CN102618362A - Friction-reducing lubricating coating composition - Google Patents

Friction-reducing lubricating coating composition Download PDF

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Publication number
CN102618362A
CN102618362A CN2012100445896A CN201210044589A CN102618362A CN 102618362 A CN102618362 A CN 102618362A CN 2012100445896 A CN2012100445896 A CN 2012100445896A CN 201210044589 A CN201210044589 A CN 201210044589A CN 102618362 A CN102618362 A CN 102618362A
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CN
China
Prior art keywords
coating composition
lubricating coating
fluorine
attrition
solvent
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Pending
Application number
CN2012100445896A
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Chinese (zh)
Inventor
李士成
杨发达
童蓉
王虹
岳风树
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Shenzhen Eubo New Material Technology Co Ltd
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Shenzhen Eubo New Material Technology Co Ltd
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Priority to CN2012100445896A priority Critical patent/CN102618362A/en
Publication of CN102618362A publication Critical patent/CN102618362A/en
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Abstract

The invention discloses a friction-reducing lubricating coating composition. The friction-reducing lubricating coating composition comprises the following components in percentage by weight: 0.1-25 percent of fluorocarbon lubricant, 0.1-10 percent of solid lubricant, 70-99.7 percent of volatile diluent and 0.1-5 percent of additive. The friction-reducing lubricating coating composition disclosed by the invention has excellent quick drying property and adhesiveness and favorable cleanness and permanent lubricating effect; and a layer of uniform and dry white semitransparent lubricating oil film can be quickly formed on the friction surface and the climbing, and diffusion and pollution are avoided, so that the reliability of products and the service life of products are ensured.

Description

The anti-attrition lubricating coating composition
Technical field
The present invention relates to the lubricant field, relate in particular to a kind of anti-attrition lubricating coating composition.
Background technology
Along with improving constantly of the industrial level of modernization, the structure of a lot of mechanical means, the vehicles, electronic product is more and more compacter, and is more and more accurate, in order to ensure its serviceability and work-ing life, also proposed increasingly high requirement for the performance of lubricant.
Lubricant is often used in forming between the friction surface of relative movement one deck oil-bound film, and this oil-bound film plays and reduces friction, prevents the effect of wearing and tearing.Existing lubricant in use; Because film forming speed is slow or rete had strong flowability; The thickness of oil-bound film is big, tack is low, and redundant lubricant causes easily creeps, spreads, permeates and pollute, even is infected with dust, breed bacteria etc.; Cause lubricating oil to be difficult to realize lifelong lubricated effect, perhaps cause quick abrasion, poor reliability, the work-ing life of product short.
Summary of the invention
The technical problem underlying that the present invention will solve is, a kind of anti-attrition lubricating coating composition is provided, and has good rapid-drying properties and tack, can avoid creeping, spreading and pollute, thereby good lubricating effect is provided for friction surface.
For solving the problems of the technologies described above, the present invention provides a kind of anti-attrition lubricating coating composition, and its quality ratio range is: the plain lubricating oil of 0.1% ~ 25% fluorine, 0.1% ~ 10% solid lubricant, 70% ~ 99.7% volatile diluent, 0.1% ~ 5% additive.
Preferably, the quality ratio range of anti-attrition lubricating coating composition is: the plain lubricating oil of 0.1% ~ 10% fluorine, 0.1% ~ 5% solid lubricant, 85% ~ 99.7% volatile diluent, 0.1% ~ 3% additive.
Further preferably, the quality ratio range of anti-attrition lubricating coating composition is: the plain lubricating oil of 1.5% ~ 10% fluorine, 0.5% ~ 3% solid lubricant, 87% ~ 99.7% volatile diluent, 0.1% ~ 3% additive.
Wherein, the plain lubricating oil of fluorine can be perfluoro polyether oil, perfluor carbon oil, fluorochlorocarbon oil, fluorine silicon grease, or its compsn.The plain lubricating oil of fluorine is as a kind of rapid-drying properties epithelium lubricant; Solve homogeneously in the volatile diluent; Can utilize its good high low temperature stability; Make the anti-attrition lubricating coating composition have that film forming speed is fast, rete covers evenly, rete is difficult for flowing and be difficult for characteristic such as absorption dust, avoid oil-bound film to creep, spread and pollute.In addition; The plain lubricating oil of fluorine also has no flash-point, no burning-point, discord oxygen even liquid oxygen generation chemical reaction, it is aging to be difficult for, not volatile, no carbon distribution under the high temperature, do not have precipitate, nothing migration, anti-steam, characteristic such as corrosion-resistant, can make the anti-attrition lubricating coating composition provide the long-acting of long lifetime, maintenance-free to lubricate.
Solid lubricant is a fluororesin powder, and said fluororesin powder comprises polytetrafluoroethylene (PTFE) powder, vinylidene powder, perfluoro alkoxy fluorocarbon resin powder, the plain ester powder of functionalization fluorine, or its compsn.Solid lubricant can evenly be suspended in the volatile diluent; Utilize its good film forming ability and adhesive ability; The oil-bound film that makes the formation of anti-attrition lubricating coating composition is securely attached to friction surface; Play the surface protection function simultaneously, prevent to produce between the friction surface of relative movement the serious melting welding or the position transfer of metal.
For pulverous solid lubricant particle is suspended in volatile diluent equably; Thereby the homogeneity that improves oil-bound film with and for the performances such as tack of base material; Can carry out functionalization to the solid lubricant powder; Specifically be that fluororesin powder is carried out the radical functino modification, the fluororesin powder that will handle through the radical functino modification is as solid lubricant.
Said volatile diluent comprises at least a in the plain solvent of fluorine, silicane solvent or the organic solvent.Its consumption in the anti-attrition lubricating coating composition is maximum; Be used for the plain lubricating oil of fluorine being dissolved as solvent; Solid lubricant is carried out suspended dispersed, and the anti-attrition lubricating coating composition can form evenly, the tack good lubricating oil film from making at product surface.More than in the quality mix proportion scheme of preferred anti-attrition lubricating coating composition, the consumption of volatile diluent increases, the dissolving that can make the plain lubricating oil of fluorine more fully, make the dispersion of solid lubricant more even.
In the volatile diluent, the plain solvent of said fluorine comprises at least a in hydrogen fluorine ether, perfluorocarbon solvent, perfluoroalkyl polyether, the perfluor ether solvents.Organic solvent can comprise one or more in the following solvent: 1. arene: benzene,toluene,xylene etc.; 2. fat hydrocarbon: pentane, hexane, octane etc.; 3. alicyclic hydrocarbon type: hexanaphthene, pimelinketone, toluene pimelinketone etc.; 4. halogenated hydrocarbons: chlorobenzene, dichlorobenzene, methylene dichloride etc.; 5. alcohols: methyl alcohol, ethanol, Virahol etc.; 6. ethers: ether, propylene oxide etc.; 7. ester class: ritalin, vinyl acetic monomer, propyl acetate etc.; 8. ketone: acetone, espeleton, mibk etc.; 9. diol, derivatives: ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether etc.; 10. other: acetonitrile, pyridine, phenol etc.
The anti-attrition lubricating coating composition prepares in the process; The proportioning of volatile diluent and the selection of kind are depended on the request for utilization that the anti-attrition lubricating coating composition is final, for example for the requirement of rate of drying, base material to the abundant dissolved solids lubricant and the toxicity property and the feature of environmental protection restricted condition that form requirement, the solvent of uniform slip coating requires, the restricted condition of solvent flash point etc. of the solvent requirement of solvent and restricted condition, solvent.
For example, drying at room temperature speed makes the anti-attrition lubricating coating composition have better rapid-drying properties in order to obtain faster, and the boiling point of volatile diluent is chosen in 20 ℃ ~ 150 ℃ scopes, further is preferably in 30 ℃ ~ 100 ℃ scopes.
In some application scenarios, be toxicity property and the feature of environmental protection requirement of satisfying solvent, and in order to meet the restricted condition of solvent flash point, said volatile diluent is preferentially selected the plain solvent of the fluorine of no flash-point for use.
In some application scenarios; When contacting plastic cement material in order to satisfy the anti-attrition lubricating coating composition; Solvent requirement for solvent; Said volatile diluent is plain solvent of fluorine or silicane solvent, or comprises plain solvent of fluorine and silicane solvent, also can be included in quality ratio range in the said anti-attrition lubricating coating composition and be 0% ~ 15% alcoholic solvent.
Additive comprises and is used at least a in tensio-active agent, coupling agent, the rust-preventive agent strengthen dissolving power, the suspending power of anti-attrition lubricating coating composition, and makes it have functions such as antirust.Tensio-active agent can be selected the plain tensio-active agent of fluorine, fluoride silicon surfactant, other silicon that are suitable for, alkanes tensio-active agent etc. for use.
The invention has the beneficial effects as follows: anti-attrition lubricating coating composition of the present invention has good rapid-drying properties and tack; Can form even, the white translucent oil-bound film of exsiccant of one deck at friction surface rapidly; Avoid creeping, spread and pollute; Spatter property is good and have good lifelong lubricant effect, therefore can improve reliability of products, guarantees or prolong the work-ing life of product.
Embodiment
Be specific embodiment of the present invention below, yet protection scope of the present invention is not limited to following examples.
Embodiment 1:
According to the quality proportioning; Get 2% molecular weight and be 3000 ~ 4000 perfluoro polyether oil, 5% low-molecular-weight PTFE powder, the plain tensio-active agent of non-ion fluorin of 0.5 % and join in the PFH of 92.5 %, make the anti-attrition lubricating coating composition through mixing and after stirring.Through test and assess the anti-attrition lubricating coating composition of this embodiment film forming speed, be coated with membrane stage and solid lubricant settling velocity (layering obviously to occur; It is the criterion calculation separation time that the clarified liq layer appears in the upper strata), the result is good for rate of drying, be coated with membrane stage evenly good, layering appearred later in 60 minutes.The rapid-drying properties of anti-attrition lubricating coating composition that shows this embodiment is good, film forming is even, tack good.
Embodiment 2:
According to the quality proportioning, get perfluor carbon oil, 4% the low-molecular-weight PTFE powder of 0.1 %, the plain tensio-active agent of non-ion fluorin of 0.4 % joins in the perflenapent of 95.5 %, makes the anti-attrition lubricating coating composition through mixing and after stirring.Through test and the anti-attrition lubricating coating composition 600 seconds of assessing this embodiment with inner drying, be coated with membrane stage evenly good, layering appears after 60 minutes.The rapid-drying properties of anti-attrition lubricating coating composition that shows this embodiment is better, film forming is even, tack good.
Embodiment 3:
According to the quality proportioning, get 5% perfluoro polyether oil, 2% in PTFE powder that the radical functino modification is handled, 0.5% the plain tensio-active agent of non-ion fluorin join 92.5% Decafluoropentane, make the anti-attrition lubricating coating composition through mixing and after stirring.Through test and assess the anti-attrition lubricating coating composition rate of drying of this embodiment good, be coated with membrane stage evenly good, layering appears after 60 minutes.The rapid-drying properties of anti-attrition lubricating coating composition that shows this embodiment is good, film forming is even, tack good.
In addition, also the anti-attrition lubricating coating composition of this embodiment is carried out the assessment of plastic cement consistency, TP is: in withstand voltage vial, put into 30mm rapid-drying properties lubricant sample and sample (18 * 30 * 2mm), maintain the temperature under 60 ℃, flooded 15 minutes; With the method for estimating be: observe specimen surface and whether have homolysis, test weight rate (%) and test size velocity of variation (%); The result is: POM, ABC, PC, SILASTIC (YSR 3286), EPDM (terpolymer EP rubber) material are got and made sample; Specimen surface does not all have homolysis; Weight rate is all less than 0.1%; Size changing rate shows that all less than 0.3% the anti-attrition lubricating coating composition of this embodiment is good to above plastic material consistency commonly used.
Volatile diluent in the present embodiment is replaced with PFH, PF 5070, perflenapent, tetrafluoro ethyl trifluoroethyl ether, tetrafluoro ethyl tetrafluoro propyl ether, nine fluorine isobutyl-methyl ethers by Decafluoropentane; Other components and quality proportioning are constant, have obtained the test result identical with PFH.
Volatile diluent with present embodiment replaces with the basic ethyl alcohol of perfluoro butyl ethyl alcohol, perfluor, perfluor ylmethyl alcohol, perfluoro capryl methylol by Decafluoropentane again; When perhaps replacing with the basic ethyl alcohol/ethanol of quality proportioning blended perfluor according to 90%:10%, perfluoro capryl ethyl alcohol/ethanol, perfluoro butyl methylol/ethanol, perfluoro capryl methylol/ethanol; Then better to the consistency of POM and ABC; Consistency to PC, SILASTIC, EPDM is relatively poor; Specimen surface has fine cracks or other homolysis phenomenons, and weight rate is greater than 0.1%, and size changing rate is greater than 0.3%.
When again the volatile diluent of present embodiment being replaced with quality proportioning blended tetrafluoro ethyl trifluoroethyl ether/ethanol according to 90%:10%, tetrafluoro ethyl tetrafluoro propyl ether/ethanol, nine fluorine isobutyl-methyl ether/ethanol, 3-pentafluorobutane/ethanol by Decafluoropentane; Only relatively poor to the consistency of PC, better to the consistency of other several kinds of plastic materials.
It is thus clear that, the plain kind solvent of fluorine is better to the plastic material consistency as volatile diluent, when particularly contacting, select the plain kind solvent of the lower fluorine of KB value (equilibrium constant of alkali reaction) safer with the PC material.
Embodiment 4:
According to the quality proportioning, get 5% perfluoro polyether oil, 10% in PTFE powder that the radical functino modification is handled, 1% the plain tensio-active agent of non-ion fluorin join 84% PFH, make the anti-attrition lubricating coating composition through mixing and after stirring.Through test and assess the anti-attrition lubricating coating composition rate of drying of this embodiment good, be coated with membrane stage evenly good, layering appears after 60 minutes.The rapid-drying properties of anti-attrition lubricating coating composition that shows this embodiment is good, film forming is even, tack good.
Embodiment 5:
According to the quality proportioning, get 10% perfluoro polyether oil, 0.1% vinylidene powder, 2% the plain tensio-active agent of non-ion fluorin and join in 87.9% the perfluoro butyl methylol, make the anti-attrition lubricating coating composition through mixing and after stirring.Through test and assess the anti-attrition lubricating coating composition rate of drying of this embodiment good, be coated with membrane stage evenly good, layering appears after 60 minutes.The rapid-drying properties of anti-attrition lubricating coating composition that shows this embodiment is good, film forming is even, tack good.
Embodiment 6:
According to the quality proportioning, get 25% perfluoro polyether oil, 2% vinylidene powder, 1% the plain tensio-active agent of non-ion fluorin and join in 72% the PFH, make the anti-attrition lubricating coating composition through mixing and after stirring.Through test and assess the anti-attrition lubricating coating composition rate of drying of this embodiment good, be coated with membrane stage evenly good, layering appears after 60 minutes.The rapid-drying properties of anti-attrition lubricating coating composition that shows this embodiment is good, film forming is even, tack good.
Embodiment 7:
According to the quality proportioning, get 4% fluorine silicon grease, 10% perfluoro alkoxy fluorocarbon resin powder, 0.5% the plain tensio-active agent of non-ion fluorin and join in 85.5% the PF 5070, make the anti-attrition lubricating coating composition through mixing and after stirring.Through test and the anti-attrition lubricating coating composition of assessing this embodiment 600 seconds inner dryings, be coated with membrane stage evenly good, layering appears after 60 minutes.The rapid-drying properties of anti-attrition lubricating coating composition that shows this embodiment is better, film forming is even, tack good.
Embodiment 8:
According to the quality proportioning, the plain tensio-active agent of non-ion fluorin of getting 0.1% perfluoro polyether oil, 0.1% polytetrafluorethylepowder powder, 0.1 % joins in 99.7% the perfluoro butyl methylol, makes the anti-attrition lubricating coating composition through mixing and after stirring.Through test and the anti-attrition lubricating coating composition of assessing this embodiment 600 seconds inner dryings, be coated with membrane stage evenly good, after 15 minutes with interior layering appearred in 60 minutes.The rapid-drying properties of anti-attrition lubricating coating composition that shows this embodiment is better, film forming is even, tack is better.
Embodiment 9:
According to the quality proportioning; Get 15% perfluoro polyether oil, 2% the plain tensio-active agent of non-ion fluorin and join 82.5% quality proportioning and mix in tetrafluoro ethyl trifluoroethyl ether/ethanol, make the anti-attrition lubricating coating composition through mixing and after stirring according to 90%:10% through PTFE powder that the radical functino modification is handled, 0.5 %.Through test and assess the anti-attrition lubricating coating composition rate of drying of this embodiment good, be coated with membrane stage evenly good, layering appears after 60 minutes.The rapid-curing cutback of anti-attrition lubricating coating composition that shows this embodiment is good, film forming is even, tack is better.
To sum up; Anti-attrition lubricating coating composition of the present invention has good rapid-drying properties and tack, can be rapidly forms even, the white translucent oil-bound film of exsiccant of one deck at friction surface, not only has good reduction friction, prevents the lubrication of wearing and tearing; And compare with existing lubricant; Because film forming speed is fast and rete is mobile low, drying property and tack are good, can effectively avoid redundant lubricant to cause and creep, spread, permeate and pollute; Even be infected with phenomenons such as dust, breed bacteria; Thereby make the anti-attrition lubricating coating composition that stable, persistent lifelong lubricated effect can be provided, improve reliability of products, guarantee or prolong its work-ing life.
Anti-attrition lubricating coating composition of the present invention is as a kind of rapid-drying properties epithelium oil, also has characteristics such as easy construction, operation economy, use range be wide.Particularly, the less consumption of anti-attrition lubricating coating composition of the present invention can cover bigger area, and the technology cost is low; Adopt simple coating side such as brush, applicator, atomizer or immersion way to construct, easy to use flexible; Can realize the internal structure of various mechanical means, the vehicles, electronic product and lubricating of outward appearance position; For example storage card, junctor, SD deck, antenna, clockwork spring etc.; Perhaps mobile phone slide rail, the dolly camera of Kamera, digital camera, opticinstrument and internal mechanism etc.

Claims (10)

1. an anti-attrition lubricating coating composition is characterized in that, its quality ratio range is: the plain lubricating oil of 0.1% ~ 25% fluorine, 0.1% ~ 10% solid lubricant, 70% ~ 99.7% volatile diluent, 0.1% ~ 5% additive.
2. anti-attrition lubricating coating composition as claimed in claim 1; It is characterized in that the quality ratio range of said anti-attrition lubricating coating composition is: the plain lubricating oil of 0.1% ~ 10% fluorine, 0.1% ~ 5% solid lubricant, 85% ~ 99.7% volatile diluent, 0.1% ~ 3% additive.
3. anti-attrition lubricating coating composition as claimed in claim 1 is characterized in that, the plain lubricating oil of said fluorine is perfluoro polyether oil, perfluor carbon oil, fluorochlorocarbon oil, fluorine silicon grease, or its compsn.
4. anti-attrition lubricating coating composition as claimed in claim 1; It is characterized in that; Said solid lubricant is a fluororesin powder, and said fluororesin powder comprises polytetrafluorethylepowder powder, vinylidene powder, perfluoro alkoxy fluorocarbon resin powder, the plain ester powder of functionalization fluorine, or its compsn.
5. anti-attrition lubricating coating composition as claimed in claim 1 is characterized in that, said solid lubricant is the fluororesin powder of handling through the radical functino modification.
6. anti-attrition lubricating coating composition as claimed in claim 1 is characterized in that, said volatile diluent comprises at least a in the plain solvent of fluorine, silicane solvent or the organic solvent.
7. anti-attrition lubricating coating composition as claimed in claim 6 is characterized in that, the plain solvent of said fluorine comprises at least a in hydrogen fluorine ether, perfluorocarbon solvent, perfluoroalkyl polyether, the perfluor ether solvents.
8. anti-attrition lubricating coating composition as claimed in claim 1; It is characterized in that; Said volatile diluent comprises plain solvent of fluorine and/or silicane solvent, and the quality ratio range is 0% ~ 15% organic solvent in said anti-attrition lubricating coating composition, and said organic solvent is an alcoholic solvent.
9. anti-attrition lubricating coating composition as claimed in claim 1 is characterized in that, the boiling spread of said volatile diluent is 20 ℃ ~ 150 ℃.
10. anti-attrition lubricating coating composition as claimed in claim 1 is characterized in that, said additive comprises at least a in tensio-active agent, coupling agent, the rust-preventive agent.
CN2012100445896A 2012-02-27 2012-02-27 Friction-reducing lubricating coating composition Pending CN102618362A (en)

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CN105018195A (en) * 2015-06-23 2015-11-04 东莞市佳丹润滑油有限公司 Special lubricant for plastic part assembly, and preparation method thereof
CN107201262A (en) * 2016-11-23 2017-09-26 阜宁协鑫光伏科技有限公司 A kind of cutting liquid for reducing diamond wire cutting broken string
CN107653037A (en) * 2017-09-26 2018-02-02 中国石油化工股份有限公司 A kind of Perfluoropolyether lubricant and preparation method thereof
CN108085111A (en) * 2017-12-22 2018-05-29 新乡市恒星科技有限责任公司 A kind of preparation method of clean type film lubrication agent
CN108178952A (en) * 2017-12-26 2018-06-19 中国建筑标准设计研究院有限公司 A kind of low-frictional coefficient paint and the application process on friction-pendulum shock-insulation support
CN108508508A (en) * 2018-03-23 2018-09-07 苏州瑞康真空科技有限公司 A kind of spectacle lens and preparation method thereof with anti-skidding protective layer
CN108774572A (en) * 2018-07-31 2018-11-09 芜湖龙兴合金有限公司 A kind of flowable bearing kollag
CN109971019A (en) * 2019-04-10 2019-07-05 苏州凝智新材料发展有限公司 A kind of elastomer and its preparation method and application of the super lubrication high transparency in surface
WO2020202717A1 (en) * 2019-03-29 2020-10-08 株式会社オートネットワーク技術研究所 Lubricant, electrical contact, connector terminal, and wire harness
CN112457901A (en) * 2020-08-26 2021-03-09 深圳华益兄弟科技有限公司 Dry film lubricant
CN114381200A (en) * 2020-10-21 2022-04-22 惠州市海兰新材料有限公司 Composite antibacterial mildew-proof coating and use method thereof
CN114571138A (en) * 2020-12-01 2022-06-03 联泓(江苏)新材料研究院有限公司 Environment-friendly soldering flux and preparation method and application thereof
CN115090501A (en) * 2022-05-23 2022-09-23 北京科技大学 Method for improving wear resistance of super-smooth coating
CN114571138B (en) * 2020-12-01 2024-05-17 联泓(江苏)新材料研究院有限公司 Environment-friendly soldering flux and preparation method and application thereof

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CN105018195B (en) * 2015-06-23 2018-07-10 东莞市佳丹润滑油有限公司 It is exclusively used in lubricant of plastic fitting assembling and preparation method thereof
CN105018195A (en) * 2015-06-23 2015-11-04 东莞市佳丹润滑油有限公司 Special lubricant for plastic part assembly, and preparation method thereof
CN107201262A (en) * 2016-11-23 2017-09-26 阜宁协鑫光伏科技有限公司 A kind of cutting liquid for reducing diamond wire cutting broken string
CN107653037A (en) * 2017-09-26 2018-02-02 中国石油化工股份有限公司 A kind of Perfluoropolyether lubricant and preparation method thereof
CN108085111A (en) * 2017-12-22 2018-05-29 新乡市恒星科技有限责任公司 A kind of preparation method of clean type film lubrication agent
CN108178952A (en) * 2017-12-26 2018-06-19 中国建筑标准设计研究院有限公司 A kind of low-frictional coefficient paint and the application process on friction-pendulum shock-insulation support
CN108508508A (en) * 2018-03-23 2018-09-07 苏州瑞康真空科技有限公司 A kind of spectacle lens and preparation method thereof with anti-skidding protective layer
CN108774572A (en) * 2018-07-31 2018-11-09 芜湖龙兴合金有限公司 A kind of flowable bearing kollag
JP7188235B2 (en) 2019-03-29 2022-12-13 株式会社オートネットワーク技術研究所 Lubricants, electrical contacts, connector terminals, and wire harnesses
WO2020202717A1 (en) * 2019-03-29 2020-10-08 株式会社オートネットワーク技術研究所 Lubricant, electrical contact, connector terminal, and wire harness
JP2020164621A (en) * 2019-03-29 2020-10-08 株式会社オートネットワーク技術研究所 Lubricant, electric contact point, connector terminal, and wire harness
CN109971019A (en) * 2019-04-10 2019-07-05 苏州凝智新材料发展有限公司 A kind of elastomer and its preparation method and application of the super lubrication high transparency in surface
CN109971019B (en) * 2019-04-10 2022-04-08 苏州凝智新材料发展有限公司 Surface super-lubricating high-transparency elastomer and preparation method and application thereof
CN112457901A (en) * 2020-08-26 2021-03-09 深圳华益兄弟科技有限公司 Dry film lubricant
CN114381200A (en) * 2020-10-21 2022-04-22 惠州市海兰新材料有限公司 Composite antibacterial mildew-proof coating and use method thereof
CN114571138A (en) * 2020-12-01 2022-06-03 联泓(江苏)新材料研究院有限公司 Environment-friendly soldering flux and preparation method and application thereof
CN114571138B (en) * 2020-12-01 2024-05-17 联泓(江苏)新材料研究院有限公司 Environment-friendly soldering flux and preparation method and application thereof
CN115090501A (en) * 2022-05-23 2022-09-23 北京科技大学 Method for improving wear resistance of super-smooth coating

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