CN104530958A - Dark low solar energy absorption coating and preparation method thereof - Google Patents

Dark low solar energy absorption coating and preparation method thereof Download PDF

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Publication number
CN104530958A
CN104530958A CN201410739126.0A CN201410739126A CN104530958A CN 104530958 A CN104530958 A CN 104530958A CN 201410739126 A CN201410739126 A CN 201410739126A CN 104530958 A CN104530958 A CN 104530958A
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China
Prior art keywords
solar energy
low solar
energy absorbing
component
dark color
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CN201410739126.0A
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Chinese (zh)
Inventor
苏孟兴
庄海燕
陈翔
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725th Research Institute of CSIC
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725th Research Institute of CSIC
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Priority to CN201410739126.0A priority Critical patent/CN104530958A/en
Publication of CN104530958A publication Critical patent/CN104530958A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints

Abstract

The invention relates to a dark low solar energy absorption coating and a preparation method thereof. The coating provided by the invention has high near-infrared reflectivity and high mid and far infrared reflectivity as well as low thermal conductivity, can be applied to ship decks and superstructures, can significantly reduce the sunlight radiation energy absorption by a hull surface and lower the temperature in the cabin, thereby saving the air conditioner cost. The dark low solar energy absorption coating can also be popularized and applied to plants, chemical containers, steel structures, terraces, building facades and other fields to play a cooling role, and has significant economic effects and broad market prospects.

Description

A kind of dark low solar energy absorbing paint and preparation method thereof
[technical field]
The present invention relates to special functional coating field, be specifically related to a kind of dark low solar energy absorbing paint and preparation method thereof.
[background technology]
External researcher has done a lot of research in low solar energy absorbing paint, oneself is through there being small part heat reflection coatings to be applied in some field, wherein Britain reports a kind of low solar energy absorbing paint of brown, it is made up of membrane-forming agent and near infrared heat reflection pigment, near infrared reflectivity >=70%, sunlight specular reflectance included >=45%; Sun power group company of the U.S. develops a kind of low solar energy absorbing paint, uses building top room, the temperature of indoor can be reduced by 5.5 ~ 14.5 DEG C, the air-conditioning expense of 8% ~ 12% can be saved, and in the winter time, thermal radiation also can be stoped to flow out outside room, the heat cost of 1% ~ 2% can be saved again; U.S.'s shield energy-saving coatings, for space shuttle, has heat-insulation and heat-preservation function, coated article internal temperature can be made greatly to reduce, saving energy 40%; Japan have developed the ceramic packing (titanium dioxide, zinc oxide, magnesium oxide, silicon-dioxide, aluminum oxide be made up of) of a kind of particle diameter at below 1nm, this material has the feature of low thermal conductivity and low specific heat, and the low solar energy absorbing paint of this filler of interpolation can be made to have obvious cooling-down effect.
Covil construction heat reflection coatings has industry internal standard at home: JG/T235-2008, index request is proposed to the decay of the solar energy reflection ratio of heat reflection coatings, hemispherical emissivity, the heat insulation temperature difference and the heat insulation temperature difference, domesticly be mainly white or light color about low solar energy absorbing paint that is energy-conservation, cooling function, as Chinese patent, publication number is CN102766366A, and publication date is the reflective heat-insulation paint on November 07th, 2012; Chinese patent, publication number is CN102234198A, and publication date is the heat reflection energy-saving coating on November 09th, 2011; In the low solar energy absorbing paint of dark color, Chinese patent, publication number is CN101531863, and publication date is grey hull finish coat in a kind of low solar absorbing energy-saving type of on 09 16th, 2009; Chinese patent, publication number is CN102181217A, publication date is colour reflective thermal insulating coating and the colour atla thereof of on 09 14th, 2011, this coating adopts the pigment such as carbon black, red iron oxide, organic yellow, phthalein viridescent, phthalocyanine blue that ferrochrome is black, ferrochrome is red, cobalt blue, titan yellow, cobalt green five kinds of pigment replace tradition conventional, higher to the reflectivity of sun power.But it is black pigment that this colo(u)r coating adopts ferrochrome black, the tinting strength that ferrochrome is black is poor, and it is black to add a large amount of ferrochrome when being prepared into dark-colored paint, causes the reflectivity of sun power to decline obviously, and ferrochrome mineral black contains poisonous chromium element, runs counter to safety and environmental protection theory.
[summary of the invention]
For overcoming the deficiency existed in background technology, the invention provides a kind of dark low solar energy absorbing paint and preparation method thereof, the present invention is by high IR transparent resin, high near-infrared reflection pigment and senior middle school's far infrared transmissivity packing screening and formulating of recipe, develop the low solar energy absorbing paint of dark color that cooling-down effect is remarkable and workability is good, for exposure portion such as boats and ships, building, locomotive, petrochemical industry storage tank and reactor outer walls, reduce internal temperature, improve comfort level and reduce air conditioning energy consumption.
For realizing goal of the invention as above, the present invention adopts technical scheme as described below:
A kind of dark low solar energy absorbing paint, the component of described coating comprises first component and second component, and described first component comprises by mass percentage:
Acrylic acid modified polyhydroxy resin 25 ~ 45%;
High infrared reflection white pigment 10 ~ 35%;
High emissivity superfine powder 3 ~ 15%;
High infrared reflection black pigment 3 ~ 20%;
High infrared reflection blue pigments 0 ~ 3.0%;
High infrared reflection veridian 0 ~ 3.5%;
High infrared reflection yellow ultramarine 0 ~ 3.5%;
High infrared reflection red pigment 0 ~ 3.5%;
Solvent 6 ~ 18%;
Auxiliary agent 1.5 ~ 5%;
Described second component is aliphatic polymeric isocyanate;
Described first component is 85 ~ 90% of coating total mass, and second component is 10 ~ 15% of coating total mass.
The low solar energy absorbing paint of described dark color, described high infrared reflection white pigment is sodium-zinc-phosphate, the one of titanium dioxide or its combination.
The low solar energy absorbing paint of described dark color, described high emissivity superfine powder is as filler, and high emissivity superfine powder is silicon carbide, zirconium dioxide, Wingdale, gypsum, the one of calcined kaolin or combination.
The low solar energy absorbing paint of described dark color, described high infrared reflection black pigment is the high near infrared reflectivity dark material be made up of Copper-cladding Aluminum Bar semiconductor oxide zinc and Copper-cladding Aluminum Bar sodium-zinc-phosphate.
The low solar energy absorbing paint of described dark color, described high infrared reflection blue pigments is the composite oxides of cobalt, zinc, phosphoric.
The low solar energy absorbing paint of described dark color, described high infrared reflection veridian is the composite oxides of copper, zinc, phosphoric.
The low solar energy absorbing paint of described dark color, described high infrared reflection red pigment is the composite oxides of iron, zinc, phosphoric.
The low solar energy absorbing paint of described dark color, described solvent is the combination of dimethylbenzene, N-BUTYL ACETATE and PMA.
The low solar energy absorbing paint of described dark color, described auxiliary agent comprises dispersion agent, defoamer, flow agent and thixotropic agent, wherein dispersion agent is the Multi-functional dispersion agent of applicable oiliness polyurethane system, defoamer is the defoamer of applicable oiliness polyurethane system, flow agent is the flow agent of applicable oiliness polyurethane system, and thixotropic agent generally selects organobentonite.
A preparation method for the low solar energy absorbing paint of dark color, described preparation method specifically comprises the steps:
One, to face, paddle dryer process:
First appropriate face, filler is taken according to dark color low solar energy absorbing paint first component proportion, then the baking oven face taken, filler being placed in 110 ± 5 DEG C is dried, drying time is 2 ~ 12h, after naturally cooling, face, filler is packed respectively sealing for subsequent use, line identifier of going forward side by side;
Two, first component is prepared:
Connect step, acrylic acid modified polyhydroxy resin, auxiliary agent are weighed by proportion speed and adds charging basket, and add partial solvent, with high speed dispersor stirring at low speed 5 ~ 45min, add filler and the pigment of step acquisition after being uniformly dispersed, high-speed stirring 15 ~ 60min, grind 0.5 ~ 4h after being uniformly dispersed again and reach less than 60 μm to coating fineness, by residual solvent adjustment viscosity to suitable scope, detect viscosity, qualified rear filtration, discharging, tinning and packaging;
Three, coating preparation:
First component and second component are mixed by proportioning, stirs, can application be carried out.
Adopt technical scheme as above, the present invention has superiority as described below:
Dark low solar energy absorbing paint of one of the present invention and preparation method thereof, the present invention has high near infrared reflectivity and high mid and far infrared reflectivity and low thermal conductivity, be applied to ship deck and superstructure, significantly can reduce the absorption of hull surface to solar radiation energy, reduce temperature in cabin, and then save air-conditioning expense, dark low solar energy absorbing paint also can promote the use of the fields such as factory building, pressure vessels for the chemical industry, steel construction, terrace, external wall, play cooling-down effect, economical effectiveness is obvious, wide market.
[accompanying drawing explanation]
Fig. 1 is the production technological process of first component of the present invention;
Fig. 2 is ultraviolet-visible light-near-infrared spectral reflectance of the present invention;
[embodiment]
Can explain the present invention in more detail by the following examples, the present invention is not limited to the following examples;
The dark low solar energy absorbing paint of one of the present invention, the component of described coating comprises first component and second component, and described first component comprises by mass percentage:
Acrylic acid modified polyhydroxy resin 25 ~ 45%; High infrared reflection white pigment 10 ~ 35%;
High emissivity superfine powder 3 ~ 15%; High infrared reflection black pigment 3 ~ 20%;
High infrared reflection blue pigments 0 ~ 3.0%; High infrared reflection veridian 0 ~ 3.5%;
High infrared reflection yellow ultramarine 0 ~ 3.5%; High infrared reflection red pigment 0 ~ 3.5%;
Solvent 6 ~ 18%; Auxiliary agent 1.5 ~ 5%.
Described second component is aliphatic polymeric isocyanate;
Described first component is 85 ~ 90% of coating total mass, and second component is 10 ~ 15% of coating total mass.
Wherein said white pigment is sodium-zinc-phosphate, the one of titanium dioxide or its combination; Described high emissivity superfine powder is silicon carbide, zirconium dioxide, Wingdale, the one of gypsum or combination; Described high infrared reflection black pigment is the high near infrared reflectivity dark material be made up of Copper-cladding Aluminum Bar semiconductor oxide zinc and Copper-cladding Aluminum Bar sodium-zinc-phosphate; Described high infrared reflection blue pigments is the composite oxides of the elements such as cobalt, zinc, phosphorus; Described high infrared reflection veridian is the composite oxides of the elements such as copper, zinc, phosphorus; Described high infrared reflection red pigment is the composite oxides of the elements such as iron, zinc, phosphorus; Described solvent is the combination of dimethylbenzene, N-BUTYL ACETATE and PMA; Described auxiliary agent comprises dispersion agent, defoamer, flow agent and thixotropic agent, wherein dispersion agent is the Multi-functional dispersion agent of applicable oiliness polyurethane system, as the BYK110 etc. of Beyer Co., Ltd, defoamer is the defoamer of applicable oiliness polyurethane system, as 6800 of De Qian company, the EFKA2020 of EFKA company, flow agent is the flow agent of applicable oiliness polyurethane system, as the EFKA3777 of EFKA company, thixotropic agent generally selects organobentonite.
A preparation method for the low solar energy absorbing paint of dark color, described preparation method specifically comprises the steps:
One, to face, paddle dryer process:
First appropriate face, filler is taken according to dark color low solar energy absorbing paint first component proportion, wherein pigment comprises high infrared reflection white pigment, high infrared reflection black pigment, high infrared reflection blue pigments, high infrared reflection veridian, high infrared reflection yellow ultramarine and high infrared reflection red pigment, and filler is high emissivity superfine powder; Then the baking oven face taken, filler being placed in 110 ± 5 DEG C is dried, and drying time is 2 ~ 12h, after naturally cooling, face, filler is packed respectively sealing for subsequent use, line identifier of going forward side by side;
Two, first component is prepared:
Connect step, by reference to the accompanying drawings 1, acrylic acid modified polyhydroxy resin, auxiliary agent are weighed by proportion speed and adds charging basket, and add partial solvent, with high speed dispersor stirring at low speed 5 ~ 45min, filler and the pigment of step acquisition is added after being uniformly dispersed, high-speed stirring 15 ~ 60min, grinds 0.5 ~ 4h again and reaches less than 60 μm to coating fineness after being uniformly dispersed, by residual solvent adjustment viscosity to suitable scope, detect viscosity, qualified rear filtration, discharging, tinning and packaging;
Three, coating preparation:
First component and second component are mixed by proportioning, stirs, can application be carried out.
For the resin of the low solar energy absorbing paint of dark color in the present invention, should have lower to visible ray, infrared Absorption rate and weathering resistance preferably, therefore should select that transparency is high, not easily be sunlighted and the resin of cracking comparatively greatly containing heat absorption group, molecular bond energies such as C O C, C=O, O H less in molecular structure as far as possible.Based on the high IR optical transparency of urethane resin, containing a large amount of bond energy higher C=N key, good weatherability, select acrylic acid modified polyhydroxy resin and aliphatic polymeric isocyanate as the resin binder of the low solar energy absorbing paint of dark color;
Selecting main coloring pigment, reaches earth surface solar radiation energy distribution and is roughly: UV-light 5%, visible ray 45%, infrared light 50%.The reflection of visible light part determines primarily of the color of coating, and color is darker, and visible light reflectance is lower, and dark paint has the visible reflectance lower than whitewash.For specific color, as Dark grey, visible light reflectance is determined, so total solar energy reflection is than determining primarily of its infrared reflectance.The key of modulating dark heat reflection coatings is the dark pigment selecting high infrared reflection.Desirable dark heat reflection pigment should have at visible light wave range and absorbs more by force, and has high-reflectivity at near-infrared band.Select the high near infrared reflectivity dark material be made up of Copper-cladding Aluminum Bar semiconductor oxide zinc and Copper-cladding Aluminum Bar sodium-zinc-phosphate as black pigment, the one of sodium-zinc-phosphate, titanium dioxide or be combined as high near-infrared reflection white pigment, cobalt, zinc, phosphorus mixed oxide are high near-infrared reflection blue pigments, copper, zinc, composite phosphorus oxide are high near-infrared reflection veridian, and iron, zinc, composite phosphorus oxide are high near-infrared reflection red pigment.
Because dark coating has high specific absorption at visible light wave range, also certain absorption is had at near-infrared band, by improving the emittance of dark coating, thus by arrive the solar radiation Conversion of energy on its surface be heat reflection electromagenetic wave radiation in air, and then improve its temperature reduction performance.Select the one of the silicon carbide of high emissivity, zirconium dioxide, Wingdale, gypsum or combine as functional stuffing, coating being fallen with the heat radiation of the form of heat emission by absorption, thus impels coated article body indoor and outdoor to keep same rate of temperature fall.
The present invention has high near infrared reflectivity and high mid and far infrared reflectivity and low thermal conductivity, is applied to ship deck and superstructure, significantly can reduces the absorption of hull surface to solar radiation energy, reduces temperature in cabin, and then saves air-conditioning expense.The present invention also can promote the use of the fields such as factory building, pressure vessels for the chemical industry, steel construction, terrace, external wall, plays cooling-down effect, and economical effectiveness is obvious, wide market.Ultraviolet-visible light-the near-infrared spectral reflectance of the low solar energy absorbing coating of a kind of dark color is shown in accompanying drawing 2.
The present invention is two component chemical reaction curable coatings, and coating can adopt two component airless spraying, high pressure Air spraying, roller coat, application is carried out in brushing, recommends application thickness to be 100 μm.Embodiment and products thereof detected result sees the following form.
The formula of embodiment
Detected result
Part not in the detailed description of the invention is prior art.
The embodiment selected in this article in order to open object of the present invention, currently thinks to be suitable for, but it is to be understood that the present invention is intended to comprise all changes belonging to the embodiment in this design and invention scope and improvement.

Claims (10)

1. the low solar energy absorbing paint of dark color, the component of described coating comprises first component and second component, it is characterized in that: described first component comprises by mass percentage:
Acrylic acid modified polyhydroxy resin 25 ~ 45%;
High infrared reflection white pigment 10 ~ 35%;
High emissivity superfine powder 3 ~ 15%;
High infrared reflection black pigment 3 ~ 20%;
High infrared reflection blue pigments 0 ~ 3.0%;
High infrared reflection veridian 0 ~ 3.5%;
High infrared reflection yellow ultramarine 0 ~ 3.5%;
High infrared reflection red pigment 0 ~ 3.5%;
Solvent 6 ~ 18%;
Auxiliary agent 1.5 ~ 5%;
Described second component is aliphatic polymeric isocyanate;
Described first component is 85 ~ 90% of coating total mass, and second component is 10 ~ 15% of coating total mass.
2. the low solar energy absorbing paint of dark color according to claim 1, is characterized in that: described high emissivity superfine powder is as filler, and high emissivity superfine powder is silicon carbide, zirconium dioxide, Wingdale, gypsum, the one of calcined kaolin or combination.
3. the low solar energy absorbing paint of dark color according to claim 1, is characterized in that: described high emissivity superfine powder is silicon carbide, zirconium dioxide, Wingdale, the one of gypsum or combination.
4. the low solar energy absorbing paint of dark color according to claim 1, is characterized in that: described high infrared reflection black pigment is the high near infrared reflectivity dark material be made up of Copper-cladding Aluminum Bar semiconductor oxide zinc and Copper-cladding Aluminum Bar sodium-zinc-phosphate.
5. the low solar energy absorbing paint of dark color according to claim 1, is characterized in that: described high infrared reflection blue pigments is the composite oxides of cobalt, zinc, phosphoric.
6. the low solar energy absorbing paint of dark color according to claim 1, is characterized in that: described high infrared reflection veridian is the composite oxides of copper, zinc, phosphoric.
7. the low solar energy absorbing paint of dark color according to claim 1, is characterized in that: described high infrared reflection red pigment is the composite oxides of iron, zinc, phosphoric.
8. the low solar energy absorbing paint of dark color according to claim 1, is characterized in that: described solvent is the combination of dimethylbenzene, N-BUTYL ACETATE and PMA.
9. the low solar energy absorbing paint of dark color according to claim 1, it is characterized in that: described auxiliary agent comprises dispersion agent, defoamer, flow agent and thixotropic agent, wherein dispersion agent is the Multi-functional dispersion agent of applicable oiliness polyurethane system, defoamer is the defoamer of applicable oiliness polyurethane system, flow agent is the flow agent of applicable oiliness polyurethane system, and thixotropic agent generally selects organobentonite.
10. utilize the preparation method of the low solar energy absorbing paint of a kind of dark color of the low solar energy absorbing paint of dark color described in the arbitrary claim of claim 1 ~ 9, it is characterized in that: described preparation method specifically comprises the steps:
One, to face, paddle dryer process:
First appropriate face, filler is taken according to dark color low solar energy absorbing paint first component proportion, then the baking oven face taken, filler being placed in 110 ± 5 DEG C is dried, drying time is 2 ~ 12h, after naturally cooling, face, filler is packed respectively sealing for subsequent use, line identifier of going forward side by side;
Two, first component is prepared:
Connect step, acrylic acid modified polyhydroxy resin, auxiliary agent are weighed by proportion speed and adds charging basket, and add partial solvent, with high speed dispersor stirring at low speed 5 ~ 45min, add filler and the pigment of step acquisition after being uniformly dispersed, high-speed stirring 15 ~ 60min, grind 0.5 ~ 4h after being uniformly dispersed again and reach less than 60 μm to coating fineness, by residual solvent adjustment viscosity to suitable scope, detect viscosity, qualified rear filtration, discharging, tinning and packaging;
Three, coating preparation:
First component and second component are mixed by proportioning, stirs, can application be carried out.
CN201410739126.0A 2014-12-08 2014-12-08 Dark low solar energy absorption coating and preparation method thereof Pending CN104530958A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105238247A (en) * 2015-10-21 2016-01-13 中国船舶重工集团公司第七二五研究所 Preparation method of waterborne polyurethane reflective insulation coating
CN108699363A (en) * 2015-12-29 2018-10-23 Ppg工业俄亥俄公司 IR fluorescence coating composition
CN110997464A (en) * 2017-08-14 2020-04-10 日产自动车株式会社 Moving body having reflection control layer
CN110997463A (en) * 2017-08-14 2020-04-10 日产自动车株式会社 Moving body having reflection control layer
US10927267B2 (en) 2014-03-31 2021-02-23 Ppg Industries Ohio, Inc. Infrared fluorescent coatings
CN114940845A (en) * 2022-04-21 2022-08-26 上海淞叶新材料有限公司 Organic black paste with infrared transmission function and preparation method thereof
US11834579B2 (en) 2020-12-18 2023-12-05 Toyota Motor Engineering & Manufacturing North America, Inc. Near infrared reflective copper oxide coated particles

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10927267B2 (en) 2014-03-31 2021-02-23 Ppg Industries Ohio, Inc. Infrared fluorescent coatings
US11584860B2 (en) 2014-03-31 2023-02-21 Ppg Industries Ohio, Inc. Infrared fluorescent coatings
CN105238247A (en) * 2015-10-21 2016-01-13 中国船舶重工集团公司第七二五研究所 Preparation method of waterborne polyurethane reflective insulation coating
CN108699363A (en) * 2015-12-29 2018-10-23 Ppg工业俄亥俄公司 IR fluorescence coating composition
CN108699363B (en) * 2015-12-29 2020-12-18 Ppg工业俄亥俄公司 Infrared fluorescent coating composition
US11370925B2 (en) 2015-12-29 2022-06-28 Ppg Industries Ohio, Inc. Infrared fluorescent coatings
US11479677B2 (en) 2015-12-29 2022-10-25 Ppg Industries Ohio, Inc. Infrared fluorescent coating compositions
US11702551B2 (en) 2015-12-29 2023-07-18 The Regents Of The University Of California Infrared fluorescent coatings
CN110997464A (en) * 2017-08-14 2020-04-10 日产自动车株式会社 Moving body having reflection control layer
CN110997463A (en) * 2017-08-14 2020-04-10 日产自动车株式会社 Moving body having reflection control layer
US11834579B2 (en) 2020-12-18 2023-12-05 Toyota Motor Engineering & Manufacturing North America, Inc. Near infrared reflective copper oxide coated particles
CN114940845A (en) * 2022-04-21 2022-08-26 上海淞叶新材料有限公司 Organic black paste with infrared transmission function and preparation method thereof

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Application publication date: 20150422