CN102584346A - Titanium-containing zirconium white frit and manufacturing method thereof - Google Patents
Titanium-containing zirconium white frit and manufacturing method thereof Download PDFInfo
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- CN102584346A CN102584346A CN2012100180861A CN201210018086A CN102584346A CN 102584346 A CN102584346 A CN 102584346A CN 2012100180861 A CN2012100180861 A CN 2012100180861A CN 201210018086 A CN201210018086 A CN 201210018086A CN 102584346 A CN102584346 A CN 102584346A
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Abstract
The invention provides a titanium-containing zirconium white frit and a manufacturing method thereof. The titanium-containing zirconium white frit consists of the following components in percentage by weight: 25 to 35 percent of feldspar, 20 to 30 percent of quartz, 2 to 18 percent of sodium borate, 2 to 8 percent of potassium nitrate, 5 to 15 percent of calcite, 2 to 5 percent of soapstone, 3 to 8 percent of boracic acid and 2 to 4 percent of titanium dioxide. By a little titanium, the whiteness of the common zirconium white frit can be obtained; the cost is low, and the whiteness is high; the titanium-containing zirconium white frit does not contain any radioactive element; the production process of the titanium-containing zirconium white frit is completely consistent with that of zirconium series opacified glaze frit, so that the price is low; and the production cost can be reduced.
Description
Technical field
The present invention relates to a kind of ceramic glazed brick production with opaque glaze clinker and preparation method thereof.
Background technology
Opaque glaze clinker is used in the production of pottery glazed brick, is during ceramic glazed brick is produced, crucial raw material, and frit is a requisite raw material in the Ceramic Material, it can make the raw material of solubility become not fusible; Can make virose raw material become nontoxicity; The combination reaction of decomposing in the time of reducing glaze firing; Can shorten firing period thereby reduce glaze firing fusion problem as a kind of solubility promoter; Can improve glaze quality and product performance.Frit can be divided into clear frit, milkiness frit, contains lead frit and not have lead frit because of the effect difference.
In the prior art, owing to use zircon sand series opacifying agent in the prescription, the good whiteness of its frit opaque effect is high; But zircon sand series contains radioactive substance as opacifying agent, in production process and product use, human body is had harm; The big cost of consumption is high, and price is at 1000～40000 yuan/ton.
Chinese patent, application number: 00109937.X discloses a kind of opaque glaze clinker and preparation method thereof, the opaque glaze clinker that this patent provides; With the phosphate ore is the opacifying agent replacement zirconium series opacifying agent of main raw material; Though made frit does not contain any radioelement,, this patent is to replace zirconium series opacifying agent with phosphate ore as opacifying agent; It is big that opacifying agent is produced consumption, and production cost is high.
Summary of the invention
The purpose of this invention is to provide a kind of titaniferous zirconium white frit and preparation method thereof, to overcome the above-mentioned defective that prior art exists.
Titaniferous zirconium white frit of the present invention, form by following components in weight percentage:
Each percentages of ingredients sum is 100%;
Preferably, titaniferous zirconium white frit of the present invention, form by following components in weight percentage:
Preferably, also comprise 0.01～0.5% fusing assistant in the component of titaniferous zirconium white frit of the present invention, said fusing assistant is basic metal or alkaline earth metal chloride;
More than one of the preferred sodium-chlor of said fusing assistant, Repone K, calcium chloride or magnesium chloride;
As another preferred embodiment, titaniferous zirconium white frit of the present invention is made up of following components in weight percentage:
The preparation method of titaniferous zirconium white frit of the present invention comprises the steps:
After above raw materials mix, found 45min～60min at 1450～1670 ℃, shrend then can obtain described frit;
With prepared titaniferous zirconium white frit and clay, after ball mill enamel frit makeing, impose in the adobe, insert roller kiln and fire, get final product final glaze for glazed tile;
The weight percent of titaniferous zirconium white frit is 95%;
After adding fusing assistant in the component, for example add calcium chloride, above-mentioned founding can be reduced by 200～350 ℃, significantly reduces sintering temperature.
The present invention has a spot of titanium just can reach the whiteness of common zirconium white frit, and is with low cost and whiteness is high.Adding unexpected remarkable reduction sintering temperature behind the specific fusing assistant, possibly be because its and other component, for example borax and boric acid compatibility, reduction system fusing point.The present invention does not contain any radioelement, and production technique and zirconium series opaque glaze clinker are in full accord, and price is low, can reduce production costs.
Embodiment
Embodiment 1
Prescription: (weight percentage)
The preparation method:
With above raw material, mix, found 50min at 1500 ℃, shrend then can obtain described frit;
Prepared frit 95% (weight) and 5% clay after ball mill enamel frit makeing, are imposed in the adobe, insert roller kiln and fire, get final product final glaze for glazed tile.
Whiteness is through instrument Minolta CM-3300d test, and whiteness reaches 85 °, and smooth surface is pure white.
Embodiment 2
Prescription: (weight percentage)
The preparation method:
With above raw material, mix, found 60min at 1450 ℃, shrend then can obtain described frit;
Prepared frit 95% (weight) and 5% clay after ball mill enamel frit makeing, are imposed in the adobe, insert roller kiln and fire, get final product final glaze for glazed tile.
Whiteness is through instrument Minolta CM-3300d test, and whiteness reaches 92.45 °, and smooth surface is pure white.
Embodiment 3
Prescription: (weight percentage)
The preparation method:
With above raw material, mix, found 45min at 1670 ℃, shrend then can obtain described frit;
Prepared frit 95% (weight) and 5% clay after ball mill enamel frit makeing, are imposed in the adobe, insert roller kiln and fire, get final product final glaze for glazed tile.
Whiteness is through instrument Minolta CM-3300d test, and whiteness reaches 87 °, and smooth surface is pure white.
Embodiment 4
Prescription: (weight percentage)
The preparation method:
With above raw material, mix, found 50min at 1150 ℃, shrend then can obtain described frit;
Prepared frit 95% (weight) and 5% clay after ball mill enamel frit makeing, are imposed in the adobe, insert roller kiln and fire, get final product final glaze for glazed tile.
Whiteness is through instrument Minolta CM-3300d test, and whiteness reaches 90.55 °, and smooth surface is pure white.
Claims (6)
1. titaniferous zirconium white frit is characterized in that, comprises following components in weight percentage:
Each percentages of ingredients sum is 100%.
2. titaniferous zirconium white frit according to claim 1 is characterized in that, is made up of following components in weight percentage:
3. titaniferous zirconium white frit according to claim 1 is characterized in that, also comprises 0.01～0.5% fusing assistant in the component, and said fusing assistant is basic metal or alkaline earth metal chloride.
4. titaniferous zirconium white frit according to claim 3 is characterized in that said fusing assistant is more than one of sodium-chlor, Repone K, calcium chloride or magnesium chloride.
5. titaniferous zirconium white frit according to claim 3 is characterized in that, is made up of following components in weight percentage:
6. like the preparation method of each described titaniferous zirconium white frit of claim 1～5, it is characterized in that comprise the steps: to found 45min～60min with after the above raw materials mix at 1450～1670 ℃, shrend then can obtain described frit.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210018086 CN102584346B (en) | 2012-01-19 | 2012-01-19 | Titanium-containing zirconium white frit and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210018086 CN102584346B (en) | 2012-01-19 | 2012-01-19 | Titanium-containing zirconium white frit and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN102584346A true CN102584346A (en) | 2012-07-18 |
| CN102584346B CN102584346B (en) | 2013-07-17 |
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| CN 201210018086 Expired - Fee Related CN102584346B (en) | 2012-01-19 | 2012-01-19 | Titanium-containing zirconium white frit and manufacturing method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107500548A (en) * | 2017-10-17 | 2017-12-22 | 湖南铜官海旭陶瓷有限公司 | A kind of metal glaze and preparation method thereof |
| CN108715516A (en) * | 2018-06-27 | 2018-10-30 | 江西和美陶瓷有限公司 | White glaze, the entire body containing white glaze are without boundary line Ceramic Tiles and preparation method thereof |
| CN111960672A (en) * | 2020-07-08 | 2020-11-20 | 湖南省醴陵市特种电瓷电器有限公司 | Glaze for 95 porcelain surface, 95 porcelain and manufacturing method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1031518A (en) * | 1987-08-22 | 1989-03-08 | 国家建筑材料工业局山东工业陶瓷研究设计院 | Titania milky glaze for making glazed brick |
| CN101066893A (en) * | 2007-06-14 | 2007-11-07 | 湖南华联溢百利瓷业有限公司 | Medium temperature alabastrine galze and its pren process |
| CN101348362A (en) * | 2008-05-30 | 2009-01-21 | 潮州市雄佳陶瓷制作有限公司 | Blank for manufacturing bakeware ceramic products, and corresponding glaze and manufactured products thereof |
-
2012
- 2012-01-19 CN CN 201210018086 patent/CN102584346B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1031518A (en) * | 1987-08-22 | 1989-03-08 | 国家建筑材料工业局山东工业陶瓷研究设计院 | Titania milky glaze for making glazed brick |
| CN101066893A (en) * | 2007-06-14 | 2007-11-07 | 湖南华联溢百利瓷业有限公司 | Medium temperature alabastrine galze and its pren process |
| CN101348362A (en) * | 2008-05-30 | 2009-01-21 | 潮州市雄佳陶瓷制作有限公司 | Blank for manufacturing bakeware ceramic products, and corresponding glaze and manufactured products thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107500548A (en) * | 2017-10-17 | 2017-12-22 | 湖南铜官海旭陶瓷有限公司 | A kind of metal glaze and preparation method thereof |
| CN108715516A (en) * | 2018-06-27 | 2018-10-30 | 江西和美陶瓷有限公司 | White glaze, the entire body containing white glaze are without boundary line Ceramic Tiles and preparation method thereof |
| CN108715516B (en) * | 2018-06-27 | 2021-05-18 | 江西和美陶瓷有限公司 | White glaze, whole body borderless ceramic tile containing white glaze and preparation method thereof |
| CN111960672A (en) * | 2020-07-08 | 2020-11-20 | 湖南省醴陵市特种电瓷电器有限公司 | Glaze for 95 porcelain surface, 95 porcelain and manufacturing method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102584346B (en) | 2013-07-17 |
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