CN102876240A - High-performance building adhesive - Google Patents
High-performance building adhesive Download PDFInfo
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- CN102876240A CN102876240A CN2012103519497A CN201210351949A CN102876240A CN 102876240 A CN102876240 A CN 102876240A CN 2012103519497 A CN2012103519497 A CN 2012103519497A CN 201210351949 A CN201210351949 A CN 201210351949A CN 102876240 A CN102876240 A CN 102876240A
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Abstract
The invention provides a high-performance building adhesive which comprises the following materials by weight: 20-80 parts of polyvinyl alcohol, 5-20 parts of epoxy resin, 0.1-2 parts of polyamide, 4-12 parts of polyacrylamide, 6-12 parts of epoxy diacrylate, 1-5 parts of nonylphenol polyoxyethylene ether, 20-60 parts of ethylene-vinyl acetate emulsion, 0.1-3 parts of initiator, 1-5 parts of octyltrimethoxysilane, 2-4 parts of gamma-methacryloxypropyltrimethoxysilane, 5-10 parts of hydroquinone, 5-10 parts of gypsum powder, 1-5 parts of bentonite, and 400-800 parts of deionized water. The building adhesive has good adhesion performance, high bonding strength, high drying speed, good waterproof performance, mildew resistance, no toxicity and harm, and no environment pollution. Compared with conventional building adhesive, the high-performance building adhesive has good bonding performance, stripping strength above 12 MPa, and tensile shearing strength above 20 MPa.
Description
Technical field
The invention provides a kind of high-performance building tackiness agent, belong to the adhesive technology field.
Background technology
Along with development and the growth in the living standard of society, building, decoration industry day by day increase the demand of architecture adhesion agent.The indexs such as the adhesive strength of the traditional architecture tackiness agent that uses at present, waterproof can not satisfy the demands, and major part contains a large amount of objectionable impuritiess such as aldehydes, organic solvent, and living environment and HUMAN HEALTH are caused great impact.Along with the enhancing of health of people consciousness, indoor finishing and environment more and more come into one's own, and traditional architecture adhesion agent is eliminated gradually, and the architecture adhesion agent with high-performance, environmental protection is more and more concerned, has the great market requirement.
Summary of the invention
For above commentary to prior art, technical problem to be solved by this invention is: improve the performance of architecture adhesion agent, reduce the pollution of tackiness agent.The technical scheme that adopts is:
A kind of high-performance building tackiness agent is made by the following raw material according to the weight part meter: 20 ~ 80 parts of polyvinyl alcohol, 5 ~ 20 parts of Resins, epoxy, 0.1 ~ 2 part of polymeric amide, 4 ~ 12 parts of polyacrylamides, 6 ~ 12 parts of propylene oxide acid diesters, 1 ~ 5 part of polyoxyethylene nonylphenol ether, 20 ~ 60 parts of ethylene-vinyl acetate emulsions, 0.1 ~ 3 part of initiator, 1 ~ 5 part of octyl group Trimethoxy silane, 2 ~ 4 parts of γ-methacryloxypropyl trimethoxy silane, 5 ~ 10 parts of Resorcinol, 5 ~ 10 parts of terra albas, 1 ~ 5 part of wilkinite, 400 ~ 800 parts of deionized waters.
The model of described polyvinyl alcohol is preferably technical grade 1799 types.
The molecular weight of described Resins, epoxy preferably 8000～200000, oxirane value is 0.48 ~ 0.54.
Described polymeric amide be molecular weight preferably 2000 ~ 12000.
Described Molecular Weight for Polyacrylamide preferably 50000 ~ 120000.
Described initiator is the mixture of ammonium persulphate and S-WAT, and mol ratio is 1:1.
Described bentonitic particle diameter is preferably less than 500 microns.
The preparation method is:
S1 adds polyvinyl alcohol, tensio-active agent and part deionized water in reactor, stir and be warming up to approximately 70 ~ 80 ℃, and polyvinyl alcohol is dissolved fully;
S2 puts into Resins, epoxy, propylene oxide acid diester, polymeric amide, polyacrylamide, polyoxyethylene nonylphenol ether, ethylene-vinyl acetate emulsion, initiator, octyl group Trimethoxy silane, γ-methacryloxypropyl trimethoxy silane and deionized water in the described reactor of S1 successively, stir, temperature is controlled at 70 ~ 80 ℃, is incubated 1 ~ 2 hour;
S3 joins Resorcinol, terra alba, wilkinite in the reactor, and 40 ~ 50 ℃ of lower stirrings 15 minutes, rear discharging stirs.
Beneficial effect
The invention provides the high-performance building tackiness agent, have good bonding strength, its shear strength can reach more than the 12MPa, and tensile strength reaches more than the 20MPa.
Embodiment
The weight proportion of table 1 embodiment 1～embodiment 3
Among the above embodiment, employing technical grade 1799 types of vinyl alcohol; The molecular weight of Resins, epoxy is 8000～200000, and oxirane value is 0.48 ~ 0.54; Polymeric amide for molecular weight be 2000 ~ 12000; Molecular Weight for Polyacrylamide is 50000 ~ 120000; Initiator is the mixture of ammonium persulphate and S-WAT, and mol ratio is 1:1; Bentonitic particle size range is 5～500 microns; Tensio-active agent adopts sodium laurylsulfonate.
The preparation method of each embodiment is:
S1 adds polyvinyl alcohol, tensio-active agent and part deionized water in reactor, stir and be warming up to approximately 70 ~ 80 ℃, and polyvinyl alcohol is dissolved fully;
S2 puts into Resins, epoxy, propylene oxide acid diester, polymeric amide, polyacrylamide, polyoxyethylene nonylphenol ether, ethene-vinyl acetate emulsion, initiator, octyl group Trimethoxy silane, γ-methacryloxypropyl trimethoxy silane and deionized water in the described reactor of S1 successively, stir, temperature is controlled at 70 ~ 80 ℃, is incubated 1 ~ 2 hour;
S3 joins Resorcinol, terra alba, wilkinite in the reactor, and 40 ~ 50 ℃ of lower stirrings 15 minutes, rear discharging stirs.
Performance test
The architecture adhesion agent of above embodiment gained is made a service test, and compare with traditional 107 building adhesives.Testing data is as shown in table 2.
The performance test data of table 2 embodiment 1～embodiment 3 and reference examples
| Test method | Embodiment 1 | Embodiment 2 | Embodiment 3 | Reference examples | |
| Outward appearance | Range estimation | White emulsion | White emulsion | White emulsion | The turbid liquid of canescence |
| Film formation time/minute | 5 | 6 | 6 | 68 | |
| The set time/hour | 16 | 15 | 16 | 25 | |
| Stripping strength/MPa | GB/T 2790-1995 | 15 | 14 | 12 | 4 |
| Tensile shear strength/MPa | GB/T 7124-1986 | 23 | 21 | 20 | 8 |
Can see from table, tackiness agent provided by the invention has good adhesiveproperties than traditional building adhesive, and stripping strength can reach more than the 12MPa, and tensile shear strength can reach more than the 20MPa.
Claims (7)
1. a high-performance building tackiness agent is made by the following raw material according to the weight part meter: 20 ~ 80 parts of polyvinyl alcohol, 5 ~ 20 parts of Resins, epoxy, 0.1 ~ 2 part of polymeric amide, 4 ~ 12 parts of polyacrylamides, 6 ~ 12 parts of propylene oxide acid diesters, 1 ~ 5 part of polyoxyethylene nonylphenol ether, 20 ~ 60 parts of ethylene-vinyl acetate emulsions, 0.1 ~ 3 part of initiator, 1 ~ 5 part of octyl group Trimethoxy silane, 2 ~ 4 parts of γ-methacryloxypropyl trimethoxy silane, 5 ~ 10 parts of Resorcinol, 5 ~ 10 parts of terra albas, 1 ~ 5 part of wilkinite, 400 ~ 800 parts of deionized waters; The preparation method is:
S1 adds polyvinyl alcohol and part deionized water in reactor, stir and be warming up to approximately 70 ~ 80 ℃, and polyvinyl alcohol is dissolved fully;
S2 puts into Resins, epoxy, propylene oxide acid diester, polymeric amide, polyacrylamide, polyoxyethylene nonylphenol ether, ethene-vinyl acetate emulsion, initiator, octyl group Trimethoxy silane, γ-methacryloxypropyl trimethoxy silane and deionized water in the reactor in the S1 step successively, stir, temperature is controlled at 70 ~ 80 ℃, is incubated 1 ~ 2 hour;
S3 joins Resorcinol, terra alba, wilkinite in the reactor, and 40 ~ 50 ℃ of lower stirrings 15 minutes, rear discharging stirs.
2. high-performance building tackiness agent according to claim 1, it is characterized in that: the model of described polyvinyl alcohol is technical grade 1799 types.
3. high-performance building tackiness agent according to claim 1, it is characterized in that: the molecular weight ranges of described Resins, epoxy is 8000～200000, oxirane value is 0.48 ~ 0.54.
4. high-performance building tackiness agent according to claim 1, it is characterized in that: described polymeric amide is that molecular weight ranges is 2000 ~ 12000.
5. high-performance building tackiness agent according to claim 1, it is characterized in that: described Molecular Weight for Polyacrylamide scope is 50000 ~ 120000.
6. high-performance building tackiness agent according to claim 1, it is characterized in that: described initiator is the mixture of ammonium persulphate and S-WAT, mol ratio is 1:1.
7. high-performance building tackiness agent according to claim 1, it is characterized in that: described bentonitic particle diameter is less than 500 microns.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN 201210351949 CN102876240B (en) | 2012-09-20 | 2012-09-20 | High-performance building adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210351949 CN102876240B (en) | 2012-09-20 | 2012-09-20 | High-performance building adhesive |
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| CN102876240A true CN102876240A (en) | 2013-01-16 |
| CN102876240B CN102876240B (en) | 2013-09-25 |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103952096A (en) * | 2014-03-24 | 2014-07-30 | 铜陵市松马食品包装机械制造有限责任公司 | Low temperature hot-seal adhesive and preparation method thereof |
| CN105440982A (en) * | 2015-05-04 | 2016-03-30 | 湖南工业大学 | Packing box used and wood-leather base material used environmentally-friendly aqueous binder |
| CN105567134A (en) * | 2016-03-16 | 2016-05-11 | 苏州华周胶带有限公司 | Heat-resistant adhesive material |
| CN105936814A (en) * | 2016-06-07 | 2016-09-14 | 刘伟 | Anti-ultraviolet plate adhesive |
| CN106010393A (en) * | 2016-06-07 | 2016-10-12 | 刘伟 | Board adhesive with good resistance to water penetration |
| CN106010367A (en) * | 2016-06-07 | 2016-10-12 | 刘伟 | Board adhesive with great bonding strength |
| CN106700984A (en) * | 2015-07-13 | 2017-05-24 | 修建东 | Waterproof and leakage-proof coating adhesive prepared from waste electronic molding compound |
| CN107746687A (en) * | 2017-09-21 | 2018-03-02 | 镇江市太浪新材料科技有限公司 | A kind of adhesive for building |
| CN107746679A (en) * | 2017-09-22 | 2018-03-02 | 镇江市太浪新材料科技有限公司 | A kind of preparation method of adhesive for building |
| CN108753207A (en) * | 2018-05-08 | 2018-11-06 | 陈少同 | A kind of aqueous binder for building |
| CN108822745A (en) * | 2018-05-16 | 2018-11-16 | 四川文希科技有限公司 | A kind of architecture adhesion agent and preparation method thereof |
| CN109880548A (en) * | 2019-03-28 | 2019-06-14 | 广州市长迅环保科技有限公司 | A kind of environment protection architecture glue and preparation method thereof |
| CN109943259A (en) * | 2019-03-28 | 2019-06-28 | 广州市长迅环保科技有限公司 | A kind of high strength building adhesive and preparation method thereof |
| CN109943258A (en) * | 2019-03-28 | 2019-06-28 | 广州市长迅环保科技有限公司 | A kind of water proof building glue and preparation method thereof |
| CN116144305A (en) * | 2023-03-09 | 2023-05-23 | 常熟市江南粘合剂有限公司 | Room temperature curing double-component epoxy adhesive and production process thereof |
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| JPS59159866A (en) * | 1983-03-02 | 1984-09-10 | Yokohama Rubber Co Ltd:The | Adhesive composition |
| CN1560165A (en) * | 2004-02-17 | 2005-01-05 | 南京林业大学 | Aldehyde-free adhesives for artificial board |
| CN101463231A (en) * | 2007-12-18 | 2009-06-24 | 第一毛织株式会社 | Adhesive composition and anisotropic conductive film using the same |
| KR20110001725A (en) * | 2009-06-30 | 2011-01-06 | 주식회사 오공 | Adhesive based vinyl acetate and method of manufacturing the same |
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2012
- 2012-09-20 CN CN 201210351949 patent/CN102876240B/en active Active
Patent Citations (4)
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| JPS59159866A (en) * | 1983-03-02 | 1984-09-10 | Yokohama Rubber Co Ltd:The | Adhesive composition |
| CN1560165A (en) * | 2004-02-17 | 2005-01-05 | 南京林业大学 | Aldehyde-free adhesives for artificial board |
| CN101463231A (en) * | 2007-12-18 | 2009-06-24 | 第一毛织株式会社 | Adhesive composition and anisotropic conductive film using the same |
| KR20110001725A (en) * | 2009-06-30 | 2011-01-06 | 주식회사 오공 | Adhesive based vinyl acetate and method of manufacturing the same |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103952096B (en) * | 2014-03-24 | 2016-04-13 | 铜陵市松马食品包装机械制造有限责任公司 | A kind of low-temperature hot-seal adhesive and preparation method thereof |
| CN103952096A (en) * | 2014-03-24 | 2014-07-30 | 铜陵市松马食品包装机械制造有限责任公司 | Low temperature hot-seal adhesive and preparation method thereof |
| CN105440982B (en) * | 2015-05-04 | 2017-05-10 | 湖南工业大学 | Packing box used and wood-leather base material used environmentally-friendly aqueous binder |
| CN105440982A (en) * | 2015-05-04 | 2016-03-30 | 湖南工业大学 | Packing box used and wood-leather base material used environmentally-friendly aqueous binder |
| CN106700984A (en) * | 2015-07-13 | 2017-05-24 | 修建东 | Waterproof and leakage-proof coating adhesive prepared from waste electronic molding compound |
| CN105567134A (en) * | 2016-03-16 | 2016-05-11 | 苏州华周胶带有限公司 | Heat-resistant adhesive material |
| CN105936814A (en) * | 2016-06-07 | 2016-09-14 | 刘伟 | Anti-ultraviolet plate adhesive |
| CN106010367A (en) * | 2016-06-07 | 2016-10-12 | 刘伟 | Board adhesive with great bonding strength |
| CN106010393A (en) * | 2016-06-07 | 2016-10-12 | 刘伟 | Board adhesive with good resistance to water penetration |
| CN107746687A (en) * | 2017-09-21 | 2018-03-02 | 镇江市太浪新材料科技有限公司 | A kind of adhesive for building |
| CN107746679A (en) * | 2017-09-22 | 2018-03-02 | 镇江市太浪新材料科技有限公司 | A kind of preparation method of adhesive for building |
| CN108753207A (en) * | 2018-05-08 | 2018-11-06 | 陈少同 | A kind of aqueous binder for building |
| CN108822745A (en) * | 2018-05-16 | 2018-11-16 | 四川文希科技有限公司 | A kind of architecture adhesion agent and preparation method thereof |
| CN109880548A (en) * | 2019-03-28 | 2019-06-14 | 广州市长迅环保科技有限公司 | A kind of environment protection architecture glue and preparation method thereof |
| CN109943259A (en) * | 2019-03-28 | 2019-06-28 | 广州市长迅环保科技有限公司 | A kind of high strength building adhesive and preparation method thereof |
| CN109943258A (en) * | 2019-03-28 | 2019-06-28 | 广州市长迅环保科技有限公司 | A kind of water proof building glue and preparation method thereof |
| CN116144305A (en) * | 2023-03-09 | 2023-05-23 | 常熟市江南粘合剂有限公司 | Room temperature curing double-component epoxy adhesive and production process thereof |
| CN116144305B (en) * | 2023-03-09 | 2023-09-26 | 常熟市江南粘合剂有限公司 | Room temperature curing double-component epoxy adhesive and production process thereof |
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| CN102876240B (en) | 2013-09-25 |
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Owner name: GUANGZHOU BAIZHUANG COMPOSITE MATERIALS CO., LTD. Free format text: FORMER OWNER: WUJIANG TIANYUAN PLASTICS CO., LTD. Effective date: 20150806 |
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Effective date of registration: 20150806 Address after: 511330 Zengcheng City, Guangzhou province stone beach town of sand on the road all the way up the East C4 No. Patentee after: Guangzhou compound material Co., Ltd. Address before: Wujiang City, Suzhou City, Jiangsu province 215212 Lili Town Industrial Park of arch bridge Patentee before: Wujiang Tianyuan Plastic Co., Ltd. |