CN102839541A - High-efficiency water-proof anti-oil high temperature-resisting dedusting treating agent for synthetic leather - Google Patents

High-efficiency water-proof anti-oil high temperature-resisting dedusting treating agent for synthetic leather Download PDF

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Publication number
CN102839541A
CN102839541A CN2011101662161A CN201110166216A CN102839541A CN 102839541 A CN102839541 A CN 102839541A CN 2011101662161 A CN2011101662161 A CN 2011101662161A CN 201110166216 A CN201110166216 A CN 201110166216A CN 102839541 A CN102839541 A CN 102839541A
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China
Prior art keywords
parts
high temperature
synthetic leather
oil
grease
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Pending
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CN2011101662161A
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Chinese (zh)
Inventor
丁海燕
聂成孙
肖欢
帅宏喜
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HANGZHOU ZFC NEW MATERIALS TECHNOLOGY Co Ltd
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HANGZHOU ZFC NEW MATERIALS TECHNOLOGY Co Ltd
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Priority to CN2011101662161A priority Critical patent/CN102839541A/en
Publication of CN102839541A publication Critical patent/CN102839541A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a high-efficiency water-proof anti-oil high temperature-resisting dedusting treating agent for synthetic leather, relating to a high temperature-resisting dedusting treating agent, comprising 18-25 parts of temperature-resistant resin, 7-12 parts of polyurethane bright resin, 23-32 parts of dimethyl formamide, 8-13 parts of ethyl acetate, 15-23 parts of butyl acetate, 2-4 parts of micronized organic polymer wax, 4-7 parts of micronized silicon dioxide, 2-7 parts of oily water-proof anti-oil aid, 1-3 parts of modified organosilicon aid, and 1-3 parts of grease. The dedusting treating agent disclosed herein has high temperature resistance, excellent water-proof anti-oil effect, charred feeling, extremely good handle, oil feel and waxy feel, and strong leather feeling.

Description

The high temperature resistant type brush finishing agent that a kind of use for synthetic leather high-effective water-proof is grease proofing
Technical field:
The present invention relates to a kind of high temperature resistant type brush finishing agent, be specifically related to the grease proofing high temperature resistant type brush finishing agent of a kind of use for synthetic leather high-effective water-proof.
Background technology:
The PU synthetic leather, the various good characteristics that it has become the best product that replaces natural leather.The popular world of synthetic leather product mainly contains three big characteristics: the one, and the young man likes removing from office product, and this consumer group pursues challenge, and individual character is unique, and fashion is praised highly in excessive consumption again, and the synthetic leather product is just catering to demand; The 2nd, color, style changes fast.Research and development new product speed is fast, in a year or so even just changed new varieties in one or two months, has satisfied the consciousness of innovation in people's life; The 3rd, the advantage of price and quality, the synthetic leather product is compared with natural leather, has absolute predominance on the price, and synthetic leather was through development in 20 years, and the physical property of many products and function of use surpass natural leather, the title that ultra corium is arranged among the people.
Along with the application of new material and new aftertreatment technology, the class of synthetic leather product and designs and varieties have obtained unprecedented development in recent years.Various special surfacings increase delustring to later be full of cracks from beginning, variable color, and crazy horse is wiped look, the sheep crust, the exploitation of materials such as spraying gloss oil and using more makes the synthetic leather product diversification, diversification.Case and bag have been widely used in, footwear material, clothes, furniture, every field such as vehicle.
The use for synthetic leather surface conditioning agent is used for PU synthetic leather surface layer or coatings, makes synthetic leather have special surface effect and feel, along with the PU synthetic leather to medium-to-high grade, personalization, functionalization development, the use of table place agent is increasing, kind is more and more.Its proportion in PU synthetic leather manufacturing cost is also increasing, along with the release and the consumption upgrading of effective consumption demand, under the situation of consumer's fashion consciousness and level of consumption raising; Current consumer demand presents tendencies such as personalization, fashion-orientation, leisureization, fashionableization, fashion, nationalization; The consumer of Different Culture, income, age, status just has different prices and selects, and style is selected; Color is selected; And the different class of synthetic leather product, numerous styles and kind, so new-product development speed is just being catered to this market demand.
Mainly there is following deficiency in some brush type products in the market: 1, feel is difficult to lastingly, and gloss hangs down the oil-free wax feel; 2, waterproof effect does not generally have grease proofing effect; The not obvious visual impression nature inadequately of on synthetic leather, handling of 3 burnt senses; 4 resistances to elevated temperatures are obviously on the low side can not to be used for more harsh synthetic leather rear section treatment process.
Summary of the invention:
The purpose of this invention is to provide the grease proofing high temperature resistant type brush finishing agent of a kind of use for synthetic leather high-effective water-proof, its heat resistance is high, and waterproof oil-proof result is excellent, and burnt sense is arranged, and the sense of feel oil wax is splendid, and kishke feel is strong.
In order to solve the existing problem of background technology, the present invention adopts following technical scheme: its prescription consists of: heatproof resin 18-25 part, polyurethane light resin 7-12 part, dimethyl formamide 23-32 part, ethyl acetate 8-13 part, butyl acetate 15-23 part, micronizing organic polymer wax 2-4 part, micronized silica 4-7 part, oiliness waterproof and oilproof auxiliary agent 2-7 part, modified organic silicon auxiliary agent 1-3 part, grease 1-3 part.
Its preparation process is:
A, with dimethyl formamide, butyl acetate, ethyl acetate, organic micropowder, inorganic micro powder mixing and stirring.
B, gained mixture among a is added the oiliness water and oil repellent agent, the modified organic silicon auxiliary agent, grease stirs.
C, gained mixture among the b is added the heatproof resin, polyurethane light resin stirs, and filters, get final product this product.
Described heatproof resin is a modified alkyd resin.
Described grease is a dehydrated castor oil.
The present invention has following beneficial effect: heat resistance is high, and waterproof oil-proof result is excellent, and burnt sense is arranged, and the sense of feel oil wax is splendid, and kishke feel is strong.
The specific embodiment:
This specific embodiment adopts following technical scheme: its prescription consists of: 25 parts of heatproof resins, 12 parts of polyurethane light resins, 32 parts of dimethyl formamides, 13 parts in ethyl acetate, 23 parts of butyl acetates, 4 parts in micronizing organic polymer wax, 7 parts of micronized silica, 7 parts of oiliness waterproof and oilproof auxiliary agents, 3 parts of modified organic silicon auxiliary agents, 3 parts of greases.
Its preparation process is:
A, with dimethyl formamide, butyl acetate, ethyl acetate, organic micropowder, inorganic micro powder mixing and stirring.
B, gained mixture among a is added the oiliness water and oil repellent agent, the modified organic silicon auxiliary agent, grease stirs.
C, gained mixture among the b is added the heatproof resin, polyurethane light resin stirs, and filters, get final product this product.
Described heatproof resin is a modified alkyd resin.
Described grease is a dehydrated castor oil.
This specific embodiment heat resistance is high, and waterproof oil-proof result is excellent, and burnt sense is arranged, and the sense of feel oil wax is splendid, and kishke feel is strong.
Embodiment 1:
A, with DMF29 part, 15 parts of butyl acetates, 12 parts in ethyl acetate, 2 parts of organic micropowders, 6 parts of mixing and stirring of inorganic micro powder.
B, gained mixture among a is added 7 parts of oiliness water and oil repellent agents, 2 parts of modified organic silicon auxiliary agents, grease stirs for 2 parts.
C, gained mixture among the b is added 18 parts of heatproof resins, 7 parts of polyurethane light resins stir, and filter, get final product the said product of present embodiment.
The technical performance index of this product is following:
Solid content (%): 22 ± 1
Viscosity (CPS/25 ℃): 300 ± 100
Outward appearance: milky white to little yellow opaque liquid
PH value: 6.5-8
Temperature tolerance: handle back 190 ℃, 30 minutes colour-fast not loss of gloss.
Characteristic: waterproof and oilproof, high temperature resistant, gloss is high, and the oil sense is burnt feels stable storage.
Embodiment 2:
A, with DMF25 part, 15 parts of butyl acetates, 10 parts in ethyl acetate, 4 parts of organic micropowders, 7 parts of mixing and stirring of inorganic micro powder.
B, gained mixture among a is added 4 parts of oiliness water and oil repellent agents, 1 part of modified organic silicon auxiliary agent, grease stirs for 1 part.
C, gained mixture among the b is added 20 parts of heatproof resins, 13 parts of polyurethane light resins stir, and filter, get final product the said product of present embodiment.
The technical performance index of this product is following:
Solid content (%): 26 ± 1
Viscosity (CPS/25 ℃): 600 ± 100
Outward appearance: milky white to little yellow opaque liquid
PH value: 6-7.5
Temperature tolerance: handle back 190 ℃, 30 minutes colour-fast not loss of gloss.
Characteristic: cloudy surface is handled, and the sense of powder wax is fine and smooth, and waterproof and oilproof is high temperature resistant, and gloss is high, and the oil sense is burnt feels stable storage.

Claims (4)

1. the high temperature resistant type brush finishing agent that the use for synthetic leather high-effective water-proof is grease proofing is characterized in that its prescription consists of: heatproof resin 18-25 part, polyurethane light resin 7-12 part, dimethyl formamide 23-32 part, ethyl acetate 8-13 part, butyl acetate 15-23 part, micronizing organic polymer wax 2-4 part, micronized silica 4-7 part, oiliness waterproof and oilproof auxiliary agent 2-7 part, modified organic silicon auxiliary agent 1-3 part, grease 1-3 part.
2. the high temperature resistant type brush finishing agent that a kind of use for synthetic leather high-effective water-proof according to claim 1 is grease proofing is characterized in that its preparation process is:
A, with dimethyl formamide, butyl acetate, ethyl acetate, organic micropowder, inorganic micro powder mixing and stirring;
B, gained mixture among a is added the oiliness water and oil repellent agent, the modified organic silicon auxiliary agent, grease stirs;
C, gained mixture among the b is added the heatproof resin, polyurethane light resin stirs, and filters, get final product this product.
3. the high temperature resistant type brush finishing agent that a kind of use for synthetic leather high-effective water-proof according to claim 1 is grease proofing is characterized in that described heatproof resin is a modified alkyd resin.
4. the high temperature resistant type brush finishing agent that a kind of use for synthetic leather high-effective water-proof according to claim 1 is grease proofing is characterized in that described grease is a dehydrated castor oil.
CN2011101662161A 2011-06-20 2011-06-20 High-efficiency water-proof anti-oil high temperature-resisting dedusting treating agent for synthetic leather Pending CN102839541A (en)

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Application Number Priority Date Filing Date Title
CN2011101662161A CN102839541A (en) 2011-06-20 2011-06-20 High-efficiency water-proof anti-oil high temperature-resisting dedusting treating agent for synthetic leather

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105297424A (en) * 2014-06-23 2016-02-03 上海央吉化工有限公司 Synthetic leather polishing coke powder and preparation method thereof
CN107059410A (en) * 2017-05-03 2017-08-18 宁波富纳新材料科技有限公司 A kind of fabric finishing agent with waterproof and oilproof antifouling property

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101328510A (en) * 2007-06-20 2008-12-24 时云刚 Washed intimating resin for processing leather surface and preparing method thereof
CN101705623A (en) * 2009-11-12 2010-05-12 江苏宝泽高分子材料股份有限公司 Water-based PU brush surface conditioning agent for synthetic leather
CN101880968A (en) * 2010-07-15 2010-11-10 江苏宝泽高分子材料股份有限公司 Spraying polishing coke powder wiping treatment agent for synthetic leather and preparation method thereof
CN101880969A (en) * 2010-07-15 2010-11-10 江苏宝泽高分子材料股份有限公司 Veneering dry-kneading hairy crazy horse resin for synthetic leather and preparation method thereof
CN101892591A (en) * 2010-07-15 2010-11-24 江苏宝泽高分子材料股份有限公司 High temperature-resistant printing burn polishing primer for synthetic leather and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101328510A (en) * 2007-06-20 2008-12-24 时云刚 Washed intimating resin for processing leather surface and preparing method thereof
CN101705623A (en) * 2009-11-12 2010-05-12 江苏宝泽高分子材料股份有限公司 Water-based PU brush surface conditioning agent for synthetic leather
CN101880968A (en) * 2010-07-15 2010-11-10 江苏宝泽高分子材料股份有限公司 Spraying polishing coke powder wiping treatment agent for synthetic leather and preparation method thereof
CN101880969A (en) * 2010-07-15 2010-11-10 江苏宝泽高分子材料股份有限公司 Veneering dry-kneading hairy crazy horse resin for synthetic leather and preparation method thereof
CN101892591A (en) * 2010-07-15 2010-11-24 江苏宝泽高分子材料股份有限公司 High temperature-resistant printing burn polishing primer for synthetic leather and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105297424A (en) * 2014-06-23 2016-02-03 上海央吉化工有限公司 Synthetic leather polishing coke powder and preparation method thereof
CN107059410A (en) * 2017-05-03 2017-08-18 宁波富纳新材料科技有限公司 A kind of fabric finishing agent with waterproof and oilproof antifouling property

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Application publication date: 20121226