CN102601540A - Welding powder composition for ornament metal wire and processing method of welding powder composition - Google Patents

Welding powder composition for ornament metal wire and processing method of welding powder composition Download PDF

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CN102601540A
CN102601540A CN2012100696593A CN201210069659A CN102601540A CN 102601540 A CN102601540 A CN 102601540A CN 2012100696593 A CN2012100696593 A CN 2012100696593A CN 201210069659 A CN201210069659 A CN 201210069659A CN 102601540 A CN102601540 A CN 102601540A
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姜熙元
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Qidong Jinzhou Welding Materials Co ltd
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Qingdao Duozhen Arts & Crafts Co Ltd
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Abstract

本发明公开了一种饰品金属丝用焊粉组合物及其加工方法。该焊粉组合物是将粉末状态的铜、锌、方柱石和硼酸、硼砂、黄油、蓖麻油混合组成,将该混合之后的焊粉组合物均匀地涂在金属链条上,在1100~1200℃温度下进行焊接加工工艺处理。本发明可以焊接比一般饰品材料铜丝强度高的金属丝断面,使得金属成为做手链或项链的材料;本发明的饰品金属丝用焊粉组合物可以焊接每节金属链条的断面,并可以为之互相连接;使用本发明的饰品金属丝用焊粉,焊接牢固结实;尽管在金属链条上进行阳刻文和阴刻文等加工而焊接面上加上切削或冲压等压力,焊接面也不会破裂或龟裂。The invention discloses a solder powder composition for ornamental wire and a processing method thereof. The solder powder composition is composed of powdered copper, zinc, square pillar, boric acid, borax, butter, and castor oil, and the mixed solder powder composition is evenly coated on the metal chain, at 1100 ~ 1200 ° C The welding process is carried out at high temperature. The present invention can weld the section of metal wire with higher strength than the copper wire of general jewelry material, so that the metal becomes the material for making bracelets or necklaces; the welding powder composition for jewelry wire of the present invention can weld the section of each metal chain, and can be use the welding powder for jewelry metal wire of the present invention, the welding is firm and strong; although the metal chain is processed with inscriptions and inscriptions on the metal chain and pressure such as cutting or stamping is added to the welding surface, the welding surface is not Will crack or crack.

Description

一种饰品金属丝用焊粉组合物及其加工方法Solder powder composition for jewelry wire and processing method thereof

技术领域 technical field

本发明涉及一种粉末组合物,特别是涉及一种能够有效地焊接金属饰品链条断面的饰品金属丝用焊粉组合物及其加工应用方法。The invention relates to a powder composition, in particular to a welding powder composition for jewelry wires capable of effectively welding metal jewelry chain sections and a processing and application method thereof.

背景技术 Background technique

饰品的常用材料为铜、铝等强度较低的非金属丝。用强度较低的非金属材料制作饰品的最大原因是因为焊接容易,在加工过程中能够防止焊接面破裂或龟裂。然而,铝作为饰品材料单价较高,比重较轻,降低饰品价值。作为饰品材料,铜的单价比铝还高。铜比重较高、耐用、饰品价值也高,然而作为饰品材料其单价较高,饰品价格也高。金属丝单价比铜低几倍,可它之所以不能用来制作项链或手链等饰品是因为在它的表面上进行阳刻文和阴刻文等各种加工时,链条的双焊接面容易破损。Commonly used materials for jewelry are non-metallic wires with low strength such as copper and aluminum. The biggest reason for making jewelry with low-strength non-metallic materials is because it is easy to weld and prevents the welded surface from cracking or cracking during processing. However, the unit price of aluminum as a jewelry material is relatively high, and its specific gravity is light, which reduces the value of jewelry. As a jewelry material, the unit price of copper is higher than that of aluminum. Copper has a high specific gravity, durability, and high jewelry value. However, as a jewelry material, its unit price is high, and the price of jewelry is also high. The unit price of metal wire is several times lower than that of copper, but the reason why it cannot be used to make jewelry such as necklaces or bracelets is that the double welding surface of the chain is easily damaged when various processes such as positive and negative carvings are performed on its surface .

焊接一般金属丝时,金属丝之所以禁不住切削或冲压等压力是因为焊接金属丝时使用低强度金属用焊粉,这些焊粉只能用于铝或铜等强度较低的金属。焊接一般金属丝时,如要使用对铝或铜等低强度金属用的焊粉切削或冲压金属丝,由于金属丝强度较高,对它需要加以比铝或铜大的切削压力或冲压,结果金属丝会收到太大的焊接压力,焊接面容易皮损。因此,尽管金属丝在经济性和实用性方面具有巨大优势,可用一般焊粉不能解决上述问题,金属丝迄今不能用来制作饰品材料。When welding ordinary metal wire, the reason why the metal wire cannot withstand the pressure of cutting or punching is that welding powder for low-strength metals is used when welding metal wire, and these solder powders can only be used for low-strength metals such as aluminum or copper. When welding general metal wires, if you want to use welding powder for low-strength metals such as aluminum or copper to cut or stamp the wires, due to the high strength of the metal wires, it needs to be subjected to a higher cutting pressure or stamping than aluminum or copper. The wire will receive too much welding pressure, and the welding surface is prone to skin damage. Therefore, although metal wire has great advantages in terms of economy and practicability, the above-mentioned problems cannot be solved by using general solder powder, and metal wire cannot be used to make jewelry materials so far.

以前,焊接铜链条的断面时使用的粘结剂是粘度高的润滑油和金属粉末溶剂硼酸混合做的焊粉。这类焊粉之所以不适于高强度金属丝的焊接是因为以下三个原因:In the past, the bonding agent used when welding the cross section of the copper chain was a solder powder made of a mixture of high-viscosity lubricating oil and metal powder solvent boric acid. The reason why this type of solder powder is not suitable for welding high-strength wire is because of the following three reasons:

第一,降低溶解力与合成力First, reduce the solvency and synthesis power

第二,由于高热,焊粉的粘着力逐渐降低,不能长时间贴在焊接面而脱离。Second, due to the high heat, the adhesion of the solder powder is gradually reduced, and it cannot be attached to the soldering surface for a long time and detached.

第三,焊粉不容易渗到断面里。Third, solder powder is not easy to penetrate into the section.

另外,由于高热导致的粘着力降低的现象,焊接面会出现不牢固不结实等问题。In addition, due to the phenomenon of reduced adhesion caused by high heat, the welding surface will be weak and weak.

发明内容 Contents of the invention

本发明的目的在于提供一种新的饰品金属丝用焊粉组合物,使得生产商能够生产用金属丝制作的高品质饰品,通过适当的焊粉来解决焊接金属丝问题,金属丝单价比铜低几倍,在重量与耐用方面具有优势,镀金过程容易而质量好;上述粉焊组合物焊接金属链条时,尽管金属链条上加以强大切削或冲压等压力,焊接面也不会破裂或龟裂。The purpose of the present invention is to provide a new welding powder composition for jewelry wire, so that manufacturers can produce high-quality jewelry made of metal wire, and solve the problem of welding wire by using appropriate solder powder. The unit price of metal wire is lower than that of copper It is several times lower and has advantages in terms of weight and durability. The gold plating process is easy and of good quality; when the above-mentioned powder welding composition welds metal chains, the welding surface will not crack or crack even though the metal chain is subjected to strong cutting or stamping pressure. .

本发明的另一目的在于提供一种饰品金属丝用焊粉组合物的加工方法,其可以焊接比一般饰品材料铜丝强度高的金属丝断面,使得金属成为做手链或项链的材料。Another object of the present invention is to provide a method for processing a solder powder composition for jewelry wire, which can weld a metal wire section with higher strength than copper wire for general jewelry materials, so that the metal can be used as a material for making bracelets or necklaces.

本发明的目的及解决其技术问题是采用以下技术方案来实现的。依据本发明提出的一种饰品金属丝用焊粉组合物,是由以下重量百分含量的各原料组分混合而成:铜粉10~30%;铁粉10~20%;银粉10~20%;方柱石粉20~30%;硼酸10~20%;硼砂5~10%;黄油3~8%;蓖麻油2~4%。The purpose of the present invention and the solution to its technical problems are achieved by adopting the following technical solutions. According to the present invention, a solder powder composition for jewelry wires is prepared by mixing the following raw material components in percentage by weight: copper powder 10-30%; iron powder 10-20%; silver powder 10-20% %; square pillar powder 20-30%; boric acid 10-20%; borax 5-10%; butter 3-8%; castor oil 2-4%.

另外,本发明还提出了一种饰品金属丝用焊粉组合物的加工方法,先将10~30%的铜粉、10~20%的铁粉、10~20%的银粉、20~30%的方柱石粉、10~20%的硼酸、5~10%的硼砂、3~8%的黄油、以及2~4%的蓖麻油混合起来,做金属丝用焊粉后,将该混合焊粉均匀地涂在金属链条上。In addition, the present invention also proposes a processing method of a solder powder composition for jewelry wire, firstly, 10-30% copper powder, 10-20% iron powder, 10-20% silver powder, 20-30% Mix sclereid powder, 10-20% boric acid, 5-10% borax, 3-8% butter, and 2-4% castor oil to make solder powder for wire, and then use the mixed solder powder Apply evenly to the metal chain.

所述金属链条预先使用用滑石粉处理后,再在1100~1200℃温度下进行焊接。The metal chain is pre-treated with talcum powder, and then welded at a temperature of 1100-1200°C.

所述金属丝的粗细增加或减小0.5~1m/m时,所述黄油及所述蓖麻油在焊粉组合物配方中的填充量会各有5~10%的增加或减小。When the thickness of the metal wire increases or decreases by 0.5-1m/m, the filling amounts of the butter and the castor oil in the solder powder composition formula increase or decrease by 5-10%.

借由上述技术方案,本发明饰品金属丝用焊粉组合物及其加工方法具有优点和有益效果是:By means of the above-mentioned technical scheme, the solder powder composition for jewelry wire and its processing method of the present invention have advantages and beneficial effects as follows:

1)本发明可以焊接比一般饰品材料铜丝强度高的金属丝断面,使得金属成为做手链或项链的材料;本发明的饰品金属丝用焊粉组合物可以焊接每节金属链条的断面,并可以为之互相连接;1) The present invention can weld the wire section with higher strength than the copper wire of general jewelry material, so that metal becomes the material for making bracelets or necklaces; the solder powder composition for jewelry wire of the present invention can weld the section of every metal chain, and can be connected to each other;

2)使用本发明的饰品金属丝用焊粉,焊接牢固结实;尽管在金属链条上进行阳刻文和阴刻文等加工而焊接面上加上切削或冲压等压力,焊接面也不会破裂或龟裂。2) Using the welding powder for jewelry metal wire of the present invention, the welding is firm and strong; even though the metal chain is processed with positive and negative inscriptions and the welding surface is subjected to cutting or stamping pressure, the welding surface will not be broken or cracked.

具体实施方式 Detailed ways

本发明的饰品金属丝用焊粉组合物是用粉末状态的铜(CU)、铁(TE)、银(AG)、方柱石(SN)和硼酸(H3BO3)、硼砂(Na2B4O7)、黄油、蓖麻油(castor oil)混合组成。采用这些原料组分的理由如下:The solder powder composition for jewelry wire of the present invention is copper (CU), iron (TE), silver (AG), square pillar (SN) and boric acid (H 3 BO 3 ), borax (Na 2 B 4 O 7 ), butter, and castor oil. The reasons for using these raw material components are as follows:

第一铜粉及铁粉以结实为特点,在加工方面具有优势;第二银粉:具有延展性好的特性,由于在低温度上的延展性与软性都明显增大且合成率高;第三方柱石粉:合成力和对锈蚀的抵抗力高;第四硼酸及硼砂:它们的溶解度高;第五黄油:凝聚力及粘着力大;第六蓖麻油:粘着力及渗透力大。The first copper powder and iron powder are characterized by solidity and have advantages in processing; the second silver powder: has the characteristics of good ductility, because the ductility and softness at low temperatures are significantly increased and the synthesis rate is high; Triangular stone powder: high synthetic power and resistance to rust; fourth boric acid and borax: high solubility; fifth butter: high cohesion and adhesion; sixth castor oil: high adhesion and penetration.

本发明的金属丝用焊粉还可以是以下重量百分含量的各粉末原料组分混合而成。其中,铜粉10~30%、铁粉10~20%、银粉10~20%、方柱石粉20~30%、硼酸10~20%、硼砂5~10%、黄油3~8%、蓖麻油2~4%。The solder powder for metal wires of the present invention can also be prepared by mixing the powder raw material components in the following weight percentages. Among them, copper powder 10-30%, iron powder 10-20%, silver powder 10-20%, square pillar powder 20-30%, boric acid 10-20%, borax 5-10%, butter 3-8%, castor oil 2 to 4%.

其中,上述铜粉、铁粉、银粉、方柱石粉的粒子粒径大约可以过30~100mesh筛。Wherein, the particle size of the above-mentioned copper powder, iron powder, silver powder, and square pillar powder can pass through a 30-100 mesh sieve.

由于根据金属丝的粗细来决定焊接时间,因此黄油与蓖麻油填充量还可以根据金属丝的粗细来调整。Since the welding time is determined according to the thickness of the wire, the filling amount of butter and castor oil can also be adjusted according to the thickness of the wire.

众所周知,焊接时间极为重要。焊接铜丝时,也根据铜丝的粗细来决定焊接时间。We all know that soldering time is extremely important. When welding copper wire, the welding time is also determined according to the thickness of the copper wire.

之所以根据金属丝的粗细来决定黄油与蓖麻油的填充量是因为金属丝越粗,焊接时间也得越长,焊粉也需要越长时间贴在焊接面。黄油与蓖麻油的填充量就决定了焊粉贴在焊接面的黏着力大小。The reason why the filling amount of butter and castor oil is determined according to the thickness of the wire is because the thicker the wire, the longer the welding time, and the longer the solder powder needs to stick to the welding surface. The filling amount of butter and castor oil determines the adhesion of solder powder to the welding surface.

黄油在高温状态下也具有优势的粘着力与凝集力,这能使硼酸、硼砂、铜粉、银粉、方柱石粉融化而实现焊接。然而,尽管黄油具有优势的粘着力与凝集力,可它只能优于非金属材料的焊接,限于金属丝的焊接,因此用金属丝制作饰品仍然存在大问题。Butter also has superior adhesion and cohesion at high temperatures, which can melt boric acid, borax, copper powder, silver powder, and square pillar powder to achieve welding. However, although butter has superior adhesion and cohesion, it can only be superior to welding of non-metallic materials, and is limited to welding of wire, so there are still big problems in making jewelry with wire.

蓖麻油能提高黄油的粘着力,而且使溶解的铜粉、银粉、方柱石粉迅速渗到断面里,结果焊接面会结实牢固。锌、方柱石通过铜或黄铜等颜色较单调的金属表面上形成保护层,防止锈蚀,特别是金属链条焊接面的锈蚀。当金属丝的粗细增加或减小0.5~1m/m时,黄油、蓖麻油的填充量就会各有5~10%的增减。Castor oil can improve the adhesion of butter, and make the dissolved copper powder, silver powder, and square pillar powder penetrate into the cross section quickly, so that the welding surface will be firm and firm. Zinc and square pillars form a protective layer on metal surfaces with relatively monotonous colors such as copper or brass to prevent corrosion, especially the corrosion of the welding surface of metal chains. When the thickness of the metal wire increases or decreases by 0.5-1m/m, the filling amounts of butter and castor oil will increase or decrease by 5-10%.

同时,金属丝的粗细越粗,焊接时间也得越长。At the same time, the thicker the wire, the longer the welding time.

以下通过具体较佳实施例对本发明作进一步详细表述,但本发明并不仅限于以下的实施例。The present invention is further described in detail through specific preferred embodiments below, but the present invention is not limited to the following embodiments.

实施例1Example 1

直径2m/m金属丝的焊接加工Welding processing of wire with a diameter of 2m/m

先将铜粉320g、铁粉250g、银粉210g、方柱石粉210g、硼酸130g、硼砂60g、黄油40g、蓖麻油30g混合起来做金属丝用焊粉后,将它均匀地涂在直径2m/m金属链条上。为了避免链条互相黏结,先用滑石粉处理链条后,在1100~1200℃进行焊接。First mix 320g of copper powder, 250g of iron powder, 210g of silver powder, 210g of square pillar powder, 130g of boric acid, 60g of borax, 40g of butter, and 30g of castor oil. on a metal chain. In order to prevent the chains from sticking to each other, the chains are first treated with talcum powder and then welded at 1100-1200 °C.

通过上述方法进行焊接,焊接面会圆润不凹凸。Welding by the above method, the welding surface will be round and not uneven.

实施例2Example 2

直径3m/m金属丝的焊接加工Welding processing of wire with a diameter of 3m/m

先将铜粉319g、铁粉200g、银粉209g、方柱石粉209g、硼酸129g、硼砂58g、黄油43g、蓖麻油33g混合起来做金属丝用焊粉后,将它均匀地涂在直径3m/m金属链条上。为了避免链条互相黏结,先用滑石粉处理链条后,在1100~1200℃进行焊接。First mix 319g of copper powder, 200g of iron powder, 209g of silver powder, 209g of square pillar powder, 129g of boric acid, 58g of borax, 43g of butter, and 33g of castor oil. on a metal chain. In order to prevent the chains from sticking to each other, the chains are first treated with talcum powder and then welded at 1100-1200 °C.

通过上述方法进行焊接,焊接面会圆润不凹凸。Welding by the above method, the welding surface will be round and not uneven.

上述实施例2和实施例1的差异在于前者金属链条的直径比后者长1m/m,焊接所需时间随之增加,焊粉贴在金属表面上的所需时间也增加。为此,增加黄油与蓖麻油的填充量7~10%,而减小其他材料的填充量。当金属丝的粗细增加或减小0.5~1m/m时,其中的黄油、蓖麻油的填充量就会各有5~10%的增减。The difference between the above-mentioned embodiment 2 and embodiment 1 is that the diameter of the former metal chain is 1m/m longer than that of the latter, the time required for welding increases accordingly, and the time required for welding powder to stick on the metal surface also increases. For this reason, increase the filling amount of butter and castor oil by 7-10%, and reduce the filling amount of other materials. When the thickness of the metal wire increases or decreases by 0.5-1m/m, the filling amounts of butter and castor oil will increase or decrease by 5-10%.

通过上述实施例1和2提供的方法做出来金属链条后,用切削或冲压等方法对每节链条进行阳刻文或阴刻文等加工,再在其表面上进行镀金处理就完成饰品。After the metal chain is made by the method provided in the above-mentioned embodiments 1 and 2, each chain is processed by cutting or stamping, etc., and then gold-plated on the surface to complete the jewelry.

金属链条的强度比铜或铝高2~4倍,因此对金属链条不能加以与铜或铝同样大的切削或冲压等压力实现加工,而对金属链条应使用2~3倍大的加工压力。如用从前的非金属焊接方法焊接金属链条,焊接面就会破裂或龟裂而不能实现加工。The strength of the metal chain is 2 to 4 times higher than that of copper or aluminum. Therefore, the metal chain cannot be processed with the same cutting or stamping pressure as copper or aluminum, but the metal chain should be processed with 2 to 3 times greater processing pressure. If the metal chain is welded by the previous non-metallic welding method, the welding surface will be cracked or cracked and cannot be processed.

然而,如用本发明金属丝用焊粉组合物对金属链条进行焊接,尽管加工压力比铜或铝大2~3倍,金属链条的焊接面也不会破裂或龟裂而能够实现加工。However, if a metal chain is welded with the solder powder composition for metal wire of the present invention, although the processing pressure is 2 to 3 times greater than that of copper or aluminum, the welding surface of the metal chain can be processed without cracking or cracking.

金属链条的单价比铜低几倍,本发明金属丝用焊粉组合物能够使得金属丝链条可以成为饰品材料,进而大幅减小饰品生产单价。而且与非金属材料相比镀金过程容易质量好,且能生产高品质的饰品。The unit price of the metal chain is several times lower than that of copper, and the solder powder composition for metal wire of the present invention can make the metal wire chain become an ornament material, thereby greatly reducing the unit price of ornament production. Moreover, compared with non-metallic materials, the gold plating process is easy and good in quality, and can produce high-quality ornaments.

以上所述,仅是本发明的较佳实施例而已,并非对本发明作任何形式上的限制,故凡是未脱离本发明技术方案内容,依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化与修饰,均仍属于本发明技术方案的范围内。The above is only a preferred embodiment of the present invention, and does not limit the present invention in any form, so any simple modification made to the above embodiments according to the technical essence of the present invention does not depart from the content of the technical solution of the present invention. , equivalent changes and modifications all still belong to the scope of the technical solution of the present invention.

Claims (6)

1.一种饰品金属丝用焊粉组合物,其特征在于:所述焊粉组合物是由铜粉、铁粉、银粉、方柱石粉、硼酸、硼砂、黄油和蓖麻油混合组成。1. A soldering powder composition for jewelry wire, characterized in that: the soldering powder composition is composed of copper powder, iron powder, silver powder, square pillar powder, boric acid, borax, butter and castor oil. 2.根据权利要求1所述的饰品金属丝用焊粉组合物,其特征在于:所述焊粉组合物是由以下重量百分含量的各原料组分混合而成:2. The solder powder composition for jewelry wire according to claim 1, characterized in that: the solder powder composition is formed by mixing the following raw material components in percentage by weight: 铜粉10~30%;Copper powder 10-30%; 铁粉10~20%;Iron powder 10-20%; 银粉10~20%;Silver powder 10-20%; 方柱石粉20~30%;20-30% of square pillar powder; 硼酸10~20%;Boric acid 10-20%; 硼砂5~10%;Borax 5-10%; 黄油3~8%;Butter 3-8%; 蓖麻油2~4%。Castor oil 2-4%. 3.权利要求1或2所述的一种饰品金属丝用焊粉组合物的加工方法,其特征在于:先将10~30%的铜粉、10~20%的铁粉、10~20%的银粉、20~30%的方柱石粉、10~20%的硼酸、5~10%的硼砂、3~8%的黄油、以及2~4%的蓖麻油混合起来,做金属丝用焊粉后,将该混合焊粉均匀地涂在金属链条上。3. The processing method of a solder powder composition for jewelry wire according to claim 1 or 2, characterized in that: firstly, 10-30% copper powder, 10-20% iron powder, 10-20% Silver powder, 20-30% square pillar powder, 10-20% boric acid, 5-10% borax, 3-8% butter, and 2-4% castor oil are mixed to make solder powder for wire Finally, apply the mixed solder powder evenly on the metal chain. 4.根据权利要求3所述的饰品金属丝用焊粉组合物的加工方法,其特征在于:所述金属链条预先使用用滑石粉处理后,再在1100~1200℃温度下进行焊接。4. The method for processing the solder powder composition for jewelry wires according to claim 3, characterized in that: the metal chains are pre-treated with talcum powder and then welded at a temperature of 1100-1200°C. 5.根据权利要求4所述的饰品金属丝用焊粉组合物的加工方法,其特征在于:所述金属链条其直径在2m/m或3m/m。5. The method for processing the solder powder composition for jewelry wires according to claim 4, characterized in that: the diameter of the metal chain is 2m/m or 3m/m. 6.根据权利要求5所述的饰品金属丝用焊粉组合物的加工方法,其特征在于:所述金属丝的粗细增加或减小0.5~1m/m时,所述黄油及所述蓖麻油在焊粉组合物配方中的填充量会各有5~10%的增加或减小。6. The method for processing the solder powder composition for decorative metal wire according to claim 5, characterized in that: when the thickness of the metal wire increases or decreases by 0.5 to 1 m/m, the butter and the castor oil The filling amount in the formulation of the solder powder composition can be increased or decreased by 5-10%.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1055134A (en) * 1990-09-22 1991-10-09 中国有色金属工业总公司昆明贵金属研究所 Gold soldering flux alloy for fine gold adornment
CN1064636A (en) * 1991-03-14 1992-09-23 中国有色金属工业总公司昆明贵金属研究所 The method for welding of copper base soldering paste and copper-made ornament
CN1064637A (en) * 1991-03-14 1992-09-23 中国有色金属工业总公司昆明贵金属研究所 The method for welding of money base soldering paste and Silver Jewelry
CN1916208A (en) * 2006-09-18 2007-02-21 陈亿斌 Alloy, method for preparing the alloy, and method for producing ornamental article

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1055134A (en) * 1990-09-22 1991-10-09 中国有色金属工业总公司昆明贵金属研究所 Gold soldering flux alloy for fine gold adornment
CN1064636A (en) * 1991-03-14 1992-09-23 中国有色金属工业总公司昆明贵金属研究所 The method for welding of copper base soldering paste and copper-made ornament
CN1064637A (en) * 1991-03-14 1992-09-23 中国有色金属工业总公司昆明贵金属研究所 The method for welding of money base soldering paste and Silver Jewelry
CN1916208A (en) * 2006-09-18 2007-02-21 陈亿斌 Alloy, method for preparing the alloy, and method for producing ornamental article

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