CN102601540A - Welding powder composition for ornament metal wire and processing method of welding powder composition - Google Patents
Welding powder composition for ornament metal wire and processing method of welding powder composition Download PDFInfo
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- CN102601540A CN102601540A CN2012100696593A CN201210069659A CN102601540A CN 102601540 A CN102601540 A CN 102601540A CN 2012100696593 A CN2012100696593 A CN 2012100696593A CN 201210069659 A CN201210069659 A CN 201210069659A CN 102601540 A CN102601540 A CN 102601540A
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- Prior art keywords
- welding
- powder
- welding powder
- powder composition
- wire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000003466 welding Methods 0.000 title claims abstract description 66
- 239000000843 powder Substances 0.000 title claims abstract description 53
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 44
- 239000002184 metal Substances 0.000 title claims abstract description 44
- 239000000203 mixture Substances 0.000 title claims abstract description 37
- 238000003672 processing method Methods 0.000 title claims abstract description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 33
- 235000014121 butter Nutrition 0.000 claims abstract description 22
- 239000004359 castor oil Substances 0.000 claims abstract description 21
- 235000019438 castor oil Nutrition 0.000 claims abstract description 21
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 21
- 229910021538 borax Inorganic materials 0.000 claims abstract description 12
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004327 boric acid Substances 0.000 claims abstract description 12
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 12
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 12
- 235000010338 boric acid Nutrition 0.000 claims abstract 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 235000013312 flour Nutrition 0.000 claims description 11
- 239000004575 stone Substances 0.000 claims description 11
- 239000002131 composite material Substances 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 238000009700 powder processing Methods 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 16
- 229910052802 copper Inorganic materials 0.000 abstract description 15
- 239000010949 copper Substances 0.000 abstract description 15
- 238000005520 cutting process Methods 0.000 abstract description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052725 zinc Inorganic materials 0.000 abstract description 2
- 239000011701 zinc Substances 0.000 abstract description 2
- -1 scapolite Chemical compound 0.000 abstract 1
- 229910000679 solder Inorganic materials 0.000 description 16
- 238000000034 method Methods 0.000 description 10
- 239000004411 aluminium Substances 0.000 description 9
- 229910052782 aluminium Inorganic materials 0.000 description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
- 238000005034 decoration Methods 0.000 description 7
- 238000004080 punching Methods 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910052755 nonmetal Inorganic materials 0.000 description 2
- XDVOLDOITVSJGL-UHFFFAOYSA-N 3,7-dihydroxy-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B(O)OB2OB(O)OB1O2 XDVOLDOITVSJGL-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Adornments (AREA)
Abstract
The invention discloses a welding powder composition for an ornament metal wire and a processing method of the welding powder composition. The welding powder composition is prepared from powdered copper, zinc, scapolite, boric acid, borax, butter and castor oil in a mixing manner. The mixed welding powder composition is uniformly coated on a metal chain and subjected to welding treatment at 1100-1200 DEG C. According to the invention, a section of the metal wire with higher strength than that of a copper wire of a general ornament material can be welded, so that the metal can become a material for preparing a bracelet or a necklace. The welding powder composition for the ornament metal wire, disclosed by the invention, can be used for welding the cross section of each metal chain and connecting the metal chains with each other. By utilizing the welding powder for the ornament metal wire disclosed by the invention, the welding is firm and stout; and although the metal chain is subjected to processing such as positive scribing, negative scribing and the like and the cutting pressure or stamping pressure and the like are applied on a welded surface, the welded surface does not crack or chap.
Description
Technical field
The present invention relates to a kind of powder composition, the ornaments wire that particularly relates to a kind of ornaments of weld metal effectively chain section is with welding powder composition and processed and applied method thereof.
Background technology
The nonmetal wire that the common used material of ornaments is a copper, the aluminium equal strength is lower.The maximum reason of making ornaments with the lower nonmetallic materials of intensity is to break or chap because welding easily, can prevent solder side in process.Yet aluminium is higher as the decoration material unit price, and proportion is lighter, reduces ornaments and is worth.As decoration material, the unit price of copper is also higher than aluminium.Copper proportion is higher, durable, ornaments value is also high, yet higher as its unit price of decoration material, the ornaments price is also high.The wire unit price is several times lower than than copper, but why can not to be used for making ornaments such as necklace or bangle be to carve with cloudy that literary composition etc. is various to add man-hour because on its surface, carry out Yang Kewen for it, and two solders side of chain are breakage easily.
During welding common metal silk, why wire can't forbid cutting or punching press equal pressure is that these welding powders can only be used for aluminium or the lower metal of copper equal strength because use low intensity metal to use welding powder during welded wire.During welding common metal silk; As to use welding powder cutting or the stamped metal silk that low intensity metal such as aluminium or copper are used, because wire intensity is higher, it is needed than aluminium or big cutting pressure or the punching press of copper in addition; Wire can be received too big welding pressure as a result, and the easy skin of solder side decreases.Therefore, although wire has huge advantage aspect economy and the practicality, available general welding powder can not address the above problem, and wire can not be used for making decoration material so far.
In the past, the binding agent that used during the section of soldering copper chain is that high lubricating oil of viscosity and metal dust solvent boric acid mix the welding powder of doing.The welding why this type welding powder is inappropriate for the high duty metal silk is because following three reasons:
The first, reduce dissolving power and composite force
The second, because high heat, the adhesion strength of welding powder reduces gradually, can not be attached to solder side for a long time and breaks away from.
The 3rd, welding powder is not easy to be seeped in the section.
In addition, because the phenomenon that the adhesion strength that causes of high thermal conductance reduces, insecure problem such as shaky can appear in solder side.
Summary of the invention
The object of the present invention is to provide a kind of new ornaments wire to use the welding powder composition; Make the manufacturer can produce the high-quality ornaments made from wire; Solve the welded wire problem through suitable welding powder; The wire unit price is several times lower than than copper, weight and durable aspect have advantage, gold-plated process is easily and quality is good; During above-mentioned powder weldering composition weld metal chain, although in addition powerful cutting or punching press equal pressure on the metal bracelet, solder side can not break or chap yet.
Another object of the present invention is to provide the processing method of a kind of ornaments wire with the welding powder composition, it can weld than the high wire section of general decoration material copper wire intensity, makes metal become to do the material of bangle or necklace.
The object of the invention and solve its technical problem and adopt following technical scheme to realize.A kind of ornaments wire according to the present invention proposes is used the welding powder composition, is that each raw material components by following weight percentage mixes: copper powder 10～30%; Iron powder 10～20%; Silver powder 10～20%; Square column stone flour 20～30%; Boric acid 10～20%; Borax 5～10%; Butter 3～8%; Castor oil 2～4%.
In addition; The invention allows for the processing method of a kind of ornaments wire with the welding powder composition; Earlier 10～30% copper powder, 10～20% iron powder, 10～20% silver powder, 20～30% square column stone flour, 10～20% boric acid, 5～10% borax, 3～8% butter and 2～4% castor oil are mixed; Do wire with welding powder after, should mix welding powder and be coated on the metal bracelet equably.
Said metal bracelet uses with after the talcum powder processing in advance, under 1100～1200 ℃ of temperature, welds again.
Said thickness wiry increases or when reducing 0.5～1m/m, said butter and the loading of said castor oil in the welding powder composite formula can respectively have 5～10% increase or reduce.
By technique scheme, ornaments wire of the present invention is with the welding powder composition and processing method has advantage and beneficial effect is:
1) the present invention can weld than the high wire section of general decoration material copper wire intensity, makes metal become to do the material of bangle or necklace; Ornaments wire of the present invention can weld the section of every joint metal bracelet with the welding powder composition, and can connect mutually for it;
2) use ornaments wire of the present invention to use welding powder, firm welding is solid; Although carve processing such as literary composition and add cutting or punching press equal pressure on the solder side with cloudy carrying out Yang Kewen on the metal bracelet, solder side can not break or chap yet.
The specific embodiment
Ornaments wire of the present invention is copper (CU), iron (TE), silver (AG), scapolite (SN) and boric acid (H with pulverulence with the welding powder composition
3BO
3), borax (Na
2B
4O
7), butter, castor oil (castor oil) mix and form.Adopt the reasons are as follows of these raw material components:
First copper powder and iron powder are characteristics with solid, aspect processing, have advantage; Second silver powder: the characteristic that is ductile, because ductility on low temperature and soft all obviously the increase and the synthetic ratio height; Third party's pillar powder: composite force and high to the resistance of corrosion; Tetraboric acid and borax: their solubility is high; The 5th butter: cohesiveness and adhesion strength are big; The 6th castor oil: adhesion strength and penetration are big.
Wire of the present invention can also be that each powder stock component of following weight percentage mixes with welding powder.Wherein, copper powder 10～30%, iron powder 10～20%, silver powder 10～20%, square column stone flour 20～30%, boric acid 10～20%, borax 5～10%, butter 3～8%, castor oil 2～4%.
Wherein, the particle diameter of above-mentioned copper powder, iron powder, silver powder, square column stone flour approximately can be crossed 30～100mesh sieve.
Owing to decide weld interval according to thickness wiry, so butter and castor oil loading can also be adjusted according to thickness wiry.
As everyone knows, weld interval is very important.During the welding copper wire, also the thickness according to copper wire decides weld interval.
Why decide the loading of butter and castor oil to be because wire is thick more according to thickness wiry, weld interval also long more, welding powder also needs be attached to more for a long time solder side.The loading of butter and castor oil has just determined welding powder to be attached to the adhesion size of solder side.
Butter also has the adhesion strength and the cohesive force of advantage under the condition of high temperature, this can make boric acid, borax, copper powder, silver powder, square column stone flour melt and realize welding.Yet although butter has the adhesion strength and the cohesive force of advantage, but it can only be superior to the welding of nonmetallic materials, is limited to welding wiry, therefore makes ornaments with wire and still has big problem.
Castor oil can improve the adhesion strength of butter, and copper powder, silver powder, the square column stone flour of dissolving are seeped into rapidly in the section, and solder side can be solid firm as a result.Zinc, scapolite than forming protective layer on the dull metal surface, prevent corrosion, particularly the corrosion of metal bracelet solder side through colors such as copper or brass.When thickness wiry increased or reduces 0.5～1m/m, the loading of butter, castor oil will respectively have 5～10% increase and decrease.
Simultaneously, thickness wiry is thick more, weld interval also long more.
Below through concrete preferred embodiment the present invention is made further detailed presentations, but the present invention is not limited in following embodiment.
Embodiment 1
Diameter 2m/m welding processing wiry
Earlier with copper powder 320g, iron powder 250g, silver powder 210g, square column stone flour 210g, boric acid 130g, borax 60g, butter 40g, castor oil 30g mix do wire with welding powder after, it is coated on the diameter 2m/m metal bracelet equably.Cohere mutually for fear of chain, with behind the talcum powder processing chain, weld earlier at 1100～1200 ℃.
Weld through said method, solder side can be mellow and full not concavo-convex.
Embodiment 2
Diameter 3m/m welding processing wiry
Earlier with copper powder 319g, iron powder 200g, silver powder 209g, square column stone flour 209g, boric acid 129g, borax 58g, butter 43g, castor oil 33g mix do wire with welding powder after, it is coated on the diameter 3m/m metal bracelet equably.Cohere mutually for fear of chain, with behind the talcum powder processing chain, weld earlier at 1100～1200 ℃.
Weld through said method, solder side can be mellow and full not concavo-convex.
The diameter that the difference of the foregoing description 2 and embodiment 1 is the former metal bracelet is than the long 1m/m of the latter, and the welding required time increases thereupon, and the required time that welding powder is attached on the metal surface also increases.For this reason, increase the loading 7～10% of butter and castor oil, and reduce the loading of other materials.When thickness wiry increased or reduces 0.5～1m/m, butter wherein, the loading of castor oil will respectively have 5～10% increase and decrease.
After the method that provides through the foregoing description 1 and 2 is worked it out metal bracelet, with methods such as cutting or punching presses every pitch chain bar is carried out Yang Kewen or cloudy and carve processing such as literary composition, carry out gold-plated processing more in its surface and just accomplish ornaments.
The strength ratio copper of metal bracelet or aluminium are high 2～4 times, therefore can not realize processing with copper or same big cutting or the punching press equal pressure of aluminium to metal bracelet, and should use 2～3 times of big tonnages to metal bracelet.Like the nonmetal welding method weld metal chain with the past, solder side will break or chap and can not realize processing.
Yet as metal bracelet being welded with the welding powder composition with wire of the present invention, although tonnage is bigger 2～3 times than copper or aluminium, the solder side of metal bracelet also can not break or chap and can realize processing.
The unit price of metal bracelet is several times lower than than copper, and wire of the present invention can make the wire chain can become decoration material with the welding powder composition, and then significantly reduces ornaments production unit price.And compare the easy quality of gold-plated process with nonmetallic materials good, and can produce high-quality ornaments.
The above; It only is preferred embodiment of the present invention; Be not that the present invention is done any pro forma restriction; Former every technical scheme content of the present invention that do not break away from, all still belongs in the scope of technical scheme of the present invention any simple modification, equivalent variations and modification that above embodiment did according to technical spirit of the present invention.
Claims (6)
1. an ornaments wire is used the welding powder composition, it is characterized in that: said welding powder composition is mixed by copper powder, iron powder, silver powder, square column stone flour, boric acid, borax, butter and castor oil and forms.
2. ornaments wire according to claim 1 is used the welding powder composition, it is characterized in that: said welding powder composition is that each raw material components by following weight percentage mixes:
Copper powder 10～30%;
Iron powder 10～20%;
Silver powder 10～20%;
Square column stone flour 20～30%;
Boric acid 10～20%;
Borax 5～10%;
Butter 3～8%;
Castor oil 2～4%.
3. claim 1 or 2 described a kind of ornaments wires are with the processing method of welding powder composition; It is characterized in that: earlier 10～30% copper powder, 10～20% iron powder, 10～20% silver powder, 20～30% square column stone flour, 10～20% boric acid, 5～10% borax, 3～8% butter and 2～4% castor oil are mixed; Do wire with welding powder after, should mix welding powder and be coated on the metal bracelet equably.
4. ornaments wire according to claim 3 is characterized in that with the processing method of welding powder composition: said metal bracelet uses with after the talcum powder processing in advance, under 1100～1200 ℃ of temperature, welds again.
5. ornaments wire according to claim 4 is characterized in that with the processing method of welding powder composition: its diameter of said metal bracelet is at 2m/m or 3m/m.
6. ornaments wire according to claim 5 is with the processing method of welding powder composition; It is characterized in that: said thickness wiry increases or when reducing 0.5～1m/m, said butter and the loading of said castor oil in the welding powder composite formula can respectively have 5～10% increase or reduce.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210069659.3A CN102601540B (en) | 2012-03-08 | 2012-03-08 | Welding powder composition for ornament metal wire and processing method of welding powder composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210069659.3A CN102601540B (en) | 2012-03-08 | 2012-03-08 | Welding powder composition for ornament metal wire and processing method of welding powder composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102601540A true CN102601540A (en) | 2012-07-25 |
| CN102601540B CN102601540B (en) | 2014-07-02 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210069659.3A Active CN102601540B (en) | 2012-03-08 | 2012-03-08 | Welding powder composition for ornament metal wire and processing method of welding powder composition |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1055134A (en) * | 1990-09-22 | 1991-10-09 | 中国有色金属工业总公司昆明贵金属研究所 | Gold soldering flux alloy for fine gold adornment |
| CN1064636A (en) * | 1991-03-14 | 1992-09-23 | 中国有色金属工业总公司昆明贵金属研究所 | The method for welding of copper base soldering paste and copper-made ornament |
| CN1064637A (en) * | 1991-03-14 | 1992-09-23 | 中国有色金属工业总公司昆明贵金属研究所 | The method for welding of money base soldering paste and Silver Jewelry |
| CN1916208A (en) * | 2006-09-18 | 2007-02-21 | 陈亿斌 | Alloy, method for preparing the alloy, and method for producing ornamental article |
-
2012
- 2012-03-08 CN CN201210069659.3A patent/CN102601540B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1055134A (en) * | 1990-09-22 | 1991-10-09 | 中国有色金属工业总公司昆明贵金属研究所 | Gold soldering flux alloy for fine gold adornment |
| CN1064636A (en) * | 1991-03-14 | 1992-09-23 | 中国有色金属工业总公司昆明贵金属研究所 | The method for welding of copper base soldering paste and copper-made ornament |
| CN1064637A (en) * | 1991-03-14 | 1992-09-23 | 中国有色金属工业总公司昆明贵金属研究所 | The method for welding of money base soldering paste and Silver Jewelry |
| CN1916208A (en) * | 2006-09-18 | 2007-02-21 | 陈亿斌 | Alloy, method for preparing the alloy, and method for producing ornamental article |
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| Publication number | Publication date |
|---|---|
| CN102601540B (en) | 2014-07-02 |
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Effective date of registration: 20200218 Address after: 226200 Xingang Industrial Park, Wangbao Town, Qidong City, Nantong City, Jiangsu Province (Xingang village, Jiulong Town) Patentee after: Qidong Jinzhou welding materials Co.,Ltd. Address before: 226100, No. 100, Dongting Lake Road, Linjiang Town, Haimen, Jiangsu, Nantong Patentee before: HAIMEN HAITUO TRADE CO.,LTD. |