CN102601540B - Welding powder composition for ornament metal wire and processing method of welding powder composition - Google Patents
Welding powder composition for ornament metal wire and processing method of welding powder composition Download PDFInfo
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- CN102601540B CN102601540B CN201210069659.3A CN201210069659A CN102601540B CN 102601540 B CN102601540 B CN 102601540B CN 201210069659 A CN201210069659 A CN 201210069659A CN 102601540 B CN102601540 B CN 102601540B
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- welding
- welding powder
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- powder composition
- wire
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- 238000003466 welding Methods 0.000 title claims abstract description 63
- 239000000843 powder Substances 0.000 title claims abstract description 51
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 43
- 239000002184 metal Substances 0.000 title claims abstract description 43
- 239000000203 mixture Substances 0.000 title claims abstract description 31
- 238000003672 processing method Methods 0.000 title claims abstract description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 32
- 235000014121 butter Nutrition 0.000 claims abstract description 21
- 239000004359 castor oil Substances 0.000 claims abstract description 20
- 235000019438 castor oil Nutrition 0.000 claims abstract description 20
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 20
- 229910021538 borax Inorganic materials 0.000 claims abstract description 11
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004327 boric acid Substances 0.000 claims abstract description 11
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 11
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims description 14
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 11
- 235000013312 flour Nutrition 0.000 claims description 10
- 239000004575 stone Substances 0.000 claims description 10
- 239000002131 composite material Substances 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 16
- 229910052802 copper Inorganic materials 0.000 abstract description 15
- 239000010949 copper Substances 0.000 abstract description 15
- 238000005520 cutting process Methods 0.000 abstract description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052725 zinc Inorganic materials 0.000 abstract description 2
- 239000011701 zinc Substances 0.000 abstract description 2
- 235000010338 boric acid Nutrition 0.000 abstract 1
- -1 scapolite Chemical compound 0.000 abstract 1
- 229910000679 solder Inorganic materials 0.000 description 16
- 239000004411 aluminium Substances 0.000 description 9
- 229910052782 aluminium Inorganic materials 0.000 description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
- 238000005034 decoration Methods 0.000 description 7
- 238000004080 punching Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910052755 nonmetal Inorganic materials 0.000 description 2
- XDVOLDOITVSJGL-UHFFFAOYSA-N 3,7-dihydroxy-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B(O)OB2OB(O)OB1O2 XDVOLDOITVSJGL-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000004021 metal welding Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
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- Adornments (AREA)
Abstract
The invention discloses a welding powder composition for an ornament metal wire and a processing method of the welding powder composition. The welding powder composition is prepared from powdered copper, zinc, scapolite, boric acid, borax, butter and castor oil in a mixing manner. The mixed welding powder composition is uniformly coated on a metal chain and subjected to welding treatment at 1100-1200 DEG C. According to the invention, a section of the metal wire with higher strength than that of a copper wire of a general ornament material can be welded, so that the metal can become a material for preparing a bracelet or a necklace. The welding powder composition for the ornament metal wire, disclosed by the invention, can be used for welding the cross section of each metal chain and connecting the metal chains with each other. By utilizing the welding powder for the ornament metal wire disclosed by the invention, the welding is firm and stout; and although the metal chain is subjected to processing such as positive scribing, negative scribing and the like and the cutting pressure or stamping pressure and the like are applied on a welded surface, the welded surface does not crack or chap.
Description
Technical field
The present invention relates to a kind of powder composition, particularly relate to a kind of ornaments wire welding powder composition and processed and applied method thereof of the jewelry chain of weld metal effectively section.
Background technology
The nonmetal wire that the common used material of ornaments is copper, aluminium equal strength is lower.The maximum reason of making ornaments by the lower nonmetallic materials of intensity is because welding easily, can prevent that in process solder side from breaking or chapping.But aluminium is higher as decoration material unit price, proportion is lighter, reduces ornaments and is worth.As decoration material, the unit price of copper is also higher than aluminium.Copper proportion is higher, durable, ornaments value is also high, but higher as its unit price of decoration material, ornaments price is also high.Wire unit price is several times lower than than copper, but why can not to be used for making the ornaments such as necklace or bangle be that two solders side of chain are breakage easily because carry out Yang Kewen and cloudy carve that literary composition etc. is various adds man-hour on its surface for it.
When welding common metal silk, why wire can't forbid cutting or punching press equal pressure is because use low intensity metal welding powder, these welding powders can only be used for aluminium or the lower metal of copper equal strength when welded wire.When welding common metal silk, welding powder cutting or the stamped metal silk the low intensity metal such as aluminium or copper used as used, because wire intensity is higher, need to be in addition than aluminium or large cutting pressure or the punching press of copper to it, result wire can be received too large welding pressure, and the easy skin of solder side damages.Therefore, although wire has huge advantage aspect economy and practicality, available general welding powder can not address the above problem, and wire can not be used for making decoration material so far.
In the past, the binding agent using when the section of soldering copper chain is that lubricating oil and the metal dust solvent boric acid that viscosity is high mixes the welding powder doing.The welding why this class welding powder is unsuitable for high duty metal silk is because following three reasons:
The first, reduce dissolving power and composite force
The second, due to high heat, the adhesion strength of welding powder reduces gradually, can not be attached to solder side for a long time and departs from.
The 3rd, welding powder is not easy to be seeped in section.
In addition, the phenomenon that the adhesion strength causing due to high thermal conductance reduces, solder side there will be the insecure problem such as shaky.
Summary of the invention
The object of the present invention is to provide a kind of new ornaments wire welding powder composition, make manufacturer can produce the high-quality ornaments of making of wire, solve welded wire problem by suitable welding powder, wire unit price is several times lower than than copper, weight and durable aspect there is advantage, gold-plated process is easily and quality is good; When above-mentioned powder weldering composition weld metal chain, although in addition powerful cutting or punching press equal pressure on metal bracelet, solder side also can not break or chap.
The processing method that another object of the present invention is to provide a kind of ornaments wire welding powder composition, it can weld than the high wire section of general decoration material copper wire intensity, metal is become do the material of bangle or necklace.
The object of the invention to solve the technical problems realizes by the following technical solutions.A kind of ornaments wire welding powder composition proposing according to the present invention is to be mixed by each raw material components of following weight percentage: copper powder 10～30%; Iron powder 10～20%; Silver powder 10～20%; Square column stone flour 20～30%; Boric acid 10～20%; Borax 5～10%; Butter 3～8%; Castor oil 2～4%.
In addition, the invention allows for the processing method of a kind of ornaments wire welding powder composition, first 10～30% copper powder, 10～20% iron powder, 10～20% silver powder, 20～30% square column stone flour, 10～20% boric acid, 5～10% borax, 3～8% butter and 2～4% castor oil are mixed, make wire with after welding powder, this mixing welding powder is coated on metal bracelet equably.
After described metal bracelet uses in advance and processes with talcum powder, then weld at 1100～1200 ℃ of temperature.
When described thickness wiry increases or reduces 0.5～1mm, described butter and the loading of described castor oil in welding powder composite formula can respectively have 5～10% increase or reduce.
By technique scheme, ornaments wire of the present invention is with welding powder composition and processing method has advantage and beneficial effect is:
1) the present invention can weld than the high wire section of general decoration material copper wire intensity, metal is become do the material of bangle or necklace; Ornaments wire of the present invention can weld the section of every joint metal bracelet with welding powder composition, and can be connected to each other for it;
2) use ornaments wire welding powder of the present invention, firm welding is solid; Carve the processing such as literary composition and on solder side, add cutting or punching press equal pressure although carry out Yang Kewen and the moon on metal bracelet, solder side also can not break or chap.
The specific embodiment
Ornaments wire of the present invention is copper (CU), iron (TE), silver (AG), scapolite (SN) and the boric acid (H by pulverulence with welding powder composition
3bO
3), borax (Na
2b
4o
7), butter, castor oil (castor oil) mix composition.Adopt the reasons are as follows of these raw material components:
The first copper powder and iron powder, take solid as feature, have advantage aspect processing; The second silver powder: the characteristic being ductile, due to the ductility on low temperature and soft all obviously increase and synthetic ratio high; Third party's pillar powder: composite force and high to the resistance of corrosion; Tetraboric acid and borax: their solubility is high; The 5th butter: cohesiveness and adhesion strength are large; The 6th castor oil: adhesion strength and penetration are large.
Wire of the present invention mixes by each powder stock component that welding powder can also be following weight percentage.Wherein, copper powder 10～30%, iron powder 10～20%, silver powder 10～20%, square column stone flour 20～30%, boric acid 10～20%, borax 5～10%, butter 3～8%, castor oil 2～4%.
Wherein, the particle diameter of above-mentioned copper powder, iron powder, silver powder, square column stone flour approximately can be crossed 30～100mesh sieve.
Owing to deciding weld interval according to thickness wiry, therefore butter and castor oil loading can also be adjusted according to thickness wiry.
As everyone knows, weld interval is very important.When welding copper wire, also decide weld interval according to the thickness of copper wire.
Why decide the loading of butter and castor oil to be because wire is thicker according to thickness wiry, weld interval also longer, welding powder also needs to be attached to more for a long time solder side.The loading of butter and castor oil has just determined that welding powder is attached to the adhesion size of solder side.
Butter also has adhesion strength and the cohesive force of advantage under the condition of high temperature, and this can make boric acid, borax, copper powder, silver powder, square column stone flour melt and realize welding.But although butter has adhesion strength and the cohesive force of advantage, but it can only be better than the welding of nonmetallic materials, is limited to welding wiry, therefore make ornaments with wire and still have large problem.
Castor oil can improve the adhesion strength of butter, and the copper powder, silver powder, the square column stone flour that dissolve are seeped into rapidly in section, and result solder side can be solid firm.Zinc, scapolite, by forming protective layer on the more dull metal surface of the color such as copper or brass, prevent corrosion, particularly the corrosion of metal bracelet solder side.In the time that thickness wiry increases or reduces 0.5～1mm, the loading of butter, castor oil will respectively have 5～10% increase and decrease.
Meanwhile, thickness wiry is thicker, weld interval also longer.
By concrete preferred embodiment, the present invention is expressed in further detail below, but the present invention is not limited in following embodiment.
embodiment 1
diameter 2mm welding processing wiry
First copper powder 320g, iron powder 250g, silver powder 210g, square column stone flour 210g, boric acid 130g, borax 60g, butter 40g, castor oil 30g are mixed and make wire with after welding powder, it is coated on diameter 2mm metal bracelet equably.Cohere mutually for fear of chain, first process after chain with talcum powder, weld at 1100～1200 ℃.
Weld by said method, solder side can be mellow and full not concavo-convex.
embodiment 2
diameter 3mm welding processing wiry
First copper powder 319g, iron powder 200g, silver powder 209g, square column stone flour 209g, boric acid 129g, borax 58g, butter 43g, castor oil 33g are mixed and make wire with after welding powder, it is coated on diameter 3mm metal bracelet equably.Cohere mutually for fear of chain, first process after chain with talcum powder, weld at 1100～1200 ℃.
Weld by said method, solder side can be mellow and full not concavo-convex.
The difference of above-described embodiment 2 and embodiment 1 is that the diameter of the former metal bracelet is than the long 1mm of the latter, and welding required time increases thereupon, and the required time that welding powder is attached on metal surface also increases.For this reason, increase the loading 7～10% of butter and castor oil, and reduce the loading of other materials.In the time that thickness wiry increases or reduces 0.5～1mm, butter wherein, the loading of castor oil will respectively have 5～10% increase and decrease.
The method providing by above-described embodiment 1 and 2 is worked it out after metal bracelet, every pitch chain bar is carried out Yang Kewen or cloudyly carves the processing such as literary composition by cutting or the method such as punching press, then carrying out in its surface gold-plated processing and just complete ornaments.
The strength ratio copper of metal bracelet or aluminium are high 2～4 times, therefore to metal bracelet in addition large cutting same with copper or aluminium or punching press equal pressure realize processing, and should use 2～3 times of large tonnages to metal bracelet.As the nonmetal welding method weld metal chain with the past, solder side will break or chap and can not realize processing.
But, as with wire of the present invention welding powder composition, metal bracelet welded, although tonnage than large 2～3 times of copper or aluminium, the solder side of metal bracelet also can not break or chap and can realize processing.
The unit price of metal bracelet is several times lower than than copper, and wire of the present invention can make wire chain can become decoration material with welding powder composition, and then significantly reduces ornaments production unit price.And the easy quality of gold-plated process is good compared with nonmetallic materials, and the ornaments of energy production high-quality.
The above, it is only preferred embodiment of the present invention, not the present invention is done to any pro forma restriction, do not depart from technical solution of the present invention content therefore every, any simple modification, equivalent variations and the modification above embodiment done according to technical spirit of the present invention, all still belong in the scope of technical solution of the present invention.
Claims (5)
1. an ornaments wire welding powder composition, is characterized in that: described welding powder composition is to be mixed by each raw material components of following weight percentage:
Copper powder 10～30%;
Iron powder 10～20%;
Silver powder 10～20%;
Square column stone flour 20～30%;
Boric acid 10～20%;
Borax 5～10%;
Butter 3～8%;
Castor oil 2～4%.
2. the processing method of welding powder composition for ornaments wire according to claim 1, it is characterized in that: first 10～30% copper powder, 10～20% iron powder, 10～20% silver powder, 20～30% square column stone flour, 10～20% boric acid, 5～10% borax, 3～8% butter and 2～4% castor oil are mixed, make wire with after welding powder, this mixing welding powder is coated on metal bracelet equably.
3. the processing method of welding powder composition for ornaments wire according to claim 2, is characterized in that: after described metal bracelet uses talcum powder to process in advance, then weld at 1100～1200 ℃ of temperature.
4. the processing method of welding powder composition for ornaments wire according to claim 3, is characterized in that: its diameter of described metal bracelet is at 2mm or 3mm.
5. the processing method of welding powder composition for ornaments wire according to claim 4, it is characterized in that: when described thickness wiry increases or reduces 0.5～1mm, described butter and the loading of described castor oil in welding powder composite formula can respectively have 5～10% increase or reduce.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210069659.3A CN102601540B (en) | 2012-03-08 | 2012-03-08 | Welding powder composition for ornament metal wire and processing method of welding powder composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210069659.3A CN102601540B (en) | 2012-03-08 | 2012-03-08 | Welding powder composition for ornament metal wire and processing method of welding powder composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102601540A CN102601540A (en) | 2012-07-25 |
| CN102601540B true CN102601540B (en) | 2014-07-02 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210069659.3A Active CN102601540B (en) | 2012-03-08 | 2012-03-08 | Welding powder composition for ornament metal wire and processing method of welding powder composition |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1055134A (en) * | 1990-09-22 | 1991-10-09 | 中国有色金属工业总公司昆明贵金属研究所 | Gold soldering flux alloy for fine gold adornment |
| CN1064636A (en) * | 1991-03-14 | 1992-09-23 | 中国有色金属工业总公司昆明贵金属研究所 | The method for welding of copper base soldering paste and copper-made ornament |
| CN1064637A (en) * | 1991-03-14 | 1992-09-23 | 中国有色金属工业总公司昆明贵金属研究所 | The method for welding of money base soldering paste and Silver Jewelry |
| CN1916208A (en) * | 2006-09-18 | 2007-02-21 | 陈亿斌 | Alloy, method for preparing the alloy, and method for producing ornamental article |
-
2012
- 2012-03-08 CN CN201210069659.3A patent/CN102601540B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1055134A (en) * | 1990-09-22 | 1991-10-09 | 中国有色金属工业总公司昆明贵金属研究所 | Gold soldering flux alloy for fine gold adornment |
| CN1064636A (en) * | 1991-03-14 | 1992-09-23 | 中国有色金属工业总公司昆明贵金属研究所 | The method for welding of copper base soldering paste and copper-made ornament |
| CN1064637A (en) * | 1991-03-14 | 1992-09-23 | 中国有色金属工业总公司昆明贵金属研究所 | The method for welding of money base soldering paste and Silver Jewelry |
| CN1916208A (en) * | 2006-09-18 | 2007-02-21 | 陈亿斌 | Alloy, method for preparing the alloy, and method for producing ornamental article |
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| Publication number | Publication date |
|---|---|
| CN102601540A (en) | 2012-07-25 |
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Effective date of registration: 20170616 Address after: 226200 Xingang industrial concentrated area, Bao Wang Town, Nantong, Jiangsu, Qidong Patentee after: JIANGSU ATLANTIC WELDING MATERIALS CO.,LTD. Address before: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China Patentee before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Effective date of registration: 20170616 Address after: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China Patentee after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: 266101 Shandong Province, Qingdao city Laoshan District, Keyuan Road No. 1 23 storey block B room 2319 Patentee before: Qingdao fruit science and technology service platform Co.,Ltd. |
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