CN102696626A - Sterilization composition containing phenylate diazole and fludioxonil - Google Patents
Sterilization composition containing phenylate diazole and fludioxonil Download PDFInfo
- Publication number
- CN102696626A CN102696626A CN2012102364200A CN201210236420A CN102696626A CN 102696626 A CN102696626 A CN 102696626A CN 2012102364200 A CN2012102364200 A CN 2012102364200A CN 201210236420 A CN201210236420 A CN 201210236420A CN 102696626 A CN102696626 A CN 102696626A
- Authority
- CN
- China
- Prior art keywords
- fludioxonil
- agricultural
- phenylate
- azoles
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 239000005781 Fludioxonil Substances 0.000 title claims abstract description 43
- MUJOIMFVNIBMKC-UHFFFAOYSA-N fludioxonil Chemical compound C=12OC(F)(F)OC2=CC=CC=1C1=CNC=C1C#N MUJOIMFVNIBMKC-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 230000001954 sterilising effect Effects 0.000 title abstract description 7
- 238000004659 sterilization and disinfection Methods 0.000 title abstract 6
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 title abstract 3
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 29
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 claims abstract description 17
- 150000003851 azoles Chemical class 0.000 claims description 39
- 240000008067 Cucumis sativus Species 0.000 claims description 17
- 239000012752 auxiliary agent Substances 0.000 claims description 10
- 239000000645 desinfectant Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 239000000375 suspending agent Substances 0.000 claims description 8
- 238000009736 wetting Methods 0.000 claims description 8
- 241000219112 Cucumis Species 0.000 claims description 7
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 claims description 7
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 claims description 7
- 239000000839 emulsion Substances 0.000 claims description 7
- 239000004530 micro-emulsion Substances 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 239000003905 agrochemical Substances 0.000 claims description 5
- 238000009472 formulation Methods 0.000 claims description 4
- 201000010099 disease Diseases 0.000 abstract description 12
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 12
- 238000012360 testing method Methods 0.000 abstract description 10
- 238000002360 preparation method Methods 0.000 abstract description 8
- 239000000575 pesticide Substances 0.000 abstract description 7
- 239000003899 bactericide agent Substances 0.000 abstract description 6
- 230000002195 synergetic effect Effects 0.000 abstract description 6
- 230000009471 action Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 238000005507 spraying Methods 0.000 abstract description 2
- 244000299906 Cucumis sativus var. sativus Species 0.000 abstract 1
- 230000002411 adverse Effects 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 38
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 18
- 229940079593 drug Drugs 0.000 description 18
- 239000004480 active ingredient Substances 0.000 description 16
- 239000000047 product Substances 0.000 description 14
- 206010039509 Scab Diseases 0.000 description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 11
- 238000005303 weighing Methods 0.000 description 11
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 229910019142 PO4 Inorganic materials 0.000 description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 9
- 239000010452 phosphate Substances 0.000 description 9
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 241000894006 Bacteria Species 0.000 description 7
- 239000005995 Aluminium silicate Substances 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- 235000012211 aluminium silicate Nutrition 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 229920001285 xanthan gum Polymers 0.000 description 6
- 241000123650 Botrytis cinerea Species 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- -1 polyoxyethylene Polymers 0.000 description 5
- 230000003449 preventive effect Effects 0.000 description 5
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 5
- 239000005711 Benzoic acid Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 239000002518 antifoaming agent Substances 0.000 description 4
- 235000010233 benzoic acid Nutrition 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000008103 glucose Substances 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 238000010298 pulverizing process Methods 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical group C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 229920001732 Lignosulfonate Polymers 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 3
- 150000008051 alkyl sulfates Chemical class 0.000 description 3
- 150000008052 alkyl sulfonates Chemical class 0.000 description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 229920001249 ethyl cellulose Polymers 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000003801 milling Methods 0.000 description 3
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 3
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 229920005646 polycarboxylate Polymers 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- LWEAHXKXKDCSIE-UHFFFAOYSA-M 2,3-di(propan-2-yl)naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S([O-])(=O)=O)=C(C(C)C)C(C(C)C)=CC2=C1 LWEAHXKXKDCSIE-UHFFFAOYSA-M 0.000 description 2
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- 241001465180 Botrytis Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 229960000892 attapulgite Drugs 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229920005551 calcium lignosulfonate Polymers 0.000 description 2
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000001934 delay Effects 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
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- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 2
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- 239000004033 plastic Substances 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 1
- 241000223600 Alternaria Species 0.000 description 1
- 241000222195 Ascochyta Species 0.000 description 1
- 241000228212 Aspergillus Species 0.000 description 1
- 206010003694 Atrophy Diseases 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 240000001980 Cucurbita pepo Species 0.000 description 1
- 235000009852 Cucurbita pepo Nutrition 0.000 description 1
- 241000371644 Curvularia ravenelii Species 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 241000228143 Penicillium Species 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 241001361634 Rhizoctonia Species 0.000 description 1
- 241000813090 Rhizoctonia solani Species 0.000 description 1
- 241000221662 Sclerotinia Species 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical group N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000037444 atrophy Effects 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical group [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
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- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 235000020995 raw meat Nutrition 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
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- 238000012216 screening Methods 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
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- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Abstract
The invention relates to an agricultural sterilization composition, wherein the weight ratio of phenylate diazole to fludioxonil in the sterilization composition is (1:100)-(100:1), and preferably, the weight ratio of phenylate diazole to fludioxonil is (1:20)-(20:1). The invention also relates to an agricultural bactericide which contains the agricultural sterilization composition and applications of the agricultural sterilization composition and the agricultural bactericide in preventing the gray mold of cucumber like crops. The composition has an obvious synergistic effect on diseases, and the sterilization effect is improved; the pesticide spraying times is reduced, so the environmental pollution and pesticide residual are reduced; and action sites are increased. The composition does not have adverse influence to the test crop, has good safety, and satisfies the safety requirements of pesticide preparations.
Description
Technical field
The invention belongs to the composition pesticide field, is the bactericidal composition of active ingredient with two azoles of phenylate and fludioxonil specifically, and the purposes of said composition in the control gray mold of cucumber.
Background technology
Gray mold (Cucurbit Gray Mould) is the important disease in the cucumber crop production, takes place extremely general.Especially in recent years, along with the improvement of safeguard measures such as greenhouse by solar heat, plastic tunnel, plastic mulching, the green cucumber area constantly enlarges, and stubble increases in addition, for spreading of gray mold of cucumber created condition, generally is lost in more than 30%.Gray mold of cucumber main harm children melon also infects leaf, stem.The morbidity of children's melon, germ is many invades from opening the female flower that loses, and causes petal to rot, and then to young melon expansion, causes umbilical region and be water stain shape, and the children spends rapid deliquescing, atrophy, rots, the mould layer of the close living grey in surface, and extend to whole sugar-preserved gourd.Sick melon stops growing and rots then or come off.Blade generally causes morbidity by etching that comes off or sick tendril attached to the blade face, forms the large-scale scab of diameter 20 ~ 50mm, subcircular or irregular shape, and the edge is obvious, the living grey mold in withered surface, back.Mashed melon or etching can cause that stem rots attached on the stem time, and the joint of bottom rots to cause climing fractureing when serious, and plant is withered.The condition that has of ash arrhizus bacteria is Fu Keer sclerotinite Sclerotinia fuckeliana (de Bary) Fuckel, belongs to the Ascomycotina Sclerotinia.No condition is Botrytis cinerea Botrytis cinerea Pers.ex Fr., belongs to the Deuteromycotina Botrytis.Botrytis cinerea is weak bacterial parasite, and a little less than the plant strain growth, patient's condition obviously increases the weight of.Generally too dense planting, nitrogen application too much or shortage, overirrigation, bad all being prone to of ventilation and penetrating light make disease popular.
The two azoles of phenylate (English common name: Difenodiconazole), chemical name: 2-[2-chloro-4-(4-chlorobenzene oxygen) phenyl]-1, two (1H-1,2,4-the triazol-1-yl)-2-propyl alcohol of 3-.Application number is chemical structural formula, preparation method and the sterilizing use that discloses the two azoles of phenylate in 200610140836.7 the one Chinese patent application, at this this patent application is incorporated herein by reference in full.The two azoles of phenylate have following structural formula:
Fludioxonil (Fludioxonil) belongs to tagging property of pyroles bactericide, through the relevant transfer of inhibition glucose phosphorylated, and the growth of inhibition fungal mycelium, finally cause pathogen dead.Lasting period is long, and is difficult for and other bactericide generation cross resistance.Fludioxonil is one of product of the whole world acquisition few in number EPA of EPA " low-risk " authentication, is the product that can buy acquisition on the market.Fludioxonil is widely used in various crop, is used for wheat, barley, corn, pea, rape, paddy rice, vegetables, grape, lawn, ornamental crops foliar treatment, and the rotten sickle spore bacterium of control snow, wheat net raw meat black rot, rhizoctonia solani etc. have special efficacy to gray mold; Cereal and non-cereal seed are handled, and control kind of biography and soil-borne disease bacterium are like Alternaria, Ascochyta, aspergillus, Fusarium, Helminthosporium, Rhizoctonia and Penicillium bacterium.
With two azoles of phenylate and fludioxonil is the bactericidal composition of active ingredient; Be used in particular for the control of cucumber class crop gray mold, can delay the drug-fast generation of germ, improve actual preventive effect; Enlarging fungicidal spectrum and reduce drug cost, is the important means of disease integrated control.
Summary of the invention
The object of the present invention is to provide the bactericidal composition that a kind of component is reasonable, bactericidal effect good, drug cost is low, be difficult for developing immunity to drugs, can be used in control cucumber crop gray mold.
For achieving the above object, the invention provides a kind of agricultural bactericidal composition, the weight ratio of two azoles of phenylate and fludioxonil is 1:100 ~ 100:1 in the said bactericidal composition.
Preferably, the weight ratio of two azoles of said phenylate and fludioxonil is 1:20 ~ 20:1.
The present invention also provides a kind of disinfectant use in agriculture, and said disinfectant use in agriculture contains the above-mentioned agricultural bactericidal composition of percentage by weight 0.1% ~ 90%, and all the other are acceptable carrier and auxiliary agent in the agricultural chemicals.Preferably contain percentage by weight 5% ~ 80%, particularly preferably 20% ~ 60%, all the other are acceptable carrier and auxiliary agent in the agricultural chemicals.
According to method known in those skilled in the art, bactericidal composition of the present invention can be mixed with the formulation that allows on the agricultural when practical application, and formulation is suspending agent, aqueous emulsion, microemulsion, wetting powder or water dispersible granules preferably.
For water dispersible granules, those skilled in the art are familiar with the use corresponding adjuvants and accomplish the present invention very much.Dispersant is selected for use from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate; Wetting agent is selected from polyoxyethylene alcohol, alkyl sulfate, alkylsulfonate, naphthalene sulfonate; Disintegrant is selected from ammonium sulfate, urea, sucrose, glucose, citric acid, succinic acid, sodium bicarbonate; Binding agent is selected from diatomite, corn starch, PVA, carboxymethyl (ethyl) cellulose family and microcrystalline cellulose class; Filler is selected from diatomite, kaolin, white carbon, fine particle calcium carbonate, sepiolite, talcum powder, attapulgite, potter's clay etc.
To wetting powder, spendable auxiliary agent has: dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate; Wetting agent is selected from alkyl sulfate, alkylsulfonate, naphthalene sulfonate; Filler is selected from diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, potter's clay etc.
To suspending agent, spendable auxiliary agent has: dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate, TERSPERSE2425 (U.S. Huntsman Corporation produces, the alkyl naphthalene sulfonic acid salt); Wetting agent is selected from alkylphenol-polyethenoxy and gathers basic ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE2500 (U.S. Huntsman Corporation product); Thickener is selected from xanthans, aluminium-magnesium silicate, bentonite; Preservative is selected from benzoic acid, Sodium Benzoate, BIT (1, the 2-benzisothiazole-3-ketone); Antifoaming agent is silicone based antifoaming agent; Antifreezing agent is selected from ethylene glycol, propane diols, glycerine, urea, inorganic salts such as sodium chloride.
To aqueous emulsion, spendable auxiliary agent has: emulsifier is selected from Nonyl pheno (EO=10) ether phosphate, triphen ethyl-phenol polyoxyethylene ether phosphate (agricultural newborn 600# phosphate), Nongru-700 #, agricultural newborn 2201#, Span-60#, emulsifier T-60, TX-10, agricultural newborn 1601#, agricultural newborn 600#, agricultural newborn 400#; Solvent is selected from xylol, toluene, cyclohexanone, solvent naphtha (trade mark: S-150, S-180, S-200); Stabilizing agent is selected from triphenyl phosphite, epoxychloropropane; Antifreezing agent is selected from ethylene glycol, propane diols, glycerine, urea, inorganic salts such as sodium chloride; Thickener is selected from xanthans, bentonite, aluminium-magnesium silicate; Preservative is selected from BIT (1, the 2-benzisothiazole-3-ketone), benzoic acid, Sodium Benzoate.
To microemulsion, spendable auxiliary agent has: emulsifier is selected from calcium dodecyl benzene sulfonate (agricultural newborn 500#), Nongru-700 #, agricultural newborn 2201#, this dish-60#, Tween-80, TX-10, farming breast 1601, agricultural newborn 600#, agricultural newborn 400#; Cosolvent is selected from methyl alcohol, isopropyl alcohol, n-butanol, ethanol; Solvent is selected from cyclohexanone, N-Methyl pyrrolidone, xylol, toluene, solvent naphtha (trade mark: S-150, S-180, S-200); Stabilizing agent is selected from triphenyl phosphite, epoxychloropropane.
The present invention also provides above-mentioned agricultural bactericidal composition or disinfectant use in agriculture in the purposes of preventing and treating cucumber class crop gray mold.
Bactericidal composition of the present invention or bactericide can provide with the finished product preparation form, and promptly each material mixes in the composition; Also can provide, in bucket (jar), directly mix before using with single agent formulation.Concentrate of the present invention mixes the concentration that obtains required active substance usually with water.
Compared with prior art, the beneficial effect of the present invention's generation is:
(1) compare with single agent, bactericidal composition according to the invention has significant synergistic effect to disease, has improved bactericidal effect;
(2) reduce the medication number of times, reduce drug cost, reduce environmental pollution and residue of pesticide;
(3) composition is made up of the active ingredient of different effects mechanism, and the action site increase helps overcoming and delays the drug-fast generation of germ.
Embodiment
Come the present invention is further specified below in conjunction with specific embodiment, but do not limit the invention to these embodiments.One skilled in the art would recognize that the present invention contained in claims scope all alternatives, improvement project and the equivalents that possibly comprise.
Among the present invention in the proportioning of all preparations percentage all be weight percentage, " active ingredient than " or " proportioning " all refers to the ratio of two azoles of phenylate and fludioxonil.
One, biologicall test
Instance: two azoles of phenylate and the composite Toxicity Determination of fludioxonil to gray mold of cucumber
Subjects is botrytis cinerea pers (Botrytis cinerea), and this bacterial classification is preserved by the laboratory.
Adopt the blade bacterination process.Select the consistent potted plant cucumber seedling of two leaf period growing ways, subsequent use.Two azoles of phenylate and fludioxonil are dissolved with DMF respectively, be mixed with the soup of series concentration again with 0.1% Tween-80 aqueous solution dilution, the more two azoles of phenylate are processed preset series concentration compound solution with fludioxonil respectively by different proportionings.To the cucumber seedling processing of spraying, after 24 hours, the ash arrhizus bacteria that will cultivate about 3 days with card punch breaks into diameter 5mm bacterium cake along the edge with the different series concentration liquid, with tweezers the bacterium cake is had the one side of mycelia to connect to be affixed on and respectively handles blade central authorities.25 ℃ of half-lights are preserved moisture behind the 24h, about about 3 days of restore nature illumination cultivation, every processing repetition 3 times.
Wait to contrast abundant morbidity back with each inoculation point scab diameter of slide calliper rule metering, calculate preventive effect.With each inoculation point scab diameter of slide calliper rule metering, represent the scab size with its mean.Obtain by following formula and respectively to handle preventive effect: control efficiency %=(contrast scab average diameter-processings scab average diameter) * 100/ contrasts the scab average diameter
On the basis of chemical control efficient, carry out the data analysis statistics with " DPS data handling system ", obtain EC
50EC that each that will measure according to Sun Yunpei (Y-P Sun) method handled
50Be converted into actual poison exponent (ATI); According to the proportioning of mixture, obtain theoretical poison exponent (TTI), calculate the co-toxicity coefficient (CTC) of mixture by following formula.
If co-toxicity coefficient is greater than 120, showing has synergistic effect; If be starkly lower than 100, be indicated as antagonism; Between 100～120, be indicated as summation action.
Two azoles of table 1 phenylate and the composite Toxicity Determination result of fludioxonil to gray mold of cucumber
Can find out that from above-mentioned Toxicity Determination result two azoles of phenylate and fludioxonil are mixed, and in mass ratio is 100:1～1:100 scope, gray mold of cucumber are all shown as synergistic effect.Wherein mass ratio is that synergistic effect is the most obvious in the scope of 20:1～1:20.The result shows, two azoles of phenylate and fludioxonil are mixed and prevent and treat gray mold and have reasonability and feasibility.
Two, preparation preparation
Percentage composition is mass percent in all preparation proportionings.
1, water dispersible granules
Press formula rate, former medicine and dispersant, wetting agent, binding agent, filler etc. are mixed, behind comminution by gas stream, obtain pulvis, add a certain amount of water and mix, in comminutor, carry out granulation, dry then, screening promptly gets granular product.
The two azoles fludioxonil water dispersible granules (active ingredient is than 1:10) of embodiment 1:55% phenylate
Take by weighing the two former medicines of azoles of 5% phenylate, the former medicine of 50% fludioxonil, 4%NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 2% Nekal BX (nekal), 4%K-12 (lauryl sodium sulfate), 5% carboxymethyl (ethyl) cellulose, 3% diatomite, 5% glucose, kaolin and add to 100%.Mix, behind comminution by gas stream, granulate.
The two azoles fludioxonil water dispersible granules (active ingredient is than 20:1) of embodiment 2:42% phenylate
Take by weighing the two former medicines of azoles of 40% phenylate, the former medicine of 2% fludioxonil, 4%NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 2% Nekal BX (nekal), 4%K-12 (lauryl sodium sulfate), 5% carboxymethyl (ethyl) cellulose, 3% diatomite, 5% glucose, kaolin and add to 100%.Mix, behind comminution by gas stream, granulate.
2, suspending agent
Pressing formula rate, is medium with water, former medicine, dispersant, suspending agent and antifreezing agent etc. is joined shear 30min in the high-shear emulsion machine, use the sand mill sand milling again after, obtain suspending agent.
The two azoles fludioxonil suspending agents (active ingredient is than 5:1) of embodiment 3:30% phenylate
Take by weighing the two former medicines of azoles of 25% phenylate, the former medicine of 5% fludioxonil, 4%FS3000 (phosphate type anion surfactant), 1%SXC (sulfonic acid type anion surfactant), 0.1% xanthans, 1% aluminium-magnesium silicate, 5% ethylene glycol, 0.15%BIT (1; The 2-benzisothiazole-3-ketone), 0.3% organically-modified silicone antifoam agent, deionized water adds to 100%.Process slurry, carry out sand milling, obtain product.
The two azoles fludioxonil suspending agents (active ingredient is than 1:20) of embodiment 4:21% phenylate
Take by weighing the two former medicines of azoles of 1% phenylate, the former medicine of 20% fludioxonil, 4%FS3000 (phosphate type anion surfactant), 1%SXC (sulfonic acid type anion surfactant), 0.1% xanthans, 1% aluminium-magnesium silicate, 5% ethylene glycol, 0.15%BIT (1; The 2-benzisothiazole-3-ketone), 0.3% organically-modified silicone antifoam agent, deionized water adds to 100%.Process slurry, carry out sand milling, obtain product.
3, wetting powder
By the prescription requirement, various auxiliary agents, filler, former medicine are mixed after after the Roughpulverizer pulverizing, get into airslide disintegrating mill and fully pulverize the mixed wetting powder that gets.
The two azoles fludioxonil wetting powders (active ingredient is than 1:5) of embodiment 5:60% phenylate
Take by weighing the two former medicines of azoles of 10% phenylate, the former medicine of 50% fludioxonil, 4%NNO, 2% Nekal BX, 5% white carbon, fine particle calcium carbonate and add to 100%.Mix, obtain product after the pulverizing.
The two azoles fludioxonil wetting powders (active ingredient is than 1:1) of embodiment 6:80% phenylate
Take by weighing the two former medicines of azoles of 40% phenylate, the former medicine of 40% fludioxonil, 5% calcium lignosulfonate, 2% Nekal BX, 1%K-12, kaolin and add to 100%.Mix, obtain product after the pulverizing.
The two azoles fludioxonil wetting powders (active ingredient is than 100:1) of embodiment 7:50.5% phenylate
Take by weighing the two former medicines of azoles of 50% phenylate, the former medicine of 0.5% fludioxonil, 5% calcium lignosulfonate, 2% Nekal BX, 1%K-12, kaolin and add to 100%.Mix, obtain product after the pulverizing.
4, microemulsion
The two azoles fludioxonil microemulsions (active ingredient is than 2:1) of embodiment 8:15% phenylate
Take by weighing the two former medicines of azoles of 10% phenylate, the former medicine of 5% fludioxonil, 5% Nongru-700 #, 5% agricultural newborn 500#, 6% agricultural newborn 1601#, 15% cyclohexanone, 5%N-methyl pyrrolidone, 5% n-butanol, through dissolving fully and mixing, deionized water adds to 100%.After stirring, obtain product.
The two azoles fludioxonil microemulsions (active ingredient is than 1:10) of embodiment 9:22% phenylate
Take by weighing the two former medicines of azoles of 2% phenylate, the former medicine of 20% fludioxonil, 5% Nongru-700 #, 5% agricultural newborn 500#, 6% agricultural newborn 1601#, 15% cyclohexanone, 5%N-methyl pyrrolidone, 5% n-butanol, through dissolving fully and mixing, deionized water adds to 100%.After stirring, obtain product.
5, aqueous emulsion
The two azoles aqueous emulsions (active ingredient is than 1:1) of embodiment 10:5% fludioxonil phenylate
Take by weighing the former medicine of 2.5% fludioxonil, the two former medicines of azoles of 2.5% phenylate, 4% agricultural newborn 2201#, 2% Nonyl pheno (EO=10) ether phosphate, 2.5% agricultural newborn 600# acid phosphatide, 20% cyclohexanone, 10% solvent naphtha S150, mixed dissolution obtains oil phase.With 5% ethylene glycol, 0.3% xanthans, 0.5% benzoic acid, deionized water adds to 100%, is made into water.Oil phase adds aqueous phase and fully mixes, and behind high-shear emulsifying, obtains product.
The two azoles aqueous emulsions (active ingredient is than 1:100) of embodiment 10:20.2% fludioxonil phenylate
Take by weighing the former medicine of 0.2% fludioxonil, the two former medicines of azoles of 20% phenylate, 4% agricultural newborn 2201#, 2% Nonyl pheno (EO=10) ether phosphate, 2.5% agricultural newborn 600# acid phosphatide, 20% cyclohexanone, 10% solvent naphtha S150, mixed dissolution obtains oil phase.With 5% ethylene glycol, 0.3% xanthans, 0.5% benzoic acid, deionized water adds to 100%, is made into water.Oil phase adds aqueous phase and fully mixes, and behind high-shear emulsifying, obtains product.
Three, field application test
Application examples: control gray mold of cucumber field control effectiveness test
Regulation with reference to medicine inspecting institute of the Ministry of Agriculture " GB/T 17980.28-2000 pesticide field efficacy medicine test criterion ()---bactericidal agent for preventing and treating eliminating vegetable botrytis "; The sub-district of test medicine, contrast medicament and blank is handled and is adopted district's group arrangement at random; Sub-district area 15m2; Repeat for 4 times, this test amounts to twice of dispenser.Be in their early stage during dispenser for the first time, execute medicine for the second time after the week.This test is investigated 2 times altogether, and 5 samplings are adopted in every experimental plot, investigates 2 strains at every, investigates whole blades of every strain, record disease grade.
The disease grade scale is following:
0 grade: no scab;
1 grade: single blade has 3 of scabs;
3 grades: single blade has 4 ~ 6 of scabs;
5 grades: single blade has 7 ~ 10 of scabs;
7 grades: single blade has 11 ~ 20 of scabs, and part is intensive in flakes;
9 grades: single blade has the intensive leaf area that accounts for of scab more than 1/4th.
The drug effect computational methods:
According to investigation result, calculate disease index and preventive effect according to following (1), (2) formula.
In the formula: CK
0, CK
1Be respectively the forward and backward disease index of blank district dispenser; PT
0, PT
1Be respectively the forward and backward disease index of chemicals treatment district medicine.
Table 2 control gray mold of cucumber field control effectiveness test result
Comprehensively above-mentioned, indoor biometrics and field control effectiveness test result show that the beneficial effect that bactericidal composition according to the invention produces is:
(1) compare with single agent, this bactericidal composition has significant synergistic effect to disease, has improved bactericidal effect;
(2) reduce the medication number of times, lower drug cost, reduce environmental pollution and residue of pesticide;
(3) composition is made up of the active ingredient of different effects mechanism, and the action site increase helps overcoming and delays the drug-fast generation of germ.The present composition does not all have obvious harmful effect to trial crops, and leaf look, growing way etc. are all normal, and safety is good, meets the security requirement of pesticidal preparations.
Bactericidal composition according to the invention has good preventive effect to melon crop gray molds such as cucumber.
Claims (8)
1. agricultural bactericidal composition is characterized in that the weight ratio of the two azoles of phenylate and fludioxonil is 1:100 ~ 100:1 in the said bactericidal composition.
2. agricultural bactericidal composition according to claim 1 is characterized in that the weight ratio of two azoles of said phenylate and fludioxonil is 1:20 ~ 20:1.
3. disinfectant use in agriculture is characterized in that wherein containing the claim 1 or the 2 described agricultural bactericidal compositions of percentage by weight 0.1% ~ 90%, and all the other are acceptable carrier and auxiliary agent in the agricultural chemicals.
4. disinfectant use in agriculture according to claim 3 is characterized in that containing the claim 1 or the 2 described agricultural bactericidal compositions of percentage by weight 5% ~ 80%, and all the other are acceptable carrier and auxiliary agent in the agricultural chemicals.
5. disinfectant use in agriculture according to claim 3 is characterized in that containing the claim 1 or the 2 described agricultural bactericidal compositions of percentage by weight 20% ~ 60%, and all the other are acceptable carrier and auxiliary agent in the agricultural chemicals.
6. according to the described disinfectant use in agriculture of each claim among the claim 3-5, it is characterized in that its formulation is suspending agent, aqueous emulsion, microemulsion, wetting powder or water dispersible granules.
7. claim 1 or 2 described agricultural bactericidal compositions are in the purposes of control melon crop gray mold.
Among the claim 3-6 the described disinfectant use in agriculture of each claim in the purposes of control cucumber class crop gray mold.
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| WO2014082871A1 (en) | 2012-11-27 | 2014-06-05 | Basf Se | Substituted 2-[phenoxy-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds and their use as fungicides |
| WO2014082881A1 (en) | 2012-11-27 | 2014-06-05 | Basf Se | Substituted 2-[phenoxy-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds and their use as fungicides |
| EP2783569A1 (en) * | 2013-03-28 | 2014-10-01 | Basf Se | Compositions comprising a triazole compound |
| CN104686527A (en) * | 2015-02-16 | 2015-06-10 | 杭州宇龙化工有限公司 | Fungicidal composition containing phenyl ether bisimidazole and zoxamide |
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| CN1923819A (en) * | 2006-10-12 | 2007-03-07 | 青岛科技大学 | compound containing aromatic ether and ditriazole and use thereof |
| CN101209042A (en) * | 2006-12-29 | 2008-07-02 | 河南农业大学 | Bactericial composition |
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| EP0111658A2 (en) * | 1980-06-02 | 1984-06-27 | Imperial Chemical Industries Plc | 1,3-Dihalopropan-2-ols |
| CN1923819A (en) * | 2006-10-12 | 2007-03-07 | 青岛科技大学 | compound containing aromatic ether and ditriazole and use thereof |
| CN101209042A (en) * | 2006-12-29 | 2008-07-02 | 河南农业大学 | Bactericial composition |
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| WO2014082871A1 (en) | 2012-11-27 | 2014-06-05 | Basf Se | Substituted 2-[phenoxy-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds and their use as fungicides |
| WO2014082881A1 (en) | 2012-11-27 | 2014-06-05 | Basf Se | Substituted 2-[phenoxy-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds and their use as fungicides |
| EP2783569A1 (en) * | 2013-03-28 | 2014-10-01 | Basf Se | Compositions comprising a triazole compound |
| CN104686527A (en) * | 2015-02-16 | 2015-06-10 | 杭州宇龙化工有限公司 | Fungicidal composition containing phenyl ether bisimidazole and zoxamide |
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