CN104558963A - Anti-static two-sided gold-stamped, printed and embossed PVC (polyvinyl chloride) sheet and preparation method thereof - Google Patents
Anti-static two-sided gold-stamped, printed and embossed PVC (polyvinyl chloride) sheet and preparation method thereof Download PDFInfo
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- CN104558963A CN104558963A CN201410839231.1A CN201410839231A CN104558963A CN 104558963 A CN104558963 A CN 104558963A CN 201410839231 A CN201410839231 A CN 201410839231A CN 104558963 A CN104558963 A CN 104558963A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C69/00—Combinations of shaping techniques not provided for in a single one of main groups B29C39/00 - B29C67/00, e.g. associations of moulding and joining techniques; Apparatus therefore
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical Kinetics & Catalysis (AREA)
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to the technical field of sheets, in particular to an anti-static two-sided gold-stamped, printed and embossed PVC (polyvinyl chloride) sheet and a preparation method thereof. The sheet comprises raw materials in parts by weight as follows: 80-120 parts of PVC resin, 32-52 parts of a plasticizer, 6-10 parts of a lubricant, 1-4 parts of a heat stabilizer, 0.03-0.07 parts of a slipping agent, 0.03-0.07 parts of pigment powder and 0.1-0.5 parts of calcium powder, wherein the calcium powder is a mixture of nano calcium carbonate and heavy calcium carbonate in the weight ratio of 1:(1.5-2.5), the particle size of the nano calcium carbonate is in a range of 120-150 nm, and the particle size of the heavy calcium carbonate is in a range of 1-10 [mu]m. The raw materials are adopted, and the weight ratio of the raw materials is strictly controlled, so that the sheet is good in anti-static effect, heat-resistant, cold-resistant, acid-resistant, alkali-resistant, heavy-load-resistant, anti-aging, smooth in surface, free of cracks and bubbles, uniform in color, strong in stereoscopic impression, soft in texture, comfortable, healthy and environment-friendly.
Description
Technical field
The present invention relates to sheet technology field, be specifically related to a kind of antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material and preparation method thereof.
Background technology
Soft PVC sheet material transparent attractive in appearance, quality is soft, has been widely used in everyday articles field, as the tablecloth, mat applying and table mat etc.This based article is generally enclose transparent film at the another side of printed patterns, when cover furniture especially on glass furniture time, both can show the printed patterns on transparent film, and the pattern of furniture can have been observed again through transparent film, play good decorative effect.But sheet material antistatic effect is bad, and overall performance is poor.
Summary of the invention
In order to overcome the shortcoming and defect existed in prior art, the object of the present invention is to provide a kind of antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material, this sheet material antistatic effect is good, and heat-resisting, cold-resistant, acidproof, alkaline-resisting, resistant to pressure, anti-aging, smooth surface, leakless, bubble-free, uniform color, stereoscopic sensation is strong, and quality is soft, hand feel and drape, health environment-friendly.
Another object of the present invention is to the preparation method that a kind of antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material is provided, this preparation method adopts two-sided gold stamping printing technology, make sheet material two sides all with metal effect, after mixing stamp, one side pattern is distinct, there is three-dimensional aesthetic, product quality is soft, hand feel and drape; Technique is simple, and convenient operation and control, steady quality, production efficiency is high, can large-scale industrial production.
Object of the present invention is achieved through the following technical solutions: a kind of antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material, comprises the raw material of following weight part:
Polyvinyl chloride resin 80-120 part
Softening agent 32-52 part
Lubricant 6-10 part
Thermo-stabilizer 1-4 part
Slipping agent 0.03-0.07 part
Pigment powder 0.03-0.07 part
Calcium powder 0.1-0.5 part;
Wherein, the mixture that described calcium powder is made up of with weight ratio 1:1.5-2.5 nano-calcium carbonate and water-ground limestone, the particle diameter of nano-calcium carbonate is 120-150nm; The particle diameter of water-ground limestone is 1-10 μm.
The present invention by adopt particle diameter be the nano-calcium carbonate of 120-150nm with particle diameter be the water-ground limestone of 1-10 μm as the composite use of calcium powder, and to control its weight ratio be 1:1.5-2.5, can improve the embossing effect of sheet material.
Sheet material of the present invention is by adopting above-mentioned raw materials, and strict its weight proportion of control, make sheet material antistatic effect good, and heat-resisting, cold-resistant, acidproof, alkaline-resisting, resistant to pressure, anti-aging, smooth surface, leakless, bubble-free, uniform color, stereoscopic sensation is strong, and quality is soft, hand feel and drape, health environment-friendly.
Preferably, described polyvinyl chloride resin be the polymerization degree at 1000-1200, particle diameter in 0.1-0.2mm, density at 1.35-1.45g/cm
3polyvinyl chloride resin.
The molecular weight (polymerization degree) of polyvinyl chloride resin, particle diameter, density are relevant with the physical and mechanical properties of sheet material, and molecular weight is higher, and the tensile strength of sheet material, shock strength, Young's modulus are higher; The present invention is by controlling at 1000-1200 by the polymerization degree of polyvinyl chloride resin, and size controlling is at 0.1-0.2mm, and density domination is at 1.35-1.45g/cm
3, sheet material can be made to have higher intensity.
Preferably, the mixture that is made up of with weight ratio 15-19:1 dioctyl phthalate (DOP) and epoxy soybean oil of described softening agent.
The present invention adopts dioctyl phthalate (DOP) and epoxy soybean oil as the composite use of softening agent, two kinds of softening agent are environment-friendly plasticizer, the reactive force between PVC molecular chain can be reduced, the fusing point of the second-order transition temperature of PVC plastic, yield temperature and contained crystallite is all reduced, softening agent can improve the plasticity-of resin, makes goods softness, resistance to low temperature good; And when the use composite with weight ratio 15-19:1 of two kinds of softening agent, flexibility and the resistance to low temperature of goods can be improved.
Preferably, the mixture that is made up of with weight ratio 1.2-1.8:1 microcrystalline wax and stearic acid monoglycerides of described lubricant.
The present invention adopts microcrystalline wax as external lubricant, can reduce the friction of PVC melt and mould, machine barrel; Adopt stearic acid monoglycerides as internal lubricant, the intermolecular friction of PVC melt can be reduced; Two kinds of lubricants improve the mobility of material and the release property of goods with the weight ratio 1.2-1.8:1 material that can make used in combination in the course of processing.
Preferably, the mixture that is made up of with weight ratio 20-40:4-8:1 Soil stability agent, auxiliary stabilizer and auxiliary agent of described thermo-stabilizer.
The present invention is by obtaining thermo-stabilizer by Soil stability agent, auxiliary stabilizer and auxiliary agent with weight ratio 20-40:4-8:1 mixing, and its thermostable effect is good.
The mixture that described main body thermo-stabilizer is made up of with weight ratio 1:1.5-2.5:6-8 hydrotalcite, barium stearate and Zinic stearas; Described auxiliary heat stabilizer is the mixture be made up of with weight ratio 1:1.8-2.6 the different fork-fatty alcohol-phosphorous acid chelate compounds polymkeric substance of carbon back-4,4-bis-and N.F,USP MANNITOL; The mixture that described auxiliary agent is made up of with weight ratio 1:4-8 emulsifying agent and defoamer.
The present invention adopts Zinic stearas, barium stearate and zinc laurate as main body thermo-stabilizer, and to control its weight ratio be 1:1.5-2.5:6-8, make material in the course of processing, have good dispersiveness, consistency and processing fluidity, make material good heat stability, there is efficient weathering resistance.
The present invention adopts carbon back-4, different fork-fatty alcohol-phosphorous acid chelate compounds the polymkeric substance of 4-bis-and N.F,USP MANNITOL are as auxiliary heat stabilizer, and to control its weight ratio be 1:1.8-2.6, the stability of main body thermo-stabilizer can be improved, make material in the course of processing, have good dispersiveness, consistency and processing fluidity, make material good heat stability, there is efficient weathering resistance.
The present invention is by adopting emulsifying agent and defoamer, and to control its weight ratio be 1:4-8, the stability of obtained thermo-stabilizer can be improved, make material in the course of processing, have good dispersiveness, consistency and processing fluidity, make material good heat stability, there is efficient weathering resistance.
Preferably, the mixture that is made up of with weight ratio 1:1.6-2.4:2.4-3.2 potassium oleate, potassium stearate and potassium rosinate of described emulsifying agent; The mixture that described defoamer is made up of with weight ratio 1.6-2.4:1 tributyl phosphate and polydimethylsiloxane.
The present invention adopts potassium oleate, potassium stearate and potassium rosinate to be emulsifying agent, and to control its weight ratio be 1:1.6-2.4:2.4-3.2, emulsify well; The present invention adopts tributyl phosphate and polydimethylsiloxane as defoamer, and to control its weight ratio be 1.6-2.4:1, and foaming effect is good.
Preferably, described slipping agent is the mixture be made up of with weight ratio 1:0.8-1.2:1.5-2.5 erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide.
The present invention is by adopting erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide is as slipping agent and to control its weight ratio be 1:0.8-1.2:1.5-2.5, mechanical resistant stirring capacity and fingerprinting stress can be strengthened, finished product good forming effect, any surface finish, the extensibility of finished product can also be strengthened, easy-to-draw not easily broken.
Preferably, the mixture that is made up of with weight ratio 1:1.4-2.2 ultramarine toner and phthalocyanine blue of described pigment powder.
The present invention is by adopting ultramarine toner and phthalocyanine blue as the composite use of pigment powder, and to control its weight ratio be 1:1.4-2.2, and product color inhibition is effective.
Object of the present invention is achieved through the following technical solutions: a kind of preparation method of antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material, comprises the steps:
A, raw material prepare: take each raw material by above-mentioned raw materials composition, mixing;
B, high-speed stirring: mixed raw material is put into high speed blender, stir 8-12min at 110-120 DEG C of temperature, and the rotating speed of stirring is 580-1160RPM;
C, once plasticizing: the raw material after stirring is carried out first time plasticizing through planetary extruder at 140-160 DEG C of temperature, obtains micelle;
D, secondary plasticizing: the micelle after first time plasticizing is carried out second time plasticizing, until evenly through pricking turbine at 130-150 DEG C of temperature;
E, level filter: the micelle after second time plasticizing is adopted 20 order nets, 60 order nets and 150 net filtrations successively through filter, and the screw speed of filter is 50-70RPM;
F, calendering formation: by the micelle after filtration through rolling press calendering formation, obtain sheet material;
G, cooling rolling: the sheet material after shaping is carried out cooling and shaping through drawing cooling wheel, then carries out rolling through winder;
H, gold stamping stamp: by the sheet material printed patterns after rolling, put to discharging frame by the sheet material after printed patterns and bronzing material, carry out gold stamping, demoulding and embossing through gold stamping stamp graining machine, obtain antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material.
Preferably, in described step F, rolling press is six roll calendars, and the temperature of each roller is followed successively by: 170-180 DEG C, 170-180 DEG C, 190-200 DEG C, 190-200 DEG C, 178-188 DEG C and 178-188 DEG C; In described step H, gold stamping preheating temperature is 75-85 DEG C, and gold stamping embossing temperature is 140-160 DEG C.
Beneficial effect of the present invention is: the present invention by adopt particle diameter be the nano-calcium carbonate of 120-150nm with particle diameter be the water-ground limestone of 1-10 μm as the composite use of calcium powder, and to control its weight ratio be 1:1.5-2.5, can improve the embossing effect of sheet material.
The present invention is by controlling at 1000-1200 by the polymerization degree of polyvinyl chloride resin, and size controlling is at 0.1-0.2mm, and density domination is at 1.35-1.45g/cm
3, sheet material can be made to have higher intensity.
The present invention adopts dioctyl phthalate (DOP) and epoxy soybean oil as the composite use of softening agent, two kinds of softening agent are environment-friendly plasticizer, the reactive force between PVC molecular chain can be reduced, the fusing point of the second-order transition temperature of PVC plastic, yield temperature and contained crystallite is all reduced, softening agent can improve the plasticity-of resin, makes goods softness, resistance to low temperature good; And when the use composite with weight ratio 15-19:1 of two kinds of softening agent, flexibility and the resistance to low temperature of goods can be improved.
The present invention adopts microcrystalline wax as external lubricant, can reduce the friction of PVC melt and mould, machine barrel; Adopt stearic acid monoglycerides as internal lubricant, the intermolecular friction of PVC melt can be reduced; Two kinds of lubricants improve the mobility of material and the release property of goods with the weight ratio 1.2-1.8:1 material that can make used in combination in the course of processing.
The present invention is by adopting erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide is as slipping agent and to control its weight ratio be 1:0.8-1.2:1.5-2.5, mechanical resistant stirring capacity and fingerprinting stress can be strengthened, finished product good forming effect, any surface finish, the extensibility of finished product can also be strengthened, easy-to-draw not easily broken.
The present invention is by adopting ultramarine toner and phthalocyanine blue as the composite use of pigment powder, and to control its weight ratio be 1:1.4-2.2, and product color inhibition is effective.
Sheet material of the present invention is by adopting above-mentioned raw materials, and strict its weight proportion of control, make sheet material antistatic effect good, and heat-resisting, cold-resistant, acidproof, alkaline-resisting, resistant to pressure, anti-aging, smooth surface, leakless, bubble-free, uniform color, stereoscopic sensation is strong, and quality is soft, hand feel and drape, health environment-friendly.
Sheet material tool of the present invention has the following advantages: product paving is on the table with the gloss of metal, look and resemble gold and silver and make and form in surface, permeability because of opaque products makes product two sides all with metal effect, after mixing stamp, one side pattern is distinct, there is three-dimensional aesthetic, product quality is soft, and hand feel and drape, has the functions such as heat-resisting, cold-resistant especially.Its cool in summer and warm in winter and that matter is soft characteristic, makes desktop office person works particularly comfortable.Because it is good and cheap, be covered on platform, desktop in order to antifouling or increase ordinary articles attractive in appearance.
2, anti-light photograph, indeformable, do not send out broken, do not harden, snappiness.
3, quality soft, be easy to write.
4, heat-resisting 100 DEG C, cold-resistant-30 DEG C, resistance to strong acid, alkali, resistant to pressure, contributes to the efficiency improving desktop work, can reduce cleaning cost, increase the graceful beautiful sexy in dining room for dining room.
5, antistatic.Electrical insulation capability is excellent, chemical property inertia, nonpoisonous and tasteless, has no adverse reaction, and have radiation resistance to human body, effectively can prevent generation and the dissipation electrostatic of electrostatic.Its high tenacity had and snappiness, effectively can play cushioning effect when floor file or paving work top, prevent the touching of sophisticated product, pull, available protecting product innovation appearance is injury-free.The precision instrument desktop of telecommunications, electronics, computer company, family expenses uses, essential product especially.
Preparation method of the present invention adopts two-sided gold stamping printing technology, makes sheet material two sides all with metal effect, and after mixing stamp, one side pattern is distinct, has three-dimensional aesthetic, and product quality is soft, hand feel and drape; Technique is simple, and convenient operation and control, steady quality, production efficiency is high, can large-scale industrial production.
Embodiment
For the ease of the understanding of those skilled in the art, below in conjunction with embodiment, the present invention is further illustrated, and the content that embodiment is mentioned not is limitation of the invention.
Embodiment 1
A kind of antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material, comprises the raw material of following weight part:
Polyvinyl chloride resin 80 parts
32 parts, softening agent
Lubricant 6 parts
Thermo-stabilizer 1 part
Slipping agent 0.03 part
0.03 part, pigment powder
Calcium powder 0.1 part;
Wherein, the mixture that described calcium powder is made up of with weight ratio 1:1.5 nano-calcium carbonate and water-ground limestone, the particle diameter of nano-calcium carbonate is 120nm; The particle diameter of water-ground limestone is 1 μm.
Described polyvinyl chloride resin is the polymerization degree 1000, particle diameter in 0.1mm, density at 1.35g/cm
3polyvinyl chloride resin.
The mixture that described softening agent is made up of with weight ratio 15:1 dioctyl phthalate (DOP) and epoxy soybean oil.
The mixture that described lubricant is made up of with weight ratio 1.2:1 microcrystalline wax and stearic acid monoglycerides.
The mixture that described thermo-stabilizer is made up of with weight ratio 20:4:1 Soil stability agent, auxiliary stabilizer and auxiliary agent; The mixture that described main body thermo-stabilizer is made up of with weight ratio 1:1.5:6 hydrotalcite, barium stearate and Zinic stearas; Described auxiliary heat stabilizer is the mixture be made up of with weight ratio 1:1.8 the different fork-fatty alcohol-phosphorous acid chelate compounds polymkeric substance of carbon back-4,4-bis-and N.F,USP MANNITOL; The mixture that described auxiliary agent is made up of with weight ratio 1:4 emulsifying agent and defoamer.
The mixture that described emulsifying agent is made up of with weight ratio 1:1.6:2.4 potassium oleate, potassium stearate and potassium rosinate; The mixture that described defoamer is made up of with weight ratio 1.6:1 tributyl phosphate and polydimethylsiloxane.
Described slipping agent is the mixture be made up of with weight ratio 1:0.8:1.5 erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide.
The mixture that described pigment powder is made up of with weight ratio 1:1.4 ultramarine toner and phthalocyanine blue.
A preparation method for antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material, comprises the steps:
A, raw material prepare: take each raw material by above-mentioned raw materials composition, mixing;
B, high-speed stirring: mixed raw material is put into high speed blender, stir 8min at 110 DEG C of temperature, and the rotating speed of stirring is 580RPM;
C, once plasticizing: the raw material after stirring is carried out first time plasticizing through planetary extruder at 140 DEG C of temperature, obtains micelle;
D, secondary plasticizing: the micelle after first time plasticizing is carried out second time plasticizing, until evenly through pricking turbine at 130 DEG C of temperature;
E, level filter: the micelle after second time plasticizing is adopted 20 order nets, 60 order nets and 150 net filtrations successively through filter, and the screw speed of filter is 50RPM;
F, calendering formation: by the micelle after filtration through rolling press calendering formation, obtain sheet material;
G, cooling rolling: the sheet material after shaping is carried out cooling and shaping through drawing cooling wheel, then carries out rolling through winder;
H, gold stamping stamp: by the sheet material printed patterns after rolling, put to discharging frame by the sheet material after printed patterns and bronzing material, carry out gold stamping, demoulding and embossing through gold stamping stamp graining machine, obtain antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material.
In described step F, rolling press is six roll calendars, and the temperature of each roller is followed successively by: 170 DEG C, 170 DEG C, 190 DEG C, 190 DEG C, 178 DEG C and 178 DEG C; In described step H, gold stamping preheating temperature is 75 DEG C, and gold stamping embossing temperature is 140 DEG C.
Embodiment 2
A kind of antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material, comprises the raw material of following weight part:
Polyvinyl chloride resin 90 parts
37 parts, softening agent
Lubricant 7 parts
Thermo-stabilizer 2 parts
Slipping agent 0.04 part
0.04 part, pigment powder
Calcium powder 0.2 part;
Wherein, the mixture that described calcium powder is made up of with weight ratio 1:1.7 nano-calcium carbonate and water-ground limestone, the particle diameter of nano-calcium carbonate is 130nm; The particle diameter of water-ground limestone is 3 μm.
Described polyvinyl chloride resin is the polymerization degree 1050, particle diameter in 0.12mm, density at 1.37g/cm
3polyvinyl chloride resin.
The mixture that described softening agent is made up of with weight ratio 16:1 dioctyl phthalate (DOP) and epoxy soybean oil.
The mixture that described lubricant is made up of with weight ratio 1.3:1 microcrystalline wax and stearic acid monoglycerides.
The mixture that described thermo-stabilizer is made up of with weight ratio 25:5:1 Soil stability agent, auxiliary stabilizer and auxiliary agent; The mixture that described main body thermo-stabilizer is made up of with weight ratio 1:1.7:6.5 hydrotalcite, barium stearate and Zinic stearas; Described auxiliary heat stabilizer is the mixture be made up of with weight ratio 1:2 the different fork-fatty alcohol-phosphorous acid chelate compounds polymkeric substance of carbon back-4,4-bis-and N.F,USP MANNITOL; The mixture that described auxiliary agent is made up of with weight ratio 1:5 emulsifying agent and defoamer.
The mixture that described emulsifying agent is made up of with weight ratio 1:1.8:2.6 potassium oleate, potassium stearate and potassium rosinate; The mixture that described defoamer is made up of with weight ratio 1.8:1 tributyl phosphate and polydimethylsiloxane.
Described slipping agent is the mixture be made up of with weight ratio 1:0.9:1.7 erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide.
The mixture that described pigment powder is made up of with weight ratio 1:1.6 ultramarine toner and phthalocyanine blue.
A preparation method for antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material, comprises the steps:
A, raw material prepare: take each raw material by above-mentioned raw materials composition, mixing;
B, high-speed stirring: mixed raw material is put into high speed blender, stir 9min at 112 DEG C of temperature, and the rotating speed of stirring is 750RPM;
C, once plasticizing: the raw material after stirring is carried out first time plasticizing through planetary extruder at 145 DEG C of temperature, obtains micelle;
D, secondary plasticizing: the micelle after first time plasticizing is carried out second time plasticizing, until evenly through pricking turbine at 135 DEG C of temperature;
E, level filter: the micelle after second time plasticizing is adopted 20 order nets, 60 order nets and 150 net filtrations successively through filter, and the screw speed of filter is 55RPM;
F, calendering formation: by the micelle after filtration through rolling press calendering formation, obtain sheet material;
G, cooling rolling: the sheet material after shaping is carried out cooling and shaping through drawing cooling wheel, then carries out rolling through winder;
H, gold stamping stamp: by the sheet material printed patterns after rolling, put to discharging frame by the sheet material after printed patterns and bronzing material, carry out gold stamping, demoulding and embossing through gold stamping stamp graining machine, obtain antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material.
In described step F, rolling press is six roll calendars, and the temperature of each roller is followed successively by: 172 DEG C, 172 DEG C, 192 DEG C, 192 DEG C, 180 DEG C and 180 DEG C; In described step H, gold stamping preheating temperature is 77 DEG C, and gold stamping embossing temperature is 145 DEG C.
Embodiment 3
A kind of antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material, comprises the raw material of following weight part:
Polyvinyl chloride resin 100 parts
42 parts, softening agent
Lubricant 8 parts
Thermo-stabilizer 3 parts
Slipping agent 0.05 part
0.05 part, pigment powder
Calcium powder 0.3 part;
Wherein, the mixture that described calcium powder is made up of with weight ratio 1:2 nano-calcium carbonate and water-ground limestone, the particle diameter of nano-calcium carbonate is 135nm; The particle diameter of water-ground limestone is 5 μm.
Described polyvinyl chloride resin is the polymerization degree 1100, particle diameter in 0.15mm, density at 1.4g/cm
3polyvinyl chloride resin.
The mixture that described softening agent is made up of with weight ratio 17:1 dioctyl phthalate (DOP) and epoxy soybean oil.
The mixture that described lubricant is made up of with weight ratio 1.5:1 microcrystalline wax and stearic acid monoglycerides.
The mixture that described thermo-stabilizer is made up of with weight ratio 30:6:1 Soil stability agent, auxiliary stabilizer and auxiliary agent; The mixture that described main body thermo-stabilizer is made up of with weight ratio 1:2:7 hydrotalcite, barium stearate and Zinic stearas; Described auxiliary heat stabilizer is the mixture be made up of with weight ratio 1:2.2 the different fork-fatty alcohol-phosphorous acid chelate compounds polymkeric substance of carbon back-4,4-bis-and N.F,USP MANNITOL; The mixture that described auxiliary agent is made up of with weight ratio 1:6 emulsifying agent and defoamer.
The mixture that described emulsifying agent is made up of with weight ratio 1:2:2.8 potassium oleate, potassium stearate and potassium rosinate; The mixture that described defoamer is made up of with weight ratio 2:1 tributyl phosphate and polydimethylsiloxane.
Described slipping agent is the mixture be made up of with weight ratio 1:1:2 erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide.
The mixture that described pigment powder is made up of with weight ratio 1:1.8 ultramarine toner and phthalocyanine blue.
A preparation method for antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material, comprises the steps:
A, raw material prepare: take each raw material by above-mentioned raw materials composition, mixing;
B, high-speed stirring: mixed raw material is put into high speed blender, stir 10min at 115 DEG C of temperature, and the rotating speed of stirring is 850RPM;
C, once plasticizing: the raw material after stirring is carried out first time plasticizing through planetary extruder at 150 DEG C of temperature, obtains micelle;
D, secondary plasticizing: the micelle after first time plasticizing is carried out second time plasticizing, until evenly through pricking turbine at 140 DEG C of temperature;
E, level filter: the micelle after second time plasticizing is adopted 20 order nets, 60 order nets and 150 net filtrations successively through filter, and the screw speed of filter is 60RPM;
F, calendering formation: by the micelle after filtration through rolling press calendering formation, obtain sheet material;
G, cooling rolling: the sheet material after shaping is carried out cooling and shaping through drawing cooling wheel, then carries out rolling through winder;
H, gold stamping stamp: by the sheet material printed patterns after rolling, put to discharging frame by the sheet material after printed patterns and bronzing material, carry out gold stamping, demoulding and embossing through gold stamping stamp graining machine, obtain antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material.
In described step F, rolling press is six roll calendars, and the temperature of each roller is followed successively by: 175 DEG C, 175 DEG C, 195 DEG C, 195 DEG C, 183 DEG C and 183 DEG C; In described step H, gold stamping preheating temperature is 80 DEG C, and gold stamping embossing temperature is 150 DEG C.
Embodiment 4
A kind of antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material, comprises the raw material of following weight part:
Polyvinyl chloride resin 110 parts
47 parts, softening agent
Lubricant 9 parts
Thermo-stabilizer 4 parts
Slipping agent 0.06 part
0.06 part, pigment powder
Calcium powder 0.4 part;
Wherein, the mixture that described calcium powder is made up of with weight ratio 1:2.3 nano-calcium carbonate and water-ground limestone, the particle diameter of nano-calcium carbonate is 142nm; The particle diameter of water-ground limestone is 7 μm.
Described polyvinyl chloride resin is the polymerization degree 1150, particle diameter in 0.18mm, density at 1.43g/cm
3polyvinyl chloride resin.
The mixture that described softening agent is made up of with weight ratio 18:1 dioctyl phthalate (DOP) and epoxy soybean oil.
The mixture that described lubricant is made up of with weight ratio 1.7:1 microcrystalline wax and stearic acid monoglycerides.
The mixture that described thermo-stabilizer is made up of with weight ratio 35:7:1 Soil stability agent, auxiliary stabilizer and auxiliary agent; The mixture that described main body thermo-stabilizer is made up of with weight ratio 1:2.3:7.5 hydrotalcite, barium stearate and Zinic stearas; Described auxiliary heat stabilizer is the mixture be made up of with weight ratio 1:2.4 the different fork-fatty alcohol-phosphorous acid chelate compounds polymkeric substance of carbon back-4,4-bis-and N.F,USP MANNITOL; The mixture that described auxiliary agent is made up of with weight ratio 1:7 emulsifying agent and defoamer.
The mixture that described emulsifying agent is made up of with weight ratio 1:2.2:3 potassium oleate, potassium stearate and potassium rosinate; The mixture that described defoamer is made up of with weight ratio 2.2:1 tributyl phosphate and polydimethylsiloxane.
Described slipping agent is the mixture be made up of with weight ratio 1:1.1:2.3 erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide.
The mixture that described pigment powder is made up of with weight ratio 1:2 ultramarine toner and phthalocyanine blue.
A preparation method for antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material, comprises the steps:
A, raw material prepare: take each raw material by above-mentioned raw materials composition, mixing;
B, high-speed stirring: mixed raw material is put into high speed blender, stir 11min at 118 DEG C of temperature, and the rotating speed of stirring is 1000RPM;
C, once plasticizing: the raw material after stirring is carried out first time plasticizing through planetary extruder at 155 DEG C of temperature, obtains micelle;
D, secondary plasticizing: the micelle after first time plasticizing is carried out second time plasticizing, until evenly through pricking turbine at 145 DEG C of temperature;
E, level filter: the micelle after second time plasticizing is adopted 20 order nets, 60 order nets and 150 net filtrations successively through filter, and the screw speed of filter is 65RPM;
F, calendering formation: by the micelle after filtration through rolling press calendering formation, obtain sheet material;
G, cooling rolling: the sheet material after shaping is carried out cooling and shaping through drawing cooling wheel, then carries out rolling through winder;
H, gold stamping stamp: by the sheet material printed patterns after rolling, put to discharging frame by the sheet material after printed patterns and bronzing material, carry out gold stamping, demoulding and embossing through gold stamping stamp graining machine, obtain antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material.
In described step F, rolling press is six roll calendars, and the temperature of each roller is followed successively by: 178 DEG C, 178 DEG C, 198 DEG C, 198 DEG C, 186 DEG C and 186 DEG C; In described step H, gold stamping preheating temperature is 83 DEG C, and gold stamping embossing temperature is 155 DEG C.
Embodiment 5
A kind of antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material, comprises the raw material of following weight part:
Polyvinyl chloride resin 120 parts
52 parts, softening agent
Lubricant 10 parts
Thermo-stabilizer 4 parts
Slipping agent 0.07 part
0.07 part, pigment powder
Calcium powder 0.5 part;
Wherein, the mixture that described calcium powder is made up of with weight ratio 1:2.5 nano-calcium carbonate and water-ground limestone, the particle diameter of nano-calcium carbonate is 150nm; The particle diameter of water-ground limestone is 10 μm.
Described polyvinyl chloride resin is the polymerization degree 1200, particle diameter in 0.2mm, density at 1.45g/cm
3polyvinyl chloride resin.
The mixture that described softening agent is made up of with weight ratio 19:1 dioctyl phthalate (DOP) and epoxy soybean oil.
The mixture that described lubricant is made up of with weight ratio 1.8:1 microcrystalline wax and stearic acid monoglycerides.
The mixture that described thermo-stabilizer is made up of with weight ratio 40:8:1 Soil stability agent, auxiliary stabilizer and auxiliary agent; The mixture that described main body thermo-stabilizer is made up of with weight ratio 1:2.5:8 hydrotalcite, barium stearate and Zinic stearas; Described auxiliary heat stabilizer is the mixture be made up of with weight ratio 1:2.6 the different fork-fatty alcohol-phosphorous acid chelate compounds polymkeric substance of carbon back-4,4-bis-and N.F,USP MANNITOL; The mixture that described auxiliary agent is made up of with weight ratio 1:8 emulsifying agent and defoamer.
The mixture that described emulsifying agent is made up of with weight ratio 1:2.4:3.2 potassium oleate, potassium stearate and potassium rosinate; The mixture that described defoamer is made up of with weight ratio 2.4:1 tributyl phosphate and polydimethylsiloxane.
Described slipping agent is the mixture be made up of with weight ratio 1:1.2:2.5 erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide.
The mixture that described pigment powder is made up of with weight ratio 1:2.2 ultramarine toner and phthalocyanine blue.
A preparation method for antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material, comprises the steps:
A, raw material prepare: take each raw material by above-mentioned raw materials composition, mixing;
B, high-speed stirring: mixed raw material is put into high speed blender, stir 12min at 120 DEG C of temperature, and the rotating speed of stirring is 1160RPM;
C, once plasticizing: the raw material after stirring is carried out first time plasticizing through planetary extruder at 160 DEG C of temperature, obtains micelle;
D, secondary plasticizing: the micelle after first time plasticizing is carried out second time plasticizing, until evenly through pricking turbine at 150 DEG C of temperature;
E, level filter: the micelle after second time plasticizing is adopted 20 order nets, 60 order nets and 150 net filtrations successively through filter, and the screw speed of filter is 70RPM;
F, calendering formation: by the micelle after filtration through rolling press calendering formation, obtain sheet material;
G, cooling rolling: the sheet material after shaping is carried out cooling and shaping through drawing cooling wheel, then carries out rolling through winder;
H, gold stamping stamp: by the sheet material printed patterns after rolling, put to discharging frame by the sheet material after printed patterns and bronzing material, carry out gold stamping, demoulding and embossing through gold stamping stamp graining machine, obtain antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material.
In described step F, rolling press is six roll calendars, and the temperature of each roller is followed successively by: 180 DEG C, 180 DEG C, 200 DEG C, 200 DEG C, 188 DEG C and 188 DEG C; In described step H, gold stamping preheating temperature is 85 DEG C, and gold stamping embossing temperature is 160 DEG C.
Above-described embodiment is the present invention's preferably implementation, and in addition, the present invention can also realize by alternate manner, and any apparent replacement is all within protection scope of the present invention without departing from the inventive concept of the premise.
Claims (10)
1. an antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material, is characterized in that: the raw material comprising following weight part:
Polyvinyl chloride resin 80-120 part
Softening agent 32-52 part
Lubricant 6-10 part
Thermo-stabilizer 1-4 part
Slipping agent 0.03-0.07 part
Pigment powder 0.03-0.07 part
Calcium powder 0.1-0.5 part;
Wherein, the mixture that is made up of with weight ratio 1:1.5-2.5 nano-calcium carbonate and water-ground limestone of described calcium powder; The particle diameter of nano-calcium carbonate is 120-150nm, and the particle diameter of water-ground limestone is 1-10 μm.
2. the antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material of one according to claim 1, is characterized in that: described polyvinyl chloride resin be the polymerization degree at 1000-1200, particle diameter in 0.1-0.2mm, density at 1.35-1.45g/cm
3polyvinyl chloride resin.
3. the antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material of one according to claim 1, is characterized in that: the mixture that described softening agent is made up of with weight ratio 15-19:1 dioctyl phthalate (DOP) and epoxy soybean oil.
4. the antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material of one according to claim 1, is characterized in that: the mixture that described lubricant is made up of with weight ratio 1.2-1.8:1 microcrystalline wax and stearic acid monoglycerides.
5. the antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material of one according to claim 1, is characterized in that: the mixture that described thermo-stabilizer is made up of with weight ratio 20-40:4-8:1 Soil stability agent, auxiliary stabilizer and auxiliary agent; The mixture that described main body thermo-stabilizer is made up of with weight ratio 1:1.5-2.5:6-8 hydrotalcite, barium stearate and Zinic stearas; Described auxiliary heat stabilizer is the mixture be made up of with weight ratio 1:1.8-2.6 the different fork-fatty alcohol-phosphorous acid chelate compounds polymkeric substance of carbon back-4,4-bis-and N.F,USP MANNITOL; The mixture that described auxiliary agent is made up of with weight ratio 1:4-8 emulsifying agent and defoamer.
6. the antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material of one according to claim 5, is characterized in that: the mixture that described emulsifying agent is made up of with weight ratio 1:1.6-2.4:2.4-3.2 potassium oleate, potassium stearate and potassium rosinate; The mixture that described defoamer is made up of with weight ratio 1.6-2.4:1 tributyl phosphate and polydimethylsiloxane.
7. the antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material of one according to claim 1, it is characterized in that: described slipping agent is the mixture be made up of with weight ratio 1:0.8-1.2:1.5-2.5 erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide.
8. the antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material of one according to claim 1, is characterized in that: the mixture that described pigment powder is made up of with weight ratio 1:1.4-2.2 ultramarine toner and phthalocyanine blue.
9. the preparation method of a kind of antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material as described in any one of claim 1-8, is characterized in that: comprise the steps:
A, raw material prepare: take each raw material by above-mentioned raw materials composition, mixing;
B, high-speed stirring: mixed raw material is put into high speed blender, stir 8-12min at 110-120 DEG C of temperature, and the rotating speed of stirring is 580-1160RPM;
C, once plasticizing: the raw material after stirring is carried out first time plasticizing through planetary extruder at 140-160 DEG C of temperature, obtains micelle;
D, secondary plasticizing: the micelle after first time plasticizing is carried out second time plasticizing, until evenly through pricking turbine at 130-150 DEG C of temperature;
E, level filter: the micelle after second time plasticizing is adopted 20 order nets, 60 order nets and 150 net filtrations successively through filter, and the screw speed of filter is 50-70RPM;
F, calendering formation: by the micelle after filtration through rolling press calendering formation, obtain sheet material;
G, cooling rolling: the sheet material after shaping is carried out cooling and shaping through drawing cooling wheel, then carries out rolling through winder;
H, gold stamping stamp: by the sheet material printed patterns after rolling, put to discharging frame by the sheet material after printed patterns and bronzing material, carry out gold stamping, demoulding and embossing through gold stamping stamp graining machine, obtain antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material.
10. the preparation method of a kind of antistatic two-sided gold stamping stamp embossing polychlorovinyl sheet material according to claim 9, it is characterized in that: in described step F, rolling press is six roll calendars, and the temperature of each roller is followed successively by: 170-180 DEG C, 170-180 DEG C, 190-200 DEG C, 190-200 DEG C, 178-188 DEG C and 178-188 DEG C; In described step H, gold stamping preheating temperature is 75-85 DEG C, and gold stamping embossing temperature is 140-160 DEG C.
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| CN201410839231.1A CN104558963A (en) | 2014-12-30 | 2014-12-30 | Anti-static two-sided gold-stamped, printed and embossed PVC (polyvinyl chloride) sheet and preparation method thereof |
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|---|---|---|---|
| CN201410839231.1A CN104558963A (en) | 2014-12-30 | 2014-12-30 | Anti-static two-sided gold-stamped, printed and embossed PVC (polyvinyl chloride) sheet and preparation method thereof |
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Application publication date: 20150429 |