CN102728605A - Harmless treatment method for aluminum phosphide fumigation residues - Google Patents
Harmless treatment method for aluminum phosphide fumigation residues Download PDFInfo
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- CN102728605A CN102728605A CN2012102191038A CN201210219103A CN102728605A CN 102728605 A CN102728605 A CN 102728605A CN 2012102191038 A CN2012102191038 A CN 2012102191038A CN 201210219103 A CN201210219103 A CN 201210219103A CN 102728605 A CN102728605 A CN 102728605A
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- harmless treatment
- aluminum phosphide
- phosphide fumigation
- gas
- residues
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/20—Waste processing or separation
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- Agricultural Chemicals And Associated Chemicals (AREA)
- Processing Of Solid Wastes (AREA)
- Fire-Extinguishing Compositions (AREA)
Abstract
The invention belongs to a harmless treatment technology for aluminum phosphide fumigation residues, wherein the technology is applicable for harmless treatment of aluminum phosphide fumigation residues in the industry. According to the harmless treatment method for aluminum phosphide fumigation residues, aluminum phosphide fumigation powder residues and excess water are mixed in a closed container; a protection gas is introduced, and a stirring treatment is performed under a certain state, wherein the state is assurance of no air; the generated PH3 gas and the protection gas enter a tail gas absorption device; an oxidizing agent spraying treatment is performed two times to carry out a tail gas absorption treatment, wherein a slight negative pressure state inside a spraying tower is ensured during the spraying process, and the PH3 gas is subjected to a completely harmless treatment; and the treated residues are adopted as a cement production raw material to be conveyed to a cement plant to be comprehensively utilized. The method of the present invention has the following advantages that: the aluminum phosphide fumigation residues are subjected to the harmless treatment while the risk coefficient of the operation is reduced, and the PH3 gas produced in the process is further subjected to the harmless treatment at the same time so as to avoid secondary pollution generation, and completely solve the pollution problem of the aluminum phosphide fumigation residues.
Description
Technical field
The present invention relates to the method for a kind of aluminum phosphide fumigation residue harmless treatment.
Background technology
Aluminum phosphate is present domestic and international widely used fumigant; Do not decompose fully and utilize and contain aluminum phosphate 3% or more in its residue after stifling, aluminum phosphate runs into water in air branch production phosphine gas, and hydrogen phosphide belongs to extremely toxic substance; So it is very important that science is handled the aluminum phosphate residue.Two kinds of forms are generally taked in the processing of aluminum phosphate residue at present: the one, handle through chemical treatments; The 2nd, look for place far away, dried up source to dig pit buried.This dual mode all can't be avoided the volatilization of residual hydrogen phosphide fully, and phosphine gas has inflammable and explosive characteristic, in processing procedure, has greatly potential safety hazard, deals with improperly and can cause combustion explosion, causes second environmental pollution simultaneously.
Summary of the invention
The objective of the invention is to overcome above-mentioned not enough problem, the method for a kind of aluminum phosphide fumigation residue harmless treatment is provided, the aluminum phosphate residue is carried out nontoxic, harmless treatment, accomplish safety, environmental protection, thoroughly solved the pollution problem of aluminum phosphide fumigation residue.
The present invention for realizing the technical scheme that above-mentioned purpose adopted is: in closed container with aluminum phosphide fumigation powder residue with after excessive water mixes, the feeding protective gas guarantees under air-free state, to stir the PH of generation
3Gas gets into the tail gas absorption treating device together with protective gas, absorbs through twice oxidant spray tail gas and handles, and the spray process guarantees that in the spray column be micro-vacuum state, PH
3Gas harmless treatment fully; Handle the back residue and advance the cement plant comprehensive utilization as cement producting material.
The method of described aluminum phosphide fumigation residue harmless treatment, wherein said protective gas is: nitrogen, carbon dioxide.
The method of described aluminum phosphide fumigation residue harmless treatment, wherein said same PH
3The oxidant of reaction is: copper sulphate, clorox or hydrogen peroxide solution etc.
The copper sulphate that said oxidant employing mass percentage concentration is 5%-20%, the mass percentage concentration of effective chlorine are that clorox or the mass percentage concentration of 5%-13% is the hydrogen peroxide solution of 5%-40%.
It is that the mass percentage concentration of 20% copper sulphate, effective chlorine is that 10% clorox or mass percentage concentration are 30% hydrogen peroxide solution that said oxidant adopts mass percentage concentration.
The method of described aluminum phosphide fumigation residue harmless treatment, wherein said tail gas are absorbed as twice spray of two kinds of identical or different oxidants for twice, and wherein spray process maintenance spray column is a negative pressure state.
Described spray column micro-vacuum state, wherein said little range of negative pressure be controlled at 0MPa---0.02MPa.
Described spray column micro-vacuum state, the optimal value of wherein said little negative pressure control is-0.005MPa.
The method of described aluminum phosphide fumigation residue harmless treatment, wherein said PH
3The complete harmless treatment of gas is meant PH
3Concentration be not more than 0.3mg/m
3
The present invention provides a kind of new method for harmless treatment aluminum phosphide fumigation residue in industry, and its advantage reduces the danger coefficient of its operation when being harmless treatment aluminum phosphide fumigation residue, and with the PH that produces in its processing procedure
3Gas also carries out harmless treatment simultaneously, avoids producing secondary pollution, has thoroughly solved the pollution problem of aluminum phosphide fumigation residue.
The specific embodiment
Below in conjunction with specific embodiment the present invention is done further explain, but the present invention is not limited to specific embodiment.
Embodiment 1:
The method of a kind of aluminum phosphide fumigation residue harmless treatment, in closed container with aluminum phosphide fumigation powder residue with after excessive 45 ℃ of water mix, feed N
2Gas, PH
3Same N
2Get into exhaust treatment system together, PH
3Gas is that twice absorption carried out in 10% liquor natrii hypochloritis reaction with the effective chlorine mass percentage concentration; Guarantee little negative pressure in the spray column in the absorption process, pressure is-0.005MPa finally to reach the harmless treatment of tail gas; Use the hydrogen phosphide detector, measure phosphine gas concentration less than 0.03mg/m
3Handle the back residue and advance the cement plant comprehensive utilization as cement producting material.
Embodiment 2:
The method of a kind of aluminum phosphide fumigation residue harmless treatment, in closed container with aluminum phosphide fumigation powder residue with after excessive 55 ℃ of water mix, feed N
2Gas, PH
3Same N
2Get into exhaust treatment system together, PH
3The hydrogen peroxide solution reaction of gas homogenous quantities percentage concentration 30% once absorbs; The copper-bath of homogenous quantities percentage concentration 20% carries out the secondary absorption again; Guarantee little negative pressure in the spray column in the absorption process, pressure is-0.05MPa finally to reach the harmless treatment of tail gas; Use the hydrogen phosphide detector, measure phosphine gas concentration less than 0.03mg/m
3Handle the back residue and advance the cement plant comprehensive utilization as cement producting material.
Embodiment 3:
The method of a kind of aluminum phosphide fumigation residue harmless treatment, in closed container with aluminum phosphide fumigation powder residue with after excessive 60 ℃ of water mix, feed CO
2Gas, PH
3Same CO
2Get into exhaust treatment system together, PH
3The hydrogen peroxide solution reaction of gas homogenous quantities percentage concentration 30% once absorbs; Liquor natrii hypochloritis with effective chlorine mass percentage concentration 10% carries out the secondary absorption again; Guarantee little negative pressure in the spray column in the absorption process, pressure is-0.01MPa finally to reach the harmless treatment of tail gas; Use the hydrogen phosphide detector, measure phosphine gas concentration less than 0.03mg/m
3Handle the back residue and advance the cement plant comprehensive utilization as cement producting material.
Claims (9)
1. the method for aluminum phosphide fumigation residue harmless treatment is characterized in that: in closed container with aluminum phosphide fumigation powder residue with after excessive water mixes, feed protective gas, guarantee under air-free state, to stir the PH of generation
3Gas gets into the tail gas absorption treating device together with protective gas, carries out tail gas through twice oxidant spray and absorbs processing, and the spray process guarantees that in the spray column be micro-vacuum state, PH
3Gas harmless treatment fully; Handle the back residue and advance the cement plant comprehensive utilization as cement producting material.
2. the method for aluminum phosphide fumigation residue according to claim 1 harmless treatment is characterized in that: wherein said protective gas is nitrogen or carbon dioxide.
3. the method for aluminum phosphide fumigation residue according to claim 1 harmless treatment is characterized in that: wherein said same PH
3The oxidant of reaction is copper sulphate, clorox or hydrogen peroxide solution.
4. the method for aluminum phosphide fumigation residue according to claim 1 harmless treatment is characterized in that: the copper sulphate that said oxidant employing mass percentage concentration is 5%-20%, the mass percentage concentration of effective chlorine are that clorox or the mass percentage concentration of 5%-13% is the hydrogen peroxide solution of 5%-40%.
5. the method for aluminum phosphide fumigation residue according to claim 1 harmless treatment is characterized in that: it is that the mass percentage concentration of 20% copper sulphate, effective chlorine is that 10% clorox or mass percentage concentration are 30% hydrogen peroxide solution that said oxidant adopts mass percentage concentration.
6. the method for aluminum phosphide fumigation residue according to claim 1 harmless treatment is characterized in that: twice absorption of said tail gas adopts identical or different oxidant to carry out spray twice.
7. the method for aluminum phosphide fumigation residue according to claim 1 harmless treatment is characterized in that: said little negative pressure be meant pressure limit be controlled at 0MPa--0.02MPa.
8. the method for aluminum phosphide fumigation residue according to claim 1 harmless treatment is characterized in that: said little negative pressure is meant that pressure limit is controlled at-0.005MPa.
9. the method for aluminum phosphide fumigation residue according to claim 1 harmless treatment is characterized in that: said PH
3The complete harmless treatment of gas is meant PH
3Concentration be not more than 0.3mg/m
3
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102191038A CN102728605A (en) | 2012-06-29 | 2012-06-29 | Harmless treatment method for aluminum phosphide fumigation residues |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102191038A CN102728605A (en) | 2012-06-29 | 2012-06-29 | Harmless treatment method for aluminum phosphide fumigation residues |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102728605A true CN102728605A (en) | 2012-10-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012102191038A Pending CN102728605A (en) | 2012-06-29 | 2012-06-29 | Harmless treatment method for aluminum phosphide fumigation residues |
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| CN (1) | CN102728605A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104058375A (en) * | 2014-05-23 | 2014-09-24 | 李达刚 | Safe production technique for manufacturing high-purity phosphine on large scale |
| CN104085867A (en) * | 2014-07-18 | 2014-10-08 | 中国人民解放军防化学院 | Method and device for treating residues of aluminum phosphide tablet fumigation agent |
| CN105642661A (en) * | 2016-03-24 | 2016-06-08 | 浙江工商大学 | Device and process for safely treating aluminum phosphide fumigating residues |
| CN111744349A (en) * | 2019-03-27 | 2020-10-09 | 东泰高科装备科技有限公司 | Cleaning method of tail gas treatment system |
| CN112844006A (en) * | 2020-12-28 | 2021-05-28 | 马边长和电力有限责任公司 | Yellow phosphorus tail gas purification method |
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| CN2456825Y (en) * | 2000-12-30 | 2001-10-31 | 左智宇 | Purifying device for fumigating and insect killing residue gas |
| US20060222574A1 (en) * | 2005-04-02 | 2006-10-05 | Kaye Gordon I | Apparatus and method for chemically reducing waste materials |
| CN200999201Y (en) * | 2007-01-30 | 2008-01-02 | 刘胜祥 | Hydrogen phosphide gas reclaimer |
| CN201320445Y (en) * | 2008-11-12 | 2009-10-07 | 绵阳华西仓储服务有限公司 | Device for purifying phosphine gas |
| CN201551945U (en) * | 2009-10-16 | 2010-08-18 | 湖北兴发化工集团股份有限公司 | Spray-absorption device |
| CN102114382A (en) * | 2011-01-14 | 2011-07-06 | 浙江诚信医化设备有限公司 | Method for separating and recovering fumigation medicine |
| CN202146710U (en) * | 2011-01-04 | 2012-02-22 | 中国人民解放军63971部队 | Phosphine gas purifier |
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2012
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Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2456825Y (en) * | 2000-12-30 | 2001-10-31 | 左智宇 | Purifying device for fumigating and insect killing residue gas |
| US20060222574A1 (en) * | 2005-04-02 | 2006-10-05 | Kaye Gordon I | Apparatus and method for chemically reducing waste materials |
| CN200999201Y (en) * | 2007-01-30 | 2008-01-02 | 刘胜祥 | Hydrogen phosphide gas reclaimer |
| CN201320445Y (en) * | 2008-11-12 | 2009-10-07 | 绵阳华西仓储服务有限公司 | Device for purifying phosphine gas |
| CN201551945U (en) * | 2009-10-16 | 2010-08-18 | 湖北兴发化工集团股份有限公司 | Spray-absorption device |
| CN202146710U (en) * | 2011-01-04 | 2012-02-22 | 中国人民解放军63971部队 | Phosphine gas purifier |
| CN102114382A (en) * | 2011-01-14 | 2011-07-06 | 浙江诚信医化设备有限公司 | Method for separating and recovering fumigation medicine |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104058375A (en) * | 2014-05-23 | 2014-09-24 | 李达刚 | Safe production technique for manufacturing high-purity phosphine on large scale |
| CN104058375B (en) * | 2014-05-23 | 2016-02-10 | 李达刚 | A kind of Safe production technology of extensive manufacture high purity phosphine |
| CN104085867A (en) * | 2014-07-18 | 2014-10-08 | 中国人民解放军防化学院 | Method and device for treating residues of aluminum phosphide tablet fumigation agent |
| CN104085867B (en) * | 2014-07-18 | 2016-04-13 | 中国人民解放军防化学院 | A kind of aluminium phosphide tablet fumigant draff processing method and device |
| CN105642661A (en) * | 2016-03-24 | 2016-06-08 | 浙江工商大学 | Device and process for safely treating aluminum phosphide fumigating residues |
| CN105642661B (en) * | 2016-03-24 | 2018-09-28 | 浙江工商大学 | A kind of secure processing device and technique of aluminum phosphide fumigation residue |
| CN111744349A (en) * | 2019-03-27 | 2020-10-09 | 东泰高科装备科技有限公司 | Cleaning method of tail gas treatment system |
| CN111744349B (en) * | 2019-03-27 | 2022-10-25 | 紫石能源有限公司 | Cleaning method of tail gas treatment system |
| CN112844006A (en) * | 2020-12-28 | 2021-05-28 | 马边长和电力有限责任公司 | Yellow phosphorus tail gas purification method |
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Application publication date: 20121017 |