CN102719150A - Reflecting heat-insulation flame-retardant paint and preparation method thereof - Google Patents
Reflecting heat-insulation flame-retardant paint and preparation method thereof Download PDFInfo
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- CN102719150A CN102719150A CN2011101025445A CN201110102544A CN102719150A CN 102719150 A CN102719150 A CN 102719150A CN 2011101025445 A CN2011101025445 A CN 2011101025445A CN 201110102544 A CN201110102544 A CN 201110102544A CN 102719150 A CN102719150 A CN 102719150A
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Abstract
The invention, relating to the field of paint, specifically relates to a reflecting heat-insulation flame-retardant paint and a preparation method thereof. The reflecting heat-insulation flame-retardant paint comprises 75-85 wt% of component A and 15-25 wt% of component B, wherein the component A is a color paste comprising 30-50 weight parts of emulsion, 5-10 weight parts of pigment, 10-25 weight parts of hollow glass beads, 5-15 weight parts of flame-retardant filling material, 2-25 weight parts of filling material, 2-3 weight parts of auxiliary agent, and 4-10 weight parts of solvent, and component B comprises 65-75 weight parts of curing agent and 25-35 weight parts of curing accelerator. According to the invention, by utilizing the reflection capability of the hollow glass beads, the reflectivity of the coating to infrared rays is raised, and the energy absorption of the coating is reduced; simultaneously by utilizing the hollow structure of the glass beads, the interior of the paint is thick with enclosed micropores, thus the coefficient of heat conductivity of the paint is reduced, and the heat insulation performance of the paint is raised.
Description
Technical field:
The present invention relates to paint field, be specially a kind of reflective thermal-insulating anti-flaming dope and preparation method thereof.
Background technology:
Along with the minimizing day by day of oil, Sweet natural gas, energy problem becomes the bottleneck of restriction various countries development gradually.In China, building energy consumption has accounted for 27.6% of national total energy consumption, and along with annual tens00000000 square metres covil construction come into operation, the building energy consumption amount also can increase.For this reason, country put teeth in the standard of building energy conservation 50% since 1997, and paid much attention to the research and development and the popularization of heat preservation technology.At present; In the building heat preservation design and construction of China; All adopted extrusion molding styrofoam (XPS), molded polystyrene porous plastics (EPS), rigid urethane foam organic thermal insulation materials such as (PU) as external-wall heat-insulation material more than 90%, but these lagging material installations are loaded down with trivial details, persistence is poor; And the flame-retardant property extreme difference of lagging material, stay potential safety hazard easily.Therefore, the reflective thermal-insulating fire retardant material of developing a kind of easy construction has bigger realistic meaning.
Summary of the invention
The object of the invention is to provide a kind of reflective thermal-insulating anti-flaming dope and preparation method thereof, and the flame-retardant property that solves traditional lagging material is poor, reaches problems such as staying potential safety hazard easily; This coating has excellent flame-retardant performance and heat retaining property; Starting material are environment-friendly materials, and are nontoxic, and can be prepared into shades of colour; Easy construction is applicable to surfaces such as building, pipeline, tank body.
Technical scheme of the present invention is following:
A kind of reflective thermal-insulating anti-flaming dope by weight percentage, is made up of first component and component B two portions, and the first component accounts for 75～85%, and component B accounts for 15～25%.Wherein,
1, first component
The first component is the mill base that emulsion, pigment, hollow glass micropearl, fire-retardant filler, filler, auxiliary agent, solvent are processed, meter by weight, prescription as follows:
30～50 parts of emulsions;
5～10 parts of pigment;
10～25 parts of hollow glass micropearls;
5～15 parts of fire-retardant fillers;
2～25 parts of fillers;
2～3 parts of auxiliary agents;
4～10 parts of solvents;
Among the present invention, emulsion is the benzene emulsion of epoxy resin latex modification, and raw material can be among EA-080, EB-370, XG-2000, the BC-3208 one or more, aqueous epoxy resin emulsion and benzene emulsion weight ratio be (0.2～1): 1.
Among the present invention; Pigment is Ginkgo Biloba Leaf Extract, ageing-resistant steady rust pigment or inert pigment; As: one or more mixing in red iron oxide, carbon black, toluidine red, white titanium pigment, phthalocyanine blue, phthalein viridescent, organic yellow, iron oxide black or the zn phosphate, requiring granularity is 300～500 μ m.
Among the present invention, fire-retardant filler can be one or more mixing in silica powder, Antimony Trioxide: 99.5Min, the gypsum fiber, and requiring granularity is 300～500 μ m.
Among the present invention, hollow glass micropearl is water white, and the surface is to handle through wetting ability, and particle diameter is 150～200 orders.Wetting ability is treated to this area conventional processing technology, sees also document: " tensio-active agent is to the research of hollow glass micropearl surface influence ".
Among the present invention, filler can be a kind of or two or more mixing in talcum powder, process white, ground barium sulfate, the GL ground limestone, and requiring granularity is 300～500 μ m.
Among the present invention, auxiliary agent is the mixture of several kinds of dispersion agent, skimmer, flow agent, anti-settling agent and thickening materials, and in the auxiliary agent, dispersion agent, skimmer, flow agent, anti-settling agent and thickening material parts by weight separately are 0.4～0.8 part.Dispersion agent is like the BYK-151 or the BYK104S of German Bi Ke chemical company, the high auxiliary agent Dispers755w of enlightening, Dispers651 or Dispers655; The high auxiliary agent Foamex of skimmer such as enlightening 815N, Foamex 810 or Foamex3062; The high auxiliary agent ViscoPlus of flow agent such as enlightening 3030, Glide440 or Wet KL245; High ViscoPlus3000 of thickening material such as enlightening or ViscoPlus3060; Anti-settling agent is a kind of or two kinds of mixing in wilkinite, the aerosil.
Among the present invention, solvent is a zero(ppm) water.
First component blending process:
In joining paint can, add aqueous epoxy resin emulsion and benzene emulsion earlier, start high speed dispersor, the revolution of dispersion machine is 800～1000 rev/mins; After 10～20 minutes, add pigment, fire-retardant filler, filler, auxiliary agent and solvent, stir; Grind on three-roller that to reach fineness be 60 μ m dischargings; Adjustment dispersion agent rotating speed stirs adding hollow glass micropearl down to 60-100 rev/min, and being uniformly dispersed gets final product packing.
2, component B
Count by weight, component B is a composite curing agent, and it is filled a prescription as follows:
65～75 parts in solidifying agent;
25～35 parts of curing catalysts;
Solidifying agent is an amine curing agent, and solidifying agent can be water miscible modified amine curing agent, like Ai Dike (ADCRE) aqueous epoxy curing agent EA-31, Zhejiang stablize the country ambient cure agent of AB-HGA water-base epoxy or Hanzhong, Shanghai H203B solidifying agent; Curing catalyst is like OP-8011/P, Lucidol or tertbutyl peroxide etc.
The blending process of component B:
Mix solidifying agent, curing catalyst to scale, stirring gets final product.
Among the present invention,, obtain the reflective thermal-insulating anti-flaming dope, can use first component and component B two portions uniform mixing in proportion.
Advantage of the present invention is following:
1, reflective thermal-insulating anti-flaming dope of the present invention is that the waterborne epoxy modified benzene emulsion of employing is a film forming matter, adds hollow glass micropearl, fire-retardant filler, auxiliary agent etc., reduces the heat conductivity of coating, improves ultrared reflectivity, plays the effect of energy-saving heat preserving.
2, reflective thermal-insulating anti-flaming dope of the present invention is to adopt the Compositional type solidifying agent to improve sticking power, curing speed and mechanical property.
3, the color stuffing that adopts of reflective thermal-insulating anti-flaming dope of the present invention satisfies fire-retardant, UV resistant, ageing-resistant requirement, and does not destroy putting in order of glass microballon.
4, reflective thermal-insulating anti-flaming dope paint film matter of the present invention is close hard, has excellent abrasive, water tolerance, stability to aging and acid corrosion-resistant characteristic.
5, reflective thermal-insulating anti-flaming dope of the present invention and base material have good sticking power and physical strength such as shock-resistant.
6, this reflective thermal-insulating anti-flaming dope can brushing, blade coating, roller coat, constructional method is simple, and the suitable construction time is arranged.
7, reflective thermal-insulating anti-flaming dope high build paint of the present invention, one-pass film-forming is thick, easy construction.
8, the present invention utilizes the reflection potential of hollow glass micropearl, has improved coating to ultrared reflectivity, has reduced the energy absorption of coating; The hollow structure of while glass microballon; Make the micropore of the densely covered sealing in inside of coating, reduced the thermal conductivity of coating, improved the heat-insulating property of coating.
Embodiment
Embodiment 1
In the present embodiment, the reflective thermal-insulating anti-flaming dope comprises: priming paint, intermediate coat and finish paint, and its concrete composition and weight:
The reflective thermal-insulating anti-flaming dope
Embodiment 2
In the present embodiment, the reflective thermal-insulating anti-flaming dope comprises: priming paint, intermediate coat and finish paint, and its concrete composition and weight:
The reflective thermal-insulating anti-flaming dope
Embodiment 3
In the present embodiment, the reflective thermal-insulating anti-flaming dope comprises: priming paint, intermediate coat and finish paint, and its concrete composition and weight:
The reflective thermal-insulating anti-flaming dope
Preparation of the present invention is undertaken by general preparation process, and preparation process is following:
First component blending process:
In joining paint can, add aqueous epoxy resin emulsion and benzene emulsion earlier, start high speed dispersor, the revolution of dispersion machine is 800～1000 rev/mins; After 10～20 minutes, add pigment, fire-retardant filler, filler, auxiliary agent and solvent, stir; Grind on three-roller that to reach fineness be 60 μ m dischargings; Adjustment dispersion agent rotating speed stirs adding hollow glass micropearl down to 60-100 rev/min, and being uniformly dispersed gets final product packing.
The blending process of component B:
Mix solidifying agent, curing catalyst to scale, stirring gets final product.
Among the present invention,, obtain the reflective thermal-insulating anti-flaming dope, can use first component and component B two portions uniform mixing in proportion.
The present invention can be in steelwork and concrete surface construction, and substrate surface need pass through polishing or sandblasting, surfaceness 40～70 μ m.
Construction technology:
Reflective thermal-insulating anti-flaming dope of the present invention can adopt conventional coating process, like brushing, blade coating, Airless spraying, roller coat etc.
Priming paint: at the substrate surface of handling, spraying, brushing or roller coat priming paint one, build 80～150 μ m.Construction 8～12 hours at interval.
Intermediate coat: blade coating intermediate coat twice, per pass build 1mm, construction is at interval more than 24 hours.
Finish paint: scrape overpainting lacquer twice, per pass film thickness 1mm, construction is at interval more than 24 hours.
Performance index detect:
Claims (10)
1. a reflective thermal-insulating anti-flaming dope is characterized in that, is made up of first component and component B two portions, and by weight percentage, the first component accounts for 75～85%, and component B accounts for 15～25%; Wherein,
(1) first component
The first component is that emulsion, pigment, hollow glass micropearl, fire-retardant filler, filler, auxiliary agent, solvent are processed, meter by weight, prescription as follows:
30～50 parts of emulsions;
5～10 parts of pigment;
10～25 parts of hollow glass micropearls;
5～15 parts of fire-retardant fillers;
2～25 parts of fillers;
2～3 parts of auxiliary agents;
4～10 parts of solvents;
(2) component B
Count by weight, component B is a composite curing agent, and it is filled a prescription as follows:
65～75 parts in solidifying agent;
25～35 parts of curing catalysts.
2. according to the described reflective thermal-insulating anti-flaming dope of claim 1, it is characterized in that emulsion is the benzene emulsion of aqueous epoxy resin emulsion modification, raw material is one or more among EA-080, EB-370, XG-2000, the BC-3208.
3. according to the described reflective thermal-insulating anti-flaming dope of claim 1, it is characterized in that pigment is Ginkgo Biloba Leaf Extract, ageing-resistant steady rust pigment or acrylic paints.
4. according to the described reflective thermal-insulating anti-flaming dope of claim 1; It is characterized in that; Pigment is one or more mixing in red iron oxide, carbon black, toluidine red, white titanium pigment, phthalocyanine blue, phthalein viridescent, organic yellow, iron oxide black or the zn phosphate, and requiring granularity is 300～500 μ m.
5. according to the described reflective thermal-insulating anti-flaming dope of claim 1, it is characterized in that hollow glass micropearl is water white, handle through wetting ability on the surface, and particle diameter is 150～200 orders.
6. according to the described reflective thermal-insulating anti-flaming dope of claim 1, it is characterized in that fire-retardant filler is a kind of or two or more mixing in silica powder, Antimony Trioxide: 99.5Min, the fibrous magnesium silicate, requiring granularity is 300～500 μ m.
7. according to the described reflective thermal-insulating anti-flaming dope of claim 1, it is characterized in that filler is a kind of or two or more mixing in talcum powder, process white, ground barium sulfate, the GL ground limestone, requiring granularity is 300～500 μ m.
8. according to the described reflective thermal-insulating anti-flaming dope of claim 1, it is characterized in that auxiliary agent is the mixture of several kinds of dispersion agent, skimmer, flow agent, anti-settling agent and thickening materials.
9. according to the described reflective thermal-insulating anti-flaming dope of claim 1, it is characterized in that solvent is a zero(ppm) water.
10. according to the preparation method of the described reflective thermal-insulating anti-flaming dope of claim 1, it is characterized in that, comprise that step is following:
(1) first component
In joining paint can, add aqueous epoxy resin emulsion and benzene emulsion earlier, start high speed dispersor, the revolution of dispersion machine is 800～1000 rev/mins; After 10～20 minutes, add pigment, fire-retardant filler, filler, auxiliary agent and solvent, stir; Grind on three-roller that to reach fineness be 60 μ m dischargings; Adjustment dispersion agent rotating speed stirs adding hollow glass micropearl down to 60-100 rev/min, and being uniformly dispersed gets final product packing;
(2) component B
Stir solidifying agent, curing catalyst to scale and to get final product;
With first component and component B two portions uniform mixing in proportion, obtain reflective thermal-insulating sun burning coating material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201110102544.5A CN102719150B (en) | 2011-04-25 | 2011-04-25 | Reflecting heat-insulation flame-retardant paint and preparation method thereof |
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| CN201110102544.5A CN102719150B (en) | 2011-04-25 | 2011-04-25 | Reflecting heat-insulation flame-retardant paint and preparation method thereof |
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| CN102719150A true CN102719150A (en) | 2012-10-10 |
| CN102719150B CN102719150B (en) | 2015-01-14 |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103146269A (en) * | 2013-01-16 | 2013-06-12 | 湖南工业大学 | Preparation method for water-based high reflection radiation compound heat preservation and heat insulation coatings |
| CN103146241A (en) * | 2012-12-11 | 2013-06-12 | 亮克威泽(北京)涂料科技有限公司 | Unsaturated polyester putty base resin used for locomotive, preparation method of base resin and putty including base resin |
| CN103289441A (en) * | 2013-05-23 | 2013-09-11 | 铜陵瑞莱科技有限公司 | Method for preparing flame-retardant iron oxide black granules |
| CN104530859A (en) * | 2014-12-11 | 2015-04-22 | 青岛佰众化工技术有限公司 | Thin-layer heat-preserving insulation coating material |
| CN104830164A (en) * | 2015-05-21 | 2015-08-12 | 黎司华 | Deep-color water-based heat-insulation external wall paint |
| CN105176217A (en) * | 2015-10-20 | 2015-12-23 | 苏州赛斯德工程设备有限公司 | Waterborne composite heat-insulating decoration coating and preparation method thereof |
| CN105457875A (en) * | 2015-12-31 | 2016-04-06 | 卓达新材料科技集团有限公司 | Spraying method |
| CN105778421A (en) * | 2016-03-31 | 2016-07-20 | 华南理工大学 | Solvent-free anti-corrosion insulation material capable of being solidified at room temperature for petrochemical pipeline and preparation method and application of solvent-free anti-corrosion insulation material |
| CN111117317A (en) * | 2020-01-06 | 2020-05-08 | 常州工程职业技术学院 | Flame-retardant heat-insulation coating for outer wall and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1974695A (en) * | 2006-11-23 | 2007-06-06 | 复旦大学 | Super thin no-halogen less-smoke fire proof organic-inorganic composite paint and its prepn process |
| CN101440249A (en) * | 2008-05-23 | 2009-05-27 | 海洋化工研究院 | Ultrathin section steel structure fire-resisting paint and preparation thereof |
-
2011
- 2011-04-25 CN CN201110102544.5A patent/CN102719150B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1974695A (en) * | 2006-11-23 | 2007-06-06 | 复旦大学 | Super thin no-halogen less-smoke fire proof organic-inorganic composite paint and its prepn process |
| CN101440249A (en) * | 2008-05-23 | 2009-05-27 | 海洋化工研究院 | Ultrathin section steel structure fire-resisting paint and preparation thereof |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103146241A (en) * | 2012-12-11 | 2013-06-12 | 亮克威泽(北京)涂料科技有限公司 | Unsaturated polyester putty base resin used for locomotive, preparation method of base resin and putty including base resin |
| CN103146241B (en) * | 2012-12-11 | 2015-12-02 | 亮克威泽(北京)涂料科技有限公司 | Unsaturated polyester putty host and preparation method thereof for railway locomotive and the putty containing this host |
| CN103146269A (en) * | 2013-01-16 | 2013-06-12 | 湖南工业大学 | Preparation method for water-based high reflection radiation compound heat preservation and heat insulation coatings |
| CN103289441A (en) * | 2013-05-23 | 2013-09-11 | 铜陵瑞莱科技有限公司 | Method for preparing flame-retardant iron oxide black granules |
| CN104530859A (en) * | 2014-12-11 | 2015-04-22 | 青岛佰众化工技术有限公司 | Thin-layer heat-preserving insulation coating material |
| CN104830164A (en) * | 2015-05-21 | 2015-08-12 | 黎司华 | Deep-color water-based heat-insulation external wall paint |
| CN105176217A (en) * | 2015-10-20 | 2015-12-23 | 苏州赛斯德工程设备有限公司 | Waterborne composite heat-insulating decoration coating and preparation method thereof |
| CN105457875A (en) * | 2015-12-31 | 2016-04-06 | 卓达新材料科技集团有限公司 | Spraying method |
| CN105778421A (en) * | 2016-03-31 | 2016-07-20 | 华南理工大学 | Solvent-free anti-corrosion insulation material capable of being solidified at room temperature for petrochemical pipeline and preparation method and application of solvent-free anti-corrosion insulation material |
| CN111117317A (en) * | 2020-01-06 | 2020-05-08 | 常州工程职业技术学院 | Flame-retardant heat-insulation coating for outer wall and preparation method thereof |
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| CN102719150B (en) | 2015-01-14 |
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Inventor after: Liu Hongwei Inventor after: Liu Wuzhu Inventor after: Zhang Lei Inventor after: Du Zhishun Inventor after: Xu Tiequn Inventor after: Sun Cheng Inventor before: Liu Hongwei Inventor before: Du Zhishun Inventor before: Xu Tiequn Inventor before: Sun Cheng |
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Free format text: CORRECT: INVENTOR; FROM: LIU HONGWEI DU ZHISHUN XU TIEQUN SUN CHENG TO: LIU HONGWEI LIU WUZHU ZHANGLEI DU ZHISHUN XU TIEQUN SUN CHENG |
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