CN102807780A - Coating composition and coat obtained therefrom - Google Patents
Coating composition and coat obtained therefrom Download PDFInfo
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- CN102807780A CN102807780A CN2011101577101A CN201110157710A CN102807780A CN 102807780 A CN102807780 A CN 102807780A CN 2011101577101 A CN2011101577101 A CN 2011101577101A CN 201110157710 A CN201110157710 A CN 201110157710A CN 102807780 A CN102807780 A CN 102807780A
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Abstract
The invention relates to a coating composition and a coat obtained therefrom. The coating composition comprises a film-forming resin, a solvent, a texture-forming agent and an optional additional additive, wherein the texture-forming agent is a crystalline compound soluble in the solvent. The invention also relates to the coat with a visible texture structure obtained from the coating composition.
Description
The present invention relates to a kind of coating composition.More specifically, the present invention relates to a kind of coating composition that can be used for forming coating with naked eyes visible texture structure.
Background technology
In coatings industry, the coating that is formed by coating composition is to---metal, timber, building materials, plastics, leather, paper, glass etc.---have provide protection by the base material of application.In many cases, for example when being used to be coated with furniture, material of construction, leatherware, glass wares or the like, hope that also coating can have decoration function.In this case, expect that the coating that coating composition forms can have macroscopic texture structure on base material.In the practice,, can carry out mechanical mold pressing processing treatment to the coating of moulding usually in order to obtain to have the coating of naked eyes visible texture structure, i.e. embossing processing, thus on coating, form desired texture structure.But this texture formation method not only needs expensive machining equipment, and needs extra procedure of processing, thereby the defective that exists consuming time, effort etc. to overcome.
In order to overcome above-mentioned defective; People such as Richard propose in PCT application publication number WO 01/53387; Can form coating through in coating composition, adding the viscosity of particle diameter greater than the inorganic solid particles and/or the raising coating composition of coat-thickness with naked eyes visible texture structure.But this coating composition is owing to contain insoluble inorganic solid particles or owing to have the HV characteristics, thereby needs special devices or technology to carry out application, is difficult to usually realize naked eyes visible texture structure through the spraying technology of routine.
Therefore, still need a kind of novel coating composition, this coating composition not only can form the coating with naked eyes visible texture structure, and does not have the viscosity of remarkable change, thereby can adopt conventional spraying technology to be coated with.
Summary of the invention
To achieve these goals; The inventor has carried out lot of experiments; The result surprisingly finds: in coating composition, add crystalline compounds in the solvent dissolve in this coating composition can obtain having naked eyes visible texture structure after the coating composition drying coating; And this coating composition be convenient to the coating, for example can adopt conventional spraying technology to be coated with.
Thereby, the invention provides a kind of coating composition, said coating composition comprises: film-forming resin; Solvent; Texture forms agent; With optional additional additives, wherein, it is the crystalline compounds that dissolves in said solvent that said texture forms agent.
The present invention also provides a kind of coating that is obtained by aforementioned coating composition, and said coating has macroscopic texture structure.In preferred embodiment, said coating has macroscopic 3D texture structure.In preferred embodiment, said coating has the 3D texture structure of featheriness or year colyliform.
The method that the present invention also provides a kind of preparation to have the coating of naked eyes visible texture, said method comprises the steps:
A) aforementioned coating composition is provided,
B) be coated with also dry gained coating composition, thereby obtain having the coating of naked eyes visible texture structure.
In the present invention; The contriver forms agent with the solubility crystalline compounds as texture in a creative way and adds in the coating composition; Not only can obtain to have the coating of naked eyes visible texture structure, and can influence the viscosity of coating composition sharply thereby can influence coating characteristics sharply.For example; The viscosity of coating composition of the present invention in standard testing GB/T1723-93 can be adjusted in 500 to 2000mPa.s the scope; Making its viscosity compare with the conventional coating composition that does not possess the performance that forms naked eyes visible texture structure does not have noticeable change, and makes that coating composition of the present invention can be through being coated with such as conventional spraying coating process such as spraying, spin coatings.
Description of drawings
Fig. 1 representes the featheriness texture structure according to coating composition formation of the present invention.
Fig. 2 representes the year colyliform texture structure according to coating composition formation of the present invention.
Embodiment
Only if this paper has statement in addition, describe the term " " that uses in the context of the present invention or " a kind of " and be appreciated that and comprise plural number.
Be described to comprise or comprise under the situation of specific components at compsn; Do not get rid of said composition and comprise other selectable components, only and if indicate in addition clearly, estimate that said composition also can be made up of related specific components or form; Perhaps be described to comprise or comprise under the situation of specific process step in method; Do not get rid of the optional process step that this method comprises other, only and if indicate in addition clearly, estimate that this method also can be made up of related specific process step or form.
For easy, this paper only discloses some numerical ranges clearly.Yet lower limit can be combined to form not the clearly scope of record with any upper limit arbitrarily; And lower limit can be combined to form not the clearly scope of record with other lower limit arbitrarily, and the same upper limit arbitrarily can be combined to form not the clearly scope of record with any other upper limit.In addition, although not clearly record, each point or single numerical value between endpoints of ranges are included in this scope.Thereby each point or single numerical value can be used as lower limit or the upper limit of self and other point or single combinations of values or be combined to form not the clearly scope of record with other lower limit or the upper limit arbitrarily.
The invention provides a kind of coating composition, said coating composition comprises: film-forming resin; Solvent; Texture forms agent; With optional additional additives, wherein, it is the crystalline compounds that dissolves in said solvent that said texture forms agent.
Term " film-forming resin " refers in this article, can all components in the coating composition be combined and the film forming resin of shape.In embodiments of the present invention; Film-forming resin can comprise, Gum Rosin, Synolac, resol, aminoresin, vibrin, acrylics, epoxy resin, urethane resin, polyureas, polyolefin resin, nitrocellulose resin, silicone resin or the film-forming resin that is usually used in coating composition well known by persons skilled in the art.In preferred implementation of the present invention, film-forming resin comprises Synolac, nitrocellulose resin or its combination.In more preferably embodiment of the present invention, film-forming resin comprises short oil-ity alcohol acid resin, nitrocellulose resin or its combination.
Term " Synolac " refers to carry out the liquid alcohol acid resin that condensation polymerization is processed together through polyvalent alcohol, polyprotonic acid or acid anhydrides and unsaturated fatty acids in this article; Perhaps refer to carry out the liquid alcohol acid resin that transesterify is processed through polyvalent alcohol and wax, this Synolac also is called as the polyester through lipid acid or wax modification.The content that term " short oil-ity alcohol acid resin " refers to lipid acid (or wax) is with respect to the total amount of the Synolac Synolac less than 40 weight %.Representative polyvalent alcohol comprises known other polyvalent alcohol that can be used for preparing Synolac of glycerine, tetramethylolmethane, sorbyl alcohol, TriMethylolPropane(TMP), terepthaloyl moietie, Diethylene Glycol, Ucar 35, dipropylene glycol and those of ordinary skills.Representative polyprotonic acid or acid anhydrides comprise diprotic acid or acid anhydrides, such as phthalic acid and acid anhydrides thereof, m-phthalic acid, terephthalic acid, toxilic acid, fumaric acid, hexanodioic acid, sebacic acid or the like; Triprotic acid is such as trimellitic acid; And known other polyprotonic acid or the acid anhydrides that can be used for preparing Synolac of those of ordinary skills.Representative lipid acid comprises dehydrated castor lipid acid, flax lipid acid, castor-oil plant lipid acid, soya fatty acid or the like and combination thereof.Representative wax comprises vegetables oil, such as that oil of Caro, Viscotrol C, synourin oil, cocounut oil, Semen Maydis oil, cotton seed oil, Peanut oil, oleum lini, peanut oil, Thistle oil, VT 18, sunflower oil, Yatall MA, tung oil, walnut oil, wood oil or the like; Animal tallow is such as fish oil, lard, chicken fat, butter or the like; And combination.
As stated, Synolac can adopt suitable preparing method's preparation well known to those of ordinary skill in the art, perhaps can derive from suitable commercially available product arbitrarily.As the commercial examples of Synolac, can use such as Synolac available from the trade mark CY468 of Dutch DSM N. V., CY472, CY474, CY499; Or available from the Synolac of the trade mark Novalkyd 2510X80C of Dutch DSM N. V., 2530X80C, 252,252X75,3731X70C, 3737X70C, 3800X60C, 3800XAI65,3811AB80,3815X70C, 3820X60,3823,3910X60,3911X70,8AL231X6.
Term " nitrocellulose " is that Mierocrystalline cellulose and nitric acid and vitriolic mixing acid carry out the product that esterification obtains.Mierocrystalline cellulose is the polysaccharide that is made up of a plurality of glucose units, hydroxyl wherein can with nitric acid generation esterification, thereby form nitrocellulose with commercial use.Representative Mierocrystalline cellulose is usually from cheap renewable raw materials such as cotton, timber, fiber crops, straw, straw, bagasse.
As stated, nitrocellulose can adopt batch production technology well known to those of ordinary skill in the art or continous way production technique to produce, and perhaps can derive from suitable commercially available product arbitrarily.As the commercial examples of nitrocellulose, can use such as 1/2S nitrocellulose available from Luzhou Chemical Plant, wherein the 1/2s in this product specification is the falling sphere time for the definition product viscosity; Perhaps can use Nitrocellulose R3510 available from ICI Nobel.
Because main ingredient (being lipid acid and wax) in the Synolac and the main ingredient (being Mierocrystalline cellulose) in the Nitrocellulose are all from the renewable raw materials of cheapness; Thereby these film-forming resins are superior to the film-forming resin that other is derived from petroleum on cost benefit, such as alkylene resin, acrylics, epoxy resin and urethane resin.
Therefore, in embodiments of the present invention, preferably use Synolac, nitrocellulose or its combination as film-forming resin.In more preferably embodiment of the present invention, the short oil-ity alcohol acid resin of coating composition employing combination and nitrocellulose are as film-forming resin.The coating composition that obtains like this has plurality of advantages such as fast dried, cheap, easy construction, excellent property.
In preferred implementation of the present invention, the gross weight that coating composition can comprise with respect to said coating composition is the film-forming resin of 5 weight % to 50 weight %.Preferably; The gross weight that coating composition can comprise with respect to said coating composition is the film-forming resin of 10 to 40 weight %; The more preferably film-forming resin of 15 to 35 weight %, the more preferably film-forming resin of 20 to 30 weight % also, even the more preferably film-forming resin of 25 to 28 weight %.
In this article, term " solvent " is meant the liquid medium that in coating composition, mainly plays diluting effect.In embodiments of the present invention; Solvent comprises the solvent that can be used for the film-forming resin commonly used in the paint field well known to those of ordinary skill in the art, and it comprises esters solvent, alcoholic solvent, ether solvent, ketones solvent, varsol or its arbitrary composition.Representational instance can comprise methyl acetate, ETHYLE ACETATE, butylacetate, Isoamyl Acetate FCC, ethylene carbonate, methyl alcohol, ethanol, n-propyl alcohol, Virahol, propyl carbinol, isopropylcarbinol, ether, butyl ether, methyl ethyl ether, ethylene glycol monomethyl ether acetate, acetone, butanone, pimelinketone, hexane, heptane, benzene,toluene,xylene, chlorobenzene or its arbitrary combination.
In preferred implementation of the present invention, the gross weight that coating composition can comprise with respect to said coating composition is the solvent of 30 weight % to 70 weight %.Preferably, the gross weight that coating composition can comprise with respect to said coating composition is the solvent of 30 to 65 weight %, the more preferably solvent of 35 to 55 weight %, the more preferably solvent of 40 to 50 weight % also, the also more preferably solvent of 45 to 50 weight %.Yet in the coating composition, the consumption of solvent is not limited thereto, and can be confirmed through the normal experiment technology by those skilled in the art according to the viscosity of desired coating composition.
In this article, term " texture formation agent " is meant the additive that can give the coating naked eyes visible texture structure that is formed by coating composition.In the present invention, texture formation agent is the crystalline compounds that dissolves in said solvent.
Term " naked eyes visible " in this article refers to, and any regular or irregular texture structure that on coatingsurface, produces all can arrive through naked-eye observation, and does not need the auxiliary of instrument such as microscope.In this article; " dissolve in the crystalline compounds of said solvent " and can be dissolved in the solvent of coating composition according to the invention; And after application, can for example crystallize into and have certain macromorphologic solid, thereby give formed coating macroscopic texture structure from solution state through operation stepss such as solvent evaporates, temperature regulation.
In preferred implementation of the present invention; The crystalline compounds that dissolves in said solvent that forms the agent use as texture comprises condensed-nuclei aromatics; Promptly; By the compound that two or more phenyl ring form with the mode of shared two adjacent carbonss, the example comprises naphthalene, anthracene, phenanthrene, tetracene, pentacene, rubrene or its arbitrary combination.
Be not to be intended to be entangled in any theory; According to the present invention; The coating composition that wherein contains the solubility crystalline compounds on being coated to base material after; Crystallization takes place and forms macroscopic texture structure in this crystalline compounds along with the evaporation of solvent, be preferably formed macroscopic 3D texture structure, more preferably forms the 3D texture structure of featheriness or year colyliform.Therefore, according to the present invention, the formation of macroscopic texture structure does not rely on the viscosity that improves coating composition or adds the inorganic solid particles of particle diameter greater than coat-thickness.And crystalline compounds may be dissolved in the solvent, so the existence of crystalline compounds brings remarkably influenced can for the viscosity of coating composition yet, and the viscosity that can regulate coating composition through the consumption of regulating solvent easily.According to preferred implementation of the present invention; The viscosity of the coating composition of measuring according to standard testing GB/T1723-93 method of the present invention is in 500 to 2000mPas scope, thereby this low viscous coating composition can be coated on the base material through conventional spraying technology such as spraying, spin coating, roller coat, dip-coating etc.This coating composition of the present invention not only can obtain to have the coating of naked eyes visible texture structure; And overcome existing coating composition and can't or be difficult to the defective that adopts conventional spraying technology to apply for the coating that obtains to have naked eyes visible texture structure, simplify operating procedure and improved production efficiency.
In preferred implementation of the present invention, it is the texture formation agent of 5 weight % to 50 weight % that coating composition can comprise with respect to the gross weight of said coating composition.Preferably; It is the texture formation agent of 10 to 45 weight % that coating composition can comprise with respect to the gross weight of said coating composition; More preferably the texture of 15 to 40 weight % forms agent; Also more preferably the texture of 20 to 30 weight % forms agent, even more preferably the texture of 20 to 25 weight % forms agent.
Alternatively, can also comprise one or more conventional additives as required according to coating composition of the present invention.Representative conventional additives comprises rheological agent, tensio-active agent, skimmer, wetting agent, antiseptic-germicide, UV absorption agent, photostabilizer, inhibitor, adhesion promotor and other any suitable conventional additives.The purposes of these conventional additives and consumption are known to those of ordinary skills.
In preferred implementation of the present invention, the gross weight that coating composition can comprise with respect to said coating composition is one or more conventional additives of 0 weight % to 5 weight %.Particularly, can to comprise the gross weight with respect to said coating composition be the conventional additives of 0.5 weight % to 4 weight %, 0.5 to 3 weight %, 0.5 to 2 weight %, 0.5 to 1 weight % to filled compositions.
The preparation of coating composition of the present invention can adopt preparation of compositions method well known to those of ordinary skill in the art to carry out.Thereby for example can adopt known any other that is applicable to dispersive composition of pony mixer, roll-type stirrer and those of ordinary skills to be coated with material mixing plant mixes each component in the coating composition simultaneously and forms coating composition; Perhaps, form coating composition thereby add part film-forming resin, texture formation agent, conventional additives and added solvent more earlier with part film-forming resin and solvent uniform mixing.
In preferred implementation of the present invention, a kind of coating composition is provided, said coating composition comprises with respect to the gross weight of said coating composition:
The said film-forming resin of 5 to 50 weight %;
The said solvent of 30 to 60 weight %;
The said texture of 5 to 50 weight % forms agent; With
The said additional additives of 0 to 5 weight %.
In more preferably embodiment of the present invention, a kind of coating composition is provided, said coating composition comprises with respect to the gross weight of said coating composition:
The said film-forming resin of 20 to 30 weight %;
The said solvent of 45 to 55 weight %;
The said texture of 5 to 50 weight % forms agent; With
0.1 said additional additives to 2 weight %.
In embodiments of the present invention, the viscosity of coating composition in standard testing GB/T1723-93 is in 500 to 2000mPa.s scope.
The present invention also provides a kind of coating, and said coating is processed by coating composition of the present invention, and has macroscopic texture structure.In preferred embodiment, said coating has macroscopic 3D texture structure.In preferred embodiment, said coating has the 3D texture structure of featheriness or year colyliform.
The method that the present invention also provides a kind of preparation to have the coating of naked eyes visible texture, said method comprises the steps:
A) aforementioned coating composition is provided,
B) be coated with also dry gained coating composition, thereby obtain having the coating of naked eyes visible texture structure.
The acceptable substrate (for example metal, timber, building materials, plastics, leather, paper, glass etc.) that can be applied to coating composition of the present invention goes up and forms coating, thereby for base material provides provide protection, and decoration function.Preferably, coating composition of the present invention can be used to be coated with furniture, material of construction, metal products, plastics, leatherware, paper, glasswork etc.
Through following examples the present invention is further set forth, but the present invention is not limited thereto.Only if statement is arranged in addition, all percentage by weight.
Embodiment 1
Table 1
| Component | Weight percent % | The source |
| Synolac Novalkyd 3911X70 | 20 | Holland DSM N. V. |
| 1/2S nitrocellulose | 7.5 | Luzhou Chemical Plant |
| Butylacetate | 17.5 | The general industry article |
| Pimelinketone | 25 | The general industry article |
| Ethanol | 6.5 | The general industry article |
| Naphthalene | 23 | The general industry article |
| Skimmer | 0.5 | Germany BYK company |
| Total amount | 100 |
Embodiment 2
Table 2
| Component | Weight percent % | The source |
| Synolac Novalkyd 3911X70 | 25 | Holland DSM N. V. |
| 1/2S nitrocellulose | 8 | Luzhou Chemical Plant |
| Butylacetate | 19 | The general industry article |
| Pimelinketone | 14.5 | The general industry article |
| Ethanol | 5 | The general industry article |
| Naphthalene | 28 | The general industry article |
| Skimmer | 0.5 | Germany BYK company |
| Total amount | 100 |
Embodiment 3
Table 3
| Component | Weight percent % | The source |
| Synolac Novalkyd 3911X70 | 15 | Holland DSM N. V. |
| 1/2S nitrocellulose | 8 | Luzhou Chemical Plant |
| Butylacetate | 35.7 | The general industry article |
| Pimelinketone | 20 | The general industry article |
| Ethanol | 6 | The general industry article |
| Anthracene | 15 | The general industry article |
| Skimmer | 0.3 | Germany BYK company |
| Total amount | 100 |
Embodiment 4
Table 4
| Component | Weight percent % | The source |
| Synolac Novalkyd 3911X70 | 20 | Holland DSM N. V. |
| 1/2S nitrocellulose | 10 | Luzhou Chemical Plant |
| Butylacetate | 20 | The general industry article |
| Pimelinketone | 18 | The general industry article |
| Ethanol | 7 | The general industry article |
| Anthracene | 25 | The general industry article |
| Skimmer | 0.5 | Germany BYK company |
| Total amount | 100 |
With each component uniform mixing in table 1 to the table 4, thereby form coating composition.。
After being sprayed on the coating composition of above embodiment 1 on the base material, it is carried out drying treatment, the result obtains to have the coating of the visible 3D texture structure of naked eyes illustrated in figures 1 and 2.Fig. 1 is illustrated in the featheriness texture structure that forms under the thicker condition of coating.Fig. 2 is illustrated in the year colyliform texture structure that forms under the thin condition of coating.This shows that coating composition of the present invention not only can obtain the coating of macroscopic 3D texture structure, can also adopt conventional coating technique, for example spraying is coated with.
Under for disengaging situation of the present invention, the present invention is carried out various corrections and changes is obvious for a person skilled in the art.Therefore, will be appreciated that the present invention is not limited to above-mentioned illustrated embodiment.
Claims (16)
1. coating composition, it comprises:
Film-forming resin;
Solvent;
Texture forms agent; With
Optional additional additives,
Wherein, said texture formation agent is the crystalline compounds that dissolves in said solvent.
2. coating composition as claimed in claim 1, wherein, said texture forms agent and comprises condensed-nuclei aromatics.
3. coating composition as claimed in claim 2, wherein, said texture forms agent and comprises naphthalene, anthracene, phenanthrene, tetracene, pentacene, rubrene or its arbitrary combination.
4. like coating composition any in the claim 1 to 3, it comprises, with respect to the gross weight of said coating composition,
The said film-forming resin of 5 to 50 weight %;
The said solvent of 30 to 70 weight %;
The said texture of 5 to 50 weight % forms agent; With
The said additional additives of 0 to 5 weight %.
5. like coating composition any in the claim 1 to 3, it comprises, with respect to the gross weight of said coating composition,
The said film-forming resin of 20 to 30 weight %;
The said solvent of 40 to 65 weight %;
The said texture of 5 to 50 weight % forms agent; With
0.1 said additional additives to 2 weight %.
6. like coating composition any in the claim 1 to 5; Wherein, Said film-forming resin comprises, Gum Rosin, Synolac, resol, aminoresin, vibrin, acrylics, epoxy resin, urethane resin, polyureas, polyolefin resin, nitrocellulose resin, silicone resin or its arbitrary combination.
7. like coating composition any in the claim 1 to 5, wherein, said film-forming resin comprises Synolac, nitrocellulose resin or its combination.
8. coating composition as claimed in claim 7, wherein, said Synolac comprises short oil-ity alcohol acid resin.
9. like coating composition any in the claim 1 to 5, wherein, said solvent comprises esters solvent, alcoholic solvent, ether solvent, ketones solvent, varsol or its arbitrary combination.
10. coating composition as claimed in claim 9; Wherein, said solvent comprises methyl acetate, ETHYLE ACETATE, butylacetate, Isoamyl Acetate FCC, ethylene carbonate, methyl alcohol, ethanol, n-propyl alcohol, Virahol, propyl carbinol, isopropylcarbinol, ether, butyl ether, methyl ethyl ether, ethylene glycol monomethyl ether acetate, acetone, butanone, pimelinketone, hexane, heptane, benzene,toluene,xylene, chlorobenzene or its arbitrary combination.
11. like coating composition any in the claim 1 to 5; Wherein, said additional additives comprises rheological agent, tensio-active agent, skimmer, wetting agent, antiseptic-germicide, UV absorption agent, photostabilizer, inhibitor, adhesion promotor or its arbitrary combination.
12. like coating composition any in the claim 1 to 11, the viscosity of said coating composition is in 500 to 2000mPa.s scope.
13. one kind by any coating that said coating composition obtains in the claim 1 to 12, said coating has macroscopic texture structure.
14. coating as claimed in claim 13, wherein said coating have macroscopic 3D texture structure.
15. coating as claimed in claim 14, wherein said coating have the 3D texture structure of featheriness or year colyliform.
16. a method for preparing the coating with naked eyes visible texture, said method comprises the steps:
A) provide like any described coating composition in the claim 1 to 12,
B) be coated with also dry gained coating composition, thereby obtain having the coating of naked eyes visible texture structure.
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| CN103450750A (en) * | 2013-08-23 | 2013-12-18 | 吴江龙硕金属制品有限公司 | Metal anticorrosive coating and preparation method thereof |
| CN103897593A (en) * | 2014-02-26 | 2014-07-02 | 施俊杰 | Method for preparing environment-friendly coating |
| WO2015011167A1 (en) * | 2013-07-26 | 2015-01-29 | Akzo Nobel Coatings International B.V. | High solids coating composition comprising an alkyd resin and isoamyl acetate |
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| CN105017865A (en) * | 2015-07-29 | 2015-11-04 | 广西梧州龙鱼漆业有限公司 | Wear-resistant wood finish paint |
| CN105273589A (en) * | 2014-06-29 | 2016-01-27 | 江苏飞翔涂料实业总公司 | Quick-drying type coating for automobile bumper |
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| WO2015011167A1 (en) * | 2013-07-26 | 2015-01-29 | Akzo Nobel Coatings International B.V. | High solids coating composition comprising an alkyd resin and isoamyl acetate |
| CN105378001A (en) * | 2013-07-26 | 2016-03-02 | 阿克佐诺贝尔国际涂料股份有限公司 | High solids coating composition comprising an alkyd resin and isoamyl acetate |
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| CN104592814A (en) * | 2015-01-09 | 2015-05-06 | 芜湖航天特种电缆厂 | Insulating paint composition and method for preparing insulating paint |
| CN104592813A (en) * | 2015-01-09 | 2015-05-06 | 芜湖航天特种电缆厂 | Insulating coating and preparation method thereof |
| CN104592814B (en) * | 2015-01-09 | 2017-01-25 | 芜湖航天特种电缆厂股份有限公司 | Insulating paint composition and method for preparing insulating paint |
| CN104592813B (en) * | 2015-01-09 | 2017-01-25 | 芜湖航天特种电缆厂股份有限公司 | Insulating coating and preparation method thereof |
| CN105017865A (en) * | 2015-07-29 | 2015-11-04 | 广西梧州龙鱼漆业有限公司 | Wear-resistant wood finish paint |
| KR20220125467A (en) * | 2021-03-05 | 2022-09-14 | 울산대학교 산학협력단 | Spray coating composition for 3D scanning |
| KR102554958B1 (en) * | 2021-03-05 | 2023-07-13 | 울산대학교 산학협력단 | Spray coating composition for 3D scanning |
| CN113667359A (en) * | 2021-04-25 | 2021-11-19 | 肇庆市哈力化工有限公司 | Strong-universality ABS plastic piece special-purpose crack effect paint and preparation method thereof |
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