CN102727395A - Sprayable hair styling compositions - Google Patents
Sprayable hair styling compositions Download PDFInfo
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- CN102727395A CN102727395A CN2011100973712A CN201110097371A CN102727395A CN 102727395 A CN102727395 A CN 102727395A CN 2011100973712 A CN2011100973712 A CN 2011100973712A CN 201110097371 A CN201110097371 A CN 201110097371A CN 102727395 A CN102727395 A CN 102727395A
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Abstract
The present invention relates to a sprayable hair styling composition comprising PEG and an anionic non-crosslinked associative linear polymer. The sprayable hair styling composition has good spray performance and can easily complete hair styling.
Description
Technical field
The present invention relates to a kind of aerosolizable Hairsetting compositions, especially contain the aerosolizable Hairsetting compositions of PEG and noncrosslinking anion association linear polymer.
Background technology
The Along with people's growth in the living standard, the hair caring product demand is more and more diversified.Difference according to hair style is selected from the main feature that suitable approved product is existing market consumption.
Wait the independent individual character hair style of pursuit popular rapidly along with dying to scald to roll up, can have the product of certain typing effect fast-developing again by conditioning hair.Gel water and gel cream are the products that is used for satisfying the demand of the single typing of short-and-medium traditional hair style.Mousse (Mousse) refers to that carrying liquid by propellant forms foamy product at normal temperatures and pressures.Yet these products all need further be smeared could accomplish Hairsetting.
Therefore, still need easily to accomplish the aerosolizable product of Hairsetting at present.
Summary of the invention
Only if point out in addition, percentage ratios all among this paper all calculate with the weight of compositions, and all ratios all are weight ratios.Unless stated otherwise, the amount of any composition for example percent or ratio or share is all calculated with the actual amount of this composition, does not comprise solvent, filler or other blending constituents.
One aspect of the present invention provides a kind of aerosolizable Hairsetting compositions, and the weight in compositions comprises:
(a) 0.1% to 30% number-average molecular weight is 150 to 10000 Polyethylene Glycol; With
(b) 0.05% to 3% anion non-crosslinked association linear polymer.
According to aerosolizable Hairsetting compositions of the present invention, the number-average molecular weight of wherein said Polyethylene Glycol is 200 to 5000, preferred 250 to 2000.
According to aerosolizable Hairsetting compositions of the present invention; Wherein said Polyethylene Glycol is PEG-4, PEG-6, PEG-8, PEG-12, PEG-20, PEG-32, PEG-75, PEG-90, PEG-100, PEG-150, PEG-180 or its mixture; Preferred PEG-4, PEG-6, PEG-8, PEG-12, PEG-20, PEG-32, PEG-75, PEG-90 or its mixture, more preferably PEG-6, PEG-8, PEG-12, PEG-20, PEG-32 or its mixture.
In the present invention; Polyethylene Glycol (be called for short PEG, be also referred to as polyoxyethylene in some cases) is added in the hair products, utilize the characteristic of its light liquid wax; Can the effective support root of hair; Difference conventional resins stiff typing the wave dynamic elastic effect of perming is had good help, and hair becomes pliable and tough smooth.
The used PEG of the present invention has following construction features:
H-(OCH
2CH
2)
n-OH
N repeateding unit (OCH wherein
2CH
2) par, n is big more, and mean molecule quantity is big more.In embodiments more of the present invention, the average number of the n of PEG can be preferably between about 4 to about 180, and corresponding mean molecule quantity is about 190 to about 8000; More preferably n is about 4 to about 90, and corresponding mean molecule quantity is about 200 to about 4400; Most preferably n is about 6 to about 32, and corresponding mean molecule quantity is about 250 to about 1600.The example of available PEG includes, but are not limited to the Carbowax series of DOW company: PEG200, PEG300, PEG 400, PEG 600, PEG1000, PEG 1450, PEG 3350, PEG 4000, PEG 4600, PEG 6000, PEG 8000 (referring to table 1); The Polyglykol 200 to Polyglykol 8000 of Clariant company; The Pluracare E200 to E8000flakes of Basf company etc.
The Carbowax series of products of table 1:DOW company
(a): PEG540Blend is the mixture that PEG-300 and PEG-1450 form by 41/59 mass ratio
(b): CTFA (Cosmetic Toiletry and Fragrance Association) expression U.S.'s cosmetics toilet articles and fragrance articles for use association
(c): the international cosmetic material name of INCI (International Nomenclatrure Cosmetic Ingredient) expression
(d): PEG-90 is the suggestion CTFA/INCI title of PEG-4000,90 expression (OCH
2CH
2) number of repeat unit
According to aerosolizable Hairsetting compositions of the present invention, said anion non-crosslinked association linear polymer is the copolymer with following formula:
Wherein, R and R1 represent to contain C respectively
1-4Alkyl is preferably methyl or ethyl; At least one expression C among R2 and the R3
1-24Alkyl-(OCH
2CH
2)
nO-, wherein n representes 1-50, preferred 10-30, integer, remaining expression C
1-24Alkyl; X, y, w and z are respectively the integer more than or equal to 0, x+y+w+z=20-100, and at least one is not 0 to guarantee to exist at least one C among x and the z
1-24At least one is not 0 among alkyl-(OCH2CH2) nO-, and y and the w.
According to aerosolizable Hairsetting compositions of the present invention, said anion non-crosslinked association linear polymer is acrylic acid (ester) class/behenyl alcohol polyethers-25 methacrylate copolymer, acrylic acid (ester) class/stearyl alcohol polyethers-20 methacrylate copolymer or its mixture.
The example of the anion non-crosslinked association linear polymer that uses among the present invention includes but not limited to ACULYN 22 (the ACRYLATES/STEARETH-20METHACRYLATE COPOLYMER of DOW company; Acrylic acid (ester) class/stearyl alcohol polyethers-20 methacrylate copolymer) and ACULTN 28 (ACRYLATES/BEHENETH-25METHACRYLATE COPOLYMER, acrylic acid (ester) class/behenyl alcohol polyoxy ether-25 methacrylate copolymer); And the Novethix L-10Polymer of Lubrizol company (ACRYLATES/BEHENETH-25METHACRYLATE COPOLYMER, acrylic acid (ester) class/behenyl alcohol polyoxy ether-25 methacrylate copolymer).
Inventor of the present invention is surprised to find; Compare with crosslinked carboxylic acid polyalcohol (for example Pemulen TR-1); The aerosolizable Hairsetting compositions of the noncrosslinking anion non-crosslinked of use according to the present invention association linear polymer has obviously more superior atomization and makes the hair moulding more easy, need not basically to come combing even by hands or comb.The Hairsetting compositions that contains crosslinked carboxylic acid polyalcohol can not spread on the hair when atomizing equably, need come combing even by hands or comb, is not easily when therefore using, and is not easy to moulding.
According to aerosolizable Hairsetting compositions of the present invention, also contain liquid-carrier.Said liquid-carrier comprises water, C
1-6Alkylol or its mixture.The C that is suitable for
1-6The object lesson of alkylol includes but not limited to: ethanol, normal propyl alcohol, isopropyl alcohol, propylene glycol, glycerin, n-butyl alcohol, amylalcohol, 1; 3-butanediol or its mixture; Be preferably monohydric alcohol, dihydroxylic alcohols or trihydroxylic alcohol with 1-4 carbon atom; For example ethanol, propanol, propylene glycol, glycerin, 1,3 butylene glycol or its mixture.In the weight of said compositions, C
1-6The total concentration of alkylol is 0-20%, preferred 0.5-10%, more preferably 0.5-5%.
According to aerosolizable Hairsetting compositions of the present invention, in the weight of compositions, also contain 0.1% to 10%, preferred 0.2% to 8%, more preferably 0.5% to 5%, the more preferably moist conditioner of 1% to 3% weight.
According to aerosolizable Hairsetting compositions of the present invention; Wherein said moist conditioner is siloxanes, tristerin, stearic acid or its mixture; Preferred siloxanes or silicone emulsion, more preferably mean diameter is that 0.1 to 10 micron and viscosity are 100 to 15000cPs silicone emulsion.
According to aerosolizable Hairsetting compositions of the present invention, wherein said siloxanes is that viscosity is 5-1000cst, preferred 5-350cst, the more preferably polydimethylsiloxane of 5-20cst.
In embodiments more of the present invention, the example of said siloxanes includes but not limited to: the Xiameter PMX-200Fluid 5CST of DOW CORNING company, 10CST, 20CST, 50CST, 100CST, 350CST, 500CST, 1000CST; The TSF451-5 of MOMENTIVE company, TSF451-10, TSF451-20, TSF451-50, TSF451-100, TSF451-350, TSF451-1000.Silicone emulsion is pre-emulsified silicone emulsion, can directly be added to usually in the batch and without High shear device.The siloxane emulsion example includes but not limited to the Silsoft EMU8105-N (the milky nonionic silicone oil emulsion that contains dimethiconol, amido silicon oil and two amino PEG/PPG-41/3-aminoethyl PG-propyl group polydimethylsiloxane terpolymers) of Momentive company and the SF16010Z silicone oil emulsion (dimethylsiloxane emulsion) of KCC company.
According to aerosolizable Hairsetting compositions of the present invention; Also can contain other optional compositions, comprise but be not limited to: antiseptic, surfactant, conditioning polymer, electrolyte, aliphatic alcohol, hair dye, end dandruff activating agent, abnormal smells from the patient covering agent, PH regulator, essential oil, essence chaotropic agent, chelating agen, softening agent, lubricant and penetrating agent such as range protein derivant, sunscreen, volatile siloxane fluid and isoparaffin (isoparrafins).Add these compositions and must verify the sprayable property (aerosolizable property) of product.The concentration range of the composition that these are optional is generally 0 to about 25%, is more typically about 0.05% to about 25%, is generally about 0.1% again to about 15%, with composition weight meter.
Aerosolizable Hairsetting compositions of the present invention can use according to spraying (atomizing) mode of routine.For example, with the container and the distribution that have the manual type atomizing pump.These containers and transporter all should be compatible with the composition of aerosolizable Hairsetting compositions of the present invention.
Be different from traditional gel cream fashion of extrusion, aerosolizable Hairsetting compositions according to the present invention pours in the spray bottle, only needs a spray gently, can fully atomize, and makes nursing and typing once accomplish with rapid shaping.
The specific embodiment
Following example further describes and demonstrates embodiment within the scope of the present invention.Provide just purpose rather than the limitation of the present invention in order to specify of these examples, they are carried out many changes is possible because do not break away from the spirit and scope of the present invention.Except as otherwise noted, all concentration of enumerating all are w/w percentage ratio.Spray composite of the present invention can provide the technology of hair setting composition to prepare through any known effectively being applicable to other.
Example I-IV
The prescription of the aerosolizable Hairsetting compositions of example I-IV is seen table 2, and it prepares according to conventional method.An amount of water and non-crosslinked anion association linear polymer are joined in the retort, stir, add PEG and polyhydric alcohol again, treat that whole solid formation dissolvings finish, stir to add alkaline solution of sodium hydroxide, fully stirred 10 minutes.Add essence, antiseptic again, mix getting final product in 10 minutes.
Table 2
1.CARBOWAX 300, available from DOW
2.CARBOWAX 1450, available from Dow
3.Aculyn 22, available from Dow
4.Aculyn 28, available from Dow
EXAMPLE V-VIII
The aerosolizable Hairsetting compositions of EXAMPLE V-VIII silicone oil emulsion, its prescription is seen table 3.The method for compositions that row V-VIII is implemented in preparation is following: water and anion non-crosslinked association linear polymer are joined in the retort; Stir; Heat temperature raising adds PEG and oiliness raw material polydimethylsiloxane, tristerin, stearic acid again to about 70 ℃ then, treat whole solid formation fusions after; Stir adding potassium hydroxide alkalescence solution, fully stirred 30 minutes.Be cooled to below 45 ℃, add silicone oil emulsion and essence, antiseptic, stir and get final product.
Table 3
1.CARBOWAX 200, available from DOW
2.CARBOWAX 300, available from DOW
3.CARBOWAX 1450, available from DOW
4.CARBOWAX 8000, available from DOW
5.Xiameter PMX-200Fluid 350cs is available from DOW CORNING
6.Silsoft EMU8105-N is available from Momentive
7.Cutina GMS is available from Cognis
8.Triple pressed stearic acid SA 1801 is available from SUMI ASIH Chemical (HK) Ltd
9.Aculyn 28, available from DOW
Example I X-XII and Comparative Examples XIII
The prescription of the Hairsetting compositions of example I X-XII and Comparative Examples XIII is seen table 4, and its preparation method is with the preparation of compositions method of implementing row V-VIII.
Table 4
1.CARBOWAX 400, available from Dow
2.CARBOWAX 1450, available from Dow
3.Xiameter PMX-200Fluid 350cs is available from DOW CORNING
4.Silsoft EMU8105-N is available from Momentive
5.Cutina GMS is available from Cognis
6.Triple pressed stearic acid SA 1801 is available from SUMI ASIH Chemical (HK) Ltd
7.Aculyn 22, available from Dow
8.Aculyn 28, available from Dow
9.Acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross linked polymer is available from Noveon
Recruitment evaluation
Effect for the compositions of above embodiment has been carried out the sensory evaluation.The method of sensory evaluation is: the professional test personnel through training carry out the half a head comparative evaluation to 5 testees.Standards of grading adopt ten point system, and 1 is the poorest, and 10 minutes best, and mark is high more good more.
Standards of grading:
Sprayability (sprayability): atomizing pump is L101A-24-410A (Guangdong Zhongshan CLC Pump Ltd.).In test; Earlier compositions to be tested was placed 18 hours in calorstat (25 ℃); Use atomizing pump to try spray then at the graph paper center of aiming at 2mm * 2mm at a distance of the 150mm place; The drippage situation of spray pattern (size of drop and dispersity on the graph paper) when observing ejection and spraying pumping hole drop, and feel that simultaneously pump head pushes easy degree.The standards of grading of pulverability are seen table 5.
Table 5
| Score | Spraying pumping hole dropping liquid | Spray pattern | Push situation |
| The 8-9 branch | Trace | Basically be uniformly dispersed | Push very easy |
| The 6-7 branch | A little | Big drop is more | Push than being easier to |
| The 4-5 branch | Have | Big drop scatter | It is not too easy to push |
| The 2-3 branch | Have | Big drop is difficult for disperseing | Push very difficult |
| The 0-1 branch | Have | Big drop does not disperse | By motionless |
Be prone to moulding: whether moulding easily
8-9 branch: be easy to moulding; 6-7 branch: than being easier to moulding; 4-5 branch: be not easy moulding; 2-3 branch: extremely difficult moulding; 0-1 branch: can not be reconfigured.
Soft and smooth sense: with forefinger and middle finger sensation topknot resistance and pliability
The 8-9 branch: very soft and smooth, non-resistance; The 6-7 branch: more soft and smooth, certain resistance is arranged; 4-5 branch: tangible resistance is arranged; 2-3 branch: stronger resistance; 0-1 branch: very strong resistance.
Tack-free: in the time of moulding, the viscosity between sensation hair and the hands
8-9 branch: do not have sticking sense, the 6-7 branch: sticking sense is arranged slightly, negligible sticking sense; 4-5 branch: more intense sticking sense; 2-3 branch: very strong sticking sense; 0-1 branch: very strong sticking sense.
Non-greasy: in the time of moulding, the greasy degree on the sensation hair
8-9 branch: no greasy feeling; 6-7 branch: some oil is arranged slightly, negligible oil; The 4-5 branch: oil content is heavier; 2-3 branch: very greasy; 0-1 branch: very greasy.
Preserve moisture: with the wettability of feel feel hair
The 8-9 branch: moisture is very sufficient, and is very moistening; The 6-7 branch: moisture is general, and is more moistening; The 4-5 branch: more dried, sensation of dryness slightly; 2-3 branch: very dry and astringent; 0-1 branch: very dry and astringent.
It is not at random to curl: the degree of flying away of observing hai roll
The 8-9 branch: hai roll remains intact; The 6-7 branch: hai roll keeps better; The 4-5 branch: hai roll keeps general, and the part has scatters; The 2-3 branch: the hai roll major part is scattered; The 0-1 branch: hai roll scatters fully.
Gentle elasticity: pinch hai roll sensation resilience up and down
The 8-9 branch: elasticity is very good, flexible; The 6-7 branch: elasticity is better, the general 4-5 branch of toughness: more stiff, nonelastic; 2-3 branch: very stiff; 0-1 branch: very stiff.
Curl (after 4 hours) not at random: observe hai roll and fly away degree
The 8-9 branch: hai roll remains intact; The 6-7 branch: hai roll keeps better; The 4-5 branch: hai roll keeps general, and the part has scatters; The 2-3 branch: hai roll scatters; The 0-1 branch: hai roll scatters fully.
Reconfigured: the ability that the water spray back is reconfigured
8-9 branch: be easy to moulding; 6-7 branch: than being easier to moulding; 4-5 branch: be not easy moulding; 2-3 branch: extremely difficult moulding; 0-1 branch: can not be reconfigured.
The assessment result of example I-XII and Comparative Examples XIII is seen table 6.
The result of table 6 shows; The compositions that contains the example I-XII of anion non-crosslinked association linear polymer all has good sprayability and accomplishes forming hair easily, and the compositions that contains the Comparative Examples XIII of cross linked polymer Pemulen TR-1 can't spray uniform droplet basically and be difficult for accomplishing forming hair.
Claims (10)
1. aerosolizable Hairsetting compositions, the weight in compositions comprises:
(a) 0.1% to 30% number-average molecular weight is 150 to 10000 Polyethylene Glycol; With
(b) 0.05% to 3% anion non-crosslinked association linear polymer.
2. according to the aerosolizable Hairsetting compositions of claim 1, the number-average molecular weight of wherein said Polyethylene Glycol is 200 to 5000, preferred 250 to 2000.
3. according to the aerosolizable Hairsetting compositions of claim 1; Wherein said Polyethylene Glycol is PEG-4, PEG-6, PEG-8, PEG-12, PEG-20, PEG-32, PEG-75, PEG-90, PEG-100, PEG-150, PEG-180 or its mixture; Preferred PEG-4, PEG-6, PEG-8, PEG-12, PEG-20, PEG-32, PEG-75, PEG-90 or its mixture, more preferably PEG-6, PEG-8, PEG-12, PEG-20, PEG-32 or its mixture.
4. according to aerosolizable Hairsetting compositions any among the claim 1-3, said anion non-crosslinked association linear polymer is the copolymer with following formula:
Wherein, R and R1 represent to contain C respectively
1-4Alkyl is preferably methyl or ethyl; At least one expression C among R2 and the R3
1-24Alkyl-(OCH
2CH
2)
nO-, wherein n representes the integer of 1-50, remaining expression C
1-24Alkyl; X, y, w and z are respectively the integer more than or equal to 0, x+y+w+z=20-100, and at least one is not 0 to guarantee that among R2 and the R3 at least one exists and to be C among x and the z
1-24Alkyl-(OCH
2CH
2)
nO-, and at least one is not 0 among y and the w.
5. according to aerosolizable Hairsetting compositions any among the claim 1-3, said anion non-crosslinked association linear polymer is acrylic acid (ester) class/behenyl alcohol polyethers-25 methacrylate copolymer, acrylic acid (ester) class/stearyl alcohol polyethers-20 methacrylate copolymer or its mixture.
6. according to aerosolizable Hairsetting compositions any among the claim 1-3, also contain liquid-carrier.
7. according to the aerosolizable Hairsetting compositions of claim 6, said liquid-carrier comprises water, C
1-6Alkylol or its mixture.
8. according to aerosolizable Hairsetting compositions any among the claim 1-7,, also contain 0.1% to 10% in the weight of compositions, preferred 0.2% to 8%, more preferably 0.5% to 5%, the more preferably moist conditioner of 1% to 3% weight.
9. according to Claim 8 aerosolizable Hairsetting compositions; Wherein said moist conditioner is siloxanes, tristerin, stearic acid or its mixture; Preferred siloxanes or silicone emulsion, more preferably mean diameter is 0.1 to 10 micron a silicone emulsion.
10. according to the aerosolizable Hairsetting compositions of claim 9, wherein said siloxanes is that viscosity is 5-1000cst, preferred 5-350cst, the more preferably polydimethylsiloxane of 5-20cst.
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|---|---|---|---|
| CN201110097371.2A CN102727395B (en) | 2011-04-12 | 2011-04-12 | Sprayable hair styling compositions |
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Cited By (1)
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| CN105025868A (en) * | 2013-03-29 | 2015-11-04 | 株式会社漫丹 | Hairstyling composition and method for producing hairstyling composition |
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