CN102532474B - 流变改性剂 - Google Patents

流变改性剂 Download PDF

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Publication number
CN102532474B
CN102532474B CN201110339493.8A CN201110339493A CN102532474B CN 102532474 B CN102532474 B CN 102532474B CN 201110339493 A CN201110339493 A CN 201110339493A CN 102532474 B CN102532474 B CN 102532474B
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China
Prior art keywords
branched
mixture
urethane
conditions used
oxide
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CN201110339493.8A
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Chinese (zh)
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CN102532474A (zh
Inventor
J·J·拉巴斯科
B·R·博布辛
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Rohm and Haas Co
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Rohm and Haas Co
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Priority to CN201410041982.9A priority Critical patent/CN103834158B/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7806—Nitrogen containing -N-C=0 groups
    • C08G18/7843—Nitrogen containing -N-C=0 groups containing urethane groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/282—Alkanols, cycloalkanols or arylalkanols including terpenealcohols
    • C08G18/2825—Alkanols, cycloalkanols or arylalkanols including terpenealcohols having at least 6 carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
    • C08G18/725—Combination of polyisocyanates of C08G18/78 with other polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/83—Chemically modified polymers
    • C08G18/831—Chemically modified polymers by oxygen-containing compounds inclusive of carbonic acid halogenides, carboxylic acid halogenides and epoxy halides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00—Coating compositions based on unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/04—Thixotropic paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/43—Thickening agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/08—Polyurethanes from polyethers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201110339493.8A 2010-10-25 2011-10-24 流变改性剂 Active CN102532474B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410041982.9A CN103834158B (zh) 2010-10-25 2011-10-24 流变改性剂

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US45570710P 2010-10-25 2010-10-25
US61/455,707 2010-10-25
US201161489906P 2011-05-25 2011-05-25
US61/489,906 2011-05-25

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201410041982.9A Division CN103834158B (zh) 2010-10-25 2011-10-24 流变改性剂

Publications (2)

Publication Number Publication Date
CN102532474A CN102532474A (zh) 2012-07-04
CN102532474B true CN102532474B (zh) 2014-12-24

Family

ID=44772837

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201110339493.8A Active CN102532474B (zh) 2010-10-25 2011-10-24 流变改性剂
CN201410041982.9A Active CN103834158B (zh) 2010-10-25 2011-10-24 流变改性剂

Family Applications After (1)

Application Number Title Priority Date Filing Date
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Country Status (6)

Country Link
US (2) US20120101223A1 (enExample)
EP (2) EP2527382B1 (enExample)
JP (1) JP5813431B2 (enExample)
KR (1) KR101310077B1 (enExample)
CN (2) CN102532474B (enExample)
AU (1) AU2011227001B2 (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5542897B2 (ja) 2011-12-14 2014-07-09 ローム アンド ハース カンパニー レオロジー調整剤
US9260559B2 (en) * 2012-11-12 2016-02-16 Elementis Specialties, Inc. Processes for the preparation of rheology modifiers
JP6542803B2 (ja) * 2014-04-23 2019-07-10 ダウ グローバル テクノロジーズ エルエルシー 疎水的に改質されたアルキレンオキシドウレタンコポリマーを使用したシリカスケールの抑制
CN106674468A (zh) * 2015-11-05 2017-05-17 罗门哈斯公司 Heur增稠剂
CA2948961C (en) 2015-12-28 2023-12-05 Dow Global Technologies Llc Polyether-urethane-urea additives for block resistance and open time
BR112018075197B1 (pt) * 2016-07-05 2022-07-12 Dow Global Technologies Llc Composição, e, tinta látex
CA2975494A1 (en) * 2016-09-01 2018-03-01 Rohm And Haas Company Alkylene oxide urethane associative thickener modified with a hydrophobic oligomer
FR3057871B1 (fr) 2016-10-20 2018-11-02 Coatex Compose urethane modificateur de rheologie
WO2019005290A1 (en) 2017-06-30 2019-01-03 Dow Global Technologies Llc AQUEOUS WATER CLARIFIER COMPOSITION STABILIZED AT LOW TEMPERATURE AND METHODS OF USE
EP3823904B1 (en) * 2018-07-20 2025-10-29 Hercules LLC Water soluble or dispersible composition
FR3087774B1 (fr) * 2018-10-26 2021-06-25 Coatex Sas Preparation continue de polyurethanes ou de polyurees
BR102020001678A2 (pt) * 2019-02-15 2020-09-15 Rohm And Haas Company Polímero de óxido de alquileno capeado com um copolímero em bloco de alcoxilato de éter arílico
EP4007787A4 (en) * 2019-08-01 2023-09-20 Hercules LLC Synthetic thickeners incorporating non-reactive diluents
CN112341852B (zh) * 2019-08-09 2023-06-16 罗门哈斯公司 流变改性剂和热塑性-环氧混合乳胶的配制物
JP7503145B2 (ja) * 2020-03-31 2024-06-19 クラリアント・インターナシヨナル・リミテツド 疎水性に変性されたポリウレタン増粘剤及びそれの製造方法
CN112225877A (zh) * 2020-09-04 2021-01-15 华南理工大学 一种三官能度异氰酸酯改性聚氨酯增稠剂及其制备方法
FR3147279A1 (fr) 2023-03-31 2024-10-04 Coatex Composition de préparation de revêtement
FR3147280A1 (fr) * 2023-03-31 2024-10-04 Coatex Composition de polyuréthanes

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4079028A (en) * 1975-10-03 1978-03-14 Rohm And Haas Company Polyurethane thickeners in latex compositions
CN101223203A (zh) * 2005-07-14 2008-07-16 帝斯曼知识产权资产管理有限公司 溶剂型聚氨酯组合物

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4155892A (en) 1975-10-03 1979-05-22 Rohm And Haas Company Polyurethane thickeners for aqueous compositions
US4180491A (en) * 1976-12-01 1979-12-25 Rohm And Haas Company Nonionic polyurethane thickener with surfactant cothickener and organic diluent, clear concentrates, aqueous print pastes, coloring compositions, methods of making and printing
US4327008A (en) * 1980-12-29 1982-04-27 Ppg Industries, Inc. Urethane rheology modifiers and coating compositions containing same
US4337184A (en) * 1980-12-29 1982-06-29 Ppg Industries, Inc. Urethane rheology modifiers substantially free of terminal hydrophobic groups and compositions containing same
US4499233A (en) * 1983-05-03 1985-02-12 Nl Industries, Inc. Water dispersible, modified polyurethane and a thickened aqueous composition containing it
US4806598A (en) * 1986-12-22 1989-02-21 Kimberly-Clark Corporation Thermoplastic polymer blends and nonwoven webs prepared therefrom
US5023309A (en) 1987-09-18 1991-06-11 Rheox, Inc. Water dispersible, modified polyurethane thickener with improved high shear viscosity in aqueous systems
US5319055A (en) * 1991-10-18 1994-06-07 Rohm And Haas Company Non-aqueous thickening agents
FR2811993B1 (fr) * 2000-07-21 2006-08-04 Oreal Nouveaux polymeres associatifs cationiques et leur utilisation comme epaississants
DE10111793A1 (de) * 2001-03-12 2002-09-26 Borchers Gmbh Neue Polyurethane und ihre Verwendung zur Verdickung wässriger Systeme
DE10207891A1 (de) * 2002-02-23 2003-09-04 Goldschmidt Ag Th Verzweigte Polyurethane, diese enthaltende Formulierungen und deren Verwendung zur Verdickung wässriger Systeme
EP1541643B1 (en) * 2003-12-10 2013-03-13 Rohm And Haas Company Nonionic associative thickener containing condensation polymer backbone
CN102304300B (zh) 2006-04-03 2016-04-27 悉尼大学 聚合物包封的固体颗粒材料及包含其的离散颗粒
US7741402B2 (en) 2007-03-21 2010-06-22 Rohm And Haas Company Thickener composition and method for thickening aqueous systems
US7868122B2 (en) 2008-06-19 2011-01-11 Southern Clay Products, Inc. Tint-viscosity stabilization polymeric thickeners
EP2253677B1 (en) 2009-05-19 2017-01-25 Rohm and Haas Company Opacifying pigment particle

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4079028A (en) * 1975-10-03 1978-03-14 Rohm And Haas Company Polyurethane thickeners in latex compositions
US4079028B1 (enExample) * 1975-10-03 1990-08-21 Rohm & Haas
CN101223203A (zh) * 2005-07-14 2008-07-16 帝斯曼知识产权资产管理有限公司 溶剂型聚氨酯组合物

Also Published As

Publication number Publication date
US20140011967A1 (en) 2014-01-09
EP2527382B1 (en) 2016-11-16
CN103834158B (zh) 2016-10-05
AU2011227001A1 (en) 2012-05-10
EP2527382A1 (en) 2012-11-28
US20120101223A1 (en) 2012-04-26
JP5813431B2 (ja) 2015-11-17
CN102532474A (zh) 2012-07-04
EP2444432B1 (en) 2013-02-13
JP2012092304A (ja) 2012-05-17
US8907008B2 (en) 2014-12-09
KR101310077B1 (ko) 2013-09-25
CN103834158A (zh) 2014-06-04
AU2011227001B2 (en) 2013-10-24
KR20120048476A (ko) 2012-05-15
EP2444432A1 (en) 2012-04-25

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