CN102643508A - Environment-friendly inflaming-retarding acrylonitrile-butadiene-styrene (ABS) material - Google Patents
Environment-friendly inflaming-retarding acrylonitrile-butadiene-styrene (ABS) material Download PDFInfo
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- CN102643508A CN102643508A CN2012101444481A CN201210144448A CN102643508A CN 102643508 A CN102643508 A CN 102643508A CN 2012101444481 A CN2012101444481 A CN 2012101444481A CN 201210144448 A CN201210144448 A CN 201210144448A CN 102643508 A CN102643508 A CN 102643508A
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Abstract
An environment-friendly inflaming-retarding acrylonitrile-butadiene-styrene (ABS) material belongs to the technical field of high polymer materials, which comprises the following components, by weight: 50-90 parts of ABS, 10-50 parts of flame retardants, 5-20 parts of flame retardant association effect agents, 0-2 parts of antioxidants and 0-2 parts of processing agents. The ABS material is friendly to the environment and has high inflaming-retarding performance and an excellent mechanics effect.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of environment friendly flame-proof ABS material.
Background technology
The ABS material has the processing characteristics of excellent chemical resistant properties, mechanical property, excellence, therefore is widely used in industries such as automobile, household electrical appliances, aviation, boats and ships.Along with the continuous demand of product to material, modified ABS also gets more and more and on market, occurs.
Flame-proof ABS is the more modified ABS material of a use.Anti-flaming ABS material in the early time adopts fire retardants such as decabromodiphenyl, and human body and environment are made pollution, according to the RoHS of European Union requirement, bans use of this fire retardant to produce.For the requirement of corresponding European Union, we study fire retardant, develop to meet the environment-friendly flame-resistant ABS that the RoHS of European Union required and reached the V0 level.
Summary of the invention
Problem to prior art exists the objective of the invention is to design the technical scheme that a kind of environment friendly flame-proof ABS material is provided, and this ABS material is environmentally friendly, has high flame resistance and excellent mechanics effect.
Described kind of environment friendly flame-proof ABS material is characterized in that being made up of following weight proportioning component:
50～90 parts of ABS
10～50 parts of fire retardants
5～20 parts of fire retarding synergists
0～2 part in oxidation inhibitor
0～2 part of processing aid.
Described a kind of environment friendly flame-proof ABS material is characterized in that being made up of following weight proportioning component:
60～80 parts of ABS
20～40 parts of fire retardants
10～15 parts of fire retarding synergists
0.5～1.5 part in oxidation inhibitor
0.5～1.5 part of processing aid.
Described a kind of environment friendly flame-proof ABS material is characterized in that being made up of following weight proportioning component:
65～75 parts of ABS
25～35 parts of fire retardants
12～14 parts of fire retarding synergists
0.8～1.2 part in oxidation inhibitor
0.8～1.2 part of processing aid.
Described a kind of environment friendly flame-proof ABS material is characterized in that described fire retardant is one or more mixtures in TDE, bromophenisic acid isocyanic ester, triphenylphosphate, trimethyl phosphite 99 and the trimeric cyanamide urate.
Described a kind of environment friendly flame-proof ABS material is characterized in that described fire retarding synergist is one or more the mixture in Antimony Trioxide: 99.5Min, zinc borate and the ammonium molybdate.
Described a kind of environment friendly flame-proof ABS material is characterized in that described oxidation inhibitor is one or more the mixture among antioxidant 1010, oxidation inhibitor 1330, antioxidant 1076, oxidation inhibitor 1034, oxidation inhibitor 168, oxidation inhibitor 618, antioxidant 300, oxidation inhibitor DSTP and the oxidation inhibitor DMTDP.
Described a kind of environment friendly flame-proof ABS material is characterized in that described processing aid is one or more the mixture in calcium stearate, Magnesium Stearate, Zinic stearas, amine hydroxybenzene, polyethylene wax and the siloxanes.
The present invention fills a prescription rationally, and compared with prior art, have following advantage and excellent effect: 1) the present invention has used environment friendly flame retardant, meets the RoHS of European Union requirement; 2) environment friendly flame-proof ABS material that obtains of the present invention, to press down fumicants efficiently composite with fire retardant because of it has added, and greatly reduces the black smoke of material release when fire-retardant; The fire retardant bromine content that the present invention simultaneously adds is high, and molecular structure is big, and decomposition temperature is high; Photostabilization is excellent, has given prominence to good processability of the present invention greatly, anti-migration; Heat-resistant stability is high, the characteristics that anti-yellowing property is good; 3) environment friendly flame-proof ABS material that obtains of the present invention has excellent excellent mechanics effect, and tensile strength, shock strength etc. are all above more than 10% of current material.
Embodiment
Further specify the present invention below in conjunction with embodiment, the used umber of the present invention is weight part.
Fire retardant is claimed flame-proofing agent again, can improve the fire performance of material, adds in the material and can improve material because of the bad fire that takes place; Fire retarding synergist mainly plays the coordinate performance, cooperates fire retardant to improve flame retardant effect, reduces the usage quantity of fire retardant simultaneously; Oxidation inhibitor mainly plays the effect that suppresses and slow down the autoxidation reaction of macromolecular material, prevents that simultaneously polymkeric substance from fading and the aged effect because of what processing or use caused; The adding of processing aid can improve workability, release property and the oilness of material.
Embodiment 1
79 parts of ABS, 15 parts of fire retardant bromophenisic acid isocyanic ester, 6 parts of fire retarding synergist Antimony Trioxide: 99.5Mins, 0.6 part of antioxidant 1010,168 0.6 parts in oxidation inhibitor, 0.6 part of processing aid calcium stearate; Join in the high mixer successively; Behind the thorough mixing 5-15min; Drop into the twin screw extruder mixed melting, make standard test piece again and carry out flame retardant properties, Mechanics Performance Testing.
Fire retardant adopts a kind of in TDE, bromophenisic acid isocyanic ester, triphenylphosphate, trimethyl phosphite 99 and the trimeric cyanamide urate among the embodiment 1; Fire retarding synergist adopts a kind of in Antimony Trioxide: 99.5Min, zinc borate and the ammonium molybdate; Oxidation inhibitor adopts a kind of among antioxidant 1010, oxidation inhibitor 1330, antioxidant 1076, oxidation inhibitor 1034, oxidation inhibitor 168, oxidation inhibitor 618, antioxidant 300, oxidation inhibitor DSTP and the oxidation inhibitor DMTDP; Processing aid adopts a kind of in calcium stearate, Magnesium Stearate, Zinic stearas, amine hydroxybenzene, polyethylene wax and the siloxanes, and it also can arrive the technique effect identical with embodiment 1 at last.
Embodiment 2
65 parts of ABS, 30 parts of fire retardant bromophenisic acid isocyanic ester, 5 parts of fire retarding synergist Antimony Trioxide: 99.5Mins, 5 parts of fire retarding synergist zinc borates, 1,330 0.2 parts in oxidation inhibitor, 1,034 0.3 parts in oxidation inhibitor, 0.6 part of processing aid Magnesium Stearate, 0.6 part of processing aid polyethylene wax; Join in the high mixer successively; Behind the thorough mixing 5-15min; Drop into the twin screw extruder mixed melting, make standard test piece again and carry out flame retardant properties, Mechanics Performance Testing.
Embodiment 3
Totally 2 parts of totally 20 parts of ABS50 part, TDE, bromophenisic acid isocyanic ester, triphenylphosphate, trimethyl phosphite 99 and trimeric cyanamide urates, fire retarding synergist Antimony Trioxide: 99.5Min, zinc borate and totally 15 parts of ammonium molybdates, antioxidant 1010, oxidation inhibitor 1330, antioxidant 1076, oxidation inhibitor 1034, oxidation inhibitor 168, oxidation inhibitor 618, antioxidant 300, oxidation inhibitor DSTP and totally 0.8 part of oxidation inhibitor DMTDP, processing aid calcium stearate, Magnesium Stearate, Zinic stearas, amine hydroxybenzene, polyethylene wax and siloxanes; Join in the high mixer successively; Behind the thorough mixing 5-15min; Drop into the twin screw extruder mixed melting, make standard test piece again and carry out flame retardant properties, Mechanics Performance Testing.
Embodiment 4
90 parts of ABS, 50 parts of fire retardant triphenylphosphates, 20 parts of fire retarding synergist zinc borates, 2 parts of oxidation inhibitor DSTP, 0.2 part of processing aid amine hydroxybenzene; Join in the high mixer successively; Behind the thorough mixing 5-15min; Drop into the twin screw extruder mixed melting, make standard test piece again and carry out flame retardant properties, Mechanics Performance Testing.
Embodiment 5
ABS85 part, 5 parts of fire retardant trimethyl phosphite 99s, 5 parts of fire retardant trimeric cyanamide urates, 2 parts of fire retarding synergist zinc borates, 3 parts of fire retarding synergist Antimony Trioxide: 99.5Mins, 0.2 part of antioxidant 1076,1 part of processing aid Zinic stearas; Join in the high mixer successively; Behind the thorough mixing 5-15min; Drop into the twin screw extruder mixed melting, make standard test piece again and carry out flame retardant properties, Mechanics Performance Testing.
To the material of the present invention that obtains by embodiment 1, through material being carried out anti-flame retardant resistance, initial stage mechanical property affirmation, test result sees table:
Table 1
The ABS material that embodiment 2～5 is obtained carries out confirming with embodiment 1 identical anti-flame retardant resistance, initial stage mechanical property, its as a result tensile strength all can reach more than 45 Mpa, shock strength reaches 18 KJ/m
2More than, flexural strength reaches more than 66 Mpa, and Young's modulus reaches more than 2200 Mpa, and thermal denaturation temperature reaches more than 88, and UL94 reaches the V0 level.
In sum, material of the present invention is the modified ABS material of high flame retardant V0 level, high weather-proof, high gloss, environmental protection, low toxicity are applicable to commercial scale prodn, and are applicable to the product material of various high performance requirements.
Claims (7)
1. environment friendly flame-proof ABS material is characterized in that being made up of following weight proportioning component:
50～90 parts of ABS
10～50 parts of fire retardants
5～20 parts of fire retarding synergists
0～2 part in oxidation inhibitor
0～2 part of processing aid.
2. a kind of environment friendly flame-proof ABS material as claimed in claim 1 is characterized in that being made up of following weight proportioning component:
60～80 parts of ABS
20～40 parts of fire retardants
10～15 parts of fire retarding synergists
0.5～1.5 part in oxidation inhibitor
0.5～1.5 part of processing aid.
3. a kind of environment friendly flame-proof ABS material as claimed in claim 1 is characterized in that being made up of following weight proportioning component:
65～75 parts of ABS
25～35 parts of fire retardants
12～14 parts of fire retarding synergists
0.8～1.2 part in oxidation inhibitor
0.8～1.2 part of processing aid.
4. like claim 1 or 2 or 3 described a kind of environment friendly flame-proof ABS materials, it is characterized in that described fire retardant is one or more mixtures in TDE, bromophenisic acid isocyanic ester, triphenylphosphate, trimethyl phosphite 99 and the trimeric cyanamide urate.
5. like claim 1 or 2 or 3 described a kind of environment friendly flame-proof ABS materials, it is characterized in that described fire retarding synergist is one or more the mixture in Antimony Trioxide: 99.5Min, zinc borate and the ammonium molybdate.
6. like claim 1 or 2 or 3 described a kind of environment friendly flame-proof ABS materials, it is characterized in that described oxidation inhibitor is one or more the mixture among antioxidant 1010, oxidation inhibitor 1330, antioxidant 1076, oxidation inhibitor 1034, oxidation inhibitor 168, oxidation inhibitor 618, antioxidant 300, oxidation inhibitor DSTP and the oxidation inhibitor DMTDP.
7. like claim 1 or 2 or 3 described a kind of environment friendly flame-proof ABS materials, it is characterized in that described processing aid is one or more the mixture in calcium stearate, Magnesium Stearate, Zinic stearas, amine hydroxybenzene, polyethylene wax and the siloxanes.
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| CN2012101444481A CN102643508A (en) | 2012-05-11 | 2012-05-11 | Environment-friendly inflaming-retarding acrylonitrile-butadiene-styrene (ABS) material |
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| CN2012101444481A CN102643508A (en) | 2012-05-11 | 2012-05-11 | Environment-friendly inflaming-retarding acrylonitrile-butadiene-styrene (ABS) material |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059346A (en) * | 2012-11-13 | 2013-04-24 | 金发科技股份有限公司 | Composite flame retardant, preparation method and application thereof |
| CN107857968A (en) * | 2017-12-12 | 2018-03-30 | 佛山早稻田科技服务有限公司 | A kind of environmentally friendly anti-flaming ABS material |
| WO2022118926A1 (en) * | 2020-12-02 | 2022-06-09 | 東ソー株式会社 | Active hydrogen-containing organic compound scavenger, composition, and applications thereof |
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| CN101096447A (en) * | 2006-06-30 | 2008-01-02 | 佛山市顺德区汉达精密电子科技有限公司 | PC/ABS alloy |
| CN101456995A (en) * | 2007-12-11 | 2009-06-17 | 天津德昊超微新材料有限公司 | Environmental protection flame retardant styrene resin |
| CN101845197A (en) * | 2009-03-25 | 2010-09-29 | 上海锦湖日丽塑料有限公司 | High-performance halogen-free flame retardant ABS modified resin and preparation method thereof |
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2012
- 2012-05-11 CN CN2012101444481A patent/CN102643508A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101096447A (en) * | 2006-06-30 | 2008-01-02 | 佛山市顺德区汉达精密电子科技有限公司 | PC/ABS alloy |
| CN101456995A (en) * | 2007-12-11 | 2009-06-17 | 天津德昊超微新材料有限公司 | Environmental protection flame retardant styrene resin |
| CN101845197A (en) * | 2009-03-25 | 2010-09-29 | 上海锦湖日丽塑料有限公司 | High-performance halogen-free flame retardant ABS modified resin and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059346A (en) * | 2012-11-13 | 2013-04-24 | 金发科技股份有限公司 | Composite flame retardant, preparation method and application thereof |
| CN107857968A (en) * | 2017-12-12 | 2018-03-30 | 佛山早稻田科技服务有限公司 | A kind of environmentally friendly anti-flaming ABS material |
| WO2022118926A1 (en) * | 2020-12-02 | 2022-06-09 | 東ソー株式会社 | Active hydrogen-containing organic compound scavenger, composition, and applications thereof |
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Application publication date: 20120822 |