight portion, puts into the mixed powder machine of taper and fully mixes.
(2) compacting
It is that 50 tons automatic moulding machine is suppressed that the powder that mixes is put into the compacting tonnage.
(3) sintering
In meshbeltfurnace, carry out sintering step; 800 ℃ of calcined temperatures, 60 minutes pre-burning time; 1100 ℃ of sintering temperatures, sintering time 4 hours.Meshbeltfurnace is in sintering process, and the flow of burning gases hydrogen is 30 cubic metres, and the flow of protective gas helium is 40 cubic metres.
(4) shaping
Adopt 90 tons of trimmer Shape corrections.
(5) the steam atomizing is processed
It is 600 ℃ steam heating 5 hours that product after the shaping is put into temperature, so that product surface forms the diaphragm of 0.005mm to 0.006mm.
Test its density, dimensional tolerance behind the product that obtains, Rockwell hardness, crushing force radially, the test result that obtains sees Table one.
Wherein, Rockwell hardness adopts the Rockwell apparatus test, and density adopts drainage (GB/T5163-1985) test, and dimensional tolerance adopts conventional universl tester to get final product with crushing force radially.
Table one
As seen from the above table, guider of shock absorber of the present invention satisfies product demand, and its cost only is about half of conventional copper, steel part, to have enlarged the range of application of powder metallurgy product.
Specific embodiment described herein only is to the explanation for example of the present invention's spirit.Those skilled in the art can make various modifications or replenish or adopt similar mode to substitute described specific embodiment, but can't depart from spirit of the present invention or surmount the defined scope of appended claims.
Claims (7)
1. guider of shock absorber, it is characterized in that: the component of this guider of shock absorber and parts by weight are:
Reduced iron powder: 40-60 part;
Electrolytic copper powder: 0.2-0.5 part;
Graphite: 0.1-0.3 part;
Lubricant: 0.25-0.35 part;
Manganese sulfide: 0.15-0.25 part.
2. guider of shock absorber as claimed in claim 1, it is characterized in that: described lubricant is zinc stearate, paraffin or polytetrafluoroethylene (PTFE).
3. guider of shock absorber as claimed in claim 1, it is characterized in that: described reduced iron powder particle diameter is the 100-150 order, the electrolytic copper powder particle diameter is the 180-250 order.
4. preparation method who prepares each described guider of shock absorber of claims 1 to 3 is characterized in that: comprise step:
S1: batching is mixed;
S2: compacting: the compacting tonnage is the 30-50 ton;
S3: sintering: 750 ℃ to 800 ℃ of calcined temperatures, 30 minutes to 60 minutes pre-burning time; Sintering temperature is 1100 ℃ to 1150 ℃, sintering time 3 to 4 hours; Be filled with 30 to 40 cubic metres of protective gas during sintering.
5. preparation method as claimed in claim 4, it is characterized in that: among the step S1, after choosing first the reduced iron powder of half weight portion and electrolytic copper powder, graphite, lubricant and manganese sulfide and mixing, again add the reduced iron powder of second half weight portion, again mix.
6. preparation method as claimed in claim 4, it is characterized in that: also comprise the shaping step, shaping pressure is the 80-90 ton.
7. such as claim 4 or 6 described preparation methods, it is characterized in that: also comprise steam atomizing treatment step: it is 550-600 ℃ steam heating 5 hours that product is put into temperature, so that product surface forms the diaphragm of 0.005mm to 0.006mm.
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| CN201210415197.6A CN102921942B (en) | 2012-10-17 | 2012-10-17 | Guider of damper and preparation method of guider |
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| CN201210415197.6A CN102921942B (en) | 2012-10-17 | 2012-10-17 | Guider of damper and preparation method of guider |
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| CN102921942A true CN102921942A (en) | 2013-02-13 |
| CN102921942B CN102921942B (en) | 2015-01-14 |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103266271A (en) * | 2013-05-29 | 2013-08-28 | 东睦(江门)粉末冶金有限公司 | Powder metallurgical formula and technology |
| CN105478743A (en) * | 2015-11-27 | 2016-04-13 | 宁波市群星粉末冶金有限公司 | Guider of automobile shock absorber and manufacturing method thereof |
| CN107470632A (en) * | 2017-07-27 | 2017-12-15 | 宁波金钟粉末冶金有限公司 | A kind of guider of shock absorber |
| CN107470633A (en) * | 2017-07-27 | 2017-12-15 | 宁波金钟粉末冶金有限公司 | A kind of damper valve seat |
| CN107552800A (en) * | 2017-07-27 | 2018-01-09 | 宁波金钟粉末冶金有限公司 | A kind of gear bush |
| CN107685147A (en) * | 2017-07-27 | 2018-02-13 | 宁波金钟粉末冶金有限公司 | A kind of high-precision guider of shock absorber |
| CN108130483A (en) * | 2017-12-25 | 2018-06-08 | 宁波市江北吉铭汽车配件有限公司 | A kind of guider of shock absorber and preparation method thereof |
| CN110039040A (en) * | 2019-04-11 | 2019-07-23 | 宁波顺达粉末冶金工业有限公司 | A kind of guider of shock absorber and preparation method thereof |
| CN112648317A (en) * | 2019-10-11 | 2021-04-13 | DRiV汽车公司 | Method for manufacturing monotube shock absorber |
| CN112648324A (en) * | 2019-10-11 | 2021-04-13 | DRiV汽车公司 | Sintered metal rod guide assembly for monotube shock absorber |
| CN117600459A (en) * | 2023-11-06 | 2024-02-27 | 广东凯洋新材料有限公司 | Heat dissipation bracket and preparation method thereof |
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Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103266271A (en) * | 2013-05-29 | 2013-08-28 | 东睦(江门)粉末冶金有限公司 | Powder metallurgical formula and technology |
| CN103266271B (en) * | 2013-05-29 | 2016-04-20 | 广东东睦新材料有限公司 | A kind of powder metallurgy prescription and technique |
| CN105478743A (en) * | 2015-11-27 | 2016-04-13 | 宁波市群星粉末冶金有限公司 | Guider of automobile shock absorber and manufacturing method thereof |
| CN107470633B (en) * | 2017-07-27 | 2019-10-11 | 宁波金钟粉末冶金有限公司 | A kind of damper valve seat |
| CN107685147B (en) * | 2017-07-27 | 2019-08-23 | 宁波金钟粉末冶金有限公司 | A kind of high-precision guider of shock absorber |
| CN107552800A (en) * | 2017-07-27 | 2018-01-09 | 宁波金钟粉末冶金有限公司 | A kind of gear bush |
| CN107685147A (en) * | 2017-07-27 | 2018-02-13 | 宁波金钟粉末冶金有限公司 | A kind of high-precision guider of shock absorber |
| CN107470633A (en) * | 2017-07-27 | 2017-12-15 | 宁波金钟粉末冶金有限公司 | A kind of damper valve seat |
| CN107470632A (en) * | 2017-07-27 | 2017-12-15 | 宁波金钟粉末冶金有限公司 | A kind of guider of shock absorber |
| CN107470632B (en) * | 2017-07-27 | 2019-07-26 | 宁波金钟粉末冶金有限公司 | A kind of guider of shock absorber |
| CN107552800B (en) * | 2017-07-27 | 2019-07-26 | 宁波金钟粉末冶金有限公司 | A kind of gear bush |
| CN108130483A (en) * | 2017-12-25 | 2018-06-08 | 宁波市江北吉铭汽车配件有限公司 | A kind of guider of shock absorber and preparation method thereof |
| CN110039040A (en) * | 2019-04-11 | 2019-07-23 | 宁波顺达粉末冶金工业有限公司 | A kind of guider of shock absorber and preparation method thereof |
| CN110039040B (en) * | 2019-04-11 | 2020-10-09 | 宁波顺达粉末冶金工业有限公司 | Guider of shock absorber and preparation method of guider |
| CN112648317A (en) * | 2019-10-11 | 2021-04-13 | DRiV汽车公司 | Method for manufacturing monotube shock absorber |
| CN112648324A (en) * | 2019-10-11 | 2021-04-13 | DRiV汽车公司 | Sintered metal rod guide assembly for monotube shock absorber |
| CN112648324B (en) * | 2019-10-11 | 2023-12-12 | DRiV汽车公司 | Sintered metal rod guide assembly for monotube shock absorber |
| CN112648317B (en) * | 2019-10-11 | 2024-01-05 | DRiV汽车公司 | Method for manufacturing single tube shock absorber |
| CN117600459A (en) * | 2023-11-06 | 2024-02-27 | 广东凯洋新材料有限公司 | Heat dissipation bracket and preparation method thereof |
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