CN102703243A - Abluent and preparation method thereof - Google Patents
Abluent and preparation method thereof Download PDFInfo
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- CN102703243A CN102703243A CN201210180837XA CN201210180837A CN102703243A CN 102703243 A CN102703243 A CN 102703243A CN 201210180837X A CN201210180837X A CN 201210180837XA CN 201210180837 A CN201210180837 A CN 201210180837A CN 102703243 A CN102703243 A CN 102703243A
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Abstract
The invention application provides a prescription for abluent which is environment-friendly, does not injury the skin, can be used for daily life such as cleaning dinnerware, and has the functions of oil removal, stain removal and rust removal. The abluent includes the following components in mass percent: 6%-12% of anionic surface active agent, 5.0%-8.0% of non-ionic surface active agent, 5.0%-8.0% of organic acid, 1.0%-2.0% of NaCl, 2.0%-15.0% of winter cherry extract, 0.2%-2.0% of essence, 0.2%-3.0% of preservative, 0.1%-1.0% of alkali, and 64.0%-75.0% of pure water. The abluent disclosed by the invention application is simple in component composition and production process, has the remarkable advantage of achieving oil removal, stain removal and rust removal effects at the same time, adopts natural winter cherry extract for rust removal, and is suitable for rust removal and cleaning of daily use articles.
Description
Technical field
Application of the present invention relates to articles for washing technical field in the chemical field, is specifically related to the cleaning agent that a kind of decontamination of deoiling is derusted, and is mainly used in tableware, the cleaning of kitchen tackle etc.
Background technology
The environmental protection of people's pay attention to day by day, as the daily necessities that is prone to consumption, people are also increasingly high to the requirement of washing composition articles for use; More and more; Decontamination is deoiled can not satisfy people's requirement far away as the basic function of washing composition, along with increasing stainless steel and mould the system tableware and be used, the rust cleaning oil removing of tableware also becomes a difficult problem that runs in the people life day by day; Present cleaning agent, very satisfied requirement to people.
The derusting method that uses at present generally has four types: one, hand cleaning, two, mechanical rust removal, three, ultrasonic cleaning, four, chemical rust removing.Hand cleaning speed is slow, and efficient is low, and metal itself is had very big influence; Be not fit to the rust cleaning of tableware, mechanical rust removal refers to use handheld tool, removes loose zone of oxidation in metallic surface and corrosion thing; Speed is fast, and it is obviously unrealistic obviously to be used in fine product such as tableware, and ultrasonic cleaning is a kind of physical method; Promptly utilize high-frequency vibration to fall the loose shake of repairing, though its environmental protection, not desired simple and efficiently do not conform in daily life is used.Acid wash is generally adopted in chemical rust removing, the general mineral acid that uses in the pickling, and like sulfuric acid, hydrochloric acid; Nitric acid, phosphoric acid etc., the mineral acid oxidisability of more than mentioning is strong, and the effect that is used for eliminating rust is fine; Yet these sour corrodibility are also very strong, if be used for not only not environmental protection in the daily life, and probably bring danger to people, and people's health is also had corrosive nature; The use organic acid is also arranged, like Hydrocerol A, thionamic acid, its advantage is a relative environmental protection; But organic acid rust cleaning cost is high, and the time is long, and temperature of reaction requires also high, is difficult to apply in the dish washing detergent.
Use the washing composition that can eliminate rust in daily life; Not only security requirement is high, environmental protection, use, simple to operate also must be its necessary conditions; But receive the limitation of the technical elements of present derusting method, above rust cleaning mode is difficult to satisfy the requirement of people's daily life to rust cleaning type washing composition.
Invention application content
One of purpose of application of the present invention is the defective that exists to existing washing composition, and a kind of environmental protection is provided, do not hinder skin, can be used for daily life such as tableware, possess simultaneously and deoil, and decontamination, the prescription of the cleaning agent that derusts:
A kind of cleaning agent comprises the various components of following quality percentage composition: aniorfic surfactant 6%-12%, nonionogenic tenside 5.0%-8.0%; Organic acid 5.0%-8.0%, NaCl 1.0%-2.0%, Sorrel extract 2.0%-15.0%; Essence 0.2%-2.0%; Sanitas 0.2%-3.0%, alkali 0.1%-1.0%, pure water 64.0%-75.0%.
Further, described aniorfic surfactant comprises fat alcohol polyethylene ether vitriol, Witco 1298 Soft Acid and sodium salt thereof or fatty acid methyl esters ethoxylate sulphonate.
Further, described fat alcohol polyethylene ether vitriol comprises polyoxyethylenated alcohol sodium sulfate (AES).
Further, described Witco 1298 Soft Acid and sodium salt thereof comprise acrylonitrile-butadiene-styrene copolymer (ABS).
Further, described fatty acid methyl esters ethoxylate sulphonate comprises fatty acid methyl esters ethoxylate sodium sulfonate.
Aniorfic surfactant has surface-active electronegative group and gains the name owing to dissolving can to dissociate out behind the water, is that present consumption is maximum, and one type of tensio-active agent that kind is maximum is widely used in washing composition, whipping agent, emulsifying agent etc.Anionic surfactants in detergents mainly plays degreasing, decontamination, foaming, emulsification, penetration effect.Like fat alcohol polyethylene ether vitriol AES, have good decontamination, emulsification, wetting, solubilising and foam performance, solvability is good, and thickening effectiveness is good, and compatibleness is wide; Anti-hard water property is strong, and biological degradability is high, and oil removing performance is preferably arranged, and is humble to skin and eye irritation; Like Witco 1298 Soft Acid and sodium salt ABS thereof, good penetrability, low price has certain oil removing performance; Be the maximum tensio-active agent of China output, it is simple to have production technique, and raw material advantage such as be easy to get is like fatty acid methyl ester ethoxylate sulphonate FMES; Be the relatively more uniform product of performance in the tensio-active agent, clean infiltration, emulsification; Dispersing property is balanced, and washing (-)off properties is splendid, is the high product of anionic type tensio-active agent the inside clearing power and emulsifying power, and possesses certain alkaline resistance properties.
Further, described ionic surfactant pack is drawn together polyoxyethylene-type nonionogenic tenside, polyol-based non-ionic surfactant.
Further, described polyoxyethylene-type ionic surfactant pack is drawn together high-carbon fatty alcohol polyoxyethylene ether (AEO).
Further, described polyol-based non-ionic surfactant comprises cocoanut fatty acid diethanolamide 6501.
It is very capable that nonionogenic tenside is removed oily dirt, and have the dirt of preventing on the synthon surface sedimentary again ability because its unionization in solution; So stability is higher, can coexist with other tensio-active agents, have good washing simultaneously; Disperse; Emulsification, increase-volume, multiple performance such as sterilization.Like AEO AEO is exactly the most important series products of nonionogenic tenside in modern age, all more or less has this type of this type tensio-active agent in the present existing washing composition, soluble in water, has good emulsification, clean, wetting function; Like cocoanut fatty acid diethanolamide 6501; Soluble in water, have functions such as good foaming, steady bubble, infiltration decontamination, anti-hard water, the compatibility thickening effectiveness is obvious especially with it when AS is acidity, can strengthen cleaning effect; Can be used as the foam tranquilizer, foaming aids.
Further, described organic acid comprises carboxylic acid, sulfonic acid or-sulfinic acid.
Organic acid is a slightly acidic, and it is safer in the daily life practicality comparing with mineral acid, has the advantages that ability and iron ion form stable comple; Scale removal effect is preferably arranged,, strengthen the wash characteristics of cleaning agent as a kind of auxiliary agent; Simultaneously, in washing composition, play a part increase-volume, prevent the liquid layering; Separate out deposition, make solution become transparence.
Further, described Sorrel extract is to filter the juice that obtains from the herbage Sorrel through smashing to pieces, and said Sorrel comprises whole strain Sorrel plant.According to " national herbal medicine compilation " record, Sorrel is named Herba Oxalidis Corniculatae again, is perennial herb, and all there is distribution all parts of the country.
The Sorrel all herbal medicine has clearing heat and detoxicatingly, and the loose effectiveness of disease of detumescence can be controlled snakeworm and sting and hinder etc.The Sorrel cauline leaf contains the volume oxalate, and leaf contains Hydrocerol A and a large amount of tartrate, and stem contains oxysuccinic acid.Oxalic acid is present in the Sorrel with the form of oxalate; Its rust removing function is very good; Can be used for the cleaning of metallic surface, tartrate then can with multiple complexing of metal ion, can make the clean-out system and the rumbling compound of metallic surface; Oxysuccinic acid also can be used as the rust remover on various metal vessels and surface, makes the metallic surface become smooth.So the Sorrel extract is except that having higher pharmaceutical use, because its herb contains a large amount of organic acids, it is effective to eliminate rust simultaneously; And as a kind of pure natural herbage; As the washing composition of daily living articles such as tableware, environmental protection is arranged, indispensable performance and advantages such as safety.
Further, described NaCl plays a part thickening in washing composition;
Further, described sanitas comprises methyl esters, butyl ester, 5-chloro-2 methyl-4 isothiazoline-3 ketone (card pine) or phenylphenol sodium salt etc.
Sanitas is mainly used in and prevents the rotten of washing composition, guarantees the effective storage life of washing composition.
Further, described essence comprises natural essence, compound essence.
Further, described natural essence comprises jasmine, rose, the extraction essence of lavandula angustifolia.
Further, described compound essence comprises complete synthesis balsamic legumin, phenylethyl alcohol, semisynthetic perfume itral, or the mono-isolate Terpineol 350.
Essence is mainly that people are had is pleasant when using Betengent product, the fragrance of delicate fragrance can be according to each essence smell when making washing composition, and economy, the different mining of compatibleness be with different perfume (or spice), and generally usefulness has odor types such as jasmine, rose, lemon.
Further, described alkali comprises yellow soda ash or caustic alkali.
Further, described caustic alkali comprises sodium hydroxide or Pottasium Hydroxide.
Alkali has fillibility preferably as a kind of washing composition that helps, and frictional property can be brought up alkaline environment simultaneously, helps the performance of washing composition effect.
Another purpose of application of the present invention provides the preparation method of above-mentioned cleaning agent, adopts following preparation process:
One, the preparation of Sorrel extract:
1. will put in order the strain Sorrel and clean the back on ice in grinding;
2. will grind the back Sorrel and put into 80% alcohol, reflux is filtered with B;
3. filtered liq is distilled processing, isolate the Sorrel extracting solution;
4. dry, process the Sorrel extract powder;
Two, the preparation of washing composition:
1. press quality respectively than the good above-mentioned material of weighing;
2. put into 15-25 ℃ of pure water;
3. put into the Sorrel extract successively, nonionogenic tenside, AS, organic acid stirs;
4. adding alkali is stirred to dissolving fully;
5. adding sanitas, essence slowly stirs simultaneously, stirs to add NaCl simultaneously;
6. add 15-25 ℃ of pure water.
Experimental implementation is to take care, and prevents when adding alkali to scald.
The washing composition that application of the present invention is developed, its one-tenth is grouped into production technique simple, and significant advantage is that it can arrive simultaneously and deoils; Decontamination; The effect of derusting, and what adopt when derusting is the Sorrel extracting solution of pure natural, is suitable for the rust cleaning cleaning of daily living article.
Embodiment
Through embodiment the scheme of application of the present invention is done detailed narration below.
Embodiment one
One, the preparation of Sorrel extract:
1) will put in order the strain Sorrel and clean the back on ice in grinding;
2) will grind the back Sorrel and put into 80% alcohol, reflux is filtered with B;
3) filtered liq is distilled processing, isolate the Sorrel extracting solution;
4) drying is processed the Sorrel extract powder;
Two, the preparation of washing composition:
By following per-cent weigh batching, secondary alkyl sulfate 6%, cocoanut fatty acid diethanolamide 8%, organic acid sulfonic acid 8%; NaCl 1.5%, Sorrel extract 2%, food flavour 2%; 5-chloro-2 methyl-4 isothiazoline-3 ketone 1.5%, yellow soda ash 0.5%, pure water 70.5%.
Press quality respectively than the good above-mentioned material of weighing, in reaction vessels, put into 15 ℃ of pure water of part, put into the Sorrel extract successively, cocoanut fatty acid diethanolamide; Secondary alkyl sulfate, sulfonic acid stirs, and adds yellow soda ash again; Be stirred to dissolving fully, add 5-chloro-2 methyl-4 isothiazoline-3 ketone, food flavour slowly stirs simultaneously; Stirring adds NaCl simultaneously, adds 15 ℃ of pure water at last, promptly makes washing composition.
Embodiment two
One, the preparation of Sorrel extract:
1) will put in order the strain Sorrel and clean the back on ice in grinding;
2) will grind the back Sorrel and put into 80% alcohol, reflux is filtered with B;
3) filtered liq is distilled processing, isolate the Sorrel extracting solution;
4) drying is processed the Sorrel extract powder;
Two, the preparation of washing composition:
By following per-cent weigh batching, polyoxyethylenated alcohol sodium sulfate 8%, pure ether phosphate 6%, organic acid sulfonic acid 6%, NaCl 2%, Sorrel extract 6%, compound essence 1.5%, butyl ester 3%, sodium hydroxide 1%, pure water 62.5%.
Press quality respectively than the good above-mentioned material of weighing, in reaction vessels, put into 18 ℃ of pure water of part, put into the Sorrel extract successively, pure ether phosphate; Polyoxyethylenated alcohol sodium sulfate, sulfonic acid stirs, and adds sodium hydroxide again; Be stirred to dissolving fully, add butyl ester, compound essence slowly stirs simultaneously; Stirring adds NaCl simultaneously, adds 18 ℃ of pure water at last, promptly makes washing composition.
Embodiment three
One, the preparation of Sorrel extract:
1) will put in order the strain Sorrel and clean the back on ice in grinding;
2) will grind the back Sorrel and put into 80% alcohol, reflux is filtered with B;
3) filtered liq is distilled processing, isolate the Sorrel extracting solution;
4) drying is processed the Sorrel extract powder;
Two, the preparation of washing composition:
By following per-cent weigh batching, aniorfic surfactant polyoxyethylenated alcohol sodium sulfate 12%, non-ionics cocoanut fatty acid diethanolamide 5%; Organic acid carboxylic acid 5%, NaCl1%, Sorrel extract 12%; Food flavour 0.2%; Sanitas 5-chloro-2 methyl-4 isothiazoline-3 ketone 0.2%, yellow soda ash 0.1%, pure water 62.9%.
Press quality respectively than the good above-mentioned material of weighing, in reaction vessels, put into 22 ℃ of pure water of part, put into the Sorrel extract successively, the agent cocoanut fatty acid diethanolamide; Polyoxyethylenated alcohol sodium sulfate, carboxylic acid stirs, and adds yellow soda ash again; Be stirred to dissolving fully, add 5-chloro-2 methyl-4 isothiazoline-3 ketone, food flavour slowly stirs simultaneously; Stirring adds NaCl simultaneously, adds 22 ℃ of pure water at last, promptly makes washing composition.
Embodiment four
One, the preparation of Sorrel extract:
1) will put in order the strain Sorrel and clean the back on ice in grinding;
2) will grind the back Sorrel and put into 80% alcohol, reflux is filtered with B;
3) filtered liq is distilled processing, isolate the Sorrel extracting solution;
4) drying is processed the Sorrel extract powder;
Two, the preparation of washing composition:
By following per-cent weigh batching, secondary alkyl sulfate 12%, pure ether phosphate 5%, organic acid oxalic acid 5%, NaCl 1%, Sorrel extract 15%, food flavour 0.2%, butyl ester 0.2%, sodium hydroxide 0.1%, pure water 63.9%.
Press quality respectively than the good above-mentioned material of weighing, in reaction vessels, put into 25 ℃ of pure water of part, put into the Sorrel extract successively, pure ether phosphate; Secondary alkyl sulfate, oxalic acid stirs, and adds sodium hydroxide again; Be stirred to dissolving fully, add butyl ester, food flavour slowly stirs simultaneously; Stirring adds NaCl simultaneously, adds 25 ℃ of pure water at last, promptly makes washing composition.
The experimental result surface, along with the increase of Sorrel extracting solution proportion, the rust cleaning effect increases, but clearing power instance power 3 is the highest, and the clearing power of instance 1 is minimum.
Claims (10)
1. a cleaning agent is characterized in that, comprises the various components of following quality percentage composition: aniorfic surfactant 6%-12%; Nonionogenic tenside 5.0%-8.0%, organic acid 5.0%-8.0%, NaCl 1.0%-2.0%; Sorrel extract 2.0%-15.0%, essence 0.2%-2.0%, sanitas 0.2%-3.0%; Alkali 0.1%-1.0%, pure water 64.0%-75.0%.
2. cleaning agent according to claim 1 is characterized in that: described aniorfic surfactant comprises fat alcohol polyethylene ether vitriol, Witco 1298 Soft Acid and sodium salt thereof or fatty acid methyl esters ethoxylate sulphonate.
3. cleaning agent according to claim 2; It is characterized in that: described fat alcohol polyethylene ether vitriol comprises polyoxyethylenated alcohol sodium sulfate; Described Witco 1298 Soft Acid and sodium salt thereof comprise acrylonitrile-butadiene-styrene copolymer, and described fatty acid methyl esters ethoxylate sulphonate comprises fatty acid methyl esters ethoxylate sodium sulfonate.
4. cleaning agent according to claim 1 is characterized in that: described ionic surfactant pack is drawn together polyoxyethylene-type nonionogenic tenside, polyol-based non-ionic surfactant.
5. cleaning agent according to claim 4 is characterized in that: described polyoxyethylene-type ionic surfactant pack is drawn together high-carbon fatty alcohol polyoxyethylene ether, and described polyol-based non-ionic surfactant comprises cocoanut fatty acid diethanolamide 6501.
6. cleaning agent according to claim 1 is characterized in that: described organic acid comprises carboxylic acid, sulfonic acid or-sulfinic acid.
7. cleaning agent according to claim 1 is characterized in that: described sanitas comprises methyl esters, butyl ester, 5-chloro-2 methyl-4 isothiazoline-3 ketone or phenylphenol sodium salt etc.
8. cleaning agent according to claim 1 is characterized in that: described essence comprises natural essence, compound essence.
9. cleaning agent according to claim 1 is characterized in that: described alkali comprises yellow soda ash or caustic alkali.
10. the preparation method of the said cleaning agent of claim 1 is characterized in that, comprises following preparation process:
One, the preparation of Sorrel extract:
1) will put in order the strain Sorrel and clean the back on ice in grinding;
2) will grind the back Sorrel and put into 80% alcohol, reflux is filtered with B;
3) filtered liq is distilled processing, isolate the Sorrel extracting solution;
4) drying is processed the Sorrel extract powder;
Two, the preparation of washing composition:
1) presses quality respectively than the good above-mentioned material of weighing;
2) put into 15-25 ℃ of pure water;
3) put into the Sorrel extract successively, nonionogenic tenside, AS, organic acid stirs;
4) add alkali, be stirred to dissolving fully;
5) add sanitas, essence slowly stirs simultaneously, stirs to add NaCl simultaneously;
6) add 15-25 ℃ of pure water.
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103013689A (en) * | 2012-12-20 | 2013-04-03 | 青岛海芬海洋生物科技有限公司 | Detergent for beer industry and preparation method of detergent |
| CN103603001A (en) * | 2013-11-06 | 2014-02-26 | 天津圳鹏清洗技术开发有限公司 | Copper alloy low-temperature cleaning agent |
| CN103756801A (en) * | 2013-12-25 | 2014-04-30 | 苏州市邦成电子科技有限公司 | Boiler disincrustant |
| CN103774165A (en) * | 2014-02-20 | 2014-05-07 | 苏州龙腾万里化工科技有限公司 | High-efficiency water-based die-casting aluminum alloy degreasing agent |
| CN104152286A (en) * | 2014-08-27 | 2014-11-19 | 江西瑞思博化工有限公司 | Air conditioner cleaning agent and preparation method thereof |
| CN104532280A (en) * | 2014-12-26 | 2015-04-22 | 苏州龙腾万里化工科技有限公司 | Steel plate printing machine detergent |
| CN105177601A (en) * | 2015-09-08 | 2015-12-23 | 刘高志 | Production method for detergent with rust removal function |
| CN106479713A (en) * | 2015-08-27 | 2017-03-08 | 西南大学 | Citrus procession industrial detergent |
| CN106498423A (en) * | 2016-12-26 | 2017-03-15 | 广西中医药大学 | A kind of natural rust remover |
| CN109735396A (en) * | 2018-12-06 | 2019-05-10 | 威莱(广州)日用品有限公司 | A kind of domestic bowl-washing detergent and preparation method thereof |
| CN111139154A (en) * | 2019-12-25 | 2020-05-12 | 胡文清 | Preparation method of environment-friendly sterilizing detergent |
| CN112662488A (en) * | 2021-01-25 | 2021-04-16 | 山东快通日用品有限公司 | Seven-agent multifunctional detergent and preparation method thereof |
| CN113652310A (en) * | 2021-08-20 | 2021-11-16 | 常州智高化学科技有限公司 | Multifunctional hydrocarbon detergent and production method thereof |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103013689A (en) * | 2012-12-20 | 2013-04-03 | 青岛海芬海洋生物科技有限公司 | Detergent for beer industry and preparation method of detergent |
| CN103603001B (en) * | 2013-11-06 | 2015-11-04 | 天津圳鹏清洗技术开发有限公司 | One Albatra metal-low-temperature cleaning agent |
| CN103603001A (en) * | 2013-11-06 | 2014-02-26 | 天津圳鹏清洗技术开发有限公司 | Copper alloy low-temperature cleaning agent |
| CN103756801A (en) * | 2013-12-25 | 2014-04-30 | 苏州市邦成电子科技有限公司 | Boiler disincrustant |
| CN103774165A (en) * | 2014-02-20 | 2014-05-07 | 苏州龙腾万里化工科技有限公司 | High-efficiency water-based die-casting aluminum alloy degreasing agent |
| CN104152286A (en) * | 2014-08-27 | 2014-11-19 | 江西瑞思博化工有限公司 | Air conditioner cleaning agent and preparation method thereof |
| CN104532280A (en) * | 2014-12-26 | 2015-04-22 | 苏州龙腾万里化工科技有限公司 | Steel plate printing machine detergent |
| CN106479713A (en) * | 2015-08-27 | 2017-03-08 | 西南大学 | Citrus procession industrial detergent |
| CN105177601A (en) * | 2015-09-08 | 2015-12-23 | 刘高志 | Production method for detergent with rust removal function |
| CN106498423A (en) * | 2016-12-26 | 2017-03-15 | 广西中医药大学 | A kind of natural rust remover |
| CN109735396A (en) * | 2018-12-06 | 2019-05-10 | 威莱(广州)日用品有限公司 | A kind of domestic bowl-washing detergent and preparation method thereof |
| CN111139154A (en) * | 2019-12-25 | 2020-05-12 | 胡文清 | Preparation method of environment-friendly sterilizing detergent |
| CN111139154B (en) * | 2019-12-25 | 2021-04-27 | 安徽省华凯轻工科技有限公司 | Preparation method of environment-friendly sterilizing detergent |
| CN112662488A (en) * | 2021-01-25 | 2021-04-16 | 山东快通日用品有限公司 | Seven-agent multifunctional detergent and preparation method thereof |
| CN113652310A (en) * | 2021-08-20 | 2021-11-16 | 常州智高化学科技有限公司 | Multifunctional hydrocarbon detergent and production method thereof |
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