CN109517519A - A kind of antique copper wire drawing aluminum veneer and preparation method thereof - Google Patents
A kind of antique copper wire drawing aluminum veneer and preparation method thereof Download PDFInfo
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- CN109517519A CN109517519A CN201811390182.2A CN201811390182A CN109517519A CN 109517519 A CN109517519 A CN 109517519A CN 201811390182 A CN201811390182 A CN 201811390182A CN 109517519 A CN109517519 A CN 109517519A
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- aluminum veneer
- wire drawing
- copper wire
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
A kind of antique copper wire drawing aluminum veneer and preparation method thereof, including prime coat, top coat layer, ink layer and layer of varnish, the top coat layer is the water-based ultraviolet (UV) curable coating containing nano material, the water-based ultraviolet (UV) curable coating by percentage to the quality, including component: 15-35 parts of polyurethane acrylate prepolymers, 1-2 parts of emulsifiers, 1-5 parts of photoinitiators, 1-5 portions of reactive diluents, 0.5-2 parts of dispersing agents, 2-5 parts of nano-ZnOs or nano-TiO2Or nanometer Ag, 30-60 parts of deionized waters.The nano material that the aluminum veneer and preparation method thereof is dexterously utilized in coating achievees the effect that save ultraviolet energy, while the effect of assign aluminum veneer long-acting bactericidal.
Description
Technical field
The present invention relates to a kind of converted products of aluminum veneer and processing methods, more particularly, to a kind of antique copper wire drawing aluminium list
Plate and preparation method thereof.
Background technique
Coating plays an important role in national economy, does not replace in modern society.But the whole world is annual
There are 10,000,000 t from the volatile organic matter (VOC) being discharged into atmosphere is evaporated in coating, is atmosphere pollution main source.
With the continuous improvement of people's environmental consciousness, the appearance of the relevant laws and regulations of VOC discharge, the green coating product of environment-friendly type are limited
With its nonstaining property, it is safe the features such as, the common recognition of entire society is had become instead of traditional seriously polluted solvent based coating.
Water paint becomes one of the green environmental friendly coatings that domestic and foreign scholars concentrate research so as to aqueous advantage, but it is led
It wants the disadvantage is that long by water evaporation curing time, baking wants certain temperature to waste energy.Aqueous ultraviolet (UV) photocureable coating is most
Big advantage is that curing time is extremely short, the principle of solidification are as follows: photoinitiator can absorb ultraviolet light, generate the work for causing curing reaction
Property group, cause cross-linking and curing reaction, formed film.Has dress using aluminum veneer prepared by water paint and photocuring technology
Decorations effect, the effect of energy conservation and environmental protection and low cost, but it still has following problems and needs to solve:
1) mass percent of the photoinitiator in coating is low, only accounts for 1-5 parts, after ultraviolet generater handles metal plate, part is purple
Outside line is reflected, and the capacity usage ratio of ultraviolet light is lower, since the wavelength of ultraviolet light is less than the partial size of high molecular polymer, is caused
A part of ultraviolet light encounters high molecular polymer generation reflection or scattering loss is fallen；
2) the aluminum veneer functionality of water paint preparation is single.
It, can be by introducing the painting containing nano material in antique copper wire drawing aluminum veneer in order to solve above-mentioned two problems
Material, and the coating containing nano material is used in aluminum veneer process, reason is as follows: due to the special knot of nano material
Quantum size effect caused by structure and tunnel-effect etc. cause it to generate many specific performances for being different from conventional material: fabulous
Microwave absorbing property, broadband, good compatibility, thin high-quality and thickness the features such as, on the one hand, due to nanoparticle having a size of l~
100 nm are much smaller than electromagnetic wavelength, and nanoparticle material is more much better than than conventional material to the transmitance of this wave, this is with regard to big
The reflectivity for reducing wave greatly, reduces the utilization rate of ultraviolet light；On the other hand, nano material can also assign antique copper aluminum veneer
Certain anti-flammability, bactericidal properties, hydrophobicity and electric conductivity, has expanded the application field of aluminum veneer.
Summary of the invention
The present invention provides a kind of antique copper wire drawing aluminum veneers and preparation method thereof, not only increase the utilization of ultraviolet light
Rate, and assign antique copper wire drawing aluminum veneer long-acting bactericidal.
Technical solution of the present invention:
A kind of antique copper wire drawing aluminum veneer, including aluminum veneer and composite layer, the composite layer successively divide outward from aluminum veneer surface
Cloth: prime coat, top coat layer, ink layer and layer of varnish, which is characterized in that the top coat layer is the aqueous UV light containing nano material
It is coating material solidified, the water-based ultraviolet (UV) curable coating by percentage to the quality, including component: 15-35 parts of polyurethane acrylate prepolymers
Aggressiveness, 1-2 parts of emulsifiers, 1-5 parts of photoinitiators, 1-5 portions of reactive diluents, 0.5-2 parts of dispersing agents, 2-5 parts of nano-ZnOs, 30-
60 parts of deionized waters.
Preferably, the nano-ZnO can be replaced nano-TiO2Or nanometer Ag.
A kind of antique copper wire drawing aluminum veneer production method successively comprises the steps of: panel beating, ungrease treatment, spraying
Priming paint, spray paint, ultraviolet generator processing spray ink, wire drawing process and lacquer varnish, which is characterized in that the spraying
During finishing coat, the finishing coat is the water-based ultraviolet (UV) curable coating containing nano material, and the water-based ultraviolet (UV) curable coating is with matter
Measure percentages, including component: 15-35 parts of polyurethane acrylate prepolymers, 1-2 parts of emulsifiers, 1-5 parts of photoinitiators, 1-5
Part reactive diluent, 0.5-2 parts of dispersing agents, 2-5 parts of nano-ZnOs, 30-60 parts of deionized waters, when the ultraviolet generator is handled
Between be 5-50 seconds.
Preferably, the nano-ZnO can be replaced nano-TiO2Or nanometer Ag.
Preferably, the panel beating process successively includes: customization steelframe structure size, drawing optimization, orders material optimization, shear
Blanking, scribing line angle of release, angle of attack code holes, bending and molding, welding equipment splicing, dress reinforcing rib, polishing, dress corner brace and polishing.
Preferably, spray-applied primer layer is with a thickness of at 8-15 μm, and for spray-coating surface thickness of paint layer at 15-20 μm, spraying ink layer is thick
Degree is at 5-10 μm, and lacquer varnish thickness degree is at 5-10 μm.
Preferably, the tool of the wire drawing process is wire-drawing surface or scouring pad.
Preferably, the temperature of the painting environments is 20-40 DEG C, and the relative humidity of painting environments is 30-60 parts.
Preferably, the ink layer is to ink: diluent mass percent is 1:0.5-1:0.8.
Technical effect of the invention:
1. shortening curing time using aqueous ultraviolet photocureable coating；
2. nano-ZnO or nano-TiO is added2Or nanometer Ag can absorb some ultra violet rays, improve the capacity usage ratio of ultraviolet light；
3. nano-ZnO or nano-TiO is added2Or nanometer Ag assigns antique copper wire drawing aluminum veneer long-acting bactericidal.
Specific embodiment
Embodiment 1
A kind of antique copper wire drawing aluminum veneer, including aluminum veneer and composite layer, the composite layer successively divide outward from aluminum veneer surface
Cloth: prime coat, top coat layer, ink layer and layer of varnish, the top coat layer are the water-based ultraviolet (UV) curable coating containing nano material, institute
State water-based ultraviolet (UV) curable coating by percentage to the quality, including component: 15-35 parts of polyurethane acrylate prepolymers, 1-2 parts of creams
Agent, 1-5 parts of photoinitiators, 1-5 portions of reactive diluents, 0.5-2 parts of dispersing agents, 2-5 parts of nano-ZnOs, 30-60 parts of deionizations
Water.
A kind of production method of antique copper wire drawing aluminum veneer successively comprises the steps of: panel beating, ungrease treatment, spray
It primes, spray paint, ultraviolet generator processing sprays ink, wire drawing process and lacquer varnish, which is characterized in that the spray
During painting, the finishing coat be the water-based ultraviolet (UV) curable coating containing nano material, the water-based ultraviolet (UV) curable coating with
Mass percent meter, including component: 15-35 parts of polyurethane acrylate prepolymers, 1-2 parts of emulsifiers, 1-5 parts of photoinitiators,
1-5 portions of reactive diluents, 0.5-2 parts of dispersing agents, 2-5 parts of nano-ZnOs, 30-60 parts of deionized waters, the ultraviolet generator processing
Time is 5-50 seconds.
As needed, the panel beating process successively includes: customization steelframe structure size, drawing optimization, orders material optimization, cuts
Plate blanking, scribing line angle of release, angle of attack code holes, bending and molding, welding equipment splicing, dress reinforcing rib, polishing, dress corner brace and polishing.
As needed, for spray-applied primer layer with a thickness of at 8-15 μm, spray-coating surface thickness of paint layer sprays ink layer at 15-20 μm
Thickness is at 5-10 μm, and lacquer varnish thickness degree is at 5-10 μm.
As needed, the tool of the wire drawing process is wire-drawing surface or scouring pad.
As needed, the temperature of the painting environments is 20-40 DEG C, and the relative humidity of painting environments is 30-60 parts.
As needed, the ink layer is to ink: diluent mass percent is 1:0.5-1:0.8.
Embodiment 2
A kind of antique copper wire drawing aluminum veneer, including aluminum veneer and composite layer, the composite layer successively divide outward from aluminum veneer surface
Cloth: prime coat, top coat layer, ink layer and layer of varnish, the top coat layer are the water-based ultraviolet (UV) curable coating containing nano material, institute
State water-based ultraviolet (UV) curable coating by percentage to the quality, including component: 15-35 parts of polyurethane acrylate prepolymers, 1-2 parts of creams
Agent, 1-5 parts of photoinitiators, 1-5 portions of reactive diluents, 0.5-2 parts of dispersing agents, 2-5 parts of nano-TiOs2, 30-60 parts of deionizations
Water.
A kind of antique copper wire drawing aluminum veneer production method successively comprises the steps of: panel beating, ungrease treatment, spraying
Priming paint, spray paint, ultraviolet generator processing spray ink, wire drawing process and lacquer varnish, which is characterized in that the spraying
During finishing coat, the finishing coat is the water-based ultraviolet (UV) curable coating containing nano material, and the water-based ultraviolet (UV) curable coating is with matter
Measure percentages, including component: 15-35 parts of polyurethane acrylate prepolymers, 1-2 parts of emulsifiers, 1-5 parts of photoinitiators, 1-5
Part reactive diluent, 0.5-2 parts of dispersing agents, 2-5 parts of nano-TiOs2, 30-60 parts of deionized waters, when the ultraviolet generator is handled
Between be 5-50 seconds.
As needed, the panel beating process successively includes: customization steelframe structure size, drawing optimization, orders material optimization, cuts
Plate blanking, scribing line angle of release, angle of attack code holes, bending and molding, welding equipment splicing, dress reinforcing rib, polishing, dress corner brace and polishing.
As needed, for spray-applied primer layer with a thickness of at 8-15 μm, spray-coating surface thickness of paint layer sprays ink layer at 15-20 μm
Thickness is at 5-10 μm, and lacquer varnish thickness degree is at 5-10 μm.
As needed, the tool of the wire drawing process is wire-drawing surface or scouring pad.
As needed, the temperature of the painting environments is 20-40 DEG C, and the relative humidity of painting environments is 30-60 parts.
As needed, the ink layer is to ink: diluent mass percent is 1:0.5-1:0.8.
Embodiment 3
A kind of antique copper wire drawing aluminum veneer, including aluminum veneer and composite layer, the composite layer successively divide outward from aluminum veneer surface
Cloth: prime coat, top coat layer, ink layer and layer of varnish, the top coat layer are the water-based ultraviolet (UV) curable coating containing nano material, institute
State water-based ultraviolet (UV) curable coating by percentage to the quality, including component: 15-35 parts of polyurethane acrylate prepolymers, 1-2 parts of creams
Agent, 1-5 parts of photoinitiators, 1-5 portions of reactive diluents, 0.5-2 parts of dispersing agents, 2-5 parts of nanometer Ags, 30-60 parts of deionized waters.
A kind of antique copper wire drawing aluminum veneer production method successively comprises the steps of: panel beating, ungrease treatment, spraying
Priming paint, spray paint, ultraviolet generator processing spray ink, wire drawing process and lacquer varnish, which is characterized in that the spraying
During finishing coat, the finishing coat is the water-based ultraviolet (UV) curable coating containing nano material, and the water-based ultraviolet (UV) curable coating is with matter
Measure percentages, including component: 15-35 parts of polyurethane acrylate prepolymers, 1-2 parts of emulsifiers, 1-5 parts of photoinitiators, 1-5
Part reactive diluent, 0.5-2 parts of dispersing agents, 2-5 parts of nanometer Ags, 30-60 parts of deionized waters, the ultraviolet generator handle the time
It is 5-50 seconds.
As needed, the panel beating process successively includes: customization steelframe structure size, drawing optimization, orders material optimization, cuts
Plate blanking, scribing line angle of release, angle of attack code holes, bending and molding, welding equipment splicing, dress reinforcing rib, polishing, dress corner brace and polishing.
As needed, for spray-applied primer layer with a thickness of at 8-15 μm, spray-coating surface thickness of paint layer sprays ink layer at 15-20 μm
Thickness is at 5-10 μm, and lacquer varnish thickness degree is at 5-10 μm.
As needed, the tool of the wire drawing process is wire-drawing surface or scouring pad.
As needed, the temperature of the painting environments is 20-40 DEG C, and the relative humidity of painting environments is 30-60 parts.
As needed, the ink layer is to ink: diluent mass percent is 1:0.5-1:0.8.
Specific embodiment is only explanation of the invention, is not the limitation to invention, and those skilled in the art exist
It can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as in invention
All by the protection of Patent Law in scope of the claims.
Claims (9)
1. a kind of antique copper wire drawing aluminum veneer, including aluminum veneer and composite layer, the composite layer from aluminum veneer surface outward successively
Distribution: prime coat, top coat layer, ink layer and layer of varnish, which is characterized in that the top coat layer is the aqueous UV containing nano material
Photocureable coating, the water-based ultraviolet (UV) curable coating by percentage to the quality, including component: 15-35 parts of urethane acrylates
Performed polymer, 1-2 parts of emulsifiers, 1-5 parts of photoinitiators, 1-5 portions of reactive diluents, 0.5-2 parts of dispersing agents, 2-5 parts of nano-ZnOs,
30-60 parts of deionized waters.
2. antique copper wire drawing aluminum veneer according to claim 1, which is characterized in that the nano-ZnO can be replaced nanometer
TiO2Or nanometer Ag.
3. a kind of antique copper wire drawing aluminum veneer production method according to claim 1, successively comprises the steps of: that metal plate adds
Work, ungrease treatment, spray-applied primer, spray paint, ultraviolet generator processing spray ink, wire drawing process and lacquer varnish, special
Sign is, during the spray paint, the finishing coat is the water-based ultraviolet (UV) curable coating containing nano material, the aqueous UV
Photocureable coating by percentage to the quality, including component: 15-35 parts of polyurethane acrylate prepolymers, 1-2 parts of emulsifiers, 1-5
Part photoinitiator, 1-5 portions of reactive diluents, 0.5-2 parts of dispersing agents, 2-5 parts of nano-ZnOs, 30-60 parts of deionized waters, the purple
The outer generator processing time is 5-50 seconds.
4. a kind of antique copper wire drawing aluminum veneer production method according to claim 3, which is characterized in that the nano-ZnO
It can be replaced nano-TiO2Or nanometer Ag.
5. antique copper wire drawing aluminum veneer production method according to claim 3 or 4, which is characterized in that the panel beating
Process successively includes: customization steelframe structure size, drawing optimization, orders material optimization, shear blanking, scribing line angle of release, angle of attack code holes, bending
Molding, welding equipment splicing, dress reinforcing rib, polishing, dress corner brace and polishing.
6. antique copper wire drawing aluminum veneer production method according to claim 5, which is characterized in that spray-applied primer layer with a thickness of
At 8-15 μm, spray-coating surface thickness of paint layer sprays ink film thickness at 5-10 μm, lacquer varnish thickness degree is in 5-10 at 15-20 μm
μm。
7. antique copper wire drawing aluminum veneer production method according to claim 5, which is characterized in that the work of the wire drawing process
Tool is wire-drawing surface or scouring pad.
8. antique copper wire drawing aluminum veneer production method according to claim 5, which is characterized in that the temperature of the painting environments
Degree is 20-40 DEG C, and the relative humidity of painting environments is 30-60 parts.
9. antique copper wire drawing aluminum veneer production method according to claim 5, which is characterized in that the ink layer is to oil
Ink: diluent mass percent is 1:0.5-1:0.8.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201811390182.2A CN109517519A (en) | 2018-11-21 | 2018-11-21 | A kind of antique copper wire drawing aluminum veneer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811390182.2A CN109517519A (en) | 2018-11-21 | 2018-11-21 | A kind of antique copper wire drawing aluminum veneer and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN109517519A true CN109517519A (en) | 2019-03-26 |
Family
ID=65777408
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201811390182.2A Pending CN109517519A (en) | 2018-11-21 | 2018-11-21 | A kind of antique copper wire drawing aluminum veneer and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113198706A (en) * | 2021-05-08 | 2021-08-03 | 张晓立 | UV vacuum plating and wire drawing process and plastic product thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999021894A1 (en) * | 1997-10-27 | 1999-05-06 | Henkel Corporation | Radiation curable polyesters |
| CN102658691A (en) * | 2012-05-04 | 2012-09-12 | 东莞市华轩幕墙材料有限公司 | Ceramic aluminum single sheet and preparation process thereof |
| CN104148258A (en) * | 2014-07-21 | 2014-11-19 | 浙江德清森朗装饰材料有限公司 | Fluorocarbon aluminum panel manufacturing technique |
| CN105856748A (en) * | 2015-01-21 | 2016-08-17 | 合肥海尔特种钢板研制开发有限公司 | Stereoscopic texture decorative metal plate and production method thereof |
-
2018
- 2018-11-21 CN CN201811390182.2A patent/CN109517519A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999021894A1 (en) * | 1997-10-27 | 1999-05-06 | Henkel Corporation | Radiation curable polyesters |
| CN102658691A (en) * | 2012-05-04 | 2012-09-12 | 东莞市华轩幕墙材料有限公司 | Ceramic aluminum single sheet and preparation process thereof |
| CN104148258A (en) * | 2014-07-21 | 2014-11-19 | 浙江德清森朗装饰材料有限公司 | Fluorocarbon aluminum panel manufacturing technique |
| CN105856748A (en) * | 2015-01-21 | 2016-08-17 | 合肥海尔特种钢板研制开发有限公司 | Stereoscopic texture decorative metal plate and production method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113198706A (en) * | 2021-05-08 | 2021-08-03 | 张晓立 | UV vacuum plating and wire drawing process and plastic product thereof |
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Application publication date: 20190326 |