CN102775640A - 官能化的纳米颗粒 - Google Patents
官能化的纳米颗粒 Download PDFInfo
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- CN102775640A CN102775640A CN201210146897XA CN201210146897A CN102775640A CN 102775640 A CN102775640 A CN 102775640A CN 201210146897X A CN201210146897X A CN 201210146897XA CN 201210146897 A CN201210146897 A CN 201210146897A CN 102775640 A CN102775640 A CN 102775640A
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- Prior art keywords
- group
- alkyl
- phenyl
- nano particle
- hydrogen
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- 239000002105 nanoparticle Substances 0.000 title claims abstract description 142
- -1 polyazo Polymers 0.000 claims abstract description 293
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 119
- 239000000975 dye Substances 0.000 claims abstract description 81
- 239000001257 hydrogen Substances 0.000 claims abstract description 72
- 125000002091 cationic group Chemical group 0.000 claims abstract description 16
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims abstract description 10
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 claims abstract description 6
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 claims abstract description 5
- 239000001000 anthraquinone dye Substances 0.000 claims abstract description 4
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 claims abstract description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 82
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- 239000000126 substance Substances 0.000 claims description 63
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- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 43
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- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 20
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- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 claims description 2
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- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
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- 239000000377 silicon dioxide Substances 0.000 abstract description 14
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- 238000010671 solid-state reaction Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000003351 stiffener Substances 0.000 description 1
- 239000012258 stirred mixture Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical compound O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 description 1
- 125000004646 sulfenyl group Chemical group S(*)* 0.000 description 1
- 239000012747 synergistic agent Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
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- 125000004627 thianthrenyl group Chemical group C1(=CC=CC=2SC3=CC=CC=C3SC12)* 0.000 description 1
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- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 125000004306 triazinyl group Chemical group 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
- 238000002371 ultraviolet--visible spectrum Methods 0.000 description 1
- 238000000584 ultraviolet--visible--near infrared spectrum Methods 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
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- 150000003751 zinc Chemical class 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- WGVKWNUPNGFDFJ-DQCZWYHMSA-N β-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C WGVKWNUPNGFDFJ-DQCZWYHMSA-N 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
- 239000002446 δ-tocopherol Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/10—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds
- C09B69/103—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds containing a diaryl- or triarylmethane dye
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0097—Dye preparations of special physical nature; Tablets, films, extrusion, microcapsules, sheets, pads, bags with dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B68/00—Organic pigments surface-modified by grafting, e.g. by establishing covalent or complex bonds, in order to improve the pigment properties, e.g. dispersibility or rheology
- C09B68/20—Organic pigments surface-modified by grafting, e.g. by establishing covalent or complex bonds, in order to improve the pigment properties, e.g. dispersibility or rheology characterised by the process features
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B68/00—Organic pigments surface-modified by grafting, e.g. by establishing covalent or complex bonds, in order to improve the pigment properties, e.g. dispersibility or rheology
- C09B68/40—Organic pigments surface-modified by grafting, e.g. by establishing covalent or complex bonds, in order to improve the pigment properties, e.g. dispersibility or rheology characterised by the chemical nature of the attached groups
- C09B68/44—Non-ionic groups, e.g. halogen, OH or SH
- C09B68/443—Carboxylic acid derivatives, e.g. carboxylic acid amides, carboxylic acid esters or CN groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/10—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/12—Treatment with organosilicon compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Silicon Compounds (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Applications Claiming Priority (2)
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| EP05104541 | 2005-05-27 | ||
| EP05104541.7 | 2005-05-27 |
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| CN2006800186080A Division CN101184803B (zh) | 2005-05-27 | 2006-05-17 | 官能化的纳米颗粒 |
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| CN102775640A true CN102775640A (zh) | 2012-11-14 |
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| CN2006800186080A Expired - Fee Related CN101184803B (zh) | 2005-05-27 | 2006-05-17 | 官能化的纳米颗粒 |
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| US (1) | US20090099282A1 (enExample) |
| EP (1) | EP1883676A1 (enExample) |
| JP (1) | JP5068746B2 (enExample) |
| KR (1) | KR20080027791A (enExample) |
| CN (2) | CN102775640A (enExample) |
| CA (1) | CA2608576A1 (enExample) |
| WO (1) | WO2006125736A1 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109370265A (zh) * | 2018-10-12 | 2019-02-22 | 安庆北化大科技园有限公司 | 一种纳米二氧化硅的表面亲油改性方法及由该法制得的亲油纳米二氧化硅 |
| CN110642258A (zh) * | 2019-10-12 | 2020-01-03 | 大连理工大学 | 一种可降低细胞毒性及官能团密度可控的纳米二氧化硅及其制备方法 |
| CN112961547A (zh) * | 2021-02-01 | 2021-06-15 | 山西吸睛科技有限公司 | 一种可回收保膜剂及其制备方法和应用 |
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|---|---|---|---|---|
| US20060045822A1 (en) | 2004-09-01 | 2006-03-02 | Board Of Regents, The University Of Texas System | Plasma polymerization for encapsulating particles |
| KR20080027791A (ko) * | 2005-05-27 | 2008-03-28 | 시바 스페셜티 케미칼스 홀딩 인크. | 관능화된 나노입자 |
| KR101388355B1 (ko) * | 2005-11-10 | 2014-04-22 | 후지필름 가부시키가이샤 | 조성물, 필름 및 액정 디스플레이 |
| US20100119697A1 (en) * | 2006-05-10 | 2010-05-13 | 3M Innovative Properties Company | Compositions and coatings containing fluorescent, inorganic nanoparticles |
| JP2010520508A (ja) * | 2007-03-05 | 2010-06-10 | ビーエーエスエフ ソシエタス・ヨーロピア | カラーフィルタ中で使用するためのカチオン性着色剤を含む表面変性されたナノ粒子 |
| FR2914656A1 (fr) * | 2007-04-03 | 2008-10-10 | Commissariat Energie Atomique | Procede de modification de fibres d'aramide et procede de teinture de ces fibres |
| EP2144918B1 (en) | 2007-05-11 | 2010-11-17 | Basf Se | Functionalized nanoparticles |
| JP5518697B2 (ja) * | 2007-05-11 | 2014-06-11 | ビーエーエスエフ ソシエタス・ヨーロピア | 高分子色素 |
| WO2009019135A1 (en) * | 2007-08-03 | 2009-02-12 | Basf Se | Fluorescent whitening nanoparticles |
| US8304242B2 (en) * | 2007-12-17 | 2012-11-06 | Life Technologies Corporation | Methods for detecting defects in inorganic-coated polymer surfaces |
| WO2009114834A2 (en) | 2008-03-13 | 2009-09-17 | Board Of Regents, The University Of Texas System | Covalently functionalized particles for synthesis of new composite materials |
| NO328788B1 (no) | 2008-03-14 | 2010-05-18 | Jotun As | Bindemiddel til lufttørkende maling |
| US8123344B2 (en) | 2008-08-04 | 2012-02-28 | Xerox Corporation | Ink carriers containing surface modified nanoparticles, phase change inks including same, and methods for making same |
| US8563110B2 (en) * | 2008-09-12 | 2013-10-22 | Brigham Young University | Optical data media containing an ultraviolet protection layer |
| US8568957B2 (en) * | 2008-10-23 | 2013-10-29 | Brigham Young University | Data storage media containing inorganic nanomaterial data layer |
| KR101462657B1 (ko) | 2008-12-19 | 2014-11-17 | 삼성전자 주식회사 | 반도체 나노 결정 복합체 |
| EP2449015A1 (en) * | 2009-06-30 | 2012-05-09 | 3M Innovative Properties Company | Transparent fluorescent structures with improved fluorescence using nanoparticles, methods of making, and uses |
| TW201114437A (en) * | 2009-10-20 | 2011-05-01 | Univ Nat Chiao Tung | Magnetic nanoparticles for magnetic resonace imaging |
| WO2011054731A1 (en) | 2009-11-05 | 2011-05-12 | Basf Se | Fluorescent materials |
| KR101068500B1 (ko) * | 2010-03-18 | 2011-09-29 | 경상대학교산학협력단 | 수은 및 유기수은을 고효율적으로 분리 및 검출 가능한 아미노나프탈이미드기를 함유하는 자성체 나노입자 |
| WO2012111452A1 (ja) * | 2011-02-17 | 2012-08-23 | 日本アエロジル株式会社 | 表面改質シリカ粉末及びその製造方法並びに電子写真用トナー組成物 |
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| CN102618258A (zh) * | 2012-02-23 | 2012-08-01 | 常州天合光能有限公司 | 一种纳米荧光颗粒及其制备方法和应用 |
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| GB948163A (en) * | 1960-10-31 | 1964-01-29 | Ici Ltd | Improvements in or relating to fillers, pigments and like materials |
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- 2006-05-17 KR KR1020077030372A patent/KR20080027791A/ko not_active Abandoned
- 2006-05-17 US US11/920,295 patent/US20090099282A1/en not_active Abandoned
- 2006-05-17 CN CN201210146897XA patent/CN102775640A/zh active Pending
- 2006-05-17 CA CA002608576A patent/CA2608576A1/en not_active Abandoned
- 2006-05-17 WO PCT/EP2006/062357 patent/WO2006125736A1/en not_active Ceased
- 2006-05-17 CN CN2006800186080A patent/CN101184803B/zh not_active Expired - Fee Related
- 2006-05-17 JP JP2008512804A patent/JP5068746B2/ja not_active Expired - Fee Related
- 2006-05-17 EP EP06755220A patent/EP1883676A1/en not_active Withdrawn
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109370265A (zh) * | 2018-10-12 | 2019-02-22 | 安庆北化大科技园有限公司 | 一种纳米二氧化硅的表面亲油改性方法及由该法制得的亲油纳米二氧化硅 |
| CN109370265B (zh) * | 2018-10-12 | 2021-04-06 | 安庆北化大科技园有限公司 | 一种纳米二氧化硅的表面亲油改性方法及由该法制得的亲油纳米二氧化硅 |
| CN110642258A (zh) * | 2019-10-12 | 2020-01-03 | 大连理工大学 | 一种可降低细胞毒性及官能团密度可控的纳米二氧化硅及其制备方法 |
| CN110642258B (zh) * | 2019-10-12 | 2022-10-21 | 大连理工大学 | 一种可降低细胞毒性及官能团密度可控的纳米二氧化硅及其制备方法 |
| CN112961547A (zh) * | 2021-02-01 | 2021-06-15 | 山西吸睛科技有限公司 | 一种可回收保膜剂及其制备方法和应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101184803B (zh) | 2013-11-06 |
| WO2006125736A1 (en) | 2006-11-30 |
| CN101184803A (zh) | 2008-05-21 |
| CA2608576A1 (en) | 2006-11-30 |
| JP5068746B2 (ja) | 2012-11-07 |
| EP1883676A1 (en) | 2008-02-06 |
| KR20080027791A (ko) | 2008-03-28 |
| US20090099282A1 (en) | 2009-04-16 |
| JP2008545606A (ja) | 2008-12-18 |
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