CN112622469A - Ink-jet printing heat transfer film capable of preventing sublimation dye ink from migrating - Google Patents
Ink-jet printing heat transfer film capable of preventing sublimation dye ink from migrating Download PDFInfo
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- CN112622469A CN112622469A CN202011595942.0A CN202011595942A CN112622469A CN 112622469 A CN112622469 A CN 112622469A CN 202011595942 A CN202011595942 A CN 202011595942A CN 112622469 A CN112622469 A CN 112622469A
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- ink
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- sublimation dye
- heat transfer
- dye ink
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/38—Intermediate layers; Layers between substrate and imaging layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/40—Cover layers; Layers separated from substrate by imaging layer; Protective layers; Layers applied before imaging
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses an ink-jet printing heat transfer film capable of preventing sublimation dye ink migration, which is prepared by taking glassine paper or double-sided PEK paper as a paper base, carrying out organic silicon release treatment or acrylic resin treatment on the surface of the paper base, sequentially coating a first heat transfer adhesive layer, a functional layer for blocking and absorbing sublimation dye ink and a Latex ink or weak solvent ink absorbing medium layer on the paper base, and cutting the paper base according to the required size after all the layers are completely dried. The inkjet printing heat transfer film capable of preventing sublimation dye ink migration can transfer images printed by a Latex inkjet ink printer, a weak solvent inkjet printer and a UV type inkjet printer to be drawn to any textile by a hot pressing tool.
Description
Technical Field
The invention belongs to the field of digital heat transfer printing materials, and relates to an ink-jet printing heat transfer printing film capable of performing digital heat transfer printing on unstable dyed fabrics such as floating-color and fancy fabrics and chemical fiber fabrics, in particular to an ink-jet printing heat transfer printing film capable of preventing sublimation dye ink from migrating.
Background
The traditional process of silk-screen printing T-shirt and box packaging printing comprises the following steps: making a picture-a phenanthroline sheet-a screen printing plate-a sample making plate-a sample calibration-silk printing-production-heat transfer printing-completion; therefore, the traditional printing process for printing T-shirts and boxes can meet the requirements of simple and batch production, but the problems of long process flow, large personnel demand, not delicate manufactured products and the like exist, and the market requirements of small batch, multiple varieties, individuation, rapid production, time and labor conservation, energy conservation, environmental protection and the like cannot be met.
Disclosure of Invention
In order to solve the problem of digital heat transfer printing on unstable dyeing fabrics such as floating-color and fancy fabrics, chemical fiber fabrics and the like, the invention provides an ink-jet printing heat transfer film capable of preventing sublimation dye ink from migrating.
In order to achieve the purpose, the invention adopts the following technical scheme:
an ink-jet printing heat transfer film capable of preventing sublimation dye ink from migrating comprises a paper base, a first heat transfer adhesive layer, a functional layer for blocking and absorbing sublimation dye ink, and a Latex ink or weak solvent ink absorbing medium layer from bottom to top.
The paper base adopts glassine paper or double-sided PEK paper.
The first heat transfer adhesive layer is prepared by mixing the following components in proportion:
30 to 40 percent of butadiene or styrene copolymer,
40 to 55 percent of polycaprolactone type polyurethane,
2 to 5 percent of rosin pentaerythritol ester,
5 to 10 percent of copolymerized polyester resin,
3 to 10 percent of terpene tackifying resin,
the sum of the weight percentages of the components is 100 percent.
The functional layer for blocking and absorbing the sublimation dye ink is prepared by mixing the following components in proportion:
30 to 40 percent of polyether polyurethane,
22 to 35 percent of active carbon,
20 to 30 percent of gas phase method silicon dioxide,
5 to 10 percent of micro-pulverized wax,
1 to 5 percent of auxiliary agent,
the sum of the weight percentages of the components is 100 percent.
The Latex ink or weak solvent ink absorbing medium layer is prepared by mixing the following components in proportion:
20-25% of polyester polyurethane resin,
45 to 50 percent of titanium dioxide,
2 to 5 percent of rosin pentaerythritol ester,
15 to 22 percent of aromatic polyurethane resin,
5 to 10 percent of micro-pulverized wax,
0.5 to 1 percent of auxiliary agent,
the sum of the weight percentages of the components is 100 percent.
The process steps of the ink-jet printing heat transfer film capable of preventing the sublimation dye ink from migrating are as follows:
1) carrying out surface treatment on the paper base: carrying out organic silicon release treatment or acrylic resin treatment on the surface of the paper base, and controlling the peel strength to be 250-550 g/inch;
2) coating of a first thermal transfer glue layer: uniformly coating the first heat transfer printing glue layer on the surface of the treated paper base to enable the thickness of a dry film to be 25-45 micrometers;
3) coating of a functional layer for blocking absorption of sublimation dye ink: uniformly coating a functional layer for blocking and absorbing the sublimation dye ink on the first heat transfer adhesive layer to enable the thickness of a dry film to be 45-65 micrometers;
4) coating of absorbing medium layer of Latex ink or weak solvent ink: coating an absorption medium layer of Latex ink or weak solvent ink on a functional layer for blocking absorption of sublimation dye ink to enable the thickness of a dry film to be 25-35 micrometers;
5) cutting paper: and after the layers are completely dried, cutting according to the required size.
The invention has the following remarkable advantages:
the ink-jet printing heat transfer film capable of preventing sublimation dye ink migration provided by the invention can meet the market requirements of small-batch heat transfer printing, rapid production, product diversification, time and labor saving, energy saving, environmental protection and individuation, is suitable for any commercially available weak solvent ink-jet printer and Latex printer, and has no requirement on the ink of the weak solvent ink-jet printer and the Latex printer.
Detailed Description
In order to make the present invention more comprehensible, the technical solutions of the present invention are further described below with reference to specific embodiments, but the present invention is not limited thereto.
Example 1
An ink-jet printing heat transfer film capable of preventing sublimation dye ink from migrating comprises a paper base, a first heat transfer adhesive layer, a functional layer for blocking and absorbing sublimation dye ink, and a Latex ink or weak solvent ink absorbing medium layer from bottom to top, and is prepared by the following steps:
1) selecting a paper base: selecting glassine paper as a paper base of the ink-jet printing heat transfer film;
2) carrying out surface treatment on the paper base: carrying out organic silicon release treatment on the surface of the paper base, and controlling the peel strength to be 250-550 g/inch;
3) coating of a first thermal transfer glue layer: mixing 30% of butadiene, 55% of polycaprolactone type polyurethane, 2% of rosin pentaerythritol ester, 10% of copolyester resin and 3% of terpene tackifying resin to prepare a first thermal transfer adhesive layer, and then uniformly coating the first thermal transfer adhesive layer on the surface of the treated paper base, wherein the thickness of a dry film is 25 microns;
4) coating of a functional layer for blocking absorption of sublimation dye ink: uniformly mixing 30% of polyether polyurethane, 35% of activated carbon, 20% of fumed silica, 10% of micronized wax and 5% of an auxiliary agent to prepare a functional layer for blocking and absorbing sublimation dye ink, and then uniformly coating the functional layer on a first thermal transfer printing adhesive layer, wherein the thickness of a dry film is 45 microns;
5) coating of absorbing medium layer of Latex ink or weak solvent ink: mixing 20% of polyester polyurethane resin, 50% of titanium dioxide, 5% of rosin pentaerythritol ester, 15% of aromatic polyurethane resin, 9.5% of micronized wax and 0.5% of auxiliary agent to prepare an absorbing medium layer of Latex ink or weak solvent ink, and uniformly coating the absorbing medium layer on a functional layer for blocking absorption of sublimation dye ink, wherein the dry film thickness is 25 micrometers;
6) cutting paper: and after the layers are completely dried, cutting according to the required size.
Example 2
An ink-jet printing heat transfer film capable of preventing sublimation dye ink from migrating comprises a paper base, a first heat transfer adhesive layer, a functional layer for blocking and absorbing sublimation dye ink, and a Latex ink or weak solvent ink absorbing medium layer from bottom to top, and is prepared by the following steps:
1) selecting a paper base: selecting glassine paper as a paper base of the ink-jet printing heat transfer film;
2) carrying out surface treatment on the paper base: carrying out acrylic resin treatment on the surface of the paper base, and controlling the peel strength to be 250-550 g/inch;
3) coating of a first thermal transfer glue layer: mixing 35% of styrene copolymer, 48% of polycaprolactone type polyurethane, 3% of rosin pentaerythritol ester, 8% of copolyester resin and 6% of terpene tackifying resin to prepare a first thermal transfer adhesive layer, and then uniformly coating the first thermal transfer adhesive layer on the surface of the treated paper base, wherein the thickness of a dry film is 32 microns;
4) coating of a functional layer for blocking absorption of sublimation dye ink: uniformly mixing 25% of polyether polyurethane, 30% of activated carbon, 25% of fumed silica, 8% of micronized wax and 2% of an auxiliary agent to prepare a functional layer for blocking and absorbing sublimation dye ink, and then uniformly coating the functional layer on a first thermal transfer printing adhesive layer, wherein the thickness of a dry film is 48 microns;
5) coating of absorbing medium layer of Latex ink or weak solvent ink: 22% of polyester polyurethane resin, 48% of titanium dioxide, 3% of rosin pentaerythritol ester, 20% of aromatic polyurethane resin, 6% of micronized wax and 1% of auxiliary agent are mixed to prepare an absorption medium layer of Latex ink or weak solvent ink, and then the absorption medium layer is uniformly coated on a functional layer for blocking absorption of sublimation dye ink, wherein the thickness of a dry film is 31 microns;
6) cutting paper: and after the layers are completely dried, cutting according to the required size.
Example 3
An ink-jet printing heat transfer film capable of preventing sublimation dye ink from migrating comprises a paper base, a first heat transfer adhesive layer, a functional layer for blocking and absorbing sublimation dye ink, and a Latex ink or weak solvent ink absorbing medium layer from bottom to top, and is prepared by the following steps:
1) selecting a paper base: selecting double-sided PEK paper as a paper base of the ink-jet printing heat transfer film;
2) carrying out surface treatment on the paper base: carrying out organic silicon release treatment on the surface of the paper base, and controlling the peel strength to be 250-550 g/inch;
3) coating of a first thermal transfer glue layer: mixing 40% of styrene copolymer, 40% of polycaprolactone type polyurethane, 5% of rosin pentaerythritol ester, 5% of copolyester resin and 10% of terpene tackifying resin to prepare a first thermal transfer adhesive layer, and then uniformly coating the first thermal transfer adhesive layer on the surface of the treated paper base, wherein the thickness of a dry film is 45 microns;
4) coating of a functional layer for blocking absorption of sublimation dye ink: uniformly mixing 40% of polyether polyurethane, 22% of activated carbon, 30% of fumed silica, 5% of micronized wax and 3% of an auxiliary agent to prepare a functional layer for blocking and absorbing sublimation dye ink, and then uniformly coating the functional layer on a first thermal transfer printing adhesive layer, wherein the thickness of a dry film is 65 micrometers;
5) coating of absorbing medium layer of Latex ink or weak solvent ink: mixing 25% of polyester polyurethane resin, 45% of titanium dioxide, 2% of rosin pentaerythritol ester, 22% of aromatic polyurethane resin, 5.5% of micronized wax and 0.5% of an auxiliary agent to prepare an absorbing medium layer of Latex ink or weak solvent ink, and uniformly coating the absorbing medium layer on a functional layer for blocking absorption of sublimation dye ink, wherein the dry film thickness is 35 microns;
6) cutting paper: and after the layers are completely dried, cutting according to the required size.
The above description is only a preferred embodiment of the present invention, and all equivalent changes and modifications made in accordance with the claims of the present invention should be covered by the present invention.
Claims (6)
1. The utility model provides a can prevent inkjet printing heat-transfer die of sublimation dyestuff ink migration which characterized in that: the ink-jet printing heat transfer film comprises a paper base, a first heat transfer glue layer, a functional layer for blocking and absorbing sublimation dye ink, and a Latex ink or weak solvent ink absorption medium layer from bottom to top.
2. The inkjet printing thermal transfer film capable of preventing migration of sublimation dye ink according to claim 1, characterized in that: the paper base adopts glassine paper or double-sided PEK paper.
3. The inkjet printing thermal transfer film capable of preventing migration of sublimation dye ink according to claim 1, characterized in that: the first heat transfer adhesive layer is prepared by mixing the following components in proportion:
30 to 40 percent of butadiene or styrene copolymer,
40 to 55 percent of polycaprolactone type polyurethane,
2 to 5 percent of rosin pentaerythritol ester,
5 to 10 percent of copolymerized polyester resin,
3 to 10 percent of terpene tackifying resin,
the sum of the weight percentages of the components is 100 percent.
4. The inkjet printing thermal transfer film capable of preventing migration of sublimation dye ink according to claim 1, characterized in that: the functional layer for blocking and absorbing the sublimation dye ink is prepared by mixing the following components in proportion:
30 to 40 percent of polyether polyurethane,
22 to 35 percent of active carbon,
20 to 30 percent of gas phase method silicon dioxide,
5 to 10 percent of micro-pulverized wax,
1 to 5 percent of auxiliary agent,
the sum of the weight percentages of the components is 100 percent.
5. The inkjet printing thermal transfer film capable of preventing migration of sublimation dye ink according to claim 1, characterized in that: the Latex ink or weak solvent ink absorbing medium layer is prepared by mixing the following components in proportion:
20-25% of polyester polyurethane resin,
45 to 50 percent of titanium dioxide,
2 to 5 percent of rosin pentaerythritol ester,
15 to 22 percent of aromatic polyurethane resin,
5 to 10 percent of micro-pulverized wax,
0.5 to 1 percent of auxiliary agent,
the sum of the weight percentages of the components is 100 percent.
6. The inkjet printing thermal transfer film capable of preventing migration of sublimation dye ink according to claim 1, characterized in that: the process comprises the following steps:
1) carrying out surface treatment on the paper base: carrying out organic silicon release treatment or acrylic resin treatment on the surface of the paper base, and controlling the peel strength to be 250-550 g/inch;
2) coating of a first thermal transfer glue layer: uniformly coating the first heat transfer printing glue layer on the surface of the treated paper base to enable the thickness of a dry film to be 25-45 micrometers;
3) coating of a functional layer for blocking absorption of sublimation dye ink: uniformly coating a functional layer for blocking and absorbing the sublimation dye ink on the first heat transfer adhesive layer to enable the thickness of a dry film to be 45-65 micrometers;
4) coating of absorbing medium layer of Latex ink or weak solvent ink: coating an absorption medium layer of Latex ink or weak solvent ink on a functional layer for blocking absorption of sublimation dye ink to enable the thickness of a dry film to be 25-35 micrometers;
5) cutting paper: and after the layers are completely dried, cutting according to the required size.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113263850A (en) * | 2021-05-13 | 2021-08-17 | 刘晨 | Latex ink digital printing film material for improving washing fading phenomenon and preparation method thereof |
CN114643796A (en) * | 2022-03-24 | 2022-06-21 | 苏州胜利精密制造科技股份有限公司 | Printing method of automobile cover plate |
CN115124941A (en) * | 2022-08-30 | 2022-09-30 | 广东昂斯新材料技术有限公司 | Anti-sublimation wear-resistant high-strength PU composite membrane and production process thereof |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113263850A (en) * | 2021-05-13 | 2021-08-17 | 刘晨 | Latex ink digital printing film material for improving washing fading phenomenon and preparation method thereof |
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CN115124941A (en) * | 2022-08-30 | 2022-09-30 | 广东昂斯新材料技术有限公司 | Anti-sublimation wear-resistant high-strength PU composite membrane and production process thereof |
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