CN105399330B - A kind of titanium white fritted glaze and preparation method thereof - Google Patents
A kind of titanium white fritted glaze and preparation method thereof Download PDFInfo
- Publication number
- CN105399330B CN105399330B CN201510851311.3A CN201510851311A CN105399330B CN 105399330 B CN105399330 B CN 105399330B CN 201510851311 A CN201510851311 A CN 201510851311A CN 105399330 B CN105399330 B CN 105399330B
- Authority
- CN
- China
- Prior art keywords
- titanium white
- glaze
- fritted glaze
- preparation
- white fritted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/08—Frit compositions, i.e. in a powdered or comminuted form containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of titanium white fritted glaze, its chemical composition is by weight percentage：Na2O2~3%、K2O4~5%、MgO0~1%、CaO16~18%、Al2O36~8%、SiO256~62%、P2O50.5~1.2%、TiO28~10%.The invention also discloses a kind of preparation method of titanium white fritted glaze.The titanium white fritted glaze of the present invention forms phosphorus split-phase in high temperature by adding a certain amount of apatite in glaze, using refringence between liquid phase, improves glaze opacity；Ensure the formedness premise of glaze simultaneously, reduce the consumption of titanium dioxide, moreover it is possible to improve opacity, whiteness, flatness.
Description
Technical field
The present invention relates to building material technical field, more particularly to a kind of titanium white fritted glaze of ceramic wall tile and its
Preparation method.
Background technology
Fritted glaze, is a kind of composition for ceramic surface.The glazed wall tile of China at this stage, its ground-coat enamel is largely used
Be all high titanium titanium white opaque glaze, good milkiness is not only played by the titanium dioxide of high content, the white of glaze can be also improved
Spend and smooth.But titanium white ground-coat enamel cost caused by the cost of the raw material of the titanium dioxide of addition is higher is high, and price is high.
The content of the invention
The technical problems to be solved by the invention there is provided a kind of titanium white fritted glaze, and it is by adding a certain amount of phosphorus ash
Stone, forms phosphorus split-phase in high temperature in glaze, using refringence between liquid phase, improves glaze opacity；Ensure the good of glaze simultaneously
Property premise, reduce titanium dioxide consumption, moreover it is possible to improve opacity, whiteness, flatness.Present invention also offers a kind of titanium white frit
The preparation method of glaze.
The technical problems to be solved by the invention are achieved by the following technical programs：
A kind of titanium white fritted glaze, its chemical composition is by weight percentage：
Na2O 2~3%
K2O 4~5%
MgO 0~1%
CaO 16~18%
Al2O3 6~8%
SiO2 56~62%
P2O5 0.5~1.2%
TiO2 8~10%。
A kind of method for preparing the titanium white fritted glaze, comprises the following steps：By potassium feldspar, titanium dioxide, apatite, pure
Alkali, dolomite, powdered whiting, quartz are well mixed in batch mixer in proportion；Fired in Cinker clew furnace, high-temperature firing temperature is
1450~1510℃；High-temperature water quenching is carried out after the completion of firing, acquisition fritted glaze is drained.Wherein, the weight percent of each material component
Than for：
Potassium feldspar 30 ~ 40%
Titanium dioxide 7 ~ 8%
Soda ash 2 ~ 3%
Dolomite 1 ~ 3%
Powdered whiting 20 ~ 26%
Quartz 20 ~ 32%
Apatite 2 ~ 3%
The percentage sum of each material component is 100%.
Water quenching refers to that the high-temperature glass liquid in tank furnace flows to water temperature into fluidization tower and is broken into 20 ~ 60 degree of ponds with current punching
Bright particle.
The present invention has the advantages that：The present invention is by adding a certain amount of phosphorus in silicate substrate glass
Lime stone, produces the second phase drop, and this drop-wise wants have the surface tension higher than host glass thus from glaze segregation to go out, and
It is uniformly distributed in glaze, and then improves opacity；Under the premise of the formedness for ensureing glaze simultaneously, the consumption of titanium dioxide is reduced, also
Opacity, whiteness, flatness can be improved.
Embodiment
With reference to embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention,
It is not limitation of the invention.
The raw mineral materials chemical composition that following examples are used for：
Embodiment 1 to 3, comparative example 1, the raw material composition of each fritted glaze specifically see the table below.
The preparation method of titanium white fritted glaze is as follows：13 tons of powders are weighed in the ratio of upper table, 20 ~ 25 are mixed in batch mixer
Minute, stir, be distributed into 1 ton of ton bag；High-temperature firing is carried out in Ceramic frit tank furnace, temperature is 1510 ~ 1540 DEG C；High-temperature water
Quench, be packaged into 50 kilograms of packaging.
Embodiment 2, the titanium white fritted glaze of comparative example are applied to porcelain products, application respectively with existing common titanium white fritted glaze
Method is as follows：Titanium white fritted glaze is worn into glaze slip, proportion is adjusted to 1.72, glaze slip is drenched on biscuit, then spoon identical zirconium white
Cover-coat enamel, into burning till, kiln discharge examines whiteness, flatness, pin hole.Under same experiment condition, the effect compared passes through white
Degree analytical instrument measurement apatite titanium white fritted glaze will be higher by the whiteness value of 1 ~ 2 point than common titanium white fritted glaze；In flatness
Compared with common titanium white fritted glaze preferably, pin hole is less.Equally, embodiment 1 to 3 is applied to porcelain products respectively, embodiment 3
Whiteness preferably, specifically see the table below.
Its chemical composition is fritted glaze made from embodiment 1 to 3 and comparative example after testing：
Embodiment described above only expresses embodiments of the present invention, and it describes more specific and detailed, but can not
Therefore the limitation to the scope of the claims of the present invention is interpreted as, as long as the skill obtained using the form of equivalent substitution or equivalent transformation
Art scheme, all should fall within the scope and spirit of the invention.
Claims (5)
1. a kind of titanium white fritted glaze, its chemical composition is by weight percentage：
Na2O2~3%
K2O4~5%
MgO0~1%
CaO16~18%
Al2O36~8%
SiO256~62%
P2O50.5~1.2%
TiO28~10%。
2. titanium white fritted glaze according to claim 1, it is characterised in that its chemical composition is by weight percentage：
Na2O2.8%
K2O4%
MgO0.5%
CaO17.8%
Al2O36.3%
SiO258.1%
P2O51%
TiO29.5%。
3. a kind of method for preparing titanium white fritted glaze as claimed in claim 1, comprises the following steps：By potassium feldspar, titanium dioxide,
Apatite, soda ash, dolomite, powdered whiting, quartz are well mixed in batch mixer in proportion；Fired in Cinker clew furnace, high temperature
Water quenching, drains acquisition fritted glaze；Wherein, the titanium white fritted glaze, its chemical composition is by weight percentage：
Na2O2~3%
K2O4~5%
MgO0~1%
CaO16~18%
Al2O36~8%
SiO256~62%
P2O50.5~1.2%
TiO28~10%。
4. the preparation method of titanium white fritted glaze according to claim 3, it is characterised in that the weight hundred of each material component
Point ratio is：
Potassium feldspar 30 ~ 40%
Titanium dioxide 7 ~ 8%
Soda ash 2 ~ 3%
Dolomite 1 ~ 3%
Powdered whiting 20 ~ 26%
Quartz 20 ~ 32%
Apatite 2 ~ 3%
The percentage sum of each material component is 100%.
5. the preparation method of titanium white fritted glaze according to claim 3, it is characterised in that high-temperature firing temperature is 1450 ~
1510℃。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510851311.3A CN105399330B (en) | 2015-11-30 | 2015-11-30 | A kind of titanium white fritted glaze and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510851311.3A CN105399330B (en) | 2015-11-30 | 2015-11-30 | A kind of titanium white fritted glaze and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105399330A CN105399330A (en) | 2016-03-16 |
| CN105399330B true CN105399330B (en) | 2017-08-25 |
Family
ID=55465141
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510851311.3A Active CN105399330B (en) | 2015-11-30 | 2015-11-30 | A kind of titanium white fritted glaze and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105399330B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106830684B (en) * | 2017-03-10 | 2020-04-10 | 佛山市大千色釉料有限公司 | Preparation method of reflective heat-insulation ceramic glazed tile |
| CN110128016A (en) * | 2019-04-26 | 2019-08-16 | 佛山市玉矶材料科技有限公司 | A kind of no zirconium ultrawhite overglaze and preparation method thereof |
| CN111439931B (en) * | 2020-06-17 | 2020-12-01 | 佛山市东鹏陶瓷有限公司 | Low-cost zirconium-free white glaze suitable for sanitary ceramics and domestic porcelain and preparation method thereof |
| CN111875414B (en) * | 2020-06-30 | 2022-08-05 | 蒙娜丽莎集团股份有限公司 | High solar light reflectivity ceramic plate and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5304516A (en) * | 1991-04-17 | 1994-04-19 | Cookson Group Plc | Glaze compositions |
| CN1962557A (en) * | 2006-12-06 | 2007-05-16 | 江苏高淳陶瓷股份有限公司 | Ceramic scarlet-variable glaze and its application method |
-
2015
- 2015-11-30 CN CN201510851311.3A patent/CN105399330B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5304516A (en) * | 1991-04-17 | 1994-04-19 | Cookson Group Plc | Glaze compositions |
| CN1962557A (en) * | 2006-12-06 | 2007-05-16 | 江苏高淳陶瓷股份有限公司 | Ceramic scarlet-variable glaze and its application method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105399330A (en) | 2016-03-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5139327B2 (en) | Glaze composition | |
| CN106431365A (en) | Ultrawhite polished tile and preparation method thereof | |
| CN105399330B (en) | A kind of titanium white fritted glaze and preparation method thereof | |
| CN106977097B (en) | Raw glaze for transparent high-gloss medium-temperature hard porcelain and preparation method thereof | |
| CN106242524A (en) | A kind of pure white polished glazed tile and preparation method thereof | |
| CN101891455A (en) | Middle-low temperature sintered fine bone china and production method thereof | |
| CN110407469B (en) | Low-temperature transparent glaze, ceramic product with glaze and preparation method | |
| Da Silva et al. | Preparation and characterization of glazes from combinations of different industrial wastes | |
| CN102180659A (en) | Talcum building ceramic brick and manufacturing method thereof | |
| BRPI0802190B1 (en) | COMPOSITION OF METAL ENAMEL AND ITS USE | |
| CN101665349B (en) | Temperature resistant ceramic product | |
| CN109942288A (en) | High silicon porcelain Antique Imitation Tiles and its production method | |
| CN105314849B (en) | A kind of zirconium white frit glaze and preparation method thereof | |
| Kalirajan et al. | Influence of glass wastes on the microstructural evolution and crystallization kinetics of glass-ceramic glaze | |
| CN106365673A (en) | Low-temperature quick burning daily ceramic and production process thereof | |
| CN104291785B (en) | Beautiful pottery of a kind of high-grade porcelain kind crystal magnesium and preparation method thereof | |
| CN111908792B (en) | Glaze mixture of metal glaze, metal glaze product and preparation process of metal glaze product | |
| CN106007663A (en) | Unglazed high-density bright crystal ceramic and preparation method thereof | |
| CN104774021A (en) | Bonding clay used for kiln refractory bricks, and preparation process thereof | |
| CN105541114B (en) | A kind of high low-expansion frit of beginning fusing point and preparation method thereof | |
| CN107032618A (en) | A kind of Ceramic Tiles cover-coat enamel with high whiteness and preparation method thereof | |
| CN86105759B (en) | Singe-step glazing method with opal ti-zn system at medium or high tmep. | |
| CN105271749B (en) | The low zirconium of apatite is combined frit and preparation method thereof | |
| CN102557755A (en) | Opacified glaze containing lithium oxide | |
| CN105236741B (en) | A kind of boron split-phase zirconium white frit high and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200103 Address after: 528500 office on the third floor, No.177, Chengshi Road, Mingcheng Town, Gaoming District, Foshan City, Guangdong Province (application for residence) Patentee after: Foshan zhongzhiheng New Material Co., Ltd Address before: 528518 Dongfanghong Farm side, Gaoming Town, Gaoming District, Guangdong, Foshan Patentee before: FOSHAN CITY GAOMING DISTRICT HAIDI CERAMIC MATERIALS CO., LTD. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210609 Address after: 526107 baihuagang, Balian village, Langgang Town, Gaoyao District, Zhaoqing City, Guangdong Province Patentee after: Zhaoqing Gaoyao Hengchun nonmetal material Co.,Ltd. Address before: 528500 office, 3rd floor, 177 Chengshi Road, Mingcheng Town, Gaoming District, Foshan City, Guangdong Province Patentee before: Foshan zhongzhiheng New Material Co.,Ltd. |