CN102675513A - 溶液法生产三元乙丙橡胶聚合反应器及工艺过程控制方法 - Google Patents
溶液法生产三元乙丙橡胶聚合反应器及工艺过程控制方法 Download PDFInfo
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- CN102675513A CN102675513A CN2012101832190A CN201210183219A CN102675513A CN 102675513 A CN102675513 A CN 102675513A CN 2012101832190 A CN2012101832190 A CN 2012101832190A CN 201210183219 A CN201210183219 A CN 201210183219A CN 102675513 A CN102675513 A CN 102675513A
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- 229920002943 EPDM rubber Polymers 0.000 title abstract 2
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- 239000005060 rubber Substances 0.000 claims abstract description 82
- 239000000178 monomer Substances 0.000 claims abstract description 64
- 239000002904 solvent Substances 0.000 claims abstract description 28
- 239000007788 liquid Substances 0.000 claims abstract description 24
- 238000006243 chemical reaction Methods 0.000 claims abstract description 23
- 238000003756 stirring Methods 0.000 claims abstract description 20
- 239000007789 gas Substances 0.000 claims abstract description 18
- 238000001704 evaporation Methods 0.000 claims abstract description 16
- 230000008020 evaporation Effects 0.000 claims abstract description 15
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 11
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 9
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- 239000006260 foam Substances 0.000 claims abstract description 6
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- 238000001514 detection method Methods 0.000 claims abstract description 5
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 claims abstract description 4
- 239000005977 Ethylene Substances 0.000 claims abstract description 4
- 229920001897 terpolymer Polymers 0.000 claims description 47
- 239000012530 fluid Substances 0.000 claims description 25
- 238000004519 manufacturing process Methods 0.000 claims description 17
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- 239000001257 hydrogen Substances 0.000 claims description 8
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- 239000000463 material Substances 0.000 claims description 7
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- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 239000002994 raw material Substances 0.000 abstract description 3
- 238000004817 gas chromatography Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 26
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 21
- 239000011541 reaction mixture Substances 0.000 description 13
- 238000013461 design Methods 0.000 description 12
- 238000005516 engineering process Methods 0.000 description 12
- 239000000047 product Substances 0.000 description 10
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- 239000007791 liquid phase Substances 0.000 description 8
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
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- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 1
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- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
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- CNFQJGLKUZBUBD-TXHUMJEOSA-N hexa-1,5-diene;(3e)-hexa-1,3-diene;(4e)-hexa-1,4-diene Chemical class CC\C=C\C=C.C\C=C\CC=C.C=CCCC=C CNFQJGLKUZBUBD-TXHUMJEOSA-N 0.000 description 1
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- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
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CN 201210183219 CN102675513B (zh) | 2012-06-06 | 2012-06-06 | 溶液法生产三元乙丙橡胶聚合反应器及工艺过程控制方法 |
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CN 201210183219 CN102675513B (zh) | 2012-06-06 | 2012-06-06 | 溶液法生产三元乙丙橡胶聚合反应器及工艺过程控制方法 |
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CN102675513B CN102675513B (zh) | 2013-08-07 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102989406A (zh) * | 2013-01-08 | 2013-03-27 | 苏州雄鹰笔墨科技有限公司 | 一种中油墨水专用搅拌装置 |
CN109012510A (zh) * | 2018-07-02 | 2018-12-18 | 中国石油集团东北炼化工程有限公司吉林设计院 | 聚合反应器 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6096840A (en) * | 1994-08-02 | 2000-08-01 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization process |
CN1292007A (zh) * | 1998-03-04 | 2001-04-18 | 埃克森化学专利公司 | 用串联反应器制备聚合物共混物的方法 |
CN1295083A (zh) * | 1999-09-10 | 2001-05-16 | 联合碳化化学品及塑料技术公司 | 将液态共聚用单体供入流化床反应器中进行聚合反应的方法 |
CN1312827A (zh) * | 1998-06-17 | 2001-09-12 | 联合碳化化学品及塑料技术公司 | 调节气相反应器生产乙丙橡胶或三元乙丙橡胶的方法 |
JP2002179706A (ja) * | 2000-12-18 | 2002-06-26 | Mitsui Chemicals Inc | 重合設備および重合方法 |
US6911504B2 (en) * | 2000-04-13 | 2005-06-28 | Bp Chemicals Limited | Apparatus and process for gas phase fluidized-bed polymerization |
CN101903423A (zh) * | 2007-12-20 | 2010-12-01 | 埃克森美孚研究工程公司 | 用于乙烯丙烯共聚物的本体均相聚合法 |
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2012
- 2012-06-06 CN CN 201210183219 patent/CN102675513B/zh not_active Expired - Fee Related
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6096840A (en) * | 1994-08-02 | 2000-08-01 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization process |
CN1292007A (zh) * | 1998-03-04 | 2001-04-18 | 埃克森化学专利公司 | 用串联反应器制备聚合物共混物的方法 |
CN1312827A (zh) * | 1998-06-17 | 2001-09-12 | 联合碳化化学品及塑料技术公司 | 调节气相反应器生产乙丙橡胶或三元乙丙橡胶的方法 |
CN1295083A (zh) * | 1999-09-10 | 2001-05-16 | 联合碳化化学品及塑料技术公司 | 将液态共聚用单体供入流化床反应器中进行聚合反应的方法 |
US6911504B2 (en) * | 2000-04-13 | 2005-06-28 | Bp Chemicals Limited | Apparatus and process for gas phase fluidized-bed polymerization |
JP2002179706A (ja) * | 2000-12-18 | 2002-06-26 | Mitsui Chemicals Inc | 重合設備および重合方法 |
CN101903423A (zh) * | 2007-12-20 | 2010-12-01 | 埃克森美孚研究工程公司 | 用于乙烯丙烯共聚物的本体均相聚合法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102989406A (zh) * | 2013-01-08 | 2013-03-27 | 苏州雄鹰笔墨科技有限公司 | 一种中油墨水专用搅拌装置 |
CN109012510A (zh) * | 2018-07-02 | 2018-12-18 | 中国石油集团东北炼化工程有限公司吉林设计院 | 聚合反应器 |
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Denomination of invention: Polymerization reactor for producing ethylene propylene diene monomer by using solution method and process flow control method Effective date of registration: 20140708 Granted publication date: 20130807 Pledgee: China Merchants Bank Limited by Share Ltd. Changchun branch Pledgor: JILIN ZHONGXIN CHEMICAL GROUP Co.,Ltd. Registration number: 2014990000549 |
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Denomination of invention: Polymerization reactor for producing ethylene propylene diene monomer by using solution method and process flow control method Effective date of registration: 20150730 Granted publication date: 20130807 Pledgee: China Merchants Bank Limited by Share Ltd. Changchun branch Pledgor: JILIN ZHONGXIN CHEMICAL GROUP Co.,Ltd. Registration number: 2015990000620 |
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Date of cancellation: 20170929 Granted publication date: 20130807 Pledgee: China Merchants Bank Limited by Share Ltd. Changchun branch Pledgor: JILIN ZHONGXIN CHEMICAL GROUP Co.,Ltd. Registration number: 2015990000620 |
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Denomination of invention: Polymerization reactor for producing ethylene propylene diene monomer by using solution method and process flow control method Effective date of registration: 20171107 Granted publication date: 20130807 Pledgee: China Merchants Bank Limited by Share Ltd. Changchun branch Pledgor: JILIN ZHONGXIN CHEMICAL GROUP Co.,Ltd. Registration number: 2017220000017 |
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