CN102807780B - Coating composition and coat obtained therefrom - Google Patents
Coating composition and coat obtained therefrom Download PDFInfo
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- CN102807780B CN102807780B CN201110157710.1A CN201110157710A CN102807780B CN 102807780 B CN102807780 B CN 102807780B CN 201110157710 A CN201110157710 A CN 201110157710A CN 102807780 B CN102807780 B CN 102807780B
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Abstract
The invention relates to a coating composition and a coat obtained therefrom. The coating composition comprises a film-forming resin, a solvent, a texture-forming agent and an optional additional additive, wherein the texture-forming agent is a crystalline compound soluble in the solvent. The invention also relates to the coat with a visible texture structure obtained from the coating composition.
Description
The present invention relates to a kind of coating composition.More particularly it relates to one kind can be used to being formed can with naked eyes
See the coating composition of the coating of texture structure.
Background technology
In coatings industry, the coating formed by coating composition is to the base material that is coated --- metal, timber, building materials,
Plastics, leather, paper, glass etc. --- with protective effect.In many cases, for example when for being coated with furniture, Building wood
When material, leatherware, glass waress etc., it is also desirable to which coating can have decoration function.In such circumstances it is desirable to coating group
The coating that compound is formed on base material can have macroscopic texture structure.It is in practice, visible with naked eyes in order to obtain
The coating of texture structure, generally can carry out machinery molding processed, i.e. Embossing processing, so as in coating to the coating of molding
It is upper to form desired texture structure.But this texture formation method not only needs the machining equipment of costliness, and needs
Extra procedure of processing is wanted, thus there is the defect that cannot be overcome such as time-consuming, laborious.
In order to overcome drawbacks described above, Richard et al. to propose in PCT Application Publication WO 01/53387, can pass through
Add particle diameter in coating composition more than the inorganic solid particles of coating layer thickness and/or improve the viscosity of coating composition, come
Form the coating with naked eyes visible texture structure.But, this coating composition is due to containing insoluble inoganic solids
Grain or due to high viscosity feature, so that special equipment or technology carry out application, is generally difficult to by conventional
Spraying technology is realizing naked eyes visible texture structure.
Therefore, there is still a need for a kind of new coating composition, this coating composition not only can be formed with naked eyes
The coating of visible texture structure, and there is no the viscosity for significantly changing, thus can be coated using Typical spray technology.
The content of the invention
To achieve these goals, present inventor has performed lot of experiments, as a result surprisingly it has been found that：To Coating material composition
The crystalline compounds that addition is dissolved in the solvent of the coating composition in thing can be had after coating composition is dried
The coating of naked eyes visible texture structure, and this coating composition is easy to coating, for example, can be entered using Typical spray technology
Row coating.
Thus, the invention provides a kind of coating composition, the coating composition is included：Film-forming resin；Solvent；Texture
Forming agent；With optional additional additives, wherein, the texturisers are soluble in the crystalline compounds of the solvent.
Present invention also offers a kind of coating obtained by aforementioned coating composition, the coating has macroscopic stricture of vagina
Reason structure.In a preferred embodiment, the coating has macroscopic 3D texture structures.In preferred embodiment
In, the coating has the 3D texture structures of featheriness or year colyliform.
Present invention also offers a kind of method for preparing the coating with naked eyes visible texture, methods described includes following step
Suddenly：
A) aforementioned coating composition is provided,
B) coated and dried gained coating composition, so as to obtain the coating with naked eyes visible texture structure.
In the present invention, inventor is added to coating group using soluble crystalline compound as texturisers in a creative way
In compound, the coating with naked eyes visible texture structure can not only be obtained, and coating composition can not adversely be affected
Viscosity, thus coating characteristics can not adversely be affected.For example, coating composition of the invention is in standard testing GB/T1723-93
In viscosity can be adjusted in the range of 500 to 2000mPa.s so that its viscosity with do not possess to be formed naked eyes visible texture knot
The conventional coating compositions of the performance of structure compare no significant changes, and allow the coating composition of the present invention by all
The such as Typical spray technique such as spraying, spin coating is coated.
Description of the drawings
Fig. 1 represents the featheriness texture structure that coating composition of the invention is formed.
Fig. 2 represents the year colyliform texture structure that coating composition of the invention is formed.
Specific embodiment
Unless stated otherwise herein, the term " one " upper and lower used herein or " one kind " for describing the present invention should be managed
Solution is to include plural number.
In the case where compositionss are described as including or include specific components, however not excluded that said composition is optional comprising other
Component, and unless clearly otherwise indicated, it is contemplated that said composition also can be constituted or be constituted by involved specific components, or
In the case where method is described as including or includes specific process step, however not excluded that the method includes other optional techniques steps
Suddenly, and unless clearly otherwise indicated, it is contemplated that the method also can be constituted or be constituted by involved specific process step.
For simplicity, some numerical rangies are only expressly disclosed herein.However, arbitrarily lower limit can be with any upper limit group
Close and form the scope not being expressly recited；And arbitrarily lower limit can form the scope not being expressly recited with other lower values, together
Any upper limit of sample can combine to form the scope not being expressly recited with any other upper limit.Although additionally, be not expressly recited,
Each point or single number between endpoints of ranges is included in the range of this.Thus, each point or single number can be used as certainly
The lower limit or the upper limit of body are combined or combine to be formed with other lower limits or the upper limit with any other point or single number and be not expressly recited
Scope.
The invention provides a kind of coating composition, the coating composition is included：Film-forming resin；Solvent；Texture is formed
Agent；With optional additional additives, wherein, the texturisers are soluble in the crystalline compounds of the solvent.
Term " film-forming resin " refers to herein, can combine and shape all components in coating composition
The resin of film forming.In embodiments of the present invention, film-forming resin can include, rosin resin, alkyd resin, phenolic resin,
Amino resins, polyester resin, acrylic resin, epoxy resin, polyurethane resin, carbamide resin, vistanex, nitric acid are fine
The plain resin of dimension, organic siliconresin or the film-forming resin for being usually used in coating composition well known by persons skilled in the art.In the present invention
Preferred implementation in, film-forming resin include alkyd resin, nitrocellulose resin or its combination.In the present invention more preferably
In embodiment, film-forming resin includes short oil-ity alcohol acid resin, nitrocellulose resin or its combination.
Term " alkyd resin " refers to herein to be carried out together by polyhydric alcohol, polyprotic acid or anhydride and unsaturated fatty acid
Condensation polymerization and made by liquid alkyd resin；Or to refer to and carry out liquid alkyd made by ester exchange by polyhydric alcohol and fatty oil
Resin, this alkyd resin are also referred to as the modified polyester of Jing fatty acids or fatty oil.Term " short oil-ity alcohol acid resin " refers to fat
Fat acid (or fatty oil) content relative to alkyd resin total amount less than 40 weight % alkyd resin.Representative is more
First alcohol include glycerol, tetramethylolmethane, Sorbitol, trimethylolpropane, ethylene glycol, diethylene glycol, Propylene Glycol, dipropylene glycol and
Those of ordinary skill in the art are known to be used in other polyhydric alcohol for preparing alkyd resin.Representative polyprotic acid or anhydride
Including binary acid or anhydride, such as phthalic acid and its anhydride, M-phthalic acid, p-phthalic acid, maleic acid, fumaric acid,
Adipic acid, decanedioic acid etc.；Ternary acid, such as trimellitic acid；And those of ordinary skill in the art are known to be used in preparing alcohol
Other polyprotic acid of acid resin or anhydride.Representative fatty acid includes dehydrated castor fatty acids, Caulis et Folium Lini fatty acid, Semen Ricini
Fatty acid, soya bean fatty acid etc. and combinations thereof.Representative fatty oil includes vegetable oil, such as that oil, Semen Ricini of Caro
Oil, dehydrated castor oil, cocos nucifera oil, Semen Maydis oil, cotton seed oil, Oleum Arachidis hypogaeae semen, oleum lini, Oleum Arachidis hypogaeae semen, safflower oil, soybean oil, Xiang
Certain herbaceous plants with big flowers oil, tall oil, Oleum Verniciae fordii, walnut oil, wood oil etc.；Animal fat, such as fish oil, Adeps Sus domestica, chicken oil, Adeps Bovis seu Bubali etc.；And its group
Close.
As described above, alkyd resin can adopt appropriate preparation method system well known to those of ordinary skill in the art
It is standby, or arbitrarily appropriate commercially available product can be derived from.As the commercial examples of alkyd resin, it is possible to use such as purchased from lotus
The trade mark Novalkyd 2510X80C of blue DSM N. V., 2530X80C, 252X75,3737X70C, 3800X60C, 3811AB80,
The alkyd resin of 3815X70C, 3910X60,3911X70.
Term " celluloid " is that cellulose carries out the product that esterification is obtained with the mixed acid of nitric acid and sulphuric acid.It is fine
Dimension element is the polysaccharide being made up of multiple glucose units, and hydroxyl therein can occur esterification with nitric acid, so as to form tool
There is the celluloid of commercial use.Representative cellulose is usually from Cotton Gossypii, timber, fiber crops, straw, Caulis et Folium Oryzae, Caulis Sacchari sinensis
The cheap renewable raw materials such as slag.
As described above, celluloid can adopt batch production technique well known to those of ordinary skill in the art or
Continuous way production technology is produced, or can derive from arbitrarily appropriate commercially available product.As the commercial examples of celluloid,
Can be using celluloid such as the 1/2s purchased from Luzhou Chemical Plant, the wherein 1/2s in the product specification is produced for definition
The falling sphere time of product viscosity；Or NC Nitroncellulose R3510 for being purchased from ICI Nobel can be used.
Due to the key component in the key component (i.e. fatty acid and fatty oil) and NC Nitroncellulose in alkyd resin
(i.e. cellulose) is all from cheap renewable raw materials, thus these film-forming resins are derived from oil better than other in cost benefit
The film-forming resin of raw material, such as olefin base resins, acrylic resin, epoxy resin and polyurethane resin.
Therefore, in embodiments of the present invention, alkyd resin, celluloid or its combination are preferably used as film forming
Resin.In the more preferably embodiment of the present invention, short oil-ity alcohol acid resin and cellulose nitrate of the coating composition using combination
Element is used as film-forming resin.The coating composition for so obtaining has quick-drying, cheap, easy construction, function admirable etc. many
Advantage.
In a preferred embodiment of the invention, coating composition can be comprising the gross weight relative to the coating composition
For the film-forming resin of 5 to 50 weight %.Preferably, coating composition comprising the gross weight relative to the coating composition can be
The film-forming resin of 10 to 40 weight %, the more preferably film-forming resin of 15 to 35 weight %, will also more preferably 20 to 30 weight %
Film-forming resin, the even more preferably film-forming resin of 25 to 28 weight %.
Herein, term " solvent " refers to the liquid medium for primarily serving diluting effect in the coating composition.At this
In the embodiment of invention, solvent includes the well known to those of ordinary skill in the art conventional film forming that can be used in paint field
The solvent of resin, which includes esters solvent, alcohols solvent, ether solvent, ketones solvent, varsol or its arbitrary composition.
Representational example can include methyl acetate, ethyl acetate, butyl acetate, isoamyl acetate, ethanol, normal propyl alcohol, isopropanol,
N-butyl alcohol, isobutanol, ether, butyl ether, methyl ethyl ether, acetone, butanone, Ketohexamethylene, hexane, heptane, toluene, dimethylbenzene, chlorine
Benzene or its combination in any.
In a preferred embodiment of the invention, coating composition can be comprising the gross weight relative to the coating composition
For the solvent of 30 to 70 weight %.Preferably, coating composition can be 30 comprising the gross weight relative to the coating composition
To the solvent of 65 weight %, the more preferably solvent of 35 to 55 weight %, will also more preferably 40 to 50 weight % solvent, will also be more
It is preferred that the solvent of 45 to 50 weight %.However, in coating composition, the consumption of solvent is not limited thereto, can be according to institute's phase
The viscosity of the coating composition of prestige is determined by conventional laboratory techniques by those skilled in the art.
Herein, term " texturisers " is to refer to give the visible stricture of vagina of coating naked eyes formed by coating composition
The additive of reason structure.In the present invention, texturisers are soluble in the crystalline compounds of the solvent.
Term " naked eyes are visible " is in this article referred to, any regular or irregular texture for producing on the coating surface
Structure all can be arrived by naked-eye observation, without the auxiliary of the instruments such as microscope.Herein, " dissolve in the solvent
Crystalline compounds " are soluble in the solvent of coating composition of the present invention, and can be from solution state after application
For example crystallized into by operating procedures such as solvent volatilization, temperature adjustments and there is certain macromorphologic solid, so as to give
The macroscopic texture structure of coating of formation.
In a preferred embodiment of the invention, the crystallised compound for dissolving in the solvent for using as texturisers
Thing includes condensed-nuclei aromatics, i.e. the chemical combination formed in the way of sharing two adjacent carbon atoms by two or more phenyl ring
Thing, the example include naphthalene, anthracene, phenanthrene, aphthacene, Benzo[b, rubrene or its combination in any.
It is not intended to be entangled in any theory, according to the present invention, wherein the Coating material composition containing soluble crystalline compound
After application to the substrate, the crystalline compounds are crystallized with the evaporation of solvent and form macroscopic stricture of vagina thing
Reason structure, is preferably formed as macroscopic 3D texture structures, more preferably forms the 3D texture structures of featheriness or year colyliform.Cause
This, according to the present invention, the formation of macroscopic texture structure does not rely on the viscosity or addition particle diameter for improving coating composition
More than the inorganic solid particles of coating layer thickness.And, crystalline compounds are can dissolve in a solvent, so the presence of crystalline compounds
Also appreciable impact will not be brought to the viscosity of coating composition, and painting can be adjusted conveniently by the consumption of regulation solvent
The viscosity of feed composition.Preferred implementation of the invention, according to standard testing GB/T1723-93 methods determine this
The viscosity of bright coating composition is in the range of 500 to 2000mPas, thus this low viscous coating composition can pass through
Typical spray technology is sprayed, spin coating, roller coat, dip-coating etc. are coated on base material.This coating composition of the present invention is not only
The coating with naked eyes visible texture structure can be obtained, and it is visible with naked eyes to obtain to overcome existing coating composition
The coating of texture structure and the defect being coated using Typical spray technology or cannot be difficult to, simplify operating procedure and carry
High production efficiency.
In a preferred embodiment of the invention, coating composition can be comprising the gross weight relative to the coating composition
For the texturisers of 5 to 50 weight %.Preferably, coating composition can be comprising the gross weight relative to the coating composition
For the texturisers of 10 to 45 weight %, more preferably texturisers of 15 to 40 weight % will also more preferably 20 to 30 weights
The texturisers of amount %, the even more preferably texturisers of 20 to 25 weight %.
Alternatively, coating composition of the invention can also include one or more conventional additives as needed.
Representative conventional additives include rheological agent, surfactant, defoamer, wetting agent, light stabilizer, antioxidant with
And other any applicable conventional additives.The purposes and consumption of these conventional additives is for those of ordinary skills
It is known.
In a preferred embodiment of the invention, coating composition can be comprising the gross weight relative to the coating composition
For one or more conventional additives of 0 to 5 weight %.Specifically, filled compositions can be comprising relative to the coating group
The gross weight of compound is 0.5 to 4 weight %, 0.5 to 3 weight %, 0.5 to 2 weight %, the conventional additives of 0.5 to 1 weight %.
Preparing for the coating composition of the present invention can be using the system of compositionss well known to those of ordinary skill in the art
Preparation Method is carrying out.For example can be using pony mixer, roll-type blender and those of ordinary skill in the art
Know any other paint mixing device suitable for dispersive composition by each component coating composition while being mixed
So as to form coating composition, or first part film-forming resin is uniformly mixed with solvent, then add part film-forming resin, texture
Forming agent, conventional additives and added solvent are so as to forming coating composition.
In a preferred embodiment of the invention, there is provided a kind of coating composition, the coating composition is relative to institute
The gross weight for stating coating composition is included：
The film-forming resin of 5 to 50 weight %；
The solvent of 30 to 60 weight %；
The texturisers of 5 to 50 weight %；With
The additional additives of 0 to 5 weight %.
The present invention more preferably embodiment in, there is provided a kind of coating composition, the coating composition relative to
The gross weight of the coating composition is included：
The film-forming resin of 20 to 30 weight %；
The solvent of 45 to 55 weight %；
The texturisers of 5 to 50 weight %；With
The additional additives of 0.1 to 2 weight %.
In embodiments of the present invention, viscosity of the coating composition in standard testing GB/T1723-93 500 to
2000mPa.s in the range of.
Present invention also offers a kind of coating, the coating is made up of the coating composition of the present invention, and has naked eyes
Visible texture structure.In a preferred embodiment, the coating has macroscopic 3D texture structures.Preferred
In embodiment, the coating has the 3D texture structures of featheriness or year colyliform.
Present invention also offers a kind of method for preparing the coating with naked eyes visible texture, methods described includes following step
Suddenly：
A) aforementioned coating composition is provided,
B) coated and dried gained coating composition, so as to obtain the coating with naked eyes visible texture structure.
The coating composition of the present invention can be applied to acceptable substrate (such as metal, timber, building materials, plastics, leather, paper
, glass etc.) on form coating, so as to provide protective effect, and decoration function for base material.Preferably, coating of the invention
Compositionss can be used for being coated with furniture, construction material, metallic article, plastic, leatherware, paper, glass etc..
The present invention is further elaborated by following examples, but the invention is not limited in this.Unless otherwise sound
Bright, all percentage rate are by weight.
Embodiment 1
Table 1
| Component | Percentage by weight % | Source |
| Alkyd resin Novalkyd 3911X70 | 20 | Dutch DSM N. V. |
| 1/2s celluloid | 7.5 | Luzhou Chemical Plant |
| Butyl acetate | 17.5 | General industry product |
| Ketohexamethylene | 25 | General industry product |
| Ethanol | 6.5 | General industry product |
| Naphthalene | 23 | General industry product |
| Defoamer | 0.5 | German BYK companies |
| Total amount | 100 |
Embodiment 2
Table 2
| Component | Percentage by weight % | Source |
| Alkyd resin Novalkyd 3911X70 | 25 | Dutch DSM N. V. |
| 1/2s celluloid | 8 | Luzhou Chemical Plant |
| Butyl acetate | 19 | General industry product |
| Ketohexamethylene | 14.5 | General industry product |
| Ethanol | 5 | General industry product |
| Naphthalene | 28 | General industry product |
| Defoamer | 0.5 | German BYK companies |
| Total amount | 100 |
Embodiment 3
Table 3
| Component | Percentage by weight % | Source |
| Alkyd resin Novalkyd 3911X70 | 15 | Dutch DSM N. V. |
| 1/2s celluloid | 8 | Luzhou Chemical Plant |
| Butyl acetate | 35.7 | General industry product |
| Ketohexamethylene | 20 | General industry product |
| Ethanol | 6 | General industry product |
| Anthracene | 15 | General industry product |
| Defoamer | 0.3 | German BYK companies |
| Total amount | 100 |
Embodiment 4
Table 4
| Component | Percentage by weight % | Source |
| Alkyd resin Novalkyd 3911X70 | 20 | Dutch DSM N. V. |
| 1/2s celluloid | 10 | Luzhou Chemical Plant |
| Butyl acetate | 20 | General industry product |
| Ketohexamethylene | 18 | General industry product |
| Ethanol | 7 | General industry product |
| Anthracene | 25 | General industry product |
| Defoamer | 0.5 | German BYK companies |
| Total amount | 100 |
Each component in table 1 to table 4 is uniformly mixed, so as to form coating composition..
After the coating composition of above example 1 is sprayed on base material, process is dried to which, is as a result had
There is the coating of the visible 3D texture structures of the naked eyes shown in Fig. 1 and Fig. 2.Fig. 1 represents the featheriness formed under the conditions of coating is thicker
Texture structure.Fig. 2 represents the year colyliform texture structure formed under the conditions of coating is relatively thin.As can be seen here, coating group of the invention
Compound not only can obtain the coating of macroscopic 3D texture structures, can also adopt conventional coating techniques, for example, spray, enter
Row coating.
In the case of to depart from the present invention, various amendments are carried out to the present invention and is changed for a person skilled in the art
It is obvious.It is to be appreciated, therefore, that the invention is not limited in illustrative above embodiment.
Claims (14)
1. a kind of method for preparing the coating with naked eyes visible texture structure, methods described comprise the steps：
A) coating composition is provided,
B) coated and dried gained coating composition, so as to obtain the coating with naked eyes visible texture structure,
Wherein, the coating composition is included：
Film-forming resin；
Solvent；
Texturisers；With
Optional additional additives,
Wherein, the crystalline compounds for dissolving in the solvent are used as the texturisers.
2. method as claimed in claim 1, wherein, the texturisers include condensed-nuclei aromatics.
3. method as claimed in claim 2, wherein, the texturisers include naphthalene, anthracene, phenanthrene, aphthacene, Benzo[b, rubrene
Or its combination in any.
4. such as the method for any one in claims 1 to 3, wherein, the coating composition is included, relative to the coating group
The gross weight of compound,
The film-forming resin of 5 to 50 weight %；
The solvent of 30 to 70 weight %；
The texturisers of 5 to 50 weight %；With
The additional additives of 0 to 5 weight %.
5. such as the method for any one in claims 1 to 3, wherein, the coating composition is included, relative to the coating group
The gross weight of compound,
The film-forming resin of 20 to 30 weight %；
The solvent of 40 to 65 weight %；
The texturisers of 5 to 50 weight %；With
The additional additives of 0.1 to 2 weight %.
6. such as the method for any one in claims 1 to 3, wherein, the film-forming resin includes, rosin resin, alkyd tree
Fat, phenolic resin, amino resins, polyester resin, acrylic resin, epoxy resin, polyurethane resin, carbamide resin, polyene
Hydrocarbon resin, nitrocellulose resin, organic siliconresin or its combination in any.
7. such as the method for any one in claims 1 to 3, wherein, the film-forming resin includes alkyd resin, celluloid
Resin or its combination.
8. method as claimed in claim 7, wherein, the alkyd resin includes short oil-ity alcohol acid resin.
9. such as the method for any one in claims 1 to 3, wherein, the solvent includes esters solvent, alcohols solvent, ethers
Solvent, ketones solvent, varsol or its combination in any.
10. method as claimed in claim 9, wherein, the solvent includes methyl acetate, ethyl acetate, butyl acetate, acetic acid isoamyl
Ester, ethanol, normal propyl alcohol, isopropanol, n-butyl alcohol, isobutanol, ether, butyl ether, methyl ethyl ether, acetone, butanone, Ketohexamethylene, oneself
Alkane, heptane, toluene, dimethylbenzene, chlorobenzene or its combination in any.
The method of any one in 11. such as claims 1 to 3, wherein, the additional additives include rheological agent, surface activity
Agent, defoamer, wetting agent, light stabilizer, antioxidant or its combination in any.
12. such as methods of any one in claims 1 to 3, wherein, the viscosity of the coating composition 500 to
2000mPa.s in the range of.
13. the method for claim 1, wherein the coating has macroscopic 3D texture structures.
14. the method for claim 1, wherein the coating has the 3D texture structures of featheriness or year colyliform.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110157710.1A CN102807780B (en) | 2011-06-01 | 2011-06-01 | Coating composition and coat obtained therefrom |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110157710.1A CN102807780B (en) | 2011-06-01 | 2011-06-01 | Coating composition and coat obtained therefrom |
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| CN102807780B true CN102807780B (en) | 2017-05-03 |
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Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3024899A1 (en) * | 2013-07-26 | 2016-06-01 | Akzo Nobel Coatings International B.V. | High solids coating composition comprising an alkyd resin and isoamyl acetate |
| CN103450750A (en) * | 2013-08-23 | 2013-12-18 | 吴江龙硕金属制品有限公司 | Metal anticorrosive coating and preparation method thereof |
| CN103897593A (en) * | 2014-02-26 | 2014-07-02 | 施俊杰 | Method for preparing environment-friendly coating |
| CN105273589A (en) * | 2014-06-29 | 2016-01-27 | 江苏飞翔涂料实业总公司 | Quick-drying type coating for automobile bumper |
| CN104592814B (en) * | 2015-01-09 | 2017-01-25 | 芜湖航天特种电缆厂股份有限公司 | Insulating paint composition and method for preparing insulating paint |
| CN104592813B (en) * | 2015-01-09 | 2017-01-25 | 芜湖航天特种电缆厂股份有限公司 | Insulating coating and preparation method thereof |
| CN105017865A (en) * | 2015-07-29 | 2015-11-04 | 广西梧州龙鱼漆业有限公司 | Wear-resistant wood finish paint |
| KR102554958B1 (en) * | 2021-03-05 | 2023-07-13 | 울산대학교 산학협력단 | Spray coating composition for 3D scanning |
| CN113667359B (en) * | 2021-04-25 | 2022-08-02 | 肇庆市哈力化工有限公司 | Strong-universality ABS plastic piece special-purpose crack effect paint and preparation method thereof |
| CN114806287B (en) * | 2021-05-26 | 2023-04-18 | 肇庆市哈力化工有限公司 | Transparent ball internal coating feather paint and preparation method thereof |
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| US2390887A (en) * | 1943-03-02 | 1945-12-11 | Chalmers F Landrey | Coating compositions |
| SU553270A1 (en) * | 1974-04-05 | 1977-04-05 | Воронежский завод синтетического каучука им.С.М.Кирова | Coating composition |
| CN1394693A (en) * | 2001-06-29 | 2003-02-05 | 关西油漆株式会社 | Multi-colour figure film forming method |
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| JPH11172196A (en) * | 1997-12-09 | 1999-06-29 | Kano Diamant:Kk | Coating composition for forming frost pattern and production of glass plate having frost pattern coating film |
| CN1074031C (en) * | 1998-11-17 | 2001-10-31 | 张炼 | Surface corrosion-resistant and water-proof treating process and surface treating agent |
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|---|---|---|---|---|
| US2390887A (en) * | 1943-03-02 | 1945-12-11 | Chalmers F Landrey | Coating compositions |
| SU553270A1 (en) * | 1974-04-05 | 1977-04-05 | Воронежский завод синтетического каучука им.С.М.Кирова | Coating composition |
| CN1394693A (en) * | 2001-06-29 | 2003-02-05 | 关西油漆株式会社 | Multi-colour figure film forming method |
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| CN102807780A (en) | 2012-12-05 |
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