CN107857968A - A kind of environmentally friendly anti-flaming ABS material - Google Patents

A kind of environmentally friendly anti-flaming ABS material Download PDF

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Publication number
CN107857968A
CN107857968A CN201711319502.0A CN201711319502A CN107857968A CN 107857968 A CN107857968 A CN 107857968A CN 201711319502 A CN201711319502 A CN 201711319502A CN 107857968 A CN107857968 A CN 107857968A
Authority
CN
China
Prior art keywords
parts
environmentally friendly
abs material
friendly anti
flaming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711319502.0A
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Chinese (zh)
Inventor
林慈生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Zaodaotian Technology Service Co Ltd
Original Assignee
Foshan Zaodaotian Technology Service Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan Zaodaotian Technology Service Co Ltd filed Critical Foshan Zaodaotian Technology Service Co Ltd
Priority to CN201711319502.0A priority Critical patent/CN107857968A/en
Publication of CN107857968A publication Critical patent/CN107857968A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/08Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention belongs to chemical technology field, specifically a kind of environmentally friendly anti-flaming ABS material, it is made up of the following component counted in parts by weight:40 80 parts of ABS resin, 8 20 parts of trimethyl phosphate, 38 parts of Firebrake ZB, 13 parts of antioxidant, 14 parts of calcium stearate, 25 parts of heat stabilizer, 6 12 parts of glass fibre, maleic anhydride 9 15 parts of compatilizer of grafting, 12 parts of lubricant.ABS material provided by the invention not only has the advantages of environmental protection, anti-flammability is strong, but also has excellent mechanical property, light resistance and heat endurance.

Description

A kind of environmentally friendly anti-flaming ABS material
Technical field
The invention belongs to chemical technology field, and in particular to a kind of environmentally friendly anti-flaming ABS material.
Background technology
At present, ABS materials have excellent chemical resistance, mechanical property, excellent processing characteristics, therefore are widely used in The industries such as automobile, household electrical appliances, aviation, ship.As product is also more and more in market to the continuous demand of material, modified ABS Upper appearance.Flame-proof ABS material in the early time, using fire retardants such as decabromodiphenyls, human body and environment are caused serious harm with Pollution, forbid producing, using this based flame retardant.In order to meet current environmentally friendly theme, numerous technical staff are carried out to fire retardant Research, it is desirable to be able to develop a kind of environmentally friendly anti-flaming ABS material.
It can be seen that prior art could be improved and improve.
The content of the invention
In view of in place of above-mentioned the deficiencies in the prior art, it is an object of the invention to provide a kind of environmentally friendly anti-flaming ABS material, With the advantages of green, anti-flammability is strong, excellent mechanical effect.
In order to achieve the above object, this invention takes following technical scheme:
A kind of environmentally friendly anti-flaming ABS material, it is made up of the following component counted in parts by weight:ABS resin 40-80 parts, tricresyl phosphate Methyl esters 8-20 parts, Firebrake ZB 3-8 parts, antioxidant 1-3 parts, calcium stearate 1-4 parts, heat stabilizer 2-5 parts, glass fibre 6-12 Part, maleic anhydride grafting compatilizer 9-15 parts, lubricant 1-2 parts.
In described environmentally friendly anti-flaming ABS material, the component is in parts by weight:60 parts of ABS resin, tricresyl phosphate 14 parts of methyl esters, 5 parts of Firebrake ZB, 2 parts of antioxidant, 2 parts of calcium stearate, 3 parts of heat stabilizer, 9 parts of glass fibre, maleic anhydride grafting 12 parts of compatilizer, 1.5 parts of lubricant.
In described environmentally friendly anti-flaming ABS material, the lubricant is fatty acid amide.
In described environmentally friendly anti-flaming ABS material, the antioxidant is diphenylamines.
In described environmentally friendly anti-flaming ABS material, the heat stabilizer is PVC stabilizer.
Beneficial effect:
The invention provides a kind of environmentally friendly anti-flaming ABS material, and it not only has the advantages of environmental protection, anti-flammability is strong, but also has There are excellent mechanical property, light resistance and heat endurance.
Embodiment
The present invention provides a kind of environmentally friendly anti-flaming ABS material, to make the purpose of the present invention, technical scheme and effect more clear Chu, clearly, enumerating embodiment below, the present invention is described in more detail.It should be appreciated that specific embodiment described herein Only to explain the present invention, it is not intended to limit the present invention.
Embodiment 1.
A kind of environmentally friendly anti-flaming ABS material provided by the invention, is made up of the following component counted in parts by weight:ABS trees 40 parts of fat, 8 parts of trimethyl phosphate, 3 parts of Firebrake ZB, 1 part of antioxidant, 1 part of calcium stearate, 2 parts of heat stabilizer, 6 parts of glass fibre, Maleic anhydride is grafted 9 parts of compatilizer, 1 part of lubricant.
Preferably, lubricant is fatty acid amide.
Preferably, antioxidant is diphenylamines.
Preferably, heat stabilizer is PVC stabilizer.
Embodiment 2.
A kind of environmentally friendly anti-flaming ABS material provided by the invention, is made up of the following component counted in parts by weight:ABS trees 60 parts of fat, 14 parts of trimethyl phosphate, 5 parts of Firebrake ZB, 2 parts of antioxidant, 2 parts of calcium stearate, 3 parts of heat stabilizer, glass fibre 9 Part, maleic anhydride 12 parts of compatilizer of grafting, 1.5 parts of lubricant.
Preferably, lubricant is fatty acid amide.
Preferably, antioxidant is diphenylamines.
Preferably, heat stabilizer is PVC stabilizer.
Embodiment 3.
A kind of environmentally friendly anti-flaming ABS material provided by the invention, is made up of the following component counted in parts by weight:ABS trees 80 parts of fat, 20 parts of trimethyl phosphate, 8 parts of Firebrake ZB, 3 parts of antioxidant, 4 parts of calcium stearate, 5 parts of heat stabilizer, glass fibre 12 Part, maleic anhydride 15 parts of compatilizer of grafting, 2 parts of lubricant.
Preferably, lubricant is fatty acid amide.
Preferably, antioxidant is diphenylamines.
Preferably, heat stabilizer is PVC stabilizer.
It is understood that for those of ordinary skills, can be with technique according to the invention scheme and its hair Bright design is subject to equivalent substitution or change, and all these changes or replacement should all belong to the guarantor of appended claims of the invention Protect scope.

Claims (5)

1. a kind of environmentally friendly anti-flaming ABS material, it is characterised in that be made up of the following component counted in parts by weight:ABS resin 40-80 parts, trimethyl phosphate 8-20 parts, Firebrake ZB 3-8 parts, antioxidant 1-3 parts, calcium stearate 1-4 parts, heat stabilizer 2-5 parts, Glass fibre 6-12 parts, maleic anhydride grafting compatilizer 9-15 parts, lubricant 1-2 parts.
2. environmentally friendly anti-flaming ABS material according to claim 1, it is characterised in that the component is in parts by weight For:60 parts of ABS resin, 14 parts of trimethyl phosphate, 5 parts of Firebrake ZB, 2 parts of antioxidant, 2 parts of calcium stearate, 3 parts of heat stabilizer, glass 9 parts of glass fiber, maleic anhydride 12 parts of compatilizer of grafting, 1.5 parts of lubricant.
3. environmentally friendly anti-flaming ABS material according to claim 2, it is characterised in that the lubricant is fatty acid amide.
4. environmentally friendly anti-flaming ABS material according to claim 3, it is characterised in that the antioxidant is diphenylamines.
5. environmentally friendly anti-flaming ABS material according to claim 4, it is characterised in that the heat stabilizer is stable for PVC Agent.
CN201711319502.0A 2017-12-12 2017-12-12 A kind of environmentally friendly anti-flaming ABS material Pending CN107857968A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711319502.0A CN107857968A (en) 2017-12-12 2017-12-12 A kind of environmentally friendly anti-flaming ABS material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711319502.0A CN107857968A (en) 2017-12-12 2017-12-12 A kind of environmentally friendly anti-flaming ABS material

Publications (1)

Publication Number Publication Date
CN107857968A true CN107857968A (en) 2018-03-30

Family

ID=61706094

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711319502.0A Pending CN107857968A (en) 2017-12-12 2017-12-12 A kind of environmentally friendly anti-flaming ABS material

Country Status (1)

Country Link
CN (1) CN107857968A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108582959A (en) * 2018-05-24 2018-09-28 无锡山秀科技有限公司 A kind of preparation method and formula of recyclable carbon fiber composite board

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102643508A (en) * 2012-05-11 2012-08-22 杭州金州高分子科技有限公司 Environment-friendly inflaming-retarding acrylonitrile-butadiene-styrene (ABS) material

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102643508A (en) * 2012-05-11 2012-08-22 杭州金州高分子科技有限公司 Environment-friendly inflaming-retarding acrylonitrile-butadiene-styrene (ABS) material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108582959A (en) * 2018-05-24 2018-09-28 无锡山秀科技有限公司 A kind of preparation method and formula of recyclable carbon fiber composite board

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Application publication date: 20180330