CN102796256A - 聚丙烯增韧浇铸尼龙及其制备方法 - Google Patents
聚丙烯增韧浇铸尼龙及其制备方法 Download PDFInfo
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- CN102796256A CN102796256A CN2012102899183A CN201210289918A CN102796256A CN 102796256 A CN102796256 A CN 102796256A CN 2012102899183 A CN2012102899183 A CN 2012102899183A CN 201210289918 A CN201210289918 A CN 201210289918A CN 102796256 A CN102796256 A CN 102796256A
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- Prior art keywords
- polypropylene
- nylon
- monomer
- crosslinked
- crosslinked polypropylene
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- 239000004743 Polypropylene Substances 0.000 title claims abstract description 170
- 239000004677 Nylon Substances 0.000 title claims abstract description 147
- 229920001778 nylon Polymers 0.000 title claims abstract description 147
- -1 Polypropylene Polymers 0.000 title claims abstract description 145
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 145
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 238000002156 mixing Methods 0.000 claims abstract description 32
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical group O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000006243 chemical reaction Methods 0.000 claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 12
- 230000005855 radiation Effects 0.000 claims abstract description 12
- 239000003999 initiator Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000001291 vacuum drying Methods 0.000 claims description 45
- 239000000843 powder Substances 0.000 claims description 42
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 claims description 22
- 239000007787 solid Substances 0.000 claims description 20
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical group S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 15
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical group CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 12
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 9
- SSVFMICWXDVRQN-UHFFFAOYSA-N ethanol;sodium Chemical compound [Na].CCO SSVFMICWXDVRQN-UHFFFAOYSA-N 0.000 claims description 9
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 229910000077 silane Inorganic materials 0.000 claims description 9
- 102220040412 rs587778307 Human genes 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical group C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- GUTLYIVDDKVIGB-OUBTZVSYSA-N Cobalt-60 Chemical compound [60Co] GUTLYIVDDKVIGB-OUBTZVSYSA-N 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 230000004927 fusion Effects 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000007654 immersion Methods 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 17
- 238000005266 casting Methods 0.000 abstract description 4
- 238000012545 processing Methods 0.000 abstract description 2
- 230000003213 activating effect Effects 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 238000010382 chemical cross-linking Methods 0.000 abstract 1
- 238000005299 abrasion Methods 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- IXSZQYVWNJNRAL-UHFFFAOYSA-N etoxazole Chemical group CCOC1=CC(C(C)(C)C)=CC=C1C1N=C(C=2C(=CC=CC=2F)F)OC1 IXSZQYVWNJNRAL-UHFFFAOYSA-N 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Polyamides (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201210289918.3A CN102796256B (zh) | 2012-08-15 | 2012-08-15 | 聚丙烯增韧浇铸尼龙及其制备方法 |
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CN201210289918.3A CN102796256B (zh) | 2012-08-15 | 2012-08-15 | 聚丙烯增韧浇铸尼龙及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN102796256A true CN102796256A (zh) | 2012-11-28 |
CN102796256B CN102796256B (zh) | 2014-05-28 |
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CN201210289918.3A Active CN102796256B (zh) | 2012-08-15 | 2012-08-15 | 聚丙烯增韧浇铸尼龙及其制备方法 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103396663A (zh) * | 2013-08-13 | 2013-11-20 | 株洲时代新材料科技股份有限公司 | 一种汽车横向限位板及其制备方法 |
CN105131278A (zh) * | 2015-09-21 | 2015-12-09 | 张文哲 | 一种高性能浇筑尼龙及其制备方法 |
CN108641351B (zh) * | 2018-04-09 | 2020-01-21 | 安徽建筑大学 | 一种粉末化聚乙烯增韧浇铸尼龙的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102146160A (zh) * | 2011-01-24 | 2011-08-10 | 淮安市山阳工矿塑料有限公司 | 一种改性浇铸尼龙 |
CN102234421A (zh) * | 2010-04-26 | 2011-11-09 | 扬州赛尔达尼龙制造有限公司 | 一种纳米氧化钐改性mc尼龙滑块及其生产工艺 |
US20120053273A1 (en) * | 2009-05-04 | 2012-03-01 | Ching Fong Hon | High Wear-Resistant Nylon Composite Material For Rollers On Airport Freight Vehicles And Preparation Method Thereof |
CN102391642A (zh) * | 2011-08-31 | 2012-03-28 | 李刚 | 改性mc尼龙6共混材料的制备方法 |
-
2012
- 2012-08-15 CN CN201210289918.3A patent/CN102796256B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120053273A1 (en) * | 2009-05-04 | 2012-03-01 | Ching Fong Hon | High Wear-Resistant Nylon Composite Material For Rollers On Airport Freight Vehicles And Preparation Method Thereof |
CN102234421A (zh) * | 2010-04-26 | 2011-11-09 | 扬州赛尔达尼龙制造有限公司 | 一种纳米氧化钐改性mc尼龙滑块及其生产工艺 |
CN102146160A (zh) * | 2011-01-24 | 2011-08-10 | 淮安市山阳工矿塑料有限公司 | 一种改性浇铸尼龙 |
CN102391642A (zh) * | 2011-08-31 | 2012-03-28 | 李刚 | 改性mc尼龙6共混材料的制备方法 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103396663A (zh) * | 2013-08-13 | 2013-11-20 | 株洲时代新材料科技股份有限公司 | 一种汽车横向限位板及其制备方法 |
CN103396663B (zh) * | 2013-08-13 | 2016-12-28 | 株洲时代新材料科技股份有限公司 | 一种汽车横向限位板及其制备方法 |
CN105131278A (zh) * | 2015-09-21 | 2015-12-09 | 张文哲 | 一种高性能浇筑尼龙及其制备方法 |
CN108641351B (zh) * | 2018-04-09 | 2020-01-21 | 安徽建筑大学 | 一种粉末化聚乙烯增韧浇铸尼龙的制备方法 |
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Publication number | Publication date |
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CN102796256B (zh) | 2014-05-28 |
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Effective date of registration: 20170125 Address after: 225816 Baoying Economic Development Zone, Jiangsu Patentee after: Jiangsu Leader Technical Plastic Co., Ltd. Address before: 225800 Jin Yuan Road, Baoying, Jiangsu Yi Industrial Zone, Yangzhou, No. 1 Patentee before: Yangzhou Saierda Nylon Manufacture Co., Ltd. |
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Effective date of registration: 20181122 Address after: 225816 Hexiang Road 899, Baoying Economic Development Zone, Yangzhou City, Jiangsu Province Patentee after: Jiangsu Liddell new Mstar Technology Ltd Address before: 225816 Jiangsu Baoying Economic Development Zone Patentee before: Jiangsu Leader Technical Plastic Co., Ltd. |
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Denomination of invention: Polypropylene toughened cast nylon and its preparation method Effective date of registration: 20190103 Granted publication date: 20140528 Pledgee: Baoying Branch of Bank of China Limited Pledgor: Jiangsu Liddell new Mstar Technology Ltd Registration number: 2019320000002 |
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Date of cancellation: 20200109 Granted publication date: 20140528 Pledgee: Baoying Branch of Bank of China Limited Pledgor: Jiangsu Liddell new Mstar Technology Ltd Registration number: 2019320000002 |
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Denomination of invention: Polypropylene toughened cast nylon and its preparation method Effective date of registration: 20200212 Granted publication date: 20140528 Pledgee: Baoying Branch of Bank of China Limited Pledgor: Jiangsu Liddell new Mstar Technology Ltd Registration number: Y2020980000231 |
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Date of cancellation: 20201208 Granted publication date: 20140528 Pledgee: Baoying Branch of Bank of China Ltd. Pledgor: JIANGSU LEADER NEW MATERIALS TECHNOLOGY Co.,Ltd. Registration number: Y2020980000231 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
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Denomination of invention: Polypropylene Toughened cast nylon and its preparation method Effective date of registration: 20201211 Granted publication date: 20140528 Pledgee: Baoying Branch of Bank of China Ltd. Pledgor: JIANGSU LEADER NEW MATERIALS TECHNOLOGY Co.,Ltd. Registration number: Y2020980009177 |
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Date of cancellation: 20220119 Granted publication date: 20140528 Pledgee: Baoying Branch of Bank of China Ltd. Pledgor: JIANGSU LEADER NEW MATERIALS TECHNOLOGY Co.,Ltd. Registration number: Y2020980009177 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Polypropylene Toughened cast nylon and its preparation method Effective date of registration: 20220120 Granted publication date: 20140528 Pledgee: Baoying Branch of Bank of China Ltd. Pledgor: JIANGSU LEADER NEW MATERIALS TECHNOLOGY Co.,Ltd. Registration number: Y2022980000795 |