CN102584403A - Ion nutritional liquid fertilizer and preparation method thereof - Google Patents
Ion nutritional liquid fertilizer and preparation method thereof Download PDFInfo
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- CN102584403A CN102584403A CN2012100531054A CN201210053105A CN102584403A CN 102584403 A CN102584403 A CN 102584403A CN 2012100531054 A CN2012100531054 A CN 2012100531054A CN 201210053105 A CN201210053105 A CN 201210053105A CN 102584403 A CN102584403 A CN 102584403A
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Abstract
The invention discloses an ion nutritional liquid fertilizer and a preparation method thereof. The fertilizer comprises the following components by weight parts: 15-35 parts of potassium hydroxide, 5-15 parts of germanium dioxide, 1-5 parts of sodium selenite or sodium selenate, 5-15 parts of zinc acetate or zinc sulfate, 1-5 parts of chromic chloride, 2-8 parts of ammonium metavanadate, 15-40 parts of organic acid, 20-50 parts of amino acid, 10-20 parts of boric acid, 2-10 parts of urea and 500-900 parts of water, wherein the organic acid is citric acid or acetic acid and the amino acid is compound amino acid or monomer amino acid. The preparation method comprises the following steps of: taking the components of the fertilizer by weight parts; dissolving germanium dioxide into the potassium hydroxide; adding the organic acid, and then performing acidizing chelation reaction for 5-10 hours; adding the sodium selenite, zinc acetate, amino acid, boric acid, chromic chloride, ammonium metavanadate, urea and water; reacting for 5-10 hours; and filtering and removing slag, thereby obtaining the ion nutritional liquid fertilizer.
Description
Technical field
The present invention relates to the agricultural fertilizer technology, be specially a kind of ion nutritive liq fertilizer and preparation method thereof.This fertilizer is ionic liquid, and is rich in several kinds of mineral elements such as germanium, selenium, zinc, chromium, vanadium.
Background technology
The people need take in various nutritive elements every day to keep fit and normal physiological function from meals.The intake of various nutritive elements is not enough in the human body, will cause function of human body decline even ill, replenishes the health level that corresponding nutritive element then can improve human body, and then eliminates associated conditions.
Organic germanium is a kind of important nutritive element.Health ministry has been listed organic germanium in the new resource food list of formal production, and has been widely used in various fields such as beverage, food and beauty treatment, skin care, health care.Selenium also is a kind of important nutritive element.And China to be the big and medium-sized cities such as country, particularly North China, northeast and northwest that lack selenium all belong to lacks the selenium area, do not reach the above standard of everyone 40 micrograms every day in the food and mend the selenium level.Zinc is the composition or the coenzyme of human body six big enzymes, 200 kinds of metalloenzyme, and general metabolism is played extensive effect, is described as " flower of life " by people.Trivalent chromium is that modern medicine is thought the element to the human body beneficial.But the chromium that people are obtained from general food every day can not satisfy the human body needs.V element also is a micro elements needed by human.It is demonstrating good prospect aspect modern diseases such as prevention and treatment mellitus, hypertension, hyperlipidemia.Experimentation on animals confirms that germanium and selenium and zinc have synergy.Trace elements such as selenium, chromium, vanadium also have synergy.Chang Ying etc. point out in " anti-oxidant micro-nutrients is to the regulating and controlling effect of diabetic mice cytokine gene expression ", replenish AM group rat peripheral blood and spleen and organize IL4, IL10 positive lymphocyte per-cent apparently higher than model control group (P＜0.05，P＜0。01), wherein the Se+VE+V+Cr group raises more obvious; Diabetic model group IL4, IL10 express and are in minimum level.Replenish each group of AM and obviously increased insulin secretion deposit (P＜0 than model group.05)。Compare with model group, AM replenishes and respectively to organize glucose level and significantly reduce, and the GSHPx activity level raises, MDA content (P＜0 that obviously descends.05)。Application number is working method and the purposes that 201010555456.6 Chinese patent " different kinds of ions healthy liquid, Its Preparation Method And Use " discloses one kind of multiple mineral ion liquid, and prompting can be used to increase production foliage fertilizer, but does not have concrete method of use.This patent is raw materials used mainly to be natural mineral and concentrated seawaters such as sylvite, wollastonite, tourmalinite, does not contain special trace elements such as selenium chrome alum basically, therefore can't satisfy the plantation demand of special nutrition plant.Simultaneously, it is raw material that this patent adopts natural mineral, and the purity of natural mineral raw and Qi Chengkuang have much relations, and all can more or less be entrained with the unwanted or even deleterious heavy metallic mineral element of plant in the natural mineral raw; Though also contain several mineral materials in the seawater, low, the complicated component of content may contain objectionable impurities, and its concentrated expense is high.Need heat among the preparation method of its acidic ionic liquid 150-250 ℃, not only production unit proposed requirements at the higher level, and increase energy consumption.
As everyone knows, human body replenishes the secure way utilize mineral element and obtains naturally no more than passing through food through vegeto-animal biological process again after with the inorganic mineral element organic transformation.And further experiment confirm, plant such as fruits and vegetables, grain and edible mushroomss such as auricularia auriculajudae, mushroom all can carry out organic transformation with inorganic mineral elements such as germanium, selenium, zinc, chromium, vanadium.In the mineral element fertilizer that existing plant, edible fungi are used; Though the existing mineral manure that contains trace elements such as selenium, zinc, the document that contains special beneficial mineral ionic liquid fertilizers such as equilibrated germanium, selenium, zinc, chromium, vanadium does not simultaneously appear in the newspapers as yet.
Summary of the invention
To the deficiency of prior art, the technical problem that quasi-solution of the present invention is determined is that a kind of ion nutritive liq fertilizer and preparation method thereof is provided.This fertilizer not only contains liquid fertilizer elements commonly used such as nitrogen, potassium, boron; But also contain equilibrated germanium, selenium, zinc, chromium, vanadium etc. to the beneficial element that human body has special healthy meaning, can make people satisfy the trace element of healthy demand through the edible food of using this fertilizer.This preparing method's technology is easy, and mineral element content is regulated and control easily, normal temperature and pressure production, and equipment is simple, and cost is suitable for industrializing implementation.
The technical scheme that the present invention solves said fertilizer technology problem is, designs a kind of ion nutritive liq fertilizer, it is characterized in that the parts by weight of this fertilizer consist of: 15～35 parts in Pottasium Hydroxide; 5～15 parts of germanium dioxides; 1～5 part of Sodium Selenite or sodium selenate; 5～15 parts in zinc acetate or zinc sulfate; 1～5 part of chromium chloride; 2～8 parts of ammonium meta-vanadates; 15～40 parts of organic acids; 20～50 parts in amino acid; 10～20 parts of boric acid; 500～900 parts in 2～10 parts in urea and water; Described organic acid is Hydrocerol A or acetate; Said amino acid is aminoacids complex or single amino acid.
The technical scheme that the present invention solves said preparing method's technical problem is; Design a kind of preparation method of ion nutritive liq fertilizer; This preparation method adopts the parts by weight of ion nutritive liq fertilizer of the present invention to form and following technology: earlier described germanium dioxide is dissolved in the Pottasium Hydroxide; Add organic acid again, carried out the acidifying chelatropic reaction 5-10 hour; Add said Sodium Selenite, zinc acetate, amino acid, boric acid, chromium chloride, ammonium meta-vanadate, urea and water then, reacted 5-10 hour, promptly process behind the filter and remove residue.
Compared with prior art; Ion nutritive liq fertilizer of the present invention is except containing liquid fertilizer elements commonly used such as nitrogen, potassium, boron; Also contain the beneficial element that equilibrated germanium, selenium, zinc, chromium, vanadium etc. have special healthy meaning to human body; Not only can promote the growth of plant, edible mushrooms; And can make fruits and vegetables, grain and edible mushrooms etc. be rich in organic germanium, selenium, zinc, chromium and vanadium etc. to the beneficial element that human body has special healthy meaning, can make people satisfy the trace element of healthy demand through the edible food of using this fertilizer.Preparing method's technology of the present invention is easy, and mineral element content is regulated and control easily, normal temperature and pressure production, and equipment is simple, and cost is suitable for industrializing implementation.
Embodiment
Further narrate the present invention below in conjunction with embodiment.
The ion nutritive liq fertilizer (abbreviation fertilizer) of the present invention's design is characterized in that the parts by weight of this fertilizer consist of: 15～35 parts in Pottasium Hydroxide; 5～15 parts of germanium dioxides; 1～5 part of Sodium Selenite or sodium selenate; 5～15 parts in zinc acetate or zinc sulfate; 1～5 part of chromium chloride; 2～8 parts of ammonium meta-vanadates; 15～40 parts of organic acids; 20～50 parts in amino acid; 10～20 parts of boric acid; 500～900 parts in 2～10 parts in urea and water; Described organic acid is Hydrocerol A or acetate; Said amino acid is aminoacids complex or single amino acid.
Fertilizer of the present invention is except containing liquid fertilizer elements commonly used such as conventional nitrogen, potassium, boron; Also contain the beneficial element that equilibrated germanium, selenium, zinc, chromium, vanadium etc. have special healthy meaning to human body; Nutritious and balanced, unique effect and the front each other that can give full play to contained mineral element itself act synergistically.The said mineral element of fertilizer of the present invention is ionic state, is easy to plant and effectively absorbs, and then can make people satisfy healthy demand to trace element through the edible food of using this fertilizer.。
The present invention has designed the preparation method (abbreviation preparation method) of said ion nutritive liq fertilizer simultaneously; This preparation method adopts the weight part of ion nutritive liq fertilizer according to the invention to form and following technology: earlier described germanium dioxide is dissolved in the Pottasium Hydroxide; Add organic acid again, carried out the acidifying chelatropic reaction 5-10 hour; Add said Sodium Selenite, zinc acetate, amino acid, boric acid, chromium chloride, ammonium meta-vanadate, urea and water then, reacted 5-10 hour, promptly process behind the filter and remove residue.
The method of use of fertilizer of the present invention is: in foliage applying fertilizer, the dilute with water mass ratio of fertilizer of the present invention is 1/500～1/1000; When in culture medium of edible fungus, using, the dilute with water mass ratio of fertilizer of the present invention also is 1/500～1/1000.Fertilizer of the present invention use on the blade face with (or) after substratum uses, can significantly increase the content of organic germanium, organoselenium, organic zinc, organic chromium and organic vanadium in vegetables, fruit or the edible mushrooms, for realizing the efficient plant husbandry of characteristic an effective way is provided.
The present invention does not address the technology that has that part is applicable to.
Provide specific embodiment of the present invention below.These embodiment only are used to specifically describe the present invention, do not limit the protection domain of the application's claim.
Embodiment 1
Preparation fruits and vegetables blade face dedicated fertilizer.
The weight fraction of design fruits and vegetables blade face dedicated fertilizer consists of: 18 parts in Pottasium Hydroxide; 10 parts of germanium dioxides; 5 parts of Sodium Selenites; 10 parts of zinc acetates; 2 parts of chromium chlorides; 3 parts of ammonium meta-vanadates; 20 parts of Hydrocerol As; 30 parts of aminoacids complexs; 10 parts of boric acid; 900 parts in 5 parts in urea and water.
The preparation method of this dedicated fertilizer adopts the weight fraction of fruits and vegetables according to the invention blade face dedicated fertilizer to form and following technology: earlier said germanium dioxide is dissolved in the Pottasium Hydroxide; Add said Hydrocerol A again, further the acidifying chelatropic reaction is 5-10 hour; Add described sodium selenate, zinc acetate, amino acid, boric acid, chromium chloride, ammonium meta-vanadate, urea and water then, reacted 5-10 hour, promptly process behind the filter and remove residue.
The method of use 1 of this dedicated fertilizer is: with the fertilizer of embodiment 1 with clear water by 1: 500～1000 mass ratio dilution after, evenly be sprayed at the blade faces of fruits and vegetables, edible mushrooms or food crop.The vegetation period, need to spray each interval 5～7 days 2-3 time; After the sprinkling, should fill spray once like rain or strong wind weather.Spraying for the last time should be in the maturation sprinkling in preceding 10 days of gathering.
The method of use 2 of this dedicated fertilizer is: with the fertilizer of embodiment 1 with clear water by 1: 500～1000 mass ratio dilution after, be mixed together with the planting edible mushroom bar, evenly back pack is used for the plantation of edible fungi.Also can be used for the edible fungi foliage spray in vegetative period simultaneously.
Embodiment 2
Preparation Fertilizer special for edible mushroom material.
The weight fraction of design Fertilizer special for edible mushroom material consists of: 30 parts in Pottasium Hydroxide; 15 parts of germanium dioxides; 3 parts of Sodium Selenites; 15 parts in zinc sulfate; 3 parts of chromium chlorides; 5 parts of ammonium meta-vanadates; 40 parts of acetate; 20 parts of aminoacids complexs; 15 parts of boric acid; 700 parts in 10 parts in urea and water.
The preparation method of present embodiment dedicated fertilizer and method of use are same as embodiment 1.
Embodiment 3
Prepare general fertilizer.
The weight fraction that designs general fertilizer consists of: 15 parts in Pottasium Hydroxide; 5 parts of germanium dioxides; 5 parts of sodium selenates; 5 parts of zinc acetates; 1 part of chromium chloride; 2 parts of ammonium meta-vanadates; 20 parts of Hydrocerol As; 50 parts of single amino acid; 20 parts of boric acid; 900 parts in 2 parts in urea and water.
The preparation method of the general fertilizer of present embodiment and method of use are same as embodiment 1.
Claims (2)
1. an ion nutritive liq fertilizer is characterized in that the parts by weight of this fertilizer consist of: 15 ~ 35 parts in Pottasium Hydroxide; 5 ~ 15 parts of germanium dioxides; 1 ~ 5 part of Sodium Selenite or sodium selenate; 5 ~ 15 parts in zinc acetate or zinc sulfate; 1 ~ 5 part of chromium chloride; 2 ~ 8 parts of ammonium meta-vanadates; 15 ~ 40 parts of organic acids; 20 ~ 50 parts in amino acid; 10 ~ 20 parts of boric acid; 500 ~ 900 parts in 2 ~ 10 parts in urea and water; Described organic acid is Hydrocerol A or acetate; Said amino acid is aminoacids complex or single amino acid.
2. the preparation method of an ion nutritive liq fertilizer; This preparation method adopts the parts by weight of the said ion nutritive liq of claim 1 fertilizer to form and following technology: earlier described germanium dioxide is dissolved in the Pottasium Hydroxide; Add organic acid again, carried out the acidifying chelatropic reaction 5-10 hour; Add said Sodium Selenite, zinc acetate, amino acid, boric acid, chromium chloride, ammonium meta-vanadate, urea and water then, reacted 5-10 hour, promptly process behind the filter and remove residue.
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Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102919049A (en) * | 2012-11-29 | 2013-02-13 | 天津市星河系科技有限公司 | Method for cultivating celery rich in multiple microelements |
| CN102919050A (en) * | 2012-11-29 | 2013-02-13 | 天津市星河系科技有限公司 | Method for cultivating eggplant rich in multiple microelements |
| CN102934584A (en) * | 2012-11-29 | 2013-02-20 | 天津市星河系科技有限公司 | Method for enriching carrot with multi-trace elements |
| CN102972270A (en) * | 2012-11-29 | 2013-03-20 | 天津市星河系科技有限公司 | Method for enabling cabbage to be rich in multiple trace elements |
| CN102972179A (en) * | 2012-11-29 | 2013-03-20 | 天津市星河系科技有限公司 | Method for enabling chili to be rich in multiple trace elements |
| CN102972272A (en) * | 2012-11-29 | 2013-03-20 | 天津市星河系科技有限公司 | Method for enabling tomato to be rich in multiple trace elements |
| CN102972271A (en) * | 2012-11-29 | 2013-03-20 | 天津市星河系科技有限公司 | Method for enabling radish to be rich in multiple trace elements |
| CN103340089A (en) * | 2013-07-26 | 2013-10-09 | 苏州科缔康农业生物科技有限公司 | Cultivation method of green turnip rich in zinc and selenium and capable of dispelling effects of alcohol and protecting liver |
| CN103408351A (en) * | 2013-07-09 | 2013-11-27 | 天津市星河系科技有限公司 | Polysaccharide composition and preparation method thereof |
| CN103626545A (en) * | 2013-11-20 | 2014-03-12 | 路平 | Amino acid compound fertilizer, preparation method and agriculture ecological cycle development method |
| CN104585003A (en) * | 2014-12-11 | 2015-05-06 | 陈程 | Soilless culture method improving content of organic selenium of carrots |
| CN105601414A (en) * | 2015-12-18 | 2016-05-25 | 山东方等生物科技有限公司 | Chromium and selenium composition, and health food, fertilizer and preparation method thereof |
| CN105646091A (en) * | 2016-03-04 | 2016-06-08 | 深圳市芭田生态工程股份有限公司 | Liquid fertilizer and preparation method thereof |
| CN105794469A (en) * | 2016-03-31 | 2016-07-27 | 太仓市东泾农场专业合作社 | Method for planting tomatoes rich in microelements |
| CN106804359A (en) * | 2015-11-30 | 2017-06-09 | 吴芳 | A kind of cultural method of the rich germanium Canton love-pea vine of Queensland nut interplanting |
| CN107216203A (en) * | 2017-06-28 | 2017-09-29 | 太仓市绿苗农场专业合作社 | A kind of selenium-rich water planting growth-promoting media |
| CN108117435A (en) * | 2016-11-29 | 2018-06-05 | 张宝金 | A kind of Chromium-rich nutrition solution and its preparation method and application |
| CN108456044A (en) * | 2017-02-17 | 2018-08-28 | 山东省农业科学院玉米研究所 | A kind of leaf surface trace fertilizer and preparation method thereof of prevention wheat and corn microelement deficiencies |
| CN108467302A (en) * | 2018-05-25 | 2018-08-31 | 王宁 | A kind of nutritional liquid fertilizer and preparation method thereof |
| CN110790597A (en) * | 2019-11-19 | 2020-02-14 | 重庆市林业科学研究院 | Nutrient solution for plant infusion and plant infusion device |
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Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102919049A (en) * | 2012-11-29 | 2013-02-13 | 天津市星河系科技有限公司 | Method for cultivating celery rich in multiple microelements |
| CN102919050A (en) * | 2012-11-29 | 2013-02-13 | 天津市星河系科技有限公司 | Method for cultivating eggplant rich in multiple microelements |
| CN102934584A (en) * | 2012-11-29 | 2013-02-20 | 天津市星河系科技有限公司 | Method for enriching carrot with multi-trace elements |
| CN102972270A (en) * | 2012-11-29 | 2013-03-20 | 天津市星河系科技有限公司 | Method for enabling cabbage to be rich in multiple trace elements |
| CN102972179A (en) * | 2012-11-29 | 2013-03-20 | 天津市星河系科技有限公司 | Method for enabling chili to be rich in multiple trace elements |
| CN102972272A (en) * | 2012-11-29 | 2013-03-20 | 天津市星河系科技有限公司 | Method for enabling tomato to be rich in multiple trace elements |
| CN102972271A (en) * | 2012-11-29 | 2013-03-20 | 天津市星河系科技有限公司 | Method for enabling radish to be rich in multiple trace elements |
| CN103408351B (en) * | 2013-07-09 | 2014-12-17 | 天津市星河系科技有限公司 | Polysaccharide composition and preparation method thereof |
| CN103408351A (en) * | 2013-07-09 | 2013-11-27 | 天津市星河系科技有限公司 | Polysaccharide composition and preparation method thereof |
| CN103340089A (en) * | 2013-07-26 | 2013-10-09 | 苏州科缔康农业生物科技有限公司 | Cultivation method of green turnip rich in zinc and selenium and capable of dispelling effects of alcohol and protecting liver |
| CN103626545B (en) * | 2013-11-20 | 2016-07-06 | 路平 | A kind of amino-acid compound fertilizer, preparation method and Agro-ecology circulation development approach |
| CN103626545A (en) * | 2013-11-20 | 2014-03-12 | 路平 | Amino acid compound fertilizer, preparation method and agriculture ecological cycle development method |
| CN104585003A (en) * | 2014-12-11 | 2015-05-06 | 陈程 | Soilless culture method improving content of organic selenium of carrots |
| CN106804359A (en) * | 2015-11-30 | 2017-06-09 | 吴芳 | A kind of cultural method of the rich germanium Canton love-pea vine of Queensland nut interplanting |
| CN105601414A (en) * | 2015-12-18 | 2016-05-25 | 山东方等生物科技有限公司 | Chromium and selenium composition, and health food, fertilizer and preparation method thereof |
| CN105601414B (en) * | 2015-12-18 | 2018-04-06 | 山东方等生物科技有限公司 | A kind of composition of selenium containing chromium and its health food, fertilizer and preparation method |
| CN105646091A (en) * | 2016-03-04 | 2016-06-08 | 深圳市芭田生态工程股份有限公司 | Liquid fertilizer and preparation method thereof |
| CN105794469A (en) * | 2016-03-31 | 2016-07-27 | 太仓市东泾农场专业合作社 | Method for planting tomatoes rich in microelements |
| CN108117435A (en) * | 2016-11-29 | 2018-06-05 | 张宝金 | A kind of Chromium-rich nutrition solution and its preparation method and application |
| CN108456044A (en) * | 2017-02-17 | 2018-08-28 | 山东省农业科学院玉米研究所 | A kind of leaf surface trace fertilizer and preparation method thereof of prevention wheat and corn microelement deficiencies |
| CN107216203A (en) * | 2017-06-28 | 2017-09-29 | 太仓市绿苗农场专业合作社 | A kind of selenium-rich water planting growth-promoting media |
| CN108467302A (en) * | 2018-05-25 | 2018-08-31 | 王宁 | A kind of nutritional liquid fertilizer and preparation method thereof |
| CN110790597A (en) * | 2019-11-19 | 2020-02-14 | 重庆市林业科学研究院 | Nutrient solution for plant infusion and plant infusion device |
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Application publication date: 20120718 |