CN102885707B - Breast washing solution for milking cow and preparation method thereof - Google Patents
Breast washing solution for milking cow and preparation method thereof Download PDFInfo
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- CN102885707B CN102885707B CN201210380021.1A CN201210380021A CN102885707B CN 102885707 B CN102885707 B CN 102885707B CN 201210380021 A CN201210380021 A CN 201210380021A CN 102885707 B CN102885707 B CN 102885707B
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- amine oxide
- mass fraction
- milking
- washing solution
- phosphate ester
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- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 210000000481 breast Anatomy 0.000 title abstract description 16
- 238000005406 washing Methods 0.000 title abstract description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 51
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 34
- 239000010452 phosphate Substances 0.000 claims abstract description 34
- 150000001412 amines Chemical class 0.000 claims abstract description 24
- 238000003756 stirring Methods 0.000 claims abstract description 22
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052740 iodine Inorganic materials 0.000 claims abstract description 20
- 239000011630 iodine Substances 0.000 claims abstract description 20
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- -1 Phosphate ester Chemical class 0.000 claims description 67
- 239000000839 emulsion Substances 0.000 claims description 42
- QUSNBJAOOMFDIB-UHFFFAOYSA-N monoethyl amine Natural products CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 11
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 claims description 10
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 10
- MLFIYYDKLNZLAO-UHFFFAOYSA-N 2-aminoethane-1,1-diol Chemical compound NCC(O)O MLFIYYDKLNZLAO-UHFFFAOYSA-N 0.000 claims description 8
- IBOBFGGLRNWLIL-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)[O-] IBOBFGGLRNWLIL-UHFFFAOYSA-N 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- QZRMKGRPCTVXBS-UHFFFAOYSA-N 2,6,8-trimethylnonan-4-yl dihydrogen phosphate Chemical compound CC(C)CC(C)CC(CC(C)C)OP(O)(O)=O QZRMKGRPCTVXBS-UHFFFAOYSA-N 0.000 claims description 6
- ZUVCYFMOHFTGDM-UHFFFAOYSA-N hexadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCOP(O)(O)=O ZUVCYFMOHFTGDM-UHFFFAOYSA-N 0.000 claims description 5
- LYRFLYHAGKPMFH-UHFFFAOYSA-N Amide-Octadecanoic acid Natural products CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 229940037312 stearamide Drugs 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 2
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- UTTVXKGNTWZECK-UHFFFAOYSA-N n,n-dimethyloctadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)[O-] UTTVXKGNTWZECK-UHFFFAOYSA-N 0.000 claims description 2
- 238000007789 sealing Methods 0.000 claims description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract description 9
- 239000012535 impurity Substances 0.000 abstract description 7
- 235000013336 milk Nutrition 0.000 abstract description 4
- 239000008267 milk Substances 0.000 abstract description 4
- 210000004080 milk Anatomy 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 3
- 238000004140 cleaning Methods 0.000 abstract description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 2
- 239000011148 porous material Substances 0.000 abstract 2
- 241000894006 Bacteria Species 0.000 abstract 1
- 230000000845 anti-microbial effect Effects 0.000 abstract 1
- 239000004599 antimicrobial Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 235000013305 food Nutrition 0.000 abstract 1
- 241000283690 Bos taurus Species 0.000 description 27
- 239000007787 solid Substances 0.000 description 12
- 230000000844 anti-bacterial effect Effects 0.000 description 7
- 235000020185 raw untreated milk Nutrition 0.000 description 7
- 238000007599 discharging Methods 0.000 description 6
- 239000003643 water by type Substances 0.000 description 6
- 235000013365 dairy product Nutrition 0.000 description 5
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Chinese gallotannin Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 208000031462 Bovine Mastitis Diseases 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 230000006651 lactation Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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- Medicinal Preparation (AREA)
- Cosmetics (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention discloses a breast washing solution for a milking cow and a preparation method of the breast washing solution. The breast washing solution comprises the following components in certain parts by weight: phosphate, amine oxide, refined iodine, glycerol and de-ionized water. The breast washing solution has an excellent cleaning function and also has an anti-microbial skin-care function without generating any residuals; when the breast washing solution is used before milking, dirt and bacteria on the surface of the breast of the milking cow are removed completely and are prevented from entering the milking pores and original milk of the milking cow, in this way, the quality of the original milk is improved, and the food potential safety hazard is reduced; when the breast washing solution is used after milking, the expanded milking pores of the milking cow are enabled to shrink naturally, and the skin is protected from chapping, in this way, the economic benefits of milking farmers and farms are directly increased. The preparation method comprises the following steps of: stirring phosphate, amine oxide and refined iodine in a reaction kettle of 40-80 DEG C for 60-120min according to a certain ratio, then adding glycerol and de-ionized water, keeping on stirring for 20-60min, and filtering to obtain the breast washing solution; the preparation method is simple in process and stable in technique; in addition, the prepared breast washing solution is long in quality guarantee period, even in components and free of impurities.
Description
Technical field
The invention belongs to washing technology field, be specifically related to a kind of milch cow and wash emulsion, the invention still further relates to the preparation method that this milch cow is washed emulsion.
Background technology
In recent years, dairy food quality has been produced a lot of problems in succession, country more and more payes attention to food-safety problem, each Dairy Production producer is also improving the quality of products by every means in all its bearings, the quality of dairy food quality depends on the quality of raw milk to a great extent in fact, and the quality that how to improve raw milk just becomes a vital problem.Traditional approach cleans generally and cleans or napkin wiping with clear water for cow breast before milking, what also have cleans by disinfectant, but the drawback of this mode is to remove thoroughly dirt and the antibacterial on cow breast surface, cause while milking dirt or antibacterial along with milking equipment enters in the middle of raw milk, pollute raw milk.Open in the newborn hole of milch cow owing to milking, this has given antibacterial opportunity, antibacterial enters into the breast inside of milch cow possibly, cause milk bovine mastitis, thereby directly cause raw milk bacterial population to raise, regular cleaning, is also easy to cause cow breast to chap, damage Lactation of Dairy Cow system, affects raw milk quality and dairy farmer's economic interests.
Summary of the invention
One of object of the present invention is in order to make up the deficiencies in the prior art; provide a kind of non-stimulated to skin; have the effect of protection skin concurrently; do not produce any residual; and can remove thoroughly dirt and the antibacterial on cow breast surface, prevent entering into the newborn hole of milch cow and the milch cow in the middle of raw milk is washed emulsion and preparation method thereof.
The technical scheme that the present invention realizes its object employing is: a kind of milch cow is washed emulsion, and by weight percentage, the technical recipe that described milch cow is washed emulsion consists of:
Phosphate ester 3%～20% amine oxide 1%～10%
Essence iodine 0.3%～1.2% glycerol 1%～12%
Surplus is deionized water
Further, the mass fraction of described phosphate ester is 90%～99%, and the mass fraction of described glycerol is 90%～99.8%, and the mass fraction of described amine oxide is 10%～35%, and the mass fraction of described smart iodine is 90%～99.8%.
Be preferably, the mass fraction of described phosphate ester is 95%～99%, and the mass fraction of described glycerol is 99.5%～99.8%, and the mass fraction of described amine oxide is 20%～30%, and the mass fraction of described smart iodine is 95%～99.8%.
Further, described phosphate ester is one or more in alkyl phosphate, NPE phosphate ester, alkylolamides phosphate ester and high molecular phosphoric acid ester.
Further, described alkyl phosphate is one or more in 1-isobutyl-3,5-dimethylhexylphosphoric acid, hexadecanyl phosphate and octadecyl phosphate ester.
Further, described amine oxide is one or more of alkyl dimethyl amine oxide, alkyl dihydroxy ethyl amine oxide, alkylamidoalkyl amine oxide.
Further, described alkyl dimethyl amine oxide is one or more in dimethyl dodecyl amine oxide, CH3-(CH2)13N(CH3)2-O, cetyl dimethyl amine oxide and octadecyl dimethyl amine oxide.
Further, described alkyl dihydroxy ethyl amine oxide is one or more in dodecyl dihydroxy ethyl amine oxide, myristyl dihydroxy ethyl amine oxide, cetyl dihydroxy ethyl amine oxide, octadecyl dihydroxy ethyl amine oxide, oil base dihydroxy ethyl amine oxide, lauryl dihydroxy ethyl amine oxide, cocoyl dihydroxy ethyl amine oxide.
Further, described alkylamidoalkyl amine oxide is one or more in dodecanamide propyl amine oxide, cocamidopropyl propyl amide amine oxide, stearamide propyl group amine oxide.
The present invention, by the synergism of various compositions, can reach protection milk cow skin, removes thoroughly the dirt on cow breast surface and the object of antibacterial.Its mechanism of action main manifestations is in the following areas:
Amine oxide: soluble in water and organic solvent is a kind of weak cation type amphoteric surfactant, has good decontamination and bactericidal property.
Phosphate ester: be a kind of phosphorous surfactant, function admirable and being widely used, has the characteristics such as good moistening, clean, solubilising.
Essence iodine: property is crisp, and solution can be made disinfectant, and escherichia coli, staphylococcus aureus etc. are had to fabulous killing action.
Glycerol: the clear and bright thick liquid of colorless and odorless, miscible with water, can from air, absorb moisture, Nonpoisonous, non-environmental-pollution, is therefore widely used in cosmetics, to skin, can play moisture-keeping function.
Another object of the present invention is to provide the preparation method that a kind of milch cow is washed emulsion, and the method comprises the steps:
(1) phosphate ester of measuring fixed amount, amine oxide and smart iodine are inserted in the reactor of sealing;
(2) reacting by heating still to 40 °～80 °;
(3) stir the mixture 60～120 minutes, mixing speed is 60～100 revs/min;
(4) add glycerol and the deionized water of measuring fixed amount;
(5) stir the mixture 20～60 minutes;
(6) filter;
(7) cooling, to be installed.
The specific embodiment
Below in conjunction with embodiment, the invention will be further described, but protection scope of the present invention is not only confined to embodiment.
Embodiment 1
The preparation of component in formula:
(1) phosphate ester:
Get mass fraction and be 3 kilograms of 90% 1-isobutyl-3,5-dimethylhexylphosphoric acid solution, be placed in clean container stand-by.
(2) glycerol:
Get mass fraction and be 1 kilogram of 90% glycerite, be placed in clean container stand-by.
(3) amine oxide:
Get mass fraction and be 10 kilograms of 10% octadecyl dihydroxy ethyl amine oxide solutions, be placed in clean container stand-by.
(4) smart iodine:
Get mass fraction and be 0.3 kilogram of 90% solid essence iodine, be placed in clean container stand-by.
Preparation milch cow is washed emulsion:
(1) 0.3 kilogram of 3 kilograms of 1-isobutyl-3,5-dimethylhexylphosphoric acid solution that are 90% by above-mentioned ready mass fraction, 10 kilograms of octadecyl dihydroxy ethyl amine oxide solutions that mass fraction is 10%, solid essence iodine that mass fraction is 90%, pour in clean reactor.
(2) heating-up temperature to 40 ℃.
(3) open and stir, rotating speed is adjusted to 60 revs/min, stirs 60 minutes.
(4) adding the above-mentioned good quality mark that takes is 1 kilogram of 90% glycerite, and 75 kilograms of deionized waters.
(5) keep equally 60 revs/min of rotating speeds, stir 20 minutes.
(6) open reactor, pour out and wash emulsion, it is 50 object drainage screens that the discharging opening of reactor is provided with aperture, filters out the impurity of washing in emulsion.
(7) wash emulsion and pack in clean hermetic container, standing to be installed.
Embodiment 2
(1) phosphate ester:
Get mass fraction and be 10 kilograms of 95% NPE phosphate ester solution, be placed in clean container stand-by.
(2) glycerol:
Get mass fraction and be 6 kilograms of 95% glycerites, be placed in clean container stand-by.
(3) amine oxide:
Get mass fraction and be 25 kilograms of 20% cetyl dimethyl amine oxide solution, be placed in clean container stand-by.
(4) smart iodine:
Get mass fraction and be 0.7 kilogram of 95% solid essence iodine, be placed in clean container stand-by.
Preparation milch cow is washed emulsion:
(1) 0.7 kilogram of 10 kilograms of NPE phosphate ester solution that are 95% by above-mentioned ready mass fraction, 25 kilograms of cetyl dimethyl amine oxide solution that mass fraction is 20%, solid essence iodine that mass fraction is 95%, pour in clean reactor.
(2) heating-up temperature to 60 ℃.
(3) open and stir, rotating speed is adjusted to 80 revs/min, stirs 80 minutes.
(4) adding the above-mentioned good quality mark that takes is 6 kilograms of 95% glycerites, and 50 kilograms of deionized waters.
(5) keep equally 80 revs/min of rotating speeds, stir 40 minutes.
(6) open reactor, pour out and wash emulsion, it is 50 object drainage screens that the discharging opening of reactor is provided with aperture, filters out the impurity of washing in emulsion.
(7) wash emulsion and pack in clean hermetic container, standing to be installed.
Embodiment 3
The preparation of component in formula:
(1) phosphate ester:
Take mass fraction and be 20 kilograms of 99% polymer acid ester solutions, be placed in clean container stand-by.
(2) glycerol:
Take mass fraction and be 12 kilograms of 99.8% glycerites, be placed in clean container.
(3) amine oxide:
Take mass fraction and be 28 kilograms of 35% stearamide propyl group amine oxide solutions, be placed in clean container.
(4) smart iodine:
Take mass fraction and be 1.2 kilograms of 99.8% solid essence iodine, be placed in clean container.
Preparation milch cow is washed emulsion:
(1) 1.2 kilograms of 20 kilograms of polymer acid ester solutions that are 99% by the above-mentioned mass fraction taking, 28 kilograms of the stearamide propyl group amine oxide solutions that mass fraction is 35%, solid essence iodine that mass fraction is 99.8%, together pour in clean reactor internal layer.
(2) heating-up temperature to 80 ℃.
(3) open and stir, rotating speed is adjusted to 100 revs/min, stirs 120 minutes.
(4) adding the above-mentioned good quality mark that takes is 12 kilograms of 99.8% glycerites, and 38.8 kilograms of deionized waters.
(5) keep equally 100 revs/min of rotating speeds, stir 60 minutes.
(6) open reactor, pour out and wash emulsion, it is 50 object drainage screens that the discharging opening of reactor is provided with aperture, filters out the impurity of washing in emulsion.
(7) wash emulsion and pack in clean hermetic container, standing to be installed.
Embodiment 4
The preparation of component in formula:
(1) phosphate ester:
Take mass fraction and be 4 kilograms of 90% octadecyl phosphate ester solution, and 4 kilograms of mass fraction alkylolamides phosphate ester solution that is 95%, be placed in clean container mix homogeneously stand-by.
(2) glycerol:
Take mass fraction and be 4.5 kilograms of 95% glycerites, be placed in clean container stand-by.
(3) amine oxide:
Take mass fraction and be each 10 kilograms of the cetyl dimethyl amine oxide solution that 22% oil base dihydroxy ethyl amine oxide solution and mass fraction are 22%, be placed in clean container mix homogeneously stand-by.
(4) smart iodine:
Take mass fraction and be 0.5 kilogram of 95% solid essence iodine, be placed in clean container.
Preparation milch cow is washed emulsion:
(1) by 20 kilograms of the mixed liquors of 8 kilograms of mixed liquors, oil base dihydroxy ethyl amine oxide solution and the cetyl dimethyl amine oxide solution of above-mentioned ready octadecyl phosphate ester solution and alkylolamides phosphate ester solution, and 0.5 kilogram of solid essence iodine, together pour in clean reactor internal layer.
(2) heating-up temperature to 70 ℃.
(3) open and stir, rotating speed is adjusted to 90 revs/min, stirs 100 minutes.
(4) adding the above-mentioned good quality mark that takes is 4.5 kilograms of 95% glycerites, and 64 kilograms of deionized waters.
(5) turn speed to 100 revs/min, stir 50 minutes.
(6) open reactor, pour out and wash emulsion, it is 50 object drainage screens that the discharging opening of reactor is provided with aperture, filters out the impurity of washing in emulsion.
(7) wash emulsion and pack in clean hermetic container, standing to be installed.
Embodiment 5
The preparation of component in formula:
(1) phosphate ester:
Take mass fraction and be each 8 kilograms of the 1-isobutyl-3,5-dimethylhexylphosphoric acid solution that 95% hexadecanyl phosphate solution and mass fraction are 95%, be placed in clean container mix homogeneously.
(2) glycerol:
Take mass fraction and be 10 kilograms of 99% glycerites, be placed in clean container.
(3) amine oxide:
Take mass fraction and be each 8 kilograms of 25% oil base dihydroxy ethyl amine oxide solution, cetyl dimethyl amine oxide solution and dodecanamide propyl amine oxide solutions, be placed in clean container mix homogeneously stand-by.
(4) smart iodine:
Take mass fraction and be 1 kilogram of 99% solid essence iodine, be placed in clean container.
Preparation milch cow is washed emulsion:
(1) 1 kilogram of the solid essence iodine that is 99% by above-mentioned ready hexadecanyl phosphate solution and 16 kilograms of 1-isobutyl-3,5-dimethylhexylphosphoric acid mixed liquors, oil base dihydroxy ethyl amine oxide solution, cetyl dimethyl amine oxide solution and 24 kilograms of dodecanamide propyl amine oxide solution mixed liquors, mass fraction, together pours in clean reactor internal layer.
(2) heating-up temperature to 70 ℃～75 ℃.
(3) rotating speed of agitator is adjusted to 70～80 revs/min, stirs 90～100 minutes.
(4) add 10 kilograms of the above-mentioned glycerites taking, then add 49 kilograms of deionized waters.
(5) turn speed to 65～70 revs/min, stir 55～60 minutes.
(6) open reactor, pour out and wash emulsion, it is 50 object drainage screens that the discharging opening of reactor is provided with aperture, filters out the impurity of washing in emulsion.
(7) wash emulsion and pack in clean hermetic container, standing to be installed.
Embodiment 6
The preparation of component in formula:
(1) phosphate ester:
Take mass fraction and be each 2 kilograms of 95% hexadecanyl phosphate solution, octadecyl phosphate ester solution, NPE phosphate ester solution, alkylolamides phosphate ester solution and high molecular phosphoric acid ester solution, be placed in clean container mix homogeneously.
(2) glycerol:
Take mass fraction and be 6 kilograms of 99% glycerites, be placed in clean container.
(3) amine oxide:
Take mass fraction and be each 5 kilograms of 25% lauryl dihydroxy ethyl amine oxide solution, myristyl dihydroxy ethyl amine oxide, CH3-(CH2)13N(CH3)2-O solution and dodecanamide propyl amine oxide solutions, be placed in clean container mix homogeneously stand-by.
(4) smart iodine:
Take mass fraction and be 0.8 kilogram of 99% solid essence iodine, be placed in clean container.
Preparation milch cow is washed emulsion:
(1) by 10 kilograms of above-mentioned ready phosphate ester solution mixed liquors, 20 kilograms of amine oxide solution mixed liquors, 0.8 kilogram of solid essence iodine, together pour in clean reactor internal layer.
(2) heating-up temperature to 50 ℃～55 ℃.
(3) rotating speed of agitator is adjusted to 75～80 revs/min, stirs 70～80 minutes.
(4) add 6 kilograms of the above-mentioned glycerites taking, then add 63 kilograms of deionized waters.
(5) turn and keep 75～80 revs/min, stir 35～40 minutes.
(6) open reactor, pour out and wash emulsion, it is 50 object drainage screens that the discharging opening of reactor is provided with aperture, filters out the impurity of washing in emulsion.
(7) wash emulsion and pack in clean hermetic container, standing to be installed.
It should be noted that, the quality that milch cow is washed emulsion is by the following index: arsenic content, lead content, mercury content, total plate count, excrement colibacillus group and sterilizing rate are measured, method of testing is with reference to GB9985-2000, GB/T4789.39-2008 and < < cosmetics health standard > > (2007) version etc., as shown in the test result of following table 1, table 2 and table 3:
The milch cow that table 1 makes is washed performance parameter-1 of emulsion
The milch cow that table 2 makes is washed performance parameter-2 of emulsion
The milch cow that table 3 makes is washed performance parameter-3 of emulsion
Finally it should be noted that: above embodiment is only in order to illustrate the present invention and unrestricted technical scheme described in the invention; Therefore, although this description has been described in detail the present invention with reference to each above-mentioned embodiment,, those of ordinary skill in the art should be appreciated that still and can modify or be equal to replacement the present invention; And all do not depart from technical scheme and the improvement thereof of the spirit and scope of the present invention, it all should be encompassed in claim scope of the present invention.
Claims (6)
1. milch cow is washed an emulsion, it is characterized in that, by weight percentage, the technical recipe that described milch cow is washed emulsion consists of:
Phosphate ester 3%～20% amine oxide 1%～10%
Essence iodine 0.3%～1.2% glycerol 1%～12%
Surplus is deionized water;
Described phosphate ester is one or more in alkyl phosphate, NPE phosphate ester, alkylolamides phosphate ester;
Described amine oxide is one or more in alkyl dimethyl amine oxide, alkyl dihydroxy ethyl amine oxide, alkylamidoalkyl amine oxide.
2. milch cow according to claim 1 is washed emulsion, it is characterized in that, the mass fraction of described phosphate ester is 90%～99%, and the mass fraction of described glycerol is 90%～99.8%, the mass fraction of described amine oxide is 10%～35%, and the mass fraction of described smart iodine is 90%～99.8%.
3. milch cow according to claim 2 is washed emulsion, it is characterized in that, the mass fraction of described phosphate ester is 95%～99%, and the mass fraction of described glycerol is 99.5%～99.8%, the mass fraction of described amine oxide is 20%～30%, and the mass fraction of described smart iodine is 95%～99.8%.
4. milch cow according to claim 1 is washed emulsion, it is characterized in that, described alkyl phosphate is one or more in 1-isobutyl-3,5-dimethylhexylphosphoric acid, hexadecanyl phosphate and octadecyl phosphate ester.
5. milch cow according to claim 1 is washed emulsion, it is characterized in that, described alkyl dimethyl amine oxide is one or more in dimethyl dodecyl amine oxide, CH3-(CH2)13N(CH3)2-O, cetyl dimethyl amine oxide and octadecyl dimethyl amine oxide; Described alkyl dihydroxy ethyl amine oxide is one or more in dodecyl dihydroxy ethyl amine oxide, myristyl dihydroxy ethyl amine oxide, cetyl dihydroxy ethyl amine oxide, octadecyl dihydroxy ethyl amine oxide, oil base dihydroxy ethyl amine oxide, lauryl dihydroxy ethyl amine oxide, cocoyl dihydroxy ethyl amine oxide; Described alkylamidoalkyl amine oxide is one or more in dodecanamide propyl amine oxide, cocamidopropyl propyl amide amine oxide, stearamide propyl group amine oxide.
6. a kind of milch cow claimed in claim 1 is washed the preparation method of emulsion, it is characterized in that, this preparation method comprises the steps:
(1) phosphate ester of measuring fixed amount, amine oxide and smart iodine are inserted in the reactor of sealing;
(2) reacting by heating still to 40 ℃～80 ℃;
(3) stir the mixture 60～120 minutes, mixing speed is 60～100 revs/min;
(4) add glycerol and the deionized water of measuring fixed amount;
(5) stir the mixture 20～60 minutes;
(6) filter;
(7) cooling, to be installed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210380021.1A CN102885707B (en) | 2012-10-09 | 2012-10-09 | Breast washing solution for milking cow and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210380021.1A CN102885707B (en) | 2012-10-09 | 2012-10-09 | Breast washing solution for milking cow and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102885707A CN102885707A (en) | 2013-01-23 |
| CN102885707B true CN102885707B (en) | 2014-11-05 |
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Family Applications (1)
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| CN201210380021.1A Active CN102885707B (en) | 2012-10-09 | 2012-10-09 | Breast washing solution for milking cow and preparation method thereof |
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| CN103655230B (en) * | 2013-12-12 | 2015-04-15 | 上海康臣生物科技有限公司 | Daily cow nipple protective agent and preparation method thereof |
| CN110934800A (en) * | 2019-12-05 | 2020-03-31 | 上海康臣生物科技有限公司 | Multifunctional milk cow milk protecting agent and preparation method thereof |
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| CN101066058A (en) * | 2007-06-05 | 2007-11-07 | 孙保兴 | Amine oxide iodine complex disinfectant |
| CN102550602A (en) * | 2010-11-30 | 2012-07-11 | 中国科学院成都有机化学有限公司 | High-iodine controlled-release type sanitizer |
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| CN101066058A (en) * | 2007-06-05 | 2007-11-07 | 孙保兴 | Amine oxide iodine complex disinfectant |
| CN102550602A (en) * | 2010-11-30 | 2012-07-11 | 中国科学院成都有机化学有限公司 | High-iodine controlled-release type sanitizer |
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| 《碘伏在奶牛保健中应用探讨》;王赞江 等;《乳业科学与技术》;20071231(第3期);157-158 * |
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