CN102888617A - Washing liquid for cleaning cold-rolled silicon steel plate - Google Patents

Washing liquid for cleaning cold-rolled silicon steel plate Download PDF

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Publication number
CN102888617A
CN102888617A CN2012103946425A CN201210394642A CN102888617A CN 102888617 A CN102888617 A CN 102888617A CN 2012103946425 A CN2012103946425 A CN 2012103946425A CN 201210394642 A CN201210394642 A CN 201210394642A CN 102888617 A CN102888617 A CN 102888617A
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CN
China
Prior art keywords
cold
parts
cleaning
rolled silicon
silicon iron
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Withdrawn
Application number
CN2012103946425A
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Chinese (zh)
Inventor
朱家生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUXI RIGUAN ELECTRICAL AND MECHANICAL MANUFACTURING Co Ltd
Original Assignee
WUXI RIGUAN ELECTRICAL AND MECHANICAL MANUFACTURING Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by WUXI RIGUAN ELECTRICAL AND MECHANICAL MANUFACTURING Co Ltd filed Critical WUXI RIGUAN ELECTRICAL AND MECHANICAL MANUFACTURING Co Ltd
Priority to CN2012103946425A priority Critical patent/CN102888617A/en
Publication of CN102888617A publication Critical patent/CN102888617A/en
Withdrawn legal-status Critical Current

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  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a washing liquid for cleaning a cold-rolled silicon steel plate. The washing liquid mainly comprises the following components in parts by weight: 20-30 parts of sodium hydroxide, 43-58 parts of sodium silicate, 14-21 parts of sodium tripolyphosphate, 2-6 parts of soap and 0.1-0.6 part of general organosilicone defoaming powder. The washing liquid for cleaning the cold-rolled silicon steel plate can overcome the defects that in the prior art, washing effect is poor, energy consumption is large, operation fault is easy to cause and the like, so as to achieve the advantages that the washing effect is good, energy consumption is small, and operation fault is difficult to cause.

Description

A kind of scavenging solution for cleaning cold-rolled silicon iron
Technical field
The present invention relates to metallic substance cleaning technique field, particularly, relate to a kind of scavenging solution for cleaning cold-rolled silicon iron.
Background technology
Because silicon steel sheet will use ROLLING OIL in cold-rolled process, so that the cold-rolled silicon iron surface is stained with one deck greasy dirt, this layer greasy dirt must clean up before annealing, to avoid silicon steel sheet greasy dirt carbonization in annealing process, the silicon steel sheet surface is polluted, affect the subsequent handling coating quality.
Usually, cold-rolled silicon iron surface and oil contaminant alkaline cleaner commonly used cleans.But these clean-out systems are bad to the cleaning performance of cold-rolled silicon iron, and one deck greasy dirt is usually also adhered on the cold-rolled silicon iron surface after the cleaning, cause the cold-rolled silicon iron surface after the annealing to form the carbonaceous stain, seriously affect the quality of surface of steel plate.And the working temperature of these clean-out systems is higher, and energy consumption is large during cleaning, and causes easily the e-quipment and pipe fouling and blocking pipe, and impact is normally produced.In addition, all do not contain defoamer in these clean-out systems, can produce a large amount of foams in to the cleaning process of cold-rolled silicon iron, these foams gently then pollute operating environment, and are heavy then production can not normally be carried out.
In realizing process of the present invention, the contriver finds to exist at least in the prior art that cleaning performance is poor, energy consumption causes the defectives such as operation fault greatly, easily.
Summary of the invention
The object of the invention is to, for the problems referred to above, propose a kind of scavenging solution for cleaning cold-rolled silicon iron, to realize that cleaning performance is good, energy consumption is little and to be difficult for causing the advantage of operation fault.
For achieving the above object, the technical solution used in the present invention is: a kind of scavenging solution for cleaning cold-rolled silicon iron, mainly comprise following component, and be expressed as with parts by weight:
Sodium hydroxide: 20 ~ 30 parts;
Water glass: 43-58 part;
Tripoly phosphate sodium STPP: 14-21 part;
Soap: 2 ~ 6 parts;
General organosilicon defoaming powder: 0.1 ~ 0.6 part.
Further, described general organosilicon defoaming powder specifically comprises general organosilicon defoaming powder T-20GB.
Owing in the greasy dirt on the cold-rolled silicon iron, contain a small amount of vegetable and animals oils (or synthetic fat) and a large amount of mineral oil.Adopt the scavenging solution that is used for cleaning cold-rolled silicon iron of various embodiments of the present invention, can overcome the defective that cleaning performance is poor in the prior art, energy consumption causes the operation fault greatly, easily, to realize that cleaning performance is good, energy consumption is little and to be difficult for causing the advantage of operation fault; For example:
⑴ can utilize on sodium hydroxide and the cold-rolled silicon iron a small amount of that saponification reaction occurs vegetable and animals oils (or synthetic fat), generates soap and glycerine, and soap and glycerine can be dissolved in the scavenging solution well, thereby the vegetable and animals oils on the cold-rolled silicon iron is removed;
⑵ can utilize the emulsifying effect of water glass, effectively removes mineral oil a large amount of on the cold-rolled silicon iron;
⑶ utilize calcium ion and the magnesium ion generation complexing action in tripoly phosphate sodium STPP and the hard water, and complexing is dissolved in other metal ion in the scavenging solution, washes simultaneously the silicon dioxide film on cold-rolled silicon iron surface off, to improve cleaning performance;
⑷ utilize soap as tensio-active agent, can reduce the surface tension of scavenging solution, increases surfactivity and the cleaning performance of scavenging solution;
⑸ utilize general organosilicon defoaming powder as defoamer, can effectively eliminate the foam that produces in the cleaning process, avoids polluting operating environment, also to normally ensureing to some extent of producing.
Other features and advantages of the present invention will be set forth in the following description, and, partly from specification sheets, become apparent, perhaps understand by implementing the present invention.
Below by embodiment, technical scheme of the present invention is described in further detail.
Embodiment
Describe below in conjunction with the preferred embodiments of the present invention, should be appreciated that preferred embodiment described herein only is used for description and interpretation the present invention, is not intended to limit the present invention.
Embodiment one
According to the embodiment of the invention, provide a kind of scavenging solution for cleaning cold-rolled silicon iron.Should be used for cleaning the scavenging solution of cold-rolled silicon iron, mainly comprise following component, be expressed as with parts by weight:
Sodium hydroxide: 20 parts;
Water glass: 58 parts;
Tripoly phosphate sodium STPP: 17.5 parts;
Soap: 2 parts;
General organosilicon defoaming powder: 0.1 part; This general organosilicon defoaming powder specifically comprises general organosilicon defoaming powder T-20GB.
After the even mixing of above-mentioned raw materials, pack and namely can be made into the qualified scavenging solution that is used for cleaning cold-rolled silicon iron.During use, only need to plant the solid-state scavenging solution that is used for the cleaning cold-rolled silicon iron and pour tap water into, fully stir and make its dissolving, be configured to concentration and be 3%, the scavenging solution of liquid temperature between 58 ℃, send into silicon steel sheet factory by pipeline and get in the strip cleaning groove, cold-rolled silicon iron is sprayed cleaning, empirical tests, clean rate can reach more than 98%, and e-quipment and pipe does not all produce fouling after using.
Embodiment two
According to the embodiment of the invention, provide a kind of scavenging solution for cleaning cold-rolled silicon iron.Should be used for cleaning the scavenging solution of cold-rolled silicon iron, mainly comprise following component, be expressed as with parts by weight:
Sodium hydroxide: 30 parts;
Water glass: 43 parts;
Tripoly phosphate sodium STPP: 14 parts;
Soap: 6 parts;
General organosilicon defoaming powder: 0.6 part; This general organosilicon defoaming powder specifically comprises general organosilicon defoaming powder T-20GB.
After the even mixing of above-mentioned raw materials, pack and namely can be made into the qualified scavenging solution that is used for cleaning cold-rolled silicon iron.During use, only need to plant the solid-state scavenging solution that is used for the cleaning cold-rolled silicon iron and pour tap water into, fully stir and make its dissolving, be configured to concentration and be 4%, the scavenging solution of liquid temperature between 65 ℃, send into silicon steel sheet factory by pipeline and get in the strip cleaning groove, cold-rolled silicon iron is sprayed cleaning, empirical tests, clean rate can reach more than 99%, and e-quipment and pipe does not all produce fouling after using.
Embodiment three
According to the embodiment of the invention, provide a kind of scavenging solution for cleaning cold-rolled silicon iron.Should be used for cleaning the scavenging solution of cold-rolled silicon iron, mainly comprise following component, be expressed as with parts by weight:
Sodium hydroxide: 25 parts;
Water glass: 50.5 parts;
Tripoly phosphate sodium STPP: 21 parts;
Soap: 6 parts;
General organosilicon defoaming powder: 0.4 part; This general organosilicon defoaming powder specifically comprises general organosilicon defoaming powder T-20GB.
After the even mixing of above-mentioned raw materials, pack and namely can be made into the qualified scavenging solution that is used for cleaning cold-rolled silicon iron.During use, only need to plant the solid-state scavenging solution that is used for the cleaning cold-rolled silicon iron and pour tap water into, fully stir and make its dissolving, be configured to concentration and be 3.5%, the scavenging solution of liquid temperature between 60 ℃, send into silicon steel sheet factory by pipeline and get in the strip cleaning groove, cold-rolled silicon iron is sprayed cleaning, empirical tests, clean rate can reach more than 97%, and e-quipment and pipe does not all produce fouling after using.
The scavenging solution that is used for cleaning cold-rolled silicon iron of the various embodiments described above of the present invention can be exclusively used in the cleaning cold-rolled silicon iron, adopts dipping degreasing or spray degreasing mode all can; Should be used for cleaning the scavenging solution of cold-rolled silicon iron, also be applicable to the matting of other steel.
It should be noted that at last: the above only is the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment the present invention is had been described in detail, for a person skilled in the art, it still can be made amendment to the technical scheme that aforementioned each embodiment puts down in writing, and perhaps part technical characterictic wherein is equal to replacement.Within the spirit and principles in the present invention all, any modification of doing, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (2)

1. a scavenging solution that is used for cleaning cold-rolled silicon iron is characterized in that, mainly comprises following component, is expressed as with parts by weight:
Sodium hydroxide: 20 ~ 30 parts;
Water glass: 43-58 part;
Tripoly phosphate sodium STPP: 14-21 part;
Soap: 2 ~ 6 parts;
General organosilicon defoaming powder: 0.1 ~ 0.6 part.
2. the scavenging solution for cleaning cold-rolled silicon iron according to claim 1 is characterized in that described general organosilicon defoaming powder specifically comprises general organosilicon defoaming powder T-20GB.
CN2012103946425A 2012-10-17 2012-10-17 Washing liquid for cleaning cold-rolled silicon steel plate Withdrawn CN102888617A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012103946425A CN102888617A (en) 2012-10-17 2012-10-17 Washing liquid for cleaning cold-rolled silicon steel plate

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Application Number Priority Date Filing Date Title
CN2012103946425A CN102888617A (en) 2012-10-17 2012-10-17 Washing liquid for cleaning cold-rolled silicon steel plate

Publications (1)

Publication Number Publication Date
CN102888617A true CN102888617A (en) 2013-01-23

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4521332A (en) * 1981-03-23 1985-06-04 Pennwalt Corporation Highly alkaline cleaning dispersion
CN1098748A (en) * 1993-08-12 1995-02-15 武汉钢铁(集团)公司 Cleaning agent for cold-rolled silicon steel plate
CN1193657A (en) * 1997-01-16 1998-09-23 狮王株式会社 Production of surfactant powder, the surfactant powder and granular detergent composition
CN101092728A (en) * 2007-04-11 2007-12-26 姜堰市德美化工有限公司 Low-foam degreasing powder for cleaning surfaces of steel materials and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4521332A (en) * 1981-03-23 1985-06-04 Pennwalt Corporation Highly alkaline cleaning dispersion
CN1098748A (en) * 1993-08-12 1995-02-15 武汉钢铁(集团)公司 Cleaning agent for cold-rolled silicon steel plate
CN1193657A (en) * 1997-01-16 1998-09-23 狮王株式会社 Production of surfactant powder, the surfactant powder and granular detergent composition
CN101092728A (en) * 2007-04-11 2007-12-26 姜堰市德美化工有限公司 Low-foam degreasing powder for cleaning surfaces of steel materials and preparation method thereof

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Application publication date: 20130123