CN102848766B - Cutting-free laser printing thermal transfer paper and production process thereof - Google Patents
Cutting-free laser printing thermal transfer paper and production process thereof Download PDFInfo
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- CN102848766B CN102848766B CN201210304386.6A CN201210304386A CN102848766B CN 102848766 B CN102848766 B CN 102848766B CN 201210304386 A CN201210304386 A CN 201210304386A CN 102848766 B CN102848766 B CN 102848766B
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Abstract
The invention relates to a cutting-free laser printing thermal transfer paper. The thermal transfer paper from bottom to top is provided with a paper substrate and a transfer adhesive layer. The thermal transfer adhesive layer comprises the following components, by weight: 20-30% of ethylene vinyl acetate copolymer, 30-40% of polystyrene-isoprene-styrene copolymer, 2-5% of polystyrene-butadiene / styrene copolymer, 5-10% of pentaerythritol ester of rosin, 10-15% of polymethyl silicone resin and 20-25% of micronized wax. At the same time, the invention also relates to a corresponding production process. The cutting-free laser printing thermal transfer paper can not only be transferred to textiles by a hot pressing tool, but also be transferred to glass, ceramic, marble and metal without surface treatment; and the part of thermal transfer adhesive with patterns is completely transferred to the textile, and the part of thermal transfer adhesive without pattern will absolutely not be transferred to the textile, so as to eliminate a cutting process.
Description
Technical field
The present invention relates to one and exempt to cut laser printing heat-transferring printing paper and manufacture craft thereof, belong to transprint material field.
Background technology
Traditional silk-screen T-sympathizes, the flow process of lodge stamp is as follows: make picture, and------------------produce---hot transfer printing---completes silk-screen check and correction sample the plate of drawing a design luxuriant and rich with fragrance beautiful jade sheet to make half tone; Therefore, adopt that traditional printing T-sympathizes, lodge printing technology, can solve requirement simple, batch production, but its technological process is simultaneously long, personnel measure greatly, make the factors such as product is exquisite not, also make it to meet the need of market at aspects such as small lot, production fast, product diversification, personalizations.Existing laser printing heat-transferring printing paper generally can only be transferred on textile, cannot be transferred in the materials such as glass, pottery, marble and metal, during due to transfer printing, still do not have the hot transfer printing glue of figuratum part all can all be transferred on textile regardless of the hot transfer printing glue of figuratum part, therefore need not have the hot transfer printing glue of figuratum part to cut away in order to avoid it is transferred on textile, technique trouble, inefficiency.
Summary of the invention
In view of the deficiencies in the prior art, the object of the present invention is to provide one to exempt to cut laser printing heat-transferring printing paper and manufacture craft thereof, this is exempted to cut laser printing heat-transferring printing paper and scalds instrument by hot pressing and not only can be transferred on textile, but also can be transferred to without on surface-treated glass, pottery, marble and metal, the hot transfer printing glue of figuratum part is transferred on textile completely, do not have the hot transfer printing glue of figuratum part can not be transferred on textile completely, removed the operation of cutting from.
To achieve these goals, technical scheme one of the present invention is: one exempts to cut laser printing heat-transferring printing paper, described heat-transferring printing paper is disposed with paper substrate and transfer printing glue-line from the bottom up, and described hot transfer printing glue-line is mixed and formed by following component by weight: 20 ~ 30% plastic of poly vinyl acetate copolymer, polystyrene-isoprene-styrol copolymer of 30 ~ 40%, polystyrene-butadiene/styrene copolymers of 2 ~ 5%, 5 ~ 10% pentalyn, 10 ~ 15% poly-methyl silicon resin and 20 ~ 25% micronizing wax.
Preferably, described paper substrate adopts glazed printing paper or printing paper body paper.
Preferably, the melt index of described plastic of poly vinyl acetate copolymer is that 18 ~ 28g/min, ethylene contents are 22 ~ 40%.
Preferably, the melt index of described polystyrene-butadiene/styrene copolymers is that 3 ~ 8g/min, styrene-content are 30 ~ 40%.
Preferably, described micronizing wax is polyethylene micropowder wax or polypropylene micronizing wax.
To achieve these goals, technical scheme two of the present invention is: a kind of manufacture craft of exempting to cut laser printing heat-transferring printing paper, carry out according to the following steps: (1) chooses paper substrate; (2) paper substrate is carried out to surface treatment: the surperficial funds of paper substrate are dragged to the processing of method micronizing wax; (3) coating of hot transfer printing glue-line: plastic of poly vinyl acetate copolymer, polystyrene-isoprene-styrol copolymer, polystyrene-butadiene/styrene copolymers, pentalyn, poly-methyl silicon resin and micronizing wax are evenly coated on the surface of treated mistake on paper substrate; (4) paper cutting: treat above-mentioned each layer parch completely after, size as required cuts.
Preferably, the paper substrate in step (1) is selected glazed printing paper or printing paper body paper.
Preferably, the transfer printing glue-line in step (3) is mixed and is formed by following component by weight: 20 ~ 30% plastic of poly vinyl acetate copolymer, polystyrene-isoprene-styrol copolymer of 30 ~ 40%, polystyrene-butadiene/styrene copolymers of 2 ~ 5%, 5 ~ 10% pentalyn, 10 ~ 15% poly-methyl silicon resin and 20 ~ 25% micronizing wax.
Preferably, the melt index of described plastic of poly vinyl acetate copolymer is that 18 ~ 28g/min, ethylene contents are 22 ~ 40%.
Preferably, the melt index of described polystyrene-butadiene/styrene copolymers is that 3 ~ 8g/min, styrene-content are 30 ~ 40%.
Preferably, described micronizing wax is polyethylene micropowder wax or polypropylene micronizing wax.
Compared with prior art, the present invention has the following advantages: this exempts to cut laser printing heat-transferring printing paper laser printer, color photocopying all-in-one or digital printer can go out institute's drawing image by Free Printing, be transferred to 100% viscose rayon by the hot pressing instrument of scalding again, on the textile of 100% cotton or polyester-cotton blend (cotton >65%) and without surface-treated glass, pottery, marble, on metal, the hot transfer printing glue of figuratum part is transferred on textile completely, do not have the hot transfer printing glue of figuratum part can not be transferred to completely on textile, remove the operation of cutting from, greatly reduce labour intensity and improved production efficiency, and the textile softness after hot transfer printing, ventilative, water-fastness, good product quality, a few minutes just can complete a textile patter or handicraft, met the small lot of heat transfer printing, the needs produced fast completely, Free Printing goes out diversified product as required simultaneously, not only can be time saving and energy saving, and the market demand that can also be satisfying personalized, and be applicable to any commercially available most of laser printers, to the not requirement of the carbon dust of laser, save the cost of configuration professional equipment.
Brief description of the drawings
Fig. 1 is the organigram of the embodiment of the present invention.
In figure: 1-paper substrate, the hot transfer printing glue-line of 2-.
Detailed description of the invention
Below in conjunction with drawings and Examples, the present invention is further elaborated.
With reference to figure 1, one exempts to cut laser printing heat-transferring printing paper, described heat-transferring printing paper is disposed with paper substrate 1 and transfer printing glue-line 2 from the bottom up, and described hot transfer printing glue-line 2 is mixed and formed by following component by weight: 20 ~ 30% plastic of poly vinyl acetate copolymer, polystyrene-isoprene-styrol copolymer of 30 ~ 40%, polystyrene-butadiene/styrene copolymers of 2 ~ 5%, 5 ~ 10% pentalyn, 10 ~ 15% poly-methyl silicon resin and 20 ~ 25% micronizing wax.
In the present embodiment, described paper substrate 1 adopts but is not limited to glazed printing paper or printing paper body paper; The melt index of described plastic of poly vinyl acetate copolymer is that 18 ~ 28g/min, ethylene contents are 22 ~ 40%; The melt index of described polystyrene-butadiene/styrene copolymers is that 3 ~ 8g/min, styrene-content are 30 ~ 40%; Described micronizing wax is polyethylene micropowder wax or polypropylene micronizing wax.
With reference to figure 1, a kind of manufacture craft of exempting to cut laser printing heat-transferring printing paper, carry out according to the following steps:
(1) choose paper substrate 1; Select glazed printing paper or printing paper body paper etc. as paper substrate 1;
(2) paper substrate 1 is carried out to surface treatment: the surperficial funds of paper substrate 1 are dragged to the processing of method micronizing wax;
(3) coating of hot transfer printing glue-line 2: plastic of poly vinyl acetate copolymer, polystyrene-isoprene-styrol copolymer, polystyrene-butadiene/styrene copolymers, pentalyn, poly-methyl silicon resin and micronizing wax are evenly coated on the surface of treated mistake on paper substrate;
(4) paper cutting: treat above-mentioned each layer parch completely after, size as required cuts.
In the present embodiment, the transfer printing glue-line in step (3) is mixed and is formed by following component by weight: 20 ~ 30% plastic of poly vinyl acetate copolymer, polystyrene-isoprene-styrol copolymer of 30 ~ 40%, polystyrene-butadiene/styrene copolymers of 2 ~ 5%, 5 ~ 10% pentalyn, 10 ~ 15% poly-methyl silicon resin and 20 ~ 25% micronizing wax.
In the present embodiment, the melt index of described plastic of poly vinyl acetate copolymer is that 18 ~ 28g/min, ethylene contents are 22 ~ 40%; The melt index of described polystyrene-butadiene/styrene copolymers is that 3 ~ 8g/min, styrene-content are 30 ~ 40%; Described micronizing wax is polyethylene micropowder wax or polypropylene micronizing wax.
The foregoing is only preferred embodiment of the present invention, all equalizations of doing according to the present patent application the scope of the claims change and modify, and all should belong to covering scope of the present invention.
Claims (6)
1. exempt to cut laser printing heat-transferring printing paper for one kind, it is characterized in that: described heat-transferring printing paper is disposed with paper substrate and hot transfer printing glue-line from the bottom up, described hot transfer printing glue-line is mixed and is formed by following component by weight: 20 ~ 30% plastic of poly vinyl acetate copolymer, polystyrene-isoprene-styrol copolymer of 30 ~ 40%, polystyrene-butadiene/styrene copolymers of 2 ~ 5%, 5 ~ 10% pentalyn, 10 ~ 15% poly-methyl silicon resin and 20 ~ 25% micronizing wax, the melt index of described plastic of poly vinyl acetate copolymer is 18 ~ 28g/min, ethylene contents is 22 ~ 40%, the melt index of described polystyrene-butadiene/styrene copolymers is 3 ~ 8g/min, styrene-content is 30 ~ 40%.
2. one according to claim 1 exempts to cut laser printing heat-transferring printing paper, it is characterized in that: described paper substrate adopts glazed printing paper or printing paper body paper.
3. one according to claim 1 exempts to cut laser printing heat-transferring printing paper, it is characterized in that: described micronizing wax is polyethylene micropowder wax or polypropylene micronizing wax.
4. a manufacture craft of exempting to cut laser printing heat-transferring printing paper, is characterized in that, carries out according to the following steps: (1) chooses paper substrate, (2) paper substrate is carried out to surface treatment: the surperficial funds of paper substrate are dragged to the processing of method micronizing wax, (3) coating of hot transfer printing glue-line: hot transfer printing glue-line is evenly coated on the surface of treated mistake on paper substrate, hot transfer printing glue-line is mixed and is formed by following component by weight: 20 ~ 30% plastic of poly vinyl acetate copolymer, polystyrene-isoprene-styrol copolymer of 30 ~ 40%, polystyrene-butadiene/styrene copolymers of 2 ~ 5%, 5 ~ 10% pentalyn, 10 ~ 15% poly-methyl silicon resin and 20 ~ 25% micronizing wax, the melt index of described plastic of poly vinyl acetate copolymer is 18 ~ 28g/min, ethylene contents is 22 ~ 40%, the melt index of described polystyrene-butadiene/styrene copolymers is 3 ~ 8g/min, styrene-content is 30 ~ 40%, (4) paper cutting: treat above-mentioned each layer parch completely after, size as required cuts.
5. a kind of manufacture craft of exempting to cut laser printing heat-transferring printing paper according to claim 4, is characterized in that: the paper substrate in step (1) is selected glazed printing paper or printing paper body paper.
6. a kind of manufacture craft of exempting to cut laser printing heat-transferring printing paper according to claim 4, is characterized in that: described micronizing wax is polyethylene micropowder wax or polypropylene micronizing wax.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210304386.6A CN102848766B (en) | 2012-08-24 | 2012-08-24 | Cutting-free laser printing thermal transfer paper and production process thereof |
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| CN201210304386.6A CN102848766B (en) | 2012-08-24 | 2012-08-24 | Cutting-free laser printing thermal transfer paper and production process thereof |
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| CN102848766A CN102848766A (en) | 2013-01-02 |
| CN102848766B true CN102848766B (en) | 2014-07-09 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105922781A (en) * | 2016-05-03 | 2016-09-07 | 武汉华工激光工程有限责任公司 | Method for carving on glass by laser |
| CN110079257B (en) * | 2019-04-04 | 2021-01-05 | 武汉华中科大新材料股份有限公司 | Alumite hot stamping glue and preparation method thereof |
| CN112622468A (en) * | 2020-12-29 | 2021-04-09 | 福州艾瑞数码影像有限公司 | Dark hollow laser printing thermal transfer paper and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101119853A (en) * | 2005-02-21 | 2008-02-06 | 大科能树脂有限公司 | Laminate for laser marking |
| CN101684398A (en) * | 2008-09-11 | 2010-03-31 | 朗盛德国有限责任公司 | Hot-melt adhesive |
| CN102381069A (en) * | 2011-08-10 | 2012-03-21 | 福州艾瑞数码影像有限公司 | Dual-use heat-transfer paper for ink-jet or laser printing |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03193493A (en) * | 1989-12-25 | 1991-08-23 | Brother Ind Ltd | Re-transfer sheet for preparing dry transfer material |
| JP2004099821A (en) * | 2002-09-12 | 2004-04-02 | Oji Paper Co Ltd | Pressure-sensitive adhesive sheet |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101119853A (en) * | 2005-02-21 | 2008-02-06 | 大科能树脂有限公司 | Laminate for laser marking |
| CN101684398A (en) * | 2008-09-11 | 2010-03-31 | 朗盛德国有限责任公司 | Hot-melt adhesive |
| CN102381069A (en) * | 2011-08-10 | 2012-03-21 | 福州艾瑞数码影像有限公司 | Dual-use heat-transfer paper for ink-jet or laser printing |
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Owner name: FUZHOU AIRUI DIGITAL IMAGING CO., LTD. Free format text: FORMER OWNER: ALIZARIN COATING CO., LTD. Effective date: 20141031 |
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Effective date of registration: 20141031 Address after: 350799, No. 3, upper road, camphor Town, Yongtai County, Fuzhou, Fujian Patentee after: Fuzhou Airui Digital Imaging Co., Ltd. Address before: Cangshan District of Fuzhou City, Fujian province 350007 Jinshan Road No. 618 Jinshan orangery Chau Industrial Zone 60 Patentee before: Fuzhou Alizarin Coating Co., Ltd. |