CN102767078A - Special process finished chitosan antibacterial and deodorant health care sock - Google Patents
Special process finished chitosan antibacterial and deodorant health care sock Download PDFInfo
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- CN102767078A CN102767078A CN2012101621293A CN201210162129A CN102767078A CN 102767078 A CN102767078 A CN 102767078A CN 2012101621293 A CN2012101621293 A CN 2012101621293A CN 201210162129 A CN201210162129 A CN 201210162129A CN 102767078 A CN102767078 A CN 102767078A
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Abstract
The present invention relates to a special process finished chitosan antibacterial and deodorant health care sock, and is characterized by providing a chitosan biological gel finishing agent and a special finishing process. Experiments have proved that the chitosan antibacterial and deodorant health care sock has stable effective components, substantial sterilization and deodorization effect, and sterilization rate on Escherichia coli, staphylococcus aureus and Candida albicans reaching higher than 98%; the chitosan antibacterial and deodorant health care sock has lasting effect and long shelf life, maintains 50% of the sterilizing effect after 15 times of washing, and is convenient for usage and without toxic or side effect on human body; and the chitosan antibacterial and deodorant health care sock has effects of sterilizing, relieving itching, removing dampness and moisturizing feet, can be widely used in the prevention and treatment of foot disease and foot health care to improve and protect the quality of life, and is applicable to people with foot skin pruritus, beriberi and stinky feet, and especially suitable for adolescent stinky feet caused by long-term wearing of rubber overshoes, stinky feet and beriberi in people with occupations requiring long-term walking, such as soldiers, athletes and construction workers, and for foot health care for elderly people doing outdoor sports, etc.
Description
Technical field the present invention relates to the health-care deodorized socks of a kind of special process arrangement chitosan anti-bacteria.It is characterized in that having invented a kind of shitosan biogel finishing agent and special finishing technique.The effective ingredient of shitosan biogel finishing agent prescription is a water soluble chitosan; High bioactivity crosslinking agent TMDM, bleeding agent 8861, biological softener DH20; It is composite synthetic that organosilicon quaternary ammonium salt CH168, polyethylene emulsion etc. are pressed different proportion; This finishing agent is hydrolyzed to gel in neutral environment, have antibiotic, deodorization, washable, soft usefulness.Special finishing technique is the finished product socks to be soaked two through this biogel finishing agent two roll and increase temperature infusion process technology; Two soak two rolls and increases temperature dipping; The finished product socks are soaked two through biogel finishing agent two to be rolled and increases temperature infusion process technology, biogel finishing agent 4-5g/l, ph=6-7; Pick-up 70%-80% is again through the 110-130 ℃ of crosslinked 5min. of drying; High temperature dipping biogel finishing agent 2-3%, 130 ℃ of temperature, handle 30min, bath raio 15-20: 1, the dehydration back is dried under 80-110 ℃ of condition and is got final product.This technology has than vegetative effect on the stronger inhibition fiber of common antibacterial deodourizing processing. press jis-10217 (103) method washing 10 times; The logarithm value of bactericidal activity. reach the standard of Japanese fine skill (jafet) sek of association (processing of system bacterium) orange monopoly trademark (generally home-use); Its LD50 is greater than 10g/kg; Belong to actual nontoxic level., skin is not also had obvious irritation and do not present the allergy of skin, be the novel health-care deodorized socks of antibiotic health of a kind of safety.Chitin is a kind of natural polysaccharide; Frenchman Braconnot proposed the plain material of a kind of like fibrous from mushroom in 1811; Because of it is present in lower animal particularly in the crust of arthropod such as shrimp, crab etc. in a large number,, have another name called chitin, glutelin so be commonly called as chitin.At occurring in nature, estimate 10,000,000,000 tons of annual biosynthetic chitins nearly, distribute extensively, comprise in the cell membrane of arthropod, mollusk etc. and rudimentary plant such as fungi, algae.In the natural organic matter that exists on earth, chitin is only second to cellulose, also is simultaneously the outer the highest natural organic matter of nitrogen content of isolating protein, it serves to show that it is a kind of inexhaustible, nexhaustible regenerated resources.Shitosan then is that chitin is separated the water-soluble products that deacetylation generates through strong lye, is a kind of important derivatives of chitin.See that from structure the chemical constitution of chitin is similar with native cellulose, difference is that cellulose is a hydroxyl on 2, and chitin is an acetamido on 2, and shitosan is an amido on 2 then.Chitin is that many N-acetyl group-D-amido glucose is through β-1, the straight chain polymer polysaccharide that 4-glucoside key couples together.Biogel finishing agent of the present invention is a water soluble chitosan, high bioactivity crosslinking agent TMDM, bleeding agent 8861, biological softener DH20, and organosilicon quaternary ammonium salt CH168, polyethylene emulsion are hydrolyzed to gel in neutral environment.Do not contain any chemical composition, through the strict screening of experiment compatibility, the compound action effect is good; Form through the special process configuration, making, easy to use is to the human non-toxic side effect; Have the effect of sterilizing and itch-relieving, clearing damp profit foot, can be widely used in the common people and prevent and treat pedopathy and health spats, improve and the protection life quality; Be applicable to pedal skin itch, the smelly crowd of beriberi pin, especially being fit to the teenager, to wear the pin that rubber overshoes cause for a long time smelly; The crowd's of various long-term walking occupations such as army, sportsman, builder the smelly and beriberi disease of pin; The crowd of the elderly's outdoor exercises person's health spats etc.
Background technology people's living standard is along with the development of society improves day by day; And increasing people is with the quickening of rhythm of life; The pressure that comes from aspects such as society, work, life is increasing, and the incidence of disease of various diseases is increasingly high, and people's health care consciousness constantly strengthens in diseases prevention; The health care of foot and protection caused pay close attention to and pay attention to, the demand of the health treatment of foot is day by day increased with research and development.This narrow space of vola has but compiled half channels and collaterals of health, is the beginning of three yin meridians (liver,spleen,kidney), and three yang channels (stomach, courage, wing) are eventually, have 60 below the foot surplus an acupuncture point with the vital organs of the human body close ties are arranged, so be called as people " second heart " enough.Foot concerns the most very that with the internal organs middle kidney so saying of " kidney master two being sufficient " arranged, " essence " is the first in " essence, gas, god " three big traditional Chinese medical science rarities; And the kidney being the origin of congenital constitution, the root of vigour, main store essential substances gas; The traditional Chinese medical science is stressed " harmony between man and nature ", i.e. the human body variation on boundary that will comply with the nature.So-called " Chun Shengxia is long, harvesting in autumn and storing of grain in winter ", therefore, the physiological status of foot function has direct influence for the normal performance of function of human body.The people often says: it is earlier withered to set dead root, leg-aging before aging.Foot is people's a root, supports foot as supports the people.The cold all kinds of diseases and ailments of pin are given birth to, so " support the tree mulch, foster people protects foot " adhered to foot protection health care, can play balance metabolism, prevent and treat the effect of various chronic diseases.Theory of traditional Chinese medical science is thought through stimulating acupoint of foot, can reach mediation through gas, and recuperating qi-blood is regulated the effect of function.Modern holobiology theory thinks that all there is its corresponding echo area at each position of whole body at foot, stimulates these echo areas of foot, can cause the physiological reaction and the variation of corresponding body part, thereby the disease of its corresponding position is played therapeutic action.The health care of foot picked-up with take orally health medicine compare have that curative effect is fast, comfortable, safety, convenience, advantage such as have no side effect, the active ingredient of health medicine is destroyed without stomach and intestine, the while can not increase the burden of liver kidney yet.The medication of tradition treatment of diseases needs through physician guidance, and is prone to develop immunity to drugs, and simultaneously general endo-medicine all can produce negative effect in various degree to human body.Because the various pedal skin diseases such as beriberi of fungal infection are perplexing many people, itch that this type disease causes and peculiar smell bring very big inconvenience for daily life and social activity.Existing various medicine is difficult to fundamentally eliminate focuses such as beriberi, pin are itched, the ringworm of the foot, and curative effect is undesirable, delays treatment easily repeatedly to form chronic disease opportunity, is difficult to more cure.In addition, on occupation mode, paste commonly used and pulvis also exist the problem that portably uses inconvenience, and the shortcoming of sufferer medication on time causes obstinate.Therefore, a kind of safe, effective, convenient and practical tegument glycan external use health socks of research invention just can be prevented and treated each systemic disease of whole body without administration; Both avoided the infringement of medicine to the stimulation of stomach and liver, kidney; Prevented the influence of gastric juice and liver again, had no side effect, improved the utilization rate of health products drug absorption; Stronger specific aim is arranged, and treatment and health-care effect are all very significantly.Foot health-care in the market mainly is to by fungus-caused pedal skin disease, through foot being cleaned and improving looks, reaches and eliminates the pin peculiar smell, control pin sweat, the purpose of prevention and treatment foot disease of skin; And the pedicure that has only relate to restore menstrual flow and invigorate blood circulation, effect such as expelling wind and clearing away cold, regulating qi-flowing for relieving pain.Many in addition foot health-care articles for use are to reduce cost and generally adopt cheap medicinal material, and process powdered substance and be difficult to investigate thoroughly active ingredient, and what have also uses sawdust and tree root, adds some additives then, as long as there is the taste of medicine just to reach purpose.In the various functional treatments of fiber and textiles, the development of antibacterial deodourizing processing in recent years is very fast.The antiseptic that uses at present can be divided into inorganic, organic and the natural antibacterial agent three major types substantially.Inorganic antiseptic mainly contains silver zeolite, silver-colored silica gel, active carbon of silver etc.Organic antibacterial agent has quaternary ammonium salt, guanidine class, organo-metallic compound etc.But the chemicals of above antibacterial finishing agent is prone to cause environmental pollution and the health of human body is all had certain damaging effect.The enhancing of Along with people's environmental consciousness and green textiles popular utilizes natural materials to make textiles have anti-microbial property and more and more causes people's attention.The chitin that mainly contains that belongs to the animal class in the natural antibacterial agent, shitosan and insect antibiotic property protein etc., the platymiscium class juniper, argy wormwood, aloe etc. are arranged, the antiseptic that from mineral matter, extracts in addition is like blue stone etc.
Because China is in the junior stage to the research of chitosan anti-bacteria deodorization, curative effect is indeterminate, uses inconvenience, is difficult to large tracts of land and promotes, and can not satisfy the demand of people's daily life consumption.From 1977, hold the international conference of four development and use chitins in succession in the world, developed 300 multiple products.The R and D work of Japan in this field maintains the leading position, and shaped article has reached tens of kinds, just applies for a relevant patent in average 3 days.States such as the United States, Russia, Korea Spro, India, Canada also attach great importance to the development and use of this resource.China carried out research to the preparation and the application of chitin at the fifties, but this important function for of research is still slower with exploitation so far.And the function of shitosan self demand just according to the invention.But the shitosan weak point is and fiber between do not set up firm chemical bond, not anti-repeatedly washing, shitosan arrangement is that COTTON FABRIC sustains damage under acid condition, brute force descends to some extent, the whiteness of arrangement back fabric descends apparent in view.And the fabric feeling hardening, intensity decreases is few, even raises.The present invention is exactly to the problems referred to above; Invent a kind of special finishing agent and finishing technique is evident in efficacy, sterilization removes tinea deodorization effect, washable good with pliability, can the effectively preventing pedopathy, alleviating fatigue and inferior health; Prevent disease, the health-care deodorized socks of the chitosan anti-bacteria of persistent.
Summary of the invention main points of the present invention are the chitin of occurring in nature is carried out extraction process in two steps; The first step removes calcium carbonate with watery hydrochloric acid: second step removed protein with hot diluted alkaline; Handle the chitin that just can obtain white through decolouring again, between the conversion ratio general 15～30%.With chitin alkalization insulation deacetylation, clean to neutrality and be shitosan, through special mocromembrane nanometer technology get final product the ultra micro shitosan.Water soluble chitosan biogel finishing agent elasticity retention rate is big, and reason is shitosan and fiber strong adhesion, the washing difficult drop-off.In addition, through chitosan treatment, the fabric feeling hardening, intensity decreases is few, even raises.Therefore, improve its flexibility and feel through additive.The crosslinked soft element and the biological crosslinking agent softener of living of high bioactivity, the CGF organic silicone oil has exactly played key effect.Fabric feeling hardening, even the deficiency that raises have been corrected merely through chitosan treatment.Natural antimicrobial agent mainly is one group in chitin and a derivative thereof.Chitin structure and cellulose are very similar, all are deoxyglucoses, and just cellulose is-the OH group that shitosan is-the NH2 group on 2 carbons.Its molecular formula is the polysaccharide that is formed by connecting with the form of β-1,4 glycosidic bond by N-acetyl-2-amino-2-deoxy-D-glucose.Contain H-OH and H-NH key in the molecule, also contain intermolecular hydrogen bonding.Acetyl group on the chitin glycosyl can be sloughed a part or reaches more than 90% with highly basic or enzymolysis, and this polysaccharide is shitosan.Shitosan can suppress pathogen and grow, and does not influence the balance of natural ecological, because of containing free amine group; Be alkaline polysaccharide unique in the natural polysaccharide, have many special physics and chemical property and physiological function, can combine acid molecule; Generating amino CATION makes it become positively charged natural polymer; Its antibacterial action mainly is a shitosan band positive electricity property, can combine with electronegative part in the bacterioprotein, and bacterium or fungi are lost activity.The shitosan of small-molecular weight may penetrate into microorganism inside in addition, stops RNA (ribonucleic acid) to transform, thereby suppresses the growth of bacterium.
Shitosan is applied to the antibiotic processing of fiber textile and shows the antibacterial and good fungistatic effect of diffused of contact-type. and the antibacterial effect of diffused antibacterial fabric is more remarkable usually; After spreading, possibly injure human body with chemical antiseptic; And shitosan is to the human body beneficial. seek the optimum process condition and the textile dyeing and finishing new technology of chitosan antibacterial finishing, give fabric higher finishing effect.
Respectively the fabric socks are carried out two with shitosan and soak two and roll and increase temperature infusion process, the result finds two-soak-roll, two soak two roll and one bathe, two to bathe dip finishing method antibacterial fabric property strong, fabric crease-resistant performance and washable effective.
Shitosan biogel finishing agent prescription of the present invention is (component and percentage by weight % thereof) as follows: water soluble chitosan 5-10; High bioactivity crosslinking agent TMDM 2-3; Bleeding agent 8861 2-3; Biological softener DH220 2-3; Organosilicon quaternary ammonium salt CH1680.5-0.8; Polyethylene emulsion 0.5-2; Dual-filtering water to 100.
The technological process of water soluble chitosan of the present invention is as follows: shrimp and crab shells → select → wash → acidleach 4～6%HCl room temperature 5h decalcification → soda boiling 5-10%NaOH, and the above-mentioned acidizing alkali metallization processes time of 80-100 ℃ of 3h deproteinization → repeat is respectively 3h, 2h → decolouring KMnO4/ oxalic acid → drying → chitin; Chitin 40～50%NaOH100 ℃ of 16h → insulation deacetylation → clean to neutrality → 80-100 ℃ of heated-air drying → shitosan → special mocromembrane nanometer technology → ultra micro shitosan; Neutral solution with 3-5% ultra micro shitosan is the effective ingredient-water soluble chitosan of shitosan biogel finishing agent prescription.
The synthesis technique of biogel finishing agent of the present invention is following: with water soluble chitosan 5-10, high bioactivity crosslinking agent TMDM2-3, bleeding agent 8861 2-3, biological softener DH220 2-3, organosilicon quaternary ammonium salt CH168 0.5-0.8, polyethylene emulsion 0.5-2, dual-filtering water to 100, stirring is mixed gets final product in dissolving under 80 ℃ of conditions of ratio separately.
Finishing technique of the present invention is following: two soak two rolls and increases temperature dipping; The finished product socks are soaked two through biogel finishing agent two to be rolled and increases temperature infusion process technology, biogel finishing agent 4-5g/l, ph=6-7; Pick-up 70%-80% is again through the 110-130 ℃ of crosslinked 5min. of drying; After arrangement, carry out soft finish again for making its good hand touch. can make health promoting socks have good and more washable water absorbing properties; And can increase the soft intensity of fabric; Improving the hand feel performance of fabric. various finishing functions are arbitrary combination mutually; Multi-functional combination arrangement selects the cooperation between auxiliary agent and auxiliary agent extremely important; The feasibility of technology particularly. infusion process is handled. and consumption is pressed the fabric tissue material, and the required effect that reaches and decide. and use 4-5%. to be used for the mixed knitting socks of polyester-cotton blend. moisture absorbing and sweat releasing is composite by hydrophily silicon quaternary ammonium salt and biological softener according to the composition of fabric fibre; The high temperature dipping needs 130 ℃ to handle 30min, and the applied amount on the fabric (in effective active components) is about 2-3%. bath raio 15-20: and 1, the dehydration back is dried under 80-110 ℃ of condition and is got final product.Better and the effect stability of high temperature impregnation technology. behind moisture absorbable and breathable finishing, decapacitation obviously improves outside the moisture absorption sweat discharging functions, and antistatic and easy clean effect is still arranged.
The present invention has the following advantages: pure natural shitosan elite composition is refined in (1), and is nontoxic to human body skin; Environmental protection, nontoxic.(2) biological degradability.Good biocompatibility; Have good spectrum antibacterial antiplaque performance and good moisture pick-up properties; Fabric performance of keeping humidity and water vapour permeability after arrangement increase, and through wearing health promoting socks, stimulate acupoint of foot; Play the function of regulating channels and collaterals, the promoting flow of qi and blood, adjustment internal organs, thereby play the effect of the multiple disease of control.(3) comfortableness of arrangement back fabric increases, and the fabric fall after the shitosan arrangement increases, and makes fabric have certain antistatic property.Have sterilizing and itch-relieving, sufficient effect is moistened in clearing damp, effectively alleviating fatigue and inferior health, control cause the effect of disease because of foot.(4) outer wearing can make the foot transdermal absorption factor high, is difficult for developing immunity to drugs, and avoided the infringement of soup for oral administration to liver, renal function, adheres to, long-term use is evident in efficacy to the disease-resistant health care of foot.(5) its making, easy to use, safety has no side effect.(6) through experiment showed, that effective ingredient is stable, the deodorization and sterilization effect is remarkable, to the sterilizing rate of Escherichia coli, staphylococcus aureus, Candida albicans more than 98%; Persistent, long shelf-life washs and still has 50% bactericidal effect 15 times,
The specific embodiment: the present invention is done further detailed description below in conjunction with embodiment:
1. carry out the synthetic of water soluble chitosan according to the technological process of water soluble chitosan of the present invention: shrimp and crab shells → select → wash → acidleach 4～6%HCl room temperature 5h decalcification → soda boiling 5-10%NaOH, the above-mentioned acidizing alkali metallization processes time of 80-100 ℃ of 3h deproteinization → repeat is respectively 3h, 2h → decolouring KMnO4/ oxalic acid → drying → chitin; Chitin 40～50%NaOH100 ℃ of 16h → insulation deacetylation → clean to neutrality → 80-100 ℃ of heated-air drying → shitosan → special mocromembrane nanometer technology → ultra micro shitosan; Neutral solution with 3-5% ultra micro shitosan is the effective ingredient-water soluble chitosan of shitosan biogel finishing agent prescription.
2. the synthesis technique according to biogel finishing agent of the present invention carries out the synthesising biological gel rubber finishing agent: following table institute column data (percentage by weight %) and said step thereof are configured: with water soluble chitosan 3-5; The crosslinked soft plain 2-3 that lives of high bioactivity; Bleeding agent 2-3; Biological crosslinking agent softener 4-5; CGF organic silicone oil 0.5-0.8; 6520 polyethylene emulsion 3-4; Two worry water to 100 stir to be mixed in dissolving under 80 ℃ of conditions of ratio separately and get final product.
3. carry out the arrangement of health promoting socks according to finishing technique of the present invention: two soak two rolls and increases temperature dipping; The finished product socks are soaked two through biogel finishing agent two to be rolled and increases temperature infusion process technology; Biogel finishing agent 4-5g/l; Ph=6-7, pick-up 70%-80% is again through the 110-130 ℃ of crosslinked 5min. of drying; High temperature dipping biogel finishing agent 2-3%, 130 ℃ of temperature, handle 30min, bath raio 15-20: 1, the dehydration back is dried under 80-110 ℃ of condition and is got final product.
Claims (4)
1. the present invention relates to the health-care deodorized socks of a kind of special process arrangement chitosan anti-bacteria, it is characterized in that having following shitosan biogel finishing agent prescription (component and percentage by weight % thereof): water soluble chitosan 5-10; High bioactivity crosslinking agent TMDM 2-3; Bleeding agent 8861 2-3; Biological softener DH220 2-3; Organosilicon quaternary ammonium salt CH168 0.5-0.8; Polyethylene emulsion 0.5-2; Dual-filtering water to 100.
2. the said special process of claim 1 is put the health-care deodorized socks of chitosan anti-bacteria in order, it is characterized in that having preparation technology's flow process of following water soluble chitosan:
Shrimp and crab shells → select → wash → acidleach 4～6%HCl room temperature 5h decalcification → soda boiling 5-10%NaOH, the above-mentioned acidizing alkali metallization processes time of 80-100 ℃ of 3h deproteinization → repeat is respectively 3h, 2h → decolouring KMnO4/ oxalic acid → drying → chitin; Chitin 40～50%NaOH100 ℃ of 16h → insulation deacetylation → clean to neutrality → 80-100 ℃ of heated-air drying → shitosan → special mocromembrane nanometer technology → ultra micro shitosan; Neutral solution with 3-5% ultra micro shitosan is the effective ingredient-water soluble chitosan of shitosan biogel finishing agent prescription.
3. the said special process of claim 1 is put the health-care deodorized socks of chitosan anti-bacteria in order, it is characterized in that having the synthesis technique of following biogel finishing agent:
With water soluble chitosan 5-10, high bioactivity crosslinking agent TMDM 2-3, bleeding agent 8861 2-3, biological softener DH2202-3, organosilicon quaternary ammonium salt CH168 0.5-0.8, polyethylene emulsion 0.5-2, dual-filtering water to 100, stirring is mixed gets final product in dissolving under 80 ℃ of conditions of ratio separately.
4. health-care deodorized socks of the said special process arrangement chitosan anti-bacteria of a claim 1 is characterized in that having following two and soak two and roll and increase temperature dip finishing technology:
The finished product socks are soaked two through biogel finishing agent two roll and increase temperature infusion process technology, biogel finishing agent 4-5g/l, ph=6-7, pick-up 70%-80% is again through the 110-130 ℃ of crosslinked 5min. of drying; High temperature dipping biogel finishing agent 2-3%, 130 ℃ of temperature, handle 30min, bath raio 15-20: 1, the dehydration back is dried under 80-110 ℃ of condition and is got final product.
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| CN2012101621293A CN102767078A (en) | 2012-05-24 | 2012-05-24 | Special process finished chitosan antibacterial and deodorant health care sock |
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| CN2012101621293A CN102767078A (en) | 2012-05-24 | 2012-05-24 | Special process finished chitosan antibacterial and deodorant health care sock |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105568673A (en) * | 2016-03-03 | 2016-05-11 | 许孟葵 | Anti-acarid and anti-UV socks and preparation method thereof |
| CN106498602A (en) * | 2016-08-31 | 2017-03-15 | 诸暨市欧美特袜业有限公司 | A kind of production technology of stink prevention hosiery |
| CN108625170A (en) * | 2018-05-25 | 2018-10-09 | 袁杰 | A kind of preparation method of textile finish |
| CN110432559A (en) * | 2018-05-03 | 2019-11-12 | 安徽世龙生物医药科技有限公司 | A kind of antibacterial odour oliminating health care stocks |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1283634A (en) * | 2000-08-28 | 2001-02-14 | 李高霖 | Process for preparing water-soluble shitosan |
| CN1324619A (en) * | 2000-05-18 | 2001-12-05 | 湖北省葛店开发区畅响生物工程园有限公司 | Health capsule of pure active chitosan and animal fiber |
-
2012
- 2012-05-24 CN CN2012101621293A patent/CN102767078A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1324619A (en) * | 2000-05-18 | 2001-12-05 | 湖北省葛店开发区畅响生物工程园有限公司 | Health capsule of pure active chitosan and animal fiber |
| CN1283634A (en) * | 2000-08-28 | 2001-02-14 | 李高霖 | Process for preparing water-soluble shitosan |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105568673A (en) * | 2016-03-03 | 2016-05-11 | 许孟葵 | Anti-acarid and anti-UV socks and preparation method thereof |
| CN105568673B (en) * | 2016-03-03 | 2018-03-06 | 许孟葵 | Anti- mite UV resistance socks and preparation method thereof |
| CN106498602A (en) * | 2016-08-31 | 2017-03-15 | 诸暨市欧美特袜业有限公司 | A kind of production technology of stink prevention hosiery |
| CN110432559A (en) * | 2018-05-03 | 2019-11-12 | 安徽世龙生物医药科技有限公司 | A kind of antibacterial odour oliminating health care stocks |
| CN108625170A (en) * | 2018-05-25 | 2018-10-09 | 袁杰 | A kind of preparation method of textile finish |
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Application publication date: 20121107 |