CN102848767A - Weak solvent or offset printing thermal transfer paper and production process thereof - Google Patents

Weak solvent or offset printing thermal transfer paper and production process thereof Download PDF

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Publication number
CN102848767A
CN102848767A CN2012103045857A CN201210304585A CN102848767A CN 102848767 A CN102848767 A CN 102848767A CN 2012103045857 A CN2012103045857 A CN 2012103045857A CN 201210304585 A CN201210304585 A CN 201210304585A CN 102848767 A CN102848767 A CN 102848767A
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Prior art keywords
paper
printing
weak solvent
hectographic
heat
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CN2012103045857A
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CN102848767B (en
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李火桂
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Fuzhou Airui Digital Imaging Co., Ltd.
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FUZHOU ALIZARIN COATING Co Ltd
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Abstract

The invention relates to a weak solvent or offset printing thermal transfer paper. The thermal transfer paper from bottom to top is provided with a paper base, a first thermal transfer adhesive layer and a weak solvent or offset printing absorption dielectric layer. The first thermal transfer adhesive layer comprises the following components, by weight: 40-50% of polycaprolactone polyurethane, 30-40% of butadiene styrene or styrene copolymer, 10-15% of copolymerization polyamide resin, 5-10% of copolyester resin and 2-5% of pentaerythritol ester of rosin. At the same time, the invention also relates to a corresponding production process. According to the invention, the drew image can be freely printed by a weak solvent inkjet printer, a solvent-type ink-jet printer, a digital printing machine and a digital label printing machine, and then transferred to any textile through a hot pressing tool; a textile pattern can be finished in a few minutes, so as to fully meet the needs on small batch and rapid production by thermal transfer printing; and the production process has advantages of low labor intensity, high production efficiency, energy saving and environmental protection.

Description

A kind of Weak solvent or hectographic printing heat-transferring printing paper and manufacture craft thereof
Technical field
The present invention relates to a kind of Weak solvent or hectographic printing heat-transferring printing paper and manufacture craft thereof, belong to the transprint material field.
Background technology
Traditional silk-screen T-sympathizes, the flow process of lodge stamp is as follows: make picture, and------------------produce---hot transfer printing---finishes silk-screen the check and correction sample plate of drawing a design luxuriant and rich with fragrance beautiful jade sheet to make half tone; Therefore, adopt that traditional printing T-sympathizes, the lodge printing technology, can solve requirement simple, batch production, but simultaneously its technological process is long, personnel measure greatly, make the factors such as product is exquisite not, also so that its can't meet the need of market at aspects such as small lot, fast production, product diversification, personalizations, labour cost is high, production efficiency is low and inadequate energy-conserving and environment-protective, and the scope of application of its product is little, has a strong impact on the development of enterprise.
Summary of the invention
In view of the deficiencies in the prior art, the object of the present invention is to provide a kind of Weak solvent or hectographic printing heat-transferring printing paper and manufacture craft thereof, can solve the small lot of heat transfer printing, fast production, product diversification, time saving and energy saving, energy-conserving and environment-protective, the Extraordinary market demand, be fit to simultaneously any commercially available Weak solvent ink-jet printer and laser printer, and the ink of Weak solvent ink-jet and the carbon dust of laser printer do not had requirement, applied widely.
To achieve these goals, technical scheme one of the present invention is: a kind of Weak solvent or hectographic printing heat-transferring printing paper, described heat-transferring printing paper is disposed with the absorbing medium layer of paper substrate, the first hot transfer printing glue-line and Weak solvent or hectographic printing from the bottom up, and the described first hot transfer printing glue-line is mixed by following component by weight and forms: 40 ~ 50% poly-lactones polyurethane, 30 ~ 40% butadiene or styrol copolymer, 10 ~ 15% copolyamide resin, 5 ~ 10% copolymer polyester resin and 2 ~ 5% pentalyn.
Preferably, described paper substrate adopts PET, Ge Laxin paper, CCK paper or two-sided PEK paper.
Preferably, the peel strength of described paper substrate is 250 ~ 650 grams/inch.
Preferably, the absorbing medium layer of described Weak solvent or hectographic printing is mixed by following component by weight and forms: 20 ~ 25% PEPA, 45 ~ 50% polyamide, 2 ~ 5% pentalyn, 15 ~ 27% poly aromatic same clan ammonia ester, 5 ~ 10% polypropylene micronizing wax, other auxiliary agent of 0.5-1%.
Preferably, described PEPA-OH base content is 10 ~ 30%.
To achieve these goals, technical scheme two of the present invention is: the manufacture craft of a kind of Weak solvent or hectographic printing heat-transferring printing paper, and carry out according to the following steps: (1) chooses paper substrate; (2) paper substrate is carried out surface treatment: the surface of paper substrate is processed through silicone release agent processing or acrylic resin, and peel strength is controlled at 250 ~ 650 grams/inch; The coating of (3) first hot transfer printing glue-lines: will evenly be coated on the surface of treated mistake on the paper substrate after butadiene or styrol copolymer, poly-lactones polyurethane, pentalyn, copolyamide resin and the copolymer polyester resin mixing; (4) coating of the absorbing medium layer of Weak solvent or hectographic printing: the top that the absorbing medium layer of Weak solvent or hectographic printing evenly is coated in the first hot transfer printing glue-line; (5) paper cutting: after treating that above-mentioned each layer parches fully, size as required cuts.
Preferably, the paper substrate in the step (1) is selected PET, Ge Laxin paper, CCK paper or two-sided PEK paper.
Preferably, the first hot transfer printing glue-line in the step (3) is mixed by following component by weight and forms: 40 ~ 50% poly-lactones polyurethane, 30 ~ 40% butadiene or styrol copolymer, 10 ~ 15% copolyamide resin, 5 ~ 10% copolymer polyester resin and 2 ~ 5% pentalyn.
Preferably, the absorbing medium layer of the Weak solvent in the step (4) or hectographic printing is mixed by following component by weight and forms: 20 ~ 25% PEPA, 45 ~ 50% polyamide, 2 ~ 5% pentalyn, 15 ~ 27% poly aromatic same clan ammonia ester, 5 ~ 10% polypropylene micronizing wax, other auxiliary agent of 0.5-1%.
Preferably, described PEPA-OH base content is 10 ~ 30%.
Compared with prior art, the present invention has the following advantages: this Weak solvent or hectographic printing heat-transferring printing paper both can be used Weak solvent ink-jet printer, solvent-borne type ink-jet printer, also can go out institute's drawing image with digitlization offset press, digitized label printing machine Free Printing, be transferred on any textile by the hot pressing instrument that scalds again, a few minutes the textile patter that just can complete, can realize in enormous quantities, the fast production of heat transfer printing fully, labour intensity is low and production efficiency is high; Free Printing goes out diversified product as required simultaneously, not only can be time saving and energy saving, the market demand that can also be satisfying personalized, and applied widely, can be fit to any commercially available Weak solvent ink-jet printer, solvent-borne type ink-jet printer, digitlization offset press and digitized label printing machine, and the ink of ink-jet and the carbon dust of laser are not required, can save the cost of configuration professional equipment, energy-conserving and environment-protective are conducive to the prodution and development of enterprise.
Description of drawings
Fig. 1 is the organigram of the embodiment of the invention.
Among the figure: 1-paper substrate, 2-the first hot transfer printing glue-line, the absorbing medium layer of 3-Weak solvent or hectographic printing.
The specific embodiment
The present invention is further elaborated below in conjunction with drawings and Examples.
With reference to figure 1, a kind of Weak solvent or hectographic printing heat-transferring printing paper, described heat-transferring printing paper is disposed with the absorbing medium layer 3 of paper substrate 1, the first hot transfer printing glue-line 2 and Weak solvent or hectographic printing from the bottom up, and the described first hot transfer printing glue-line 2 is mixed by following component by weight and forms: 40 ~ 50% poly-lactones polyurethane, 30 ~ 40% butadiene or styrol copolymer, 10 ~ 15% copolyamide resin, 5 ~ 10% copolymer polyester resin and 2 ~ 5% pentalyn.
In the present embodiment, described paper substrate 1 adopts the PET(polyester film), Ge Laxin paper, CCK paper (Clay Coated Craft Paper) or two-sided PEK paper (film release liners), the peel strength of described paper substrate 1 is 250 ~ 650 grams/inch.
In the present embodiment, the absorbing medium layer 3 of described Weak solvent or hectographic printing is mixed by following component by weight and forms: 20 ~ 25% PEPA, 45 ~ 50% polyamide, 2 ~ 5% pentalyn, 15 ~ 27% poly aromatic same clan ammonia ester, 5 ~ 10% polypropylene micronizing wax, other auxiliary agent of 0.5-1%.Wherein, described PEPA-OH base content is 10 ~ 30%.
With reference to figure 1, the manufacture craft of a kind of Weak solvent or hectographic printing heat-transferring printing paper, carry out according to the following steps:
(1) chooses paper substrate 1: can select PET, Ge Laxin paper, CCK paper or two-sided PEK paper etc. as paper substrate 1;
(2) paper substrate 1 is carried out surface treatment: the surface of paper substrate 1 is processed through silicone release agent processing or acrylic resin, and peel strength is controlled at 250 ~ 650 grams/inch;
The coating of (3) first hot transfer printing glue-lines 2: will evenly be coated on the surface of treated mistake on the paper substrate after butadiene or styrol copolymer, poly-lactones polyurethane, pentalyn, copolyamide resin and the copolymer polyester resin mixing; (4) coating of the absorbing medium layer 3 of Weak solvent or hectographic printing: the top that the absorbing medium layer 3 of Weak solvent or hectographic printing evenly is coated in the first hot transfer printing glue-line;
(5) paper cutting: after treating that above-mentioned each layer parches fully, size as required cuts.
In the present embodiment, the first hot transfer printing glue-line 2 in the step (3) is mixed by following component by weight and forms: 40 ~ 50% poly-lactones polyurethane, 30 ~ 40% butadiene or styrol copolymer, 10 ~ 15% copolyamide resin, 5 ~ 10% copolymer polyester resin and 2 ~ 5% pentalyn.
In the present embodiment, the absorbing medium layer 3 of the Weak solvent in the step (4) or hectographic printing is mixed by following component by weight and forms: 20 ~ 25% PEPA, 45 ~ 50% polyamide, 2 ~ 5% pentalyn, 15 ~ 27% poly aromatic same clan ammonia ester, 5 ~ 10% polypropylene micronizing wax, other auxiliary agent of 0.5-1%.Wherein, described PEPA-OH base content is 10 ~ 30%.
The above only is preferred embodiment of the present invention, and all equalizations of doing according to the present patent application claim change and modify, and all should belong to covering scope of the present invention.

Claims (10)

1. a Weak solvent or hectographic printing heat-transferring printing paper, it is characterized in that: described heat-transferring printing paper is disposed with the absorbing medium layer of paper substrate, the first hot transfer printing glue-line and Weak solvent or hectographic printing from the bottom up, and the described first hot transfer printing glue-line is mixed by following component by weight and forms: 40 ~ 50% poly-lactones polyurethane, 30 ~ 40% butadiene or styrol copolymer, 10 ~ 15% copolyamide resin, 5 ~ 10% copolymer polyester resin and 2 ~ 5% pentalyn.
2. a kind of Weak solvent according to claim 1 or hectographic printing heat-transferring printing paper is characterized in that: described paper substrate employing PET, Ge Laxin paper, CCK paper or two-sided PEK paper.
3. a kind of Weak solvent according to claim 1 and 2 or hectographic printing heat-transferring printing paper is characterized in that: the peel strength of described paper substrate is 250 ~ 650 grams/inch.
4. a kind of Weak solvent according to claim 1 or hectographic printing heat-transferring printing paper is characterized in that: the absorbing medium layer of described Weak solvent or hectographic printing is mixed by following component by weight and forms: 20 ~ 25% PEPA, 45 ~ 50% polyamide, 2 ~ 5% pentalyn, 15 ~ 27% poly aromatic same clan ammonia ester, 5 ~ 10% polypropylene micronizing wax, other auxiliary agent of 0.5-1%.
5. a kind of Weak solvent according to claim 4 or hectographic printing heat-transferring printing paper is characterized in that: described PEPA-OH base content is 10 ~ 30%.
6. the manufacture craft of a Weak solvent or hectographic printing heat-transferring printing paper is characterized in that, carry out according to the following steps: (1) chooses paper substrate; (2) paper substrate is carried out surface treatment: the surface of paper substrate is processed through silicone release agent processing or acrylic resin, and peel strength is controlled at 250 ~ 650 grams/inch; The coating of (3) first hot transfer printing glue-lines: will evenly be coated on the surface of treated mistake on the paper substrate after butadiene or styrol copolymer, poly-lactones polyurethane, pentalyn, copolyamide resin and the copolymer polyester resin mixing; (4) coating of the absorbing medium layer of Weak solvent or hectographic printing: the top that the absorbing medium layer of Weak solvent or hectographic printing evenly is coated in the first hot transfer printing glue-line; (5) paper cutting: after treating that above-mentioned each layer parches fully, size as required cuts.
7. the manufacture craft of a kind of Weak solvent according to claim 6 or hectographic printing heat-transferring printing paper, it is characterized in that: the paper substrate in the step (1) is selected PET, Ge Laxin paper, CCK paper or two-sided PEK paper.
8. the manufacture craft of a kind of Weak solvent according to claim 6 or hectographic printing heat-transferring printing paper is characterized in that: the first hot transfer printing glue-line in the step (3) is mixed by following component by weight and forms: 40 ~ 50% poly-lactones polyurethane, 30 ~ 40% butadiene or styrol copolymer, 10 ~ 15% copolyamide resin, 5 ~ 10% copolymer polyester resin and 2 ~ 5% pentalyn.
9. the manufacture craft of a kind of Weak solvent according to claim 6 or hectographic printing heat-transferring printing paper is characterized in that: the Weak solvent in the step (4) or the absorbing medium layer of hectographic printing are mixed by following component by weight and form: 20 ~ 25% PEPA, 45 ~ 50% polyamide, 2 ~ 5% pentalyn, 15 ~ 27% poly aromatic same clan ammonia ester, 5 ~ 10% polypropylene micronizing wax, other auxiliary agent of 0.5-1%.
10. the manufacture craft of a kind of Weak solvent according to claim 9 or hectographic printing heat-transferring printing paper is characterized in that: described PEPA-OH base content is 10 ~ 30%.
CN201210304585.7A 2012-08-24 2012-08-24 Weak solvent or offset printing thermal transfer paper and production process thereof Active CN102848767B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104044376A (en) * 2014-06-27 2014-09-17 桐城市新丰彩印包装有限公司 Special-type gravure technology
CN104077958A (en) * 2014-05-23 2014-10-01 晋江市深沪键升印刷有限公司 Heat transfer silica gel trademark sign, forming technique and forming device
CN107215117A (en) * 2017-06-16 2017-09-29 广东毅科新材料有限公司 Gilding film and its preparation method and application
CN111631861A (en) * 2020-06-17 2020-09-08 扬州百思泰医疗科技有限公司 Silica gel remaining needle paste
CN112622469A (en) * 2020-12-29 2021-04-09 福州艾瑞数码影像有限公司 Ink-jet printing heat transfer film capable of preventing sublimation dye ink from migrating

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Publication number Priority date Publication date Assignee Title
CN1900830A (en) * 2005-03-28 2007-01-24 富士施乐株式会社 Image transfer sheet for electrophotography, and image recorded medium, as well as method for manufacturing the same
US20100243142A1 (en) * 2009-03-30 2010-09-30 Fujifilm Corporation Thermal transfer sheet and image formation method
CN102381069A (en) * 2011-08-10 2012-03-21 福州艾瑞数码影像有限公司 Dual-use heat-transfer paper for ink-jet or laser printing
CN102635018A (en) * 2012-04-25 2012-08-15 焦作卓林数码材料有限公司 Ink bearing paper for thermal dye sublimation record and preparation method of ink bearing paper

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1900830A (en) * 2005-03-28 2007-01-24 富士施乐株式会社 Image transfer sheet for electrophotography, and image recorded medium, as well as method for manufacturing the same
US20100243142A1 (en) * 2009-03-30 2010-09-30 Fujifilm Corporation Thermal transfer sheet and image formation method
CN102381069A (en) * 2011-08-10 2012-03-21 福州艾瑞数码影像有限公司 Dual-use heat-transfer paper for ink-jet or laser printing
CN102635018A (en) * 2012-04-25 2012-08-15 焦作卓林数码材料有限公司 Ink bearing paper for thermal dye sublimation record and preparation method of ink bearing paper

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104077958A (en) * 2014-05-23 2014-10-01 晋江市深沪键升印刷有限公司 Heat transfer silica gel trademark sign, forming technique and forming device
CN106205358A (en) * 2014-05-23 2016-12-07 晋江市深沪键升印刷有限公司 A kind of thermal transfer silica gel trademark and former
CN106205358B (en) * 2014-05-23 2019-07-23 晋江市深沪键升印刷有限公司 A kind of molding equipment of thermal transfer silica gel trademark
CN104044376A (en) * 2014-06-27 2014-09-17 桐城市新丰彩印包装有限公司 Special-type gravure technology
CN107215117A (en) * 2017-06-16 2017-09-29 广东毅科新材料有限公司 Gilding film and its preparation method and application
CN107215117B (en) * 2017-06-16 2019-05-03 广东毅科新材料有限公司 Gilding film and its preparation method and application
CN111631861A (en) * 2020-06-17 2020-09-08 扬州百思泰医疗科技有限公司 Silica gel remaining needle paste
CN112622469A (en) * 2020-12-29 2021-04-09 福州艾瑞数码影像有限公司 Ink-jet printing heat transfer film capable of preventing sublimation dye ink from migrating

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Address before: Cangshan District of Fuzhou City, Fujian province 350007 Jinshan Road No. 618 Jinshan orangery Chau Industrial Zone 60

Patentee before: Fuzhou Alizarin Coating Co., Ltd.