CN102658691A - Ceramic aluminum single sheet and preparation process thereof - Google Patents
Ceramic aluminum single sheet and preparation process thereof Download PDFInfo
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- CN102658691A CN102658691A CN2012101357483A CN201210135748A CN102658691A CN 102658691 A CN102658691 A CN 102658691A CN 2012101357483 A CN2012101357483 A CN 2012101357483A CN 201210135748 A CN201210135748 A CN 201210135748A CN 102658691 A CN102658691 A CN 102658691A
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Abstract
The invention relates to the technical field of building materials and particularly relates to a ceramic aluminum single sheet and a preparation process of the ceramic aluminum single sheet. The ceramic aluminum single sheet comprises an aluminum alloy panel, wherein a sand-sprayed passivation layer, a chromizing pre-treatment layer and a fluorine-carbon ceramic coating are sequentially and outwardly arranged at the outer side of the aluminum alloy panel; the fluorine-carbon ceramic coating sequentially comprises a fluorine-carbon primer layer, a fluorine-carbon paint layer and a fluorine-carbon protection layer from inside to outside; a chromizing protection layer is arranged at the inner side of the aluminum alloy panel, and then the sand-sprayed passivation layer and the chromizing pre-treatment layer are arranged, and finally the fluorine-carbon ceramic coating is arranged, so that the surface of the alloy panel is cleaned and the adhesive force is strong; and the fluorine-carbon ceramic coating is firmly attached and is not easy to drop off. The preparation process of the ceramic aluminum single sheet disclosed by the invention is reliable and feasible, so that the final product ceramic aluminum single sheet has the advantages of excellent adhesive force, excellent acid resistance, excellent solvent resistance, excellent abrasion resistance, excellent impact resistance and excellent mechanical property.
Description
Technical field
The present invention relates to building material technical field, be specifically related to a kind of ceramic aluminum veneer and preparation technology.
Background technology
Traditional building and ornament materials great majority adopt stone material or plasterboard, but these ornament materials self are heavier, and building safety is poor, and the installation processing characteristics is also very poor.Aluminum veneer is because its excellent processing characteristics and factor such as own wt is light, price is low are widely used in the building decoration field.Along with the demand of market development and the raising of industry product class, people are also increasingly high to the various performance requirements of aluminum veneer in recent years.
Aluminum veneer uses owing to quilt in light weight widely; The patent No. be ZL03229332.1 Chinese disclosure of the Invention a kind of porcelain aluminum veneer building and ornament materials; Aluminium sheet is a base material, and the aluminium sheet architectural surface obtains corundum sand blasted surface processing layer through sandblast earlier, covers silica dioxide coating then; Corundum sand blasted surface processing layer camber is 5～10 μ m, thick 25～40 μ m of silica dioxide coating.As above-mentioned patent; Though market has some to carry out aluminum veneer coating material and preparation technology thereof; The product coating and the aluminum veneer adhesion of producing are not enough; Come off easily, the face coat atmospheric corrosion resistance is poor, be prone to produce light pollution, self-cleaning is poor, be not easy to the operational maintenance maintenance, color is single and be easy to generate aberration.
Summary of the invention
The objective of the invention is to the deficiency to prior art, and a kind of ceramic aluminum veneer and preparation technology thereof be provided, its be difficult for absorption dust, corrosion-resistant, self-cleaning strong, be convenient to operational maintenance maintenance, the non-fading characteristics of rich color.
The present invention realizes through following technology:
A kind of ceramic aluminum veneer; Comprise aluminium alloy panel; The outside of said aluminium alloy panel outwards is provided with sandblast passivation layer, chromaking pretreatment layer, fluorine carbon ceramics coating successively; Said fluorine carbon ceramics coating is divided into fluorine carbon prime coat, fluorine carbon finishing paint layer and fluorine carbon protective layer from inside to outside successively, and the inboard of said aluminium alloy panel is provided with the chromaking protective layer.
The preparation technology of aforesaid a kind of ceramic aluminum veneer is characterized in that: it comprises following processing step:
A, panel beating: the aluminium alloy panel of choosing thick aluminium of 2-4mm or alloy sheets formation is carried out panel beating;
B, blasting treatment: diamond dust is injected in the aluminium alloy panel outside forms the sandblast passivation layer;
C, pre-treatment:
C1, degreasing: the aluminium alloy panel that steps A obtains with degreaser at 50-80 ℃ of following degreasing 1-10 minute;
C2, washing;
C3, pickling: at room temperature carry out pickling 2-3min with pickle;
C4, washing;
C5, chromaking: with chromaking liquid chromaking 2-3 minute at normal temperatures;
C6, washing;
C7, oven dry: ℃ oven dry down in temperature≤60, final chromaking protective layer, the chromaking pretreatment layer of forming respectively on the surface, aluminium alloy panel medial and lateral of aluminium alloy panel;
D, spraying:
D1: handling the chromaking pretreatment layer surface spraying fluorine carbon ceramics coating formation fluorine carbon prime coat that obtains through step C, the thickness of control enamelled coating is 10～20um;
D2: levelling 10-15min under the room temperature;
D3: continue spray spraying fluorine carbon ceramics coating and form the fluorine carbon finishing paint layer, the thickness of control fluorine carbon finishing paint layer is 5～10um;
D4: levelling 10-15min under the room temperature;
D5: spray fluorine carbon finishing varnish at last and form the fluorine carbon protective layer, the thickness of control fluorine carbon protective layer is 10-20um;
D6: levelling 15-30min under the room temperature;
D7: be to dry under 235-250 ℃ the condition in temperature, promptly get fluorine carbon ceramics aluminum veneer of the present invention.
Preferable, in the said steps A panel beating comprise technological design successively, cut out, moulding, welding, kind nail, install reinforcing rib, established angle sign indicating number, polishing.
Preferable, every liter of degreaser of said step side C1 comprises the raw material of following content:
Preferable, said nonionic surface active agent is an emulsifier op-10.
Preferable, said antifoaming agent is the organic silicon modified by polyether antifoaming agent.
Preferable, every liter of pickle comprises the raw material of following content among the said step C3:
Preferable, said pyridines corrosion inhibiter is the chloro-hexadecane yl pyridines.
Preferable, every liter of chromaking liquid comprises the raw material of following content among the said step C5:
Beneficial effect of the present invention is: ceramic aluminum veneer of the present invention; Comprise aluminium alloy panel, the outside of said aluminium alloy panel outwards is provided with sandblast passivation layer, chromaking pretreatment layer, fluorine carbon ceramics coating successively, and said fluorine carbon ceramics coating is divided into fluorine carbon prime coat, fluorine carbon finishing paint layer and fluorine carbon protective layer from inside to outside successively; The inboard of said aluminium alloy panel is provided with the chromaking protective layer; Through sandblast passivation layer, chromaking pretreatment layer fluorine carbon ceramics coating is set again, makes alloy panel surface cleaning, strong adhesion; Make fluorine carbon ceramics coating adhesion-tight, difficult drop-off; The arranged outside fluorine carbon ceramics coating of aluminium alloy panel; Strengthened atmospheric corrosion resistance of the present invention; Simultaneously since the existence of fluorine carbon ceramics coating also make the present invention have no light pollution, self-cleaning by force, be convenient to operational maintenance maintenance, the non-fading characteristics of rich color; The manufacture craft of ceramic aluminum veneer of the present invention, technology reliably are prone to row, make adhesive force, acid resistance, solvent resistance, wearability, resistance to impact and the good mechanical properties of final products pottery aluminum veneer.
Description of drawings
Fig. 1 is the structural representation of the present invention's pottery aluminum veneer.
The specific embodiment
For the ease of those skilled in the art's understanding, the present invention is further described below in conjunction with embodiment and accompanying drawing:
As shown in Figure 1; A kind of ceramic aluminum veneer comprises aluminium alloy panel 1, and the outside of said aluminium alloy panel 1 outwards is provided with sandblast passivation layer 2, chromaking pretreatment layer 3, fluorine carbon ceramics coating 4 successively; Said fluorine carbon ceramics coating 4 is divided into fluorine carbon prime coat 41, fluorine carbon finishing paint layer 42 and fluorine carbon protective layer 43 from inside to outside successively; Through sandblast passivation layer 2, chromaking pretreatment layer 3 fluorine carbon ceramics coating 4 is set again, makes aluminium alloy panel 1 cleaning surfaces, strong adhesion; Make fluorine carbon ceramics coating 4 adhesion-tights, difficult drop-off; The arranged outside fluorine carbon ceramics coating 4 of aluminium alloy panel 1; Strengthened atmospheric corrosion resistance of the present invention; Simultaneously since the existence of fluorine carbon ceramics coating 4 also make the present invention have no light pollution, self-cleaning by force, be convenient to operational maintenance maintenance, the non-fading characteristics of rich color, the inboard of aluminium alloy panel 1 is provided with chromaking protective layer 5, carries out with chromaking pretreatment layer 3 man-hour adding; Save the technology cost, prevent that effectively the medial surface of aluminium alloy panel 1 from being corroded.
The invention still further relates to the preparation technology of a kind of the present invention of preparation pottery aluminum veneer, below several then embodiment describe in detail:
A, panel beating: choose the aluminium alloy panel that thick aluminium of 2mm or alloy sheets constitute and carry out panel beating, panel beating comprises technological design successively, cuts out, moulding, welding, kind nail, install reinforcing rib, established angle sign indicating number, polishing;
B, blasting treatment: diamond dust is injected in the aluminium alloy panel outside forms the sandblast passivation layer, generally use 60# diamond dust, carry out summer at normal temperatures, and carry out warm-up operation (preheat temperature 25～30 ℃) to base material winter.Through adjustment spray angle, pressure, distance adjustment workpiece surface roughness, it is preferable that surface roughness reaches the Ra3 level;
C, pre-treatment:
C1, degreasing: 50 ℃ of following degreasings 10 minutes, every liter of degreaser comprised the raw material of following content to the aluminium alloy panel that steps A obtains with degreaser:
C2, washing;
C3, pickling: at room temperature carry out pickling 2min with pickle, every liter of pickle comprises the raw material of following content:
C4, washing;
C5, chromaking: with chromaking liquid chromaking 2 minutes at normal temperatures, every liter of chromaking liquid comprises the raw material of following content:
C6, washing;
C7, oven dry: ℃ oven dry down in temperature≤60, final chromaking protective layer, the chromaking pretreatment layer of forming respectively on the surface, aluminium alloy panel medial and lateral of aluminium alloy panel;
D, spraying:
D1: handling the chromaking pretreatment layer surface spraying fluorine carbon ceramics coating formation fluorine carbon prime coat that obtains through step C, the thickness of control enamelled coating is 10um;
D2: levelling 10min under the room temperature;
D3: continue spray spraying fluorine carbon ceramics coating and form the fluorine carbon finishing paint layer, the thickness of control fluorine carbon finishing paint layer is 5um;
D4: levelling 10min under the room temperature;
D5: spray fluorine carbon finishing varnish at last and form the fluorine carbon protective layer, the thickness of control fluorine carbon protective layer is 10-20um;
D6: levelling 15min under the room temperature;
D7: be to dry under 235 ℃ the condition in temperature, promptly get fluorine carbon ceramics aluminum veneer of the present invention.
Embodiment 2, a kind of preparation technology of ceramic aluminum veneer: it comprises following processing step:
A, panel beating: choose the aluminium alloy panel that thick aluminium of 4mm or alloy sheets constitute and carry out panel beating, panel beating comprises technological design successively, cuts out, moulding, welding, kind nail, install reinforcing rib, established angle sign indicating number, polishing;
B, blasting treatment: diamond dust is injected in the aluminium alloy panel outside forms the sandblast passivation layer, generally use 80# diamond dust, carry out summer at normal temperatures, and carry out warm-up operation (preheat temperature 25～30 ℃) to base material winter.Through adjustment spray angle, pressure, distance adjustment workpiece surface roughness, it is preferable that surface roughness reaches the Ra3 level;
C, pre-treatment:
C1, degreasing: 80 ℃ of following degreasings 1 minute, every liter of degreaser comprised the raw material of following content to the aluminium alloy panel that steps A obtains with degreaser:
C2, washing;
C3, pickling: at room temperature carry out pickling 3min with pickle, every liter of pickle comprises the raw material of following content:
C4, washing;
C5, chromaking: with chromaking liquid chromaking 3 minutes at normal temperatures, every liter of chromaking liquid comprises the raw material of following content:
C6, washing;
C7, oven dry: ℃ oven dry down in temperature≤60, final chromaking protective layer, the chromaking pretreatment layer of forming respectively on the surface, aluminium alloy panel medial and lateral of aluminium alloy panel;
D, spraying:
D1: handling the chromaking pretreatment layer surface spraying fluorine carbon ceramics coating formation fluorine carbon prime coat that obtains through step C, the thickness of control enamelled coating is 20um;
D2: levelling 15min under the room temperature;
D3: continue spray spraying fluorine carbon ceramics coating and form the fluorine carbon finishing paint layer, the thickness of control fluorine carbon finishing paint layer is 10um;
D4: levelling 15min under the room temperature;
D5: spray fluorine carbon finishing varnish at last and form the fluorine carbon protective layer, the thickness of control fluorine carbon protective layer is 20um;
D6: levelling 30min under the room temperature;
D7: be to dry under 250 ℃ the condition in temperature, promptly get fluorine carbon ceramics aluminum veneer of the present invention.
A, panel beating: choose the aluminium alloy panel that thick aluminium of 3mm or alloy sheets constitute and carry out panel beating, panel beating comprises technological design successively, cuts out, moulding, welding, kind nail, install reinforcing rib, established angle sign indicating number, polishing;
B, blasting treatment: diamond dust is injected in the aluminium alloy panel outside forms the sandblast passivation layer, generally use 70# diamond dust, carry out summer at normal temperatures, and carry out warm-up operation (preheat temperature 25～30 ℃) to base material winter.Through adjustment spray angle, pressure, distance adjustment workpiece surface roughness, it is preferable that surface roughness reaches the Ra3 level;
C, pre-treatment:
C1, degreasing: at 70 ℃ of following degreasing 1-10 minutes, every liter of degreaser comprised the raw material of following content to the aluminium alloy panel that steps A obtains with degreaser:
C2, washing;
C3, pickling: at room temperature carry out pickling 2.5min with pickle, every liter of pickle comprises the raw material of following content:
C4, washing;
C5, chromaking: with chromaking liquid chromaking 2.5 minutes at normal temperatures, every liter of chromaking liquid comprises the raw material of following content:
C6, washing;
C7, oven dry: ℃ oven dry down in temperature≤60, final chromaking protective layer, the chromaking pretreatment layer of forming respectively on the surface, aluminium alloy panel medial and lateral of aluminium alloy panel;
D, spraying:
D1: handling the chromaking pretreatment layer surface spraying fluorine carbon ceramics coating formation fluorine carbon prime coat that obtains through step C, the thickness of control enamelled coating is 18um;
D2: levelling 12min under the room temperature;
D3: continue spray spraying fluorine carbon ceramics coating and form the fluorine carbon finishing paint layer, the thickness of control fluorine carbon finishing paint layer is 8um;
D4: levelling 13min under the room temperature;
D5: spray fluorine carbon finishing varnish at last and form the fluorine carbon protective layer, the thickness of control fluorine carbon protective layer is 10-20um;
D6: levelling 15-30min under the room temperature;
D7: be to dry under 235-250 ℃ the condition in temperature, promptly get fluorine carbon ceramics aluminum veneer of the present invention.
Embodiment 4, a kind of preparation technology of ceramic aluminum veneer: it comprises following processing step:
A, panel beating: choose the aluminium alloy panel that thick aluminium of 4mm or alloy sheets constitute and carry out panel beating, panel beating comprises technological design successively, cuts out, moulding, welding, kind nail, install reinforcing rib, established angle sign indicating number, polishing;
B, blasting treatment: diamond dust is injected in the aluminium alloy panel outside forms the sandblast passivation layer, generally use 70# diamond dust, carry out summer at normal temperatures, and carry out warm-up operation (preheat temperature 25～30 ℃) to base material winter.Through adjustment spray angle, pressure, distance adjustment workpiece surface roughness, it is preferable that surface roughness reaches the Ra3 level;
C, pre-treatment:
C1, degreasing: at 78 ℃ of following degreasing 1-10 minutes, every liter of degreaser comprised the raw material of following content to the aluminium alloy panel that steps A obtains with degreaser:
C2, washing;
C3, pickling: at room temperature carry out pickling 2-3min with pickle, every liter of pickle comprises the raw material of following content:
C4, washing;
C5, chromaking: with chromaking liquid chromaking 2.6 minutes at normal temperatures, every liter of chromaking liquid comprises the raw material of following content:
C6, washing;
C7, oven dry: ℃ oven dry down in temperature≤60, final chromaking protective layer, the chromaking pretreatment layer of forming respectively on the surface, aluminium alloy panel medial and lateral of aluminium alloy panel;
D, spraying:
D1: handling the chromaking pretreatment layer surface spraying fluorine carbon ceramics coating formation fluorine carbon prime coat that obtains through step C, the thickness of control enamelled coating is 16um;
D2: levelling 12.5min under the room temperature;
D3: continue spray spraying fluorine carbon ceramics coating and form the fluorine carbon finishing paint layer, the thickness of control fluorine carbon finishing paint layer is 8um;
D4: levelling 13min under the room temperature;
D5: spray fluorine carbon finishing varnish at last and form the fluorine carbon protective layer, the thickness of control fluorine carbon protective layer is 18um;
D6: levelling 25min under the room temperature;
D7: be to dry under 240 ℃ the condition in temperature, promptly get fluorine carbon ceramics aluminum veneer of the present invention.
Table 1 is the The performance test results that the ceramic aluminum veneer that embodiment 1-4 obtains is carried out.
Table 1
Above content is merely preferred embodiment of the present invention, and for those of ordinary skill in the art, according to thought of the present invention, the part that on the specific embodiment and range of application, all can change, this description should not be construed as limitation of the present invention.
Claims (9)
1. ceramic aluminum veneer; Comprise aluminium alloy panel; It is characterized in that: the outside of said aluminium alloy panel outwards is provided with sandblast passivation layer, chromaking pretreatment layer, fluorine carbon ceramics coating successively; Said fluorine carbon ceramics coating is divided into fluorine carbon prime coat, fluorine carbon finishing paint layer and fluorine carbon protective layer from inside to outside successively, and the inboard of said aluminium alloy panel is provided with the chromaking protective layer.
2. a kind of preparation technology of ceramic aluminum veneer according to claim 1, it is characterized in that: it comprises following processing step:
A, panel beating: the aluminium alloy panel of choosing thick aluminium of 2-4mm or alloy sheets formation is carried out panel beating;
B, blasting treatment: diamond dust is injected in the aluminium alloy panel outside forms the sandblast passivation layer;
C, pre-treatment:
C1, degreasing: the aluminium alloy panel that steps A obtains with degreaser at 50-80 ℃ of following degreasing 1-10 minute;
C2, washing;
C3, pickling: at room temperature carry out pickling 2-3min with pickle;
C4, washing;
C5, chromaking: with chromaking liquid chromaking 2-3 minute at normal temperatures;
C6, washing;
C7, oven dry: ℃ oven dry down in temperature≤60, final chromaking protective layer, the chromaking pretreatment layer of forming respectively on the surface, aluminium alloy panel medial and lateral of aluminium alloy panel;
D, spraying:
D1: handling the chromaking pretreatment layer surface spraying fluorine carbon ceramics coating formation fluorine carbon prime coat that obtains through step C, the thickness of control enamelled coating is 10～20um;
D2: levelling 10-15min under the room temperature;
D3: continue spray spraying fluorine carbon ceramics coating and form the fluorine carbon finishing paint layer, the thickness of control fluorine carbon finishing paint layer is 5～10um;
D4: levelling 10-15min under the room temperature;
D5: spray fluorine carbon finishing varnish at last and form the fluorine carbon protective layer, the thickness of control fluorine carbon protective layer is 10-20um;
D6: levelling 15-30min under the room temperature;
D7: be to dry under 235-250 ℃ the condition in temperature, promptly get fluorine carbon ceramics aluminum veneer of the present invention.
3. the manufacture craft of a kind of ceramic aluminum veneer according to claim 2 is characterized in that: in the said steps A panel beating comprise technological design successively, cut out, moulding, welding, kind nail, install reinforcing rib, established angle sign indicating number, polishing.
4. the manufacture craft of a kind of ceramic aluminum veneer according to claim 1, it is characterized in that: every liter of degreaser of said step side C1 comprises the raw material of following content:
5. the manufacture craft of a kind of ceramic aluminum veneer according to claim 4, it is characterized in that: said nonionic surface active agent is an emulsifier op-10.
6. the manufacture craft of a kind of ceramic aluminum veneer according to claim 4, it is characterized in that: said antifoaming agent is the organic silicon modified by polyether antifoaming agent.
7. the manufacture craft of a kind of ceramic aluminum veneer according to claim 2 is characterized in that: every liter of pickle comprises the raw material of following content among the said step C3:
8. the manufacture craft of a kind of ceramic aluminum veneer according to claim 7, it is characterized in that: said pyridines corrosion inhibiter is the chloro-hexadecane yl pyridines.
9. the manufacture craft of a kind of ceramic aluminum veneer according to claim 2 is characterized in that: every liter of chromaking liquid comprises the raw material of following content among the said step C5:
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| CN103206053A (en) * | 2013-03-27 | 2013-07-17 | 成都阳光铝制品有限公司 | Self-cleaning aluminum section and preparation process thereof |
| CN103711278A (en) * | 2013-12-19 | 2014-04-09 | 方大新材料（江西）有限公司 | Rare earth ceramic aluminum-coated single board for building decoration and manufacturing method |
| CN104014471A (en) * | 2014-06-24 | 2014-09-03 | 洛斐尔建材（沈阳）集团有限公司 | Fluorocarbon spraying method of aluminum alloy sections |
| CN104358343A (en) * | 2014-09-30 | 2015-02-18 | 浙江墙煌建材有限公司 | Water-based organic ceramic sprayed aluminum veneer and manufacturing technology thereof |
| CN105715003A (en) * | 2016-01-20 | 2016-06-29 | 宁波红杉高新板业有限公司 | Baked porcelain aluminium plate and preparation method thereof |
| CN109014774A (en) * | 2018-07-04 | 2018-12-18 | 安徽省浦菲尔建材有限公司 | A kind of porcelain aluminium sheet method for processing sheet material |
| CN109517519A (en) * | 2018-11-21 | 2019-03-26 | 嘉兴才蛮幕墙材料有限公司 | A kind of antique copper wire drawing aluminum veneer and preparation method thereof |
| CN109531060A (en) * | 2018-11-20 | 2019-03-29 | 嘉兴才蛮幕墙材料有限公司 | A kind of porous Scagliola aluminum veneer and preparation method thereof |
| CN111545991A (en) * | 2020-03-20 | 2020-08-18 | 浙江林德纳新型建材有限公司 | Production process of high-strength light aluminum veneer |
| CN111701829A (en) * | 2020-06-12 | 2020-09-25 | 重庆津浦科技发展有限公司 | Aluminum veneer coating production process |
| CN111823666A (en) * | 2020-08-06 | 2020-10-27 | 方大新材料（江西）有限公司 | Copper-aluminum composite decorative plate for building external wall and manufacturing process |
| CN112024244A (en) * | 2020-09-02 | 2020-12-04 | 江苏佰大幕墙科技有限公司 | Spraying production line for aluminum veneer and spraying process thereof |
| CN112127569A (en) * | 2020-09-24 | 2020-12-25 | 强徽新型建材有限公司 | Porcelain aluminum veneer and manufacturing process thereof |
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| CN103206053B (en) * | 2013-03-27 | 2015-07-22 | 成都阳光铝制品有限公司 | Preparation process for self-cleaning aluminum section |
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| CN103711278B (en) * | 2013-12-19 | 2015-09-16 | 方大新材料（江西）有限公司 | A kind of architectural decoration rare-earth ceramic coated with aluminum veneer and preparation method |
| CN104014471A (en) * | 2014-06-24 | 2014-09-03 | 洛斐尔建材（沈阳）集团有限公司 | Fluorocarbon spraying method of aluminum alloy sections |
| CN104014471B (en) * | 2014-06-24 | 2016-07-20 | 洛斐尔建材（沈阳）集团有限公司 | A kind of fluorocarbon-sprayed method of aluminium alloy extrusions |
| CN104358343A (en) * | 2014-09-30 | 2015-02-18 | 浙江墙煌建材有限公司 | Water-based organic ceramic sprayed aluminum veneer and manufacturing technology thereof |
| CN105715003B (en) * | 2016-01-20 | 2020-04-28 | 宁波红杉高新材料有限公司 | Porcelain aluminum plate and preparation method thereof |
| CN105715003A (en) * | 2016-01-20 | 2016-06-29 | 宁波红杉高新板业有限公司 | Baked porcelain aluminium plate and preparation method thereof |
| CN109014774A (en) * | 2018-07-04 | 2018-12-18 | 安徽省浦菲尔建材有限公司 | A kind of porcelain aluminium sheet method for processing sheet material |
| CN109531060A (en) * | 2018-11-20 | 2019-03-29 | 嘉兴才蛮幕墙材料有限公司 | A kind of porous Scagliola aluminum veneer and preparation method thereof |
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Application publication date: 20120912 |