CN102613246A - Plant growth regulating composition and its application - Google Patents
Plant growth regulating composition and its application Download PDFInfo
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- CN102613246A CN102613246A CN2011104150979A CN201110415097A CN102613246A CN 102613246 A CN102613246 A CN 102613246A CN 2011104150979 A CN2011104150979 A CN 2011104150979A CN 201110415097 A CN201110415097 A CN 201110415097A CN 102613246 A CN102613246 A CN 102613246A
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Abstract
The invention discloses a plant growth regulating composition and its application. The composition comprises the following components: A) natural abscisic acid, B) gibberellic acid (GA3, or of GA4 +7), and C) an existing plant growth regulator. The existing plant growth regulator is selected from one or more than two of 6-BA (6-benzylaminopurine), thidiazuron, brassinolide, sodium nitrophenolate, potassium nitrophenolate, chlormequat chloride, triacontanol, naphthlcetic acid and its salt, indolebutyric acid and its salt, indoleacetic acid and its salt, ethephon, diethyl aminoethyl hexanoate, paclobutrazol, uniconazole, fulvic acid, Mepiquat chloride, nitrohumic acid, jasmonic acid and triapenthenol. Specifically, the components A), B) and C) are in a weight ratio of 1:0.001-500:0.001-500. The S-ABA (S-abscisic acid) added in the invention can expand the prevention and treatment objects, reduce or prevent phytotoxicity, reduce dosage, and lower the use cost.
Description
Technical field
The present invention relates to the plant growth regulator field, be particularly related to a kind of plant growth regualting composition and application thereof.
Background technology
In recent years the application area of plant growth regulator constantly enlarge, the amount of growth of plant growth regulator and consumption also improve year by year, the plant growth regulator of single variety is good to the regulating effect of some crop, but because the range of application of single plant growth regulator is narrow, effect is single, crop-selective is strong, effect is undesirable, also exist potential poisoning dangerous simultaneously.Therefore, the composite and mixture preparation of plant growth regulator, become the plant growth regulator industry one of main developing direction, plant growth regulator is composite and mixture preparation can enlarge sphere of action, improve drug effect, reduce application risk, effectively avoid or reduce the generation thereby the composite main developing direction that has become the plant growth regulator industry of plant growth regulator of poisoning.
The a series of growth that is used for regulating has appearred at present on the market; The composite product of plant growth regulator of raising the output; As: 0.4% rape gibberellic acid aqua (oranges and tangerines; Lichee; Longan; Regulate growth; Raising the output); 2.5% nitre potassium gibberellic acid aqua (Chinese cabbage; Regulate growth); 3.2% red mould paclobutrazol wetting powder (paddy rice; Regulate growth; Raising the output); 3.6% benzyl ammonia gibberellic acid missible oil (regulating the fruit type); 0.59% red mould CPPU soluble concentrate (grape yield increasing); 0.0.135% rape Yin second gibberellic acid wetting powder (tea tree; Cucumber; Apple; Wheat; Regulate the growth raising the output); Or the like.The composition that uses natural abscisic acid, agricultural chemicals common name S-abscisic acid (S-ABA) and other components composition is wherein arranged as plant growth regulator.
Also do not have a kind of coordinate plant growth simultaneously, promotion fruit growth in the prior art, improve the plant growth regualting composition that contains natural abscisic acid that fruit quality, increasing both production and income, reduction perhaps prevent the generation of poisoning.
Summary of the invention
The purpose of the embodiment of the invention is to the defective of above-mentioned prior art, provides a kind of and be used for coordinate plant growth, promotes fruit growth, improves the plant growth regualting composition of fruit quality, increasing both production and income.
The technical scheme taked of the present invention is to achieve these goals:
A kind of plant growth regualting composition contains following component: A) natural abscisic acid, B) gibberellic acid (GA
3, or GA
4+7), C) plant growth regulator;
Said plant growth regulator is selected from one or more in 6-BA (6-benzyl aminopurine), Thidiazuron, brassin lactones, compound sodium nitrophenolate, potassium para-nitrophenate, chlormequat, triacontanol, methyl and salt, indolebutyric acid and salt thereof, heteroauxin and salt thereof, ethrel, diethyl aminoethyl hexanoate, paclobutrazol, uniconazole P, fulvic acid, first piperazine, nitro humus acid, jasmonic and the triapenthenol.
Component A wherein): B): weight ratio C) is 1: 0.001-500: 0.001-500.
Said component A): B): weight ratio C) is 1: 0.1-300: 0.1-300.
Said plant growth regulator is selected from one or more in 6-BA, brassin lactones, Thidiazuron, paclobutrazol, compound sodium nitrophenolate, diethyl aminoethyl hexanoate, indolebutyric acid, heteroauxin, the methyl.
The present invention also provides a plant growth to adjust, and said composition and auxiliary agent or excipient processing are mixed with plant growing and adjust.
The formulation of said plant growth regulator is selected from wetting powder, soluble concentrate, solvable granula, solvable pulvis, suspending agent, suspension emulsion, microemulsion, missible oil, water dispersible granules, aqueous dispersion tablets, ultra low volume liquids or effervescent agent.Be diluted with water to working concentration with above-mentioned formulation, handle crops such as fruit tree, vegetables, economic crops, grain and oil crop, herbage, lawn, gardens crop, tealeaves through spraying, pouring, drip irrigation, broad irrigation, sprinkling etc.
The embodiment of the invention also provides plant growth regualting composition to handle the application of fruit tree, vegetables, economic crops, oil crop, cereal crops, herbage, lawn, gardens crop.
Said fruit tree comprises grape, apple, pears, peach, Lee, apricot, cherry, kiwi fruit, jujube, oranges and tangerines, lichee, longan, banana and mango; Said vegetables comprise custard squash, cucumber, wax gourd, pumpkin, watermelon, muskmelon, capsicum, tomato, eggplant, class's beans, day lily, potato, carrot, leek, shallot and onion; Said economic crops comprise beans, tobacco, cotton, tealeaves, rubber, coffee and flax; Said oil crop comprise rape, peanut and sesame; Said cereal crops comprise wheat, corn and paddy rice; Said herbage comprises clover.
Preparation of the present invention adopts known formulation processing method to prepare; For example, through plant growth regulator is become the solid, powdery preparation or is processed into granular formulations through granulation again through mix, grinding and processing with described inert filler, surfactant, other auxiliary agent etc.Through plant growth regulator is become liquid preparation with solvent, surfactant, other auxiliary agents through Over emulsfication, stirring or shearing, attrition process.Depend on that plant growth regulator of desiring to be processed into and nonionic, cation, anion or the amphoteric surfactant that is fit to it prepare.The instance of the surfactant that is fit to is listed in " formulations of pesticide process technology " second edition of Liu Bulin chief editor.
Plant growth regulator of the present invention, preferential preparation group is following: (by weight percentage)
1, missible oil:
2, wetting powder
3, solvable pulvis
4, water dispersible granules
5, solvable granula
6, soluble concentrate
The beneficial effect that the technical scheme that the embodiment of the invention provides is brought is: compared with prior art; The S-ABA that adds among the present invention can the expanding prevention object, coordinate plant growth, promotes fruit growth, improves fruit quality, increasing both production and income, minimizing or prevents poisoning, reduces dosage, reduces use cost.
Wherein A is S-ABA, and B is gibberellic acid (GA
3, or GA
4+7), C is existing plant growth regulator.
Description of drawings
Fig. 1 is the process chart of the embodiment of the invention 1 and embodiment 6;
Fig. 2 is the process chart of the embodiment of the invention 2;
Fig. 3 is the process chart of the embodiment of the invention 3;
Fig. 4 is the process chart of the embodiment of the invention 4;
Fig. 5 is the process chart of the embodiment of the invention 5.
Embodiment
For make the object of the invention, technical scheme and advantage clearer, do to describe in detail further in the face of embodiment of the present invention down.
Embodiment 1
The preparation of missible oil: (A is S-ABA in following examples, and B is gibberellic acid (GA
3, or GA
4+7))
(1) formula for a product
(2) processing process
More than three kinds of prescriptions prepare missible oil according to technological process as shown in Figure 1 respectively:
Active ingredient is dissolved in solvent N, in N dimethyl-octa formamide in the last of the ten Heavenly stems and the fatty acid methyl ester, stirs, dissolving is added the newborn 500# of auxiliary agent farming, agricultural newborn 602# fully then; Antioxidant BHT mixes, and emulsification is stirred, sedimentation; Filter, behind the removal impurity, it is qualified to detect, the packing warehouse-in.
(3) control of product project indicator (writing standard HG/T 2467.2-2003) with reference to the emulsifiable concentrates for agricultural chemicals product standard
Annotate: the heat storage stability test, under normal circumstances, detected once in per at least six months.
Embodiment 2
The wetting powder preparation:
(1) formula for a product
(2) processing process
More than three kinds of prescriptions prepare wetting powder according to technological process as shown in Figure 2 respectively:
With active ingredient and auxiliary agent sodium lignin sulfonate, NNO, CMC fully mixes, and adds filler kaolin then and fully mixes, and comminution by gas stream leaves standstill, and it is qualified to detect, the packing warehouse-in.
(3) control of product project indicator (writing standard HG/T2467.3-2003) with reference to the pesticide wettable product standard
Annotate: the heat storage stability test, under normal circumstances, detected once in per at least six months.
Embodiment 3
Solvable pulvis preparation:
(1) formula for a product
(2) processing process
More than three kinds of prescriptions prepare solvable pulvis according to technological process as shown in Figure 3 respectively:
Active ingredient is fully mixed with auxiliary agent sodium lignin sulfonate, NNO and CMC, mix the back and add the filler soluble starch, fully mix, comminution by gas stream leaves standstill, and it is qualified to detect, the packing warehouse-in.
(3) control of product project indicator (writing standard HG/T2467.15-2003) with reference to the solvable pulvis product standard of agricultural chemicals
Annotate: the heat storage stability test, under normal circumstances, detected once in per at least six months.
Embodiment 4
The water dispersible granules preparation:
(1) formula for a product
(2) processing process
More than three kinds of prescriptions prepare water dispersible granules according to technological process as shown in Figure 4 respectively:
With active ingredient and auxiliary agent Morwet D-425, Morwet efw, NaCl, CMC; Fully mix, mix the back and add the fully mixing again of filler kaolin, mix laggard promoting the circulation of qi stream and pulverize; Then binding agent PEG6000 is dissolved in the water, mediates in kneader with powder before, then through extruder grain; Drying, screening detects the qualified warehouse-in of packing later on.
(3) control of product project indicator (writing standard HG/T 2467.13-2003) with reference to the pesticide water dispersible granules product standard
Annotate: the heat storage stability test, under normal circumstances, detected once in per at least six months.
Embodiment 5
Solvable granula preparation:
(1) formula for a product
(2) processing process
More than three kinds of prescriptions prepare solvable granula according to technological process as shown in Figure 5 respectively:
With active ingredient and auxiliary agent Morwet D-425, Morwet efw, NaCl, CMC; Fully mix, mix the back and add the fully mixing again of filler kaolin, mix laggard promoting the circulation of qi stream and pulverize; Then binding agent PEG6000 is dissolved in the water, mediates in kneader with powder before, then through extruder grain; Drying, screening detects the qualified warehouse-in of packing later on.
(3) control of product project indicator (writing standard HG/T2467.16-2003) with reference to the solvable granula product standard of agricultural chemicals
Annotate: the heat storage stability test, under normal circumstances, detected once in per at least six months.
Embodiment 6
The soluble concentrate preparation:
(1) formula for a product
(2) processing process
More than three kinds of prescriptions prepare solvable granula according to technological process as shown in Figure 1 respectively:
Active ingredient is dissolved in the solvent isopropyl alcohol, adds auxiliary agent O-20, TWEEN-20 and antioxidant BHT stir, and dissolving mixes, and sedimentation is filtered, and it is qualified to detect, the packing warehouse-in.
(3) control of product project indicator (writing standard HG/T2467.7-2003) with reference to agricultural chemicals soluble concentrate product standard
Annotate: the heat storage stability test, under normal circumstances, detected once in per at least six months.
Composition of the present invention also can contain other component, for example other compound with desinsection or bactericidal property protective fungicide particularly.Also can mix use with nutrient for plants, foliage fertilizer.
According to the difference of target crop, plant growth stage, controlling object, the application concentration of the present composition when regulating crop is: the working concentration of S-ABA is preferably 1-200mg/kg for 0.01-600mg/kg; Gibberellic acid (GA
3, or GA
4+7) working concentration be 1-600mg/kg, be preferably 10-200mg/kg.The working concentration of 6-BA is preferably 1-200mg/kg at 0.1-600mg/kg, and the working concentration of brassin lactones is 1 * 10
-6-10mg/kg is preferably 0.0001-1mg/kg, and compound sodium nitrophenolate 0.01-100mg/kg is preferably 0.1-50mg/kg, and the other plant growth regulator all has different working concentrations in use, in follow-up data, all has to show.Through spraying; Pouring; Drip irrigation; Broad irrigation; Processing fruit trees such as sprinkling (comprise grape; Apple; Pears; Peach; Lee; Apricot; Cherry; Kiwi fruit; Jujube; Oranges and tangerines; Lichee; Longan; Banana; Mango); Vegetables (comprise custard squash; Cucumber; Wax gourd; Pumpkin; Watermelon; Muskmelon; Capsicum; Tomato; Eggplant; Class's beans; Day lily; Potato; Carrot; Leek; Shallot; Onion); Economic crops (comprise beans; Tobacco; Cotton; Tealeaves; Rubber; Coffee; Flax); Oil crop (comprise rape; Peanut; Sesame); Cereal crops (comprise wheat; Corn; Paddy rice); Herbage (comprising clover); The lawn; Crops such as gardens crop.
Activity chemistry thing that can be used according to the invention can mix use with other reactive compounds, for example mixes use with plant nutrient, foliage fertilizer, widens action spectrum thus or treat plant nutrition to lack.As a rule, can obtain better effect.
Instance in the mixture is like potassium dihydrogen phosphate, potassium sulphate, potassium chloride, urea, carbonic hydroammonium, ammonium dihydrogen phosphate (ADP), calcium phosphate, calcium dihydrogen phosphate, double superphosphate ammonium nitrate, ammonium sulfate; Trace element fertilizers such as trace element fertilizer such as zinc, boron, copper, manganese, molybdenum, iron, and rare earth element fertilizer: rare earth element fertilizer such as lanthanum, cerium, praseodymium, neodymium.
The present invention describes through following non-limiting embodiment:
The application implementation example:
Application implementation example 1: be used for increasing production of rice test (kind is hilllock excellent 725)
Before the paddy rice cut 3-5 days, carry out the routine spraying.Preceding 2 days of paddy rice harvesting investigation survey data, each handles paddy rice, singly cuts, singles, the single solarization, is converted to real product.
Above data can be found out, S-ABA and GA
3, paclobutrazol complex preparation and GA
3Compare with the complex preparation of paclobutrazol, can significantly reduce GA
3, paclobutrazol usage amount, and effect of increasing production is obvious, real grain number, thousand kernel weight, the advantage that average fringe is heavy, per mu yield all can show this compounded combination.
Application implementation example 2: raising the output on grape, raising quality test (kind is a kyoto grape)
When the grape fruit soybean grain is big or small, use, carried out in 7-14 days at interval after the medication for the first time handling the second time, gather in the crops the line data investigation of advancing, and write down final result of the test.Record following index.
Annotate: '+' expression fruit powder is relatively good in the fruit powder situation, and '+' is many more, and expression fruit powder is good more
Can find out that from above data S-ABA is to GA
3+ 6-BA and GA
3Combination has obvious synergistic effect with brassin lactones, and effect of increasing production is obvious, and can effectively reduce dehiscent fruit and fall fruit, improves fruit quality simultaneously, avoids the injury to the uva powder, increases sugar content.
Application implementation example 3: use the application (kind is a Starkrimson) on raising the output, the adjustment fruit type at apple
Spray once at the apple full-bloom stage, behind the 15d, spray for the second time.
Can find out that from the data of last table S-ABA can reduce GA
4+7The usage amount of+6-BA improves drug effect, and more better improves the quality of apple.
Application implementation example 4: the application on tomato
In tomato flowering stage, spray, except that spraying medicament, the plantation that each is handled, the fertilising situation is all identical.
Can find out that from the data of last table the individual complex preparation that adds S-ABA obviously is better than the clear water contrast, and is better than the product that does not add S-ABA after using on the tomato.
Application implementation example 5:
The pepper seed germination test
To the pepper seed processing of soaking seed, behind the 48h, pull seed out, conventional seed planting, after 40 days, index in the application form.
The result shows that above complex preparation all is better than the clear water contrast to each item investigation index of seed; The complex preparation of S-ABA all is better than the complex preparation that does not add S-ABA, and each item index all has growth, especially highly significant aspect seedling resistance.
Application example 6:
On flowers, promote to bloom
The test flowers are chrysanthemum, dip in the processing soup with writing brush after chrysanthemum is buddingged bud is handled.Once developed the color in per 5 days until bud.20 days " Invest, Then Investigate "s of medication number of blooming for the first time.
Can find out that from above form S-ABA+GA compares with contrast
3+ triacontanol can obviously shift to an earlier date the chrysanthemum flowering time, adds S-ABA and can improve drug effect.
The above be merely preferred embodiment of the present invention, not in order to restriction the present invention, all within spirit of the present invention and principle, any modification of being done, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. a plant growth regualting composition is characterized in that, contains following component: A) natural abscisic acid, B) gibberellic acid (GA
3,Or GA
4+7), C) existing plant growth regulator;
Said existing plant growth regulator is selected from one or more in 6-benzyl aminopurine, Thidiazuron, brassin lactones, compound sodium nitrophenolate, potassium para-nitrophenate, chlormequat, triacontanol, methyl and salt thereof, indolebutyric acid and salt thereof, heteroauxin and salt thereof, ethrel, diethyl aminoethyl hexanoate, paclobutrazol, uniconazole P, fulvic acid, first piperazine, nitro humus acid, jasmonic and the triapenthenol.
Component A wherein): B): weight ratio C) is 1: 0.001-500: 0.001-500.
2. plant growth regualting composition according to claim 1 is characterized in that, said component A): B): weight ratio C) is 1: 0.1-300: 0.1-300.
3. plant growth regualting composition according to claim 1; It is characterized in that said existing plant growth regulator is selected from a kind of in 6-benzyl aminopurine, brassin lactones, Thidiazuron, paclobutrazol, compound sodium nitrophenolate, diethyl aminoethyl hexanoate, indolebutyric acid, heteroauxin, the methyl.
4. plant growth regualting composition according to claim 1 is characterized in that, also contains in macroelement fertilizer, secondary nutrients, trace element fertilizer and the rare earth element fertilizer one or more.
5. a plant growth regulators is characterized in that, the plant growing that each described plant growth regualting composition of claim 1-4 and auxiliary agent or excipient processing is mixed with required formulation is adjusted.
6. plant growth regulator according to claim 5; It is characterized in that the formulation of said plant growth regulator is selected from wetting powder, soluble concentrate, solvable granula, solvable pulvis, suspending agent, suspension emulsion, microemulsion, missible oil, water dispersible granules, aqueous dispersion tablets, ultra low volume liquids or effervescent agent.
7. plant growth regulator according to claim 6 is characterized in that,
Said missible oil comprises the material of following percentage by weight:
A?0.01%~50%;
Combination of active principles B 0.01%~50%;
C?0.01%~50%;
Alkyl benzene calcium sulfonate 1%~10%;
Phenethyl phenol polyoxyethylene poly-oxygen propylene aether 1%~10%;
Fat-soluble antioxidant 0.01%~2%;
Fatty acid methyl ester 5%~95%;
Said wetting powder comprises the material of following percentage by weight:
A?0.01%~50%;
Combination of active principles B 0.01%~50%;
C?0.01%~50%;
Lignosulfonates 5%~15%;
Sodium metnylene bis-naphthalene sulfonate 5%~15%;
CMC salt 0.1%~4%;
Inert filler 30%%~90%;
Said solvable pulvis comprises the material of following percentage by weight:
A?0.01%~50%;
Combination of active principles B 0.01%~50%;
C?0.01%~50%;
Lignosulfonates 5%~15%;
Sodium metnylene bis-naphthalene sulfonate 5%~15%;
CMC salt 0.1%~4%;
Inert filler 30%%~90%;
Said water dispersible granules comprises the material of following percentage by weight:
A?0.01%~50%;
Combination of active principles B 0.01%~50%;
C?0.01%~50%;
Naphthalene sulfonate condensation polymer 1%~10%;
Alkylnaphthalene sulfonate and anion mixture 1%~10%;
Mineral salt 1%~10%;
Polyethylene glycol 1%~10%;
CMC salt 0.5%~4%;
Inert filler 30%%~90%, preferred 50%~90%
Said solvable granula comprises the material of following percentage by weight:
A?0.01%~50%;
Combination of active principles B 0.01%~50%;
C?0.01%~50%;
Naphthalene sulfonate condensation polymer 1%~10%;
Alkylnaphthalene sulfonate and anion mixture 1%~10%;
Mineral salt 1%~10%;
Polyethylene glycol 1%~10%;
CMC salt 0.5%~4%;
Inert filler 30%%~90%;
Said soluble concentrate comprises the material of following percentage by weight:
A?0.01%~50%;
Combination of active principles B 0.01%~50%;
C?0.01%~50%;
Ethoxylated dodecyl alcohol 1%~15%;
Tween-20 1%~15%;
Fat-soluble antioxidant 0.5%~4%;
Alcohols 20%~90%.
8. plant growth regulator according to claim 7 is characterized in that,
Said missible oil comprises the material of following percentage by weight:
A?0.1%~30%;
Combination of active principles B 0.05%~30%;
C?0.01%~30%;
Alkyl benzene calcium sulfonate 2%~8%;
Phenethyl phenol polyoxyethylene poly-oxygen propylene aether 2%~8%;
Fat-soluble antioxidant 0.2%%~1%;
Fatty acid methyl ester 60%~80%;
Said wetting powder comprises the material of following percentage by weight:
A 0.1%~50%;
Combination of active principles B 1%~50%;
C 1%~50%;
Lignosulfonates 8%~12%;
Sodium metnylene bis-naphthalene sulfonate 8%~12%;
CMC salt 0.5%~3%;
Inert filler 50%~90%;
Said solvable pulvis comprises the material of following percentage by weight:
A 0.1%~50%;
Combination of active principles B 1%~50%;
C 1%~50%;
Lignosulfonates 8%~12%;
Sodium metnylene bis-naphthalene sulfonate 8%~12%;
CMC salt 0.5%~3%;
Inert filler 30%%~90%, preferred 50%~90%
Said water dispersible granules comprises the material of following percentage by weight:
A 0.1%~50%;
Combination of active principles B 1%~50%;
C 1%~50%;
Naphthalene sulfonate condensation polymer 2%~8%;
Alkylnaphthalene sulfonate and anion mixture 2%~8%;
Mineral salt 2%~8%;
Polyethylene glycol 2%~8%;
CMC salt 1%~3%;
Inert filler 30%%~90%, preferred 50%~90%
Said solvable granula comprises the material of following percentage by weight:
A?0.02%~30%;
Combination of active principles B 0.02%~30%;
C?1%~30%;
Naphthalene sulfonate condensation polymer 2%~8%;
Alkylnaphthalene sulfonate and anion mixture 2%~8%;
Mineral salt 2%~8%;
Polyethylene glycol 2%~8%;
CMC salt 1%~3%;
Inert filler 50%~90%;
Said soluble concentrate comprises the material of following percentage by weight:
Combination of active principles A 0.02%~30%;
B?0.5%~30%;
C?0.02%~30%;
Ethoxylated dodecyl alcohol 1%~10%;
Tween-20 1%~10%;
Fat-soluble antioxidant 1%~3%;
Alcohols 20%~60%.
9. according to claim 7 or 8 described plant growth regulator, it is characterized in that,
Said inert filler is selected from a kind of in soluble starch, kaolin, the diatomite.
10. plant growth regulator according to claim 6 is handled the application of fruit tree, vegetables, economic crops, oil crop, cereal crops, herbage, lawn, gardens crop.
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