CN102531681A - furnace transmutation gold filament glaze and preparation method thereof - Google Patents
furnace transmutation gold filament glaze and preparation method thereof Download PDFInfo
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- CN102531681A CN102531681A CN2011103981316A CN201110398131A CN102531681A CN 102531681 A CN102531681 A CN 102531681A CN 2011103981316 A CN2011103981316 A CN 2011103981316A CN 201110398131 A CN201110398131 A CN 201110398131A CN 102531681 A CN102531681 A CN 102531681A
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Abstract
The invention discloses a furnace transmutation gold filament glaze and a preparation method of the furnace transmutation gold filament glaze. The furnace transmutation gold filament glaze consists of the following constituents in percentage by weight: 66-76% of glass powder, 5-8.5% of zinc oxide, 12.5-17.5% of titanium dioxide, 3-6.5% of kaolin, and 2-6.5% of iron sesquioxide; the preparation method is as follows: the various constituents of the furnace transmutation gold filament glaze are blended and crushed to conduct wet ball-milling to obtain glaze slip; the glaze slip is put on a biscuit-firing blank to perform glazing directly; after dried, a glaze layer is put into a furnace for baking, the warming speed is kept to be 120-180 DEG C per hour at the oxidizing atmosphere, after 5 hours, the warming speed is controlled to be 60-80 DEG C per hour, after reaching 1260-1300 DEG C, the warming speed is controlled to be 20-40 DEG C per hour, and the warming is stopped when the temperature reaches 1320 DEG C, so that a ceramic product with the furnace transmutation gold filament glaze is obtained. Glaze on the surface of the ceramic product is golden, is uniform in color, appears to be concave and convex on the surface seen from the distance, is smooth in the surface and presents gold-filament-shaped current lamination at a closer look.
Description
Technical field
The invention belongs to the ceramic glaze field, be specifically related to a kind of transmutation spun gold glaze and preparation method thereof.
Background technology
There has been history for a long time in the China that is produced on of transmutation glaze.Yet because its formation relates to complicated chemistry and physical change, influenced by glaze formula, technology etc., can produce different transmutation results, therefore, the manufacture difficulty of transmutation glaze is bigger.Also, has higher economic value because it is difficult to obtain.People have carried out a large amount of further investigations to the transmutation glaze, have obtained certain achievement.Disclose like Chinese patent CN1724477A and a kind ofly to form the ceramic glaze of red credit change of weather order effect and to use the method that this ceramic glaze is fired red credit change of weather order pottery; According to the disclosed technology of this patent; Its glaze can be separated out redness or yellow crystal spot when burning till; Be the halation that gold has mirror effect and metalluster on every side, luminous position moves with the variation of viewing angle, forms dazzling brilliant effect.Chinese patent CN100415692C discloses a kind of ceramic scarlet-variable glaze and application method thereof, and this patent is through to the selection of basestocks, obtains that glaze is bright and clean to burn till stable scarlet-variable glaze.But firing color and luster at present, to have the transmutation glaze research of technique difficulty of spun gold effect uniformly big.
Summary of the invention
The objective of the invention is to disclose a kind of transmutation spun gold glaze, it is golden that its glaze is, and color even has seen that far there is concave-convex sense on the surface, closely sees smooth surface and be the flowing water texture of spun gold shape.
Another object of the present invention is to disclose a kind of preparation method of said transmutation spun gold glaze.
Above-mentioned purpose of the present invention is achieved through following technical scheme:
A kind of transmutation spun gold glaze is made up of the component of counting by weight percentage as follows: glass powder 66 ~ 76%, zinc oxide 5 ~ 8.5%, titanium oxide 12.5 ~ 17.5%, kaolin 3 ~ 6.5 %, red oxide of iron 2 ~ 6.5%.
As a kind of preferred version, said transmutation spun gold glaze is preferably by the component of counting by weight percentage as follows to be formed: glass powder 66 ~ 76%, zinc oxide 5.5 ~ 8.5%, titanium oxide 13 ~ 17.5%, kaolin 3 ~ 6.5%, red oxide of iron 2 ~ 6.5%.
As a kind of more preferably scheme, said transmutation spun gold glaze more preferably is made up of the component of counting by weight percentage as follows: glass powder 66 ~ 76%, zinc oxide 6 ~ 8.5%, titanium oxide 13 ~ 17.5%, kaolin 3 ~ 6.5%, red oxide of iron 2 ~ 6.5%.
The preparation method of said transmutation spun gold glaze comprises the steps:
(1) each component of transmutation spun gold glaze is mixed pulverizing, carry out wet ball mill, obtain glaze slip;
(2) above-mentioned glaze slip is put in after the biscuiting carries out direct glazing on the base substrate;
(3) after the glaze layer drying; Place kiln to fire, under oxidizing atmosphere, keep heat-up rate at 120 ~ 180 ℃/hour, the control heat-up rate is at 60 ~ 80 ℃/hour after 5 hours; After reaching 1260 ~ 1300 ℃; Heat up by 20 ~ 40 ℃/hour speed, stop when temperature reaches 1320 ℃ heating up, promptly obtain having the ceramic of transmutation spun gold glaze.
As a kind of preferred version, in the step (1), the fineness of gained glaze slip is controlled at 10000-hole sieve and tails over 0.03 ~ 0.05%.
As a kind of preferred version, in the step (1), the processing condition of gained wet ball mill are by weight calculating, to expect: ball: water=1:1.6 ~ 2.6:0.5 ~ 0.7.
As a kind of preferred version, in the step (2), the mode of said glazing is preferably waters glaze.
As a kind of preferred version, in the step (2), the thickness of glaze layer is preferably 0.5 ~ 2.5mm.
As a kind of more preferably scheme, in the step (2), the thickness of glaze layer is 1.5 ~ 2mm more preferably.
As a kind of preferred version, in the step (3), the total time of firing is preferably 10 ~ 12 hours.
As a kind of most preferably scheme, in the step (3), the total time of firing most preferably is 11 hours.
Compared with prior art, the present invention has following beneficial effect:
The transmutation effect that the present invention obtains is that the surface is the golden glaze, and color even has seen that far there is concave-convex sense on the surface, closely sees smooth surface and is the flowing water texture of spun gold shape, create an aesthetic feeling.
Embodiment
Come further to explain the present invention below in conjunction with embodiment, but embodiment does not do any type of qualification to the present invention.The various raw materials that embodiment uses all are conventional raw materials of buying on the market.
Embodiment 1
Transmutation spun gold glaze formula: glass powder 68%, zinc oxide 8%, titanium oxide 15%, kaolin 5%, red oxide of iron 4%.
Its preparation method is:
(1) each component of transmutation spun gold glaze is mixed pulverizing, carry out wet ball mill, by weight calculating, material: ball: water=1:1.8:0.5,10000-hole sieve tails over 0.05%; Obtain glaze slip;
(2) above-mentioned glaze slip is put in after the biscuiting soaks glaze, glaze layer thickness 1mm on the base substrate;
(3) after the glaze layer drying; Place kiln to fire, under oxidizing atmosphere, keep heat-up rate at 130 ℃/hour, the control heat-up rate is at 70 ℃/hour after 5 hours; After reaching 1300 ℃; Heat up by 20 ℃/hour speed, stop when temperature reaches 1320 ℃ heating up, promptly obtain having the ceramic of transmutation spun gold glaze.
It is golden that gained ceramic surface glaze is, and color even has seen that far there is concave-convex sense on the surface, closely sees smooth surface and be the flowing water texture of spun gold shape.
Embodiment 2
Transmutation spun gold glaze formula: glass powder 70%, zinc oxide 6%, titanium oxide 13.5%, kaolin 5 %, red oxide of iron 5.5%.
Its preparation method is:
(1) each component of transmutation spun gold glaze is mixed pulverizing, carry out wet ball mill, by weight calculating, material: ball: water=1:2:0.5,10000-hole sieve tails over 0.03%; Obtain glaze slip;
(2) above-mentioned glaze slip is put in after the biscuiting soaks glaze, glaze layer thickness 1.5mm on the base substrate;
(3) after the glaze layer drying; Place kiln to fire, under oxidizing atmosphere, keep heat-up rate at 150 ℃/hour, the control heat-up rate is at 60 ℃/hour after 5 hours; After reaching 1280 ℃; Heat up by 30 ℃/hour speed, stop when temperature reaches 1320 ℃ heating up, promptly obtain having the ceramic of transmutation spun gold glaze.
It is golden that gained ceramic surface glaze is, and color even has seen that far there is concave-convex sense on the surface, closely sees smooth surface and be the flowing water texture of spun gold shape.
Embodiment 3
Transmutation spun gold glaze formula: glass powder 72%, zinc oxide 7%, titanium oxide 14%, kaolin 4%, red oxide of iron 3%.
Its preparation method is:
(1) each component of transmutation spun gold glaze is mixed pulverizing, carry out wet ball mill, by weight calculating, material: ball: water=1:2.4:0.7,10000-hole sieve tails over 0.02%; Obtain glaze slip;
(2) above-mentioned glaze slip is put in after the biscuiting soaks glaze, glaze layer thickness 2mm on the base substrate;
(3) after the glaze layer drying; Place kiln to fire, under oxidizing atmosphere, keep heat-up rate at 180 ℃/hour, the control heat-up rate is at 80 ℃/hour after 5 hours; After reaching 1280 ℃; Heat up by 30 ℃/hour speed, stop when temperature reaches 1320 ℃ heating up, promptly obtain having the ceramic of transmutation spun gold glaze.
It is golden that gained ceramic surface glaze is, and color even has seen that far there is concave-convex sense on the surface, closely sees smooth surface and be the flowing water texture of spun gold shape.
Embodiment 4
Transmutation spun gold glaze formula: glass powder 66%, zinc oxide 8%, titanium oxide 16%, kaolin 4%, red oxide of iron 6%.
Its preparation method is:
(1) each component of transmutation spun gold glaze is mixed pulverizing, carry out wet ball mill, by weight calculating, material: ball: water=1:2.3:0.6,10000-hole sieve tails over 0.02%; Obtain glaze slip;
(2) above-mentioned glaze slip is put in after the biscuiting soaks glaze, glaze layer thickness 2mm on the base substrate;
(3) after the glaze layer drying; Place kiln to fire, under oxidizing atmosphere, keep heat-up rate at 160 ℃/hour, the control heat-up rate is at 80 ℃/hour after 5 hours; After reaching 1280 ℃; Heat up by 20 ℃/hour speed, stop when temperature reaches 1320 ℃ heating up, promptly obtain having the ceramic of transmutation spun gold glaze.
It is golden that gained ceramic surface glaze is, and color even has seen that far there is concave-convex sense on the surface, closely sees smooth surface and be the flowing water texture of spun gold shape.
Claims (10)
1. a transmutation spun gold glaze is characterized in that, is made up of the component of counting by weight percentage as follows: glass powder 66 ~ 76%, zinc oxide 5 ~ 8.5%, titanium oxide 12.5 ~ 17.5%, kaolin 3 ~ 6.5 %, red oxide of iron 2 ~ 6.5%.
2. transmutation spun gold glaze according to claim 1 is characterized in that, is made up of the component of counting by weight percentage as follows: glass powder 66 ~ 76%, zinc oxide 5.5 ~ 8.5%, titanium oxide 12.5 ~ 17.5%, kaolin 3 ~ 6.5 %, red oxide of iron 2 ~ 6.5%.
3. like the said transmutation spun gold of claim 2 glaze, it is characterized in that, form: glass powder 66 ~ 76%, zinc oxide 6 ~ 8.5%, titanium oxide 12.5 ~ 17.5%, kaolin 3 ~ 6.5 %, red oxide of iron 2 ~ 6.5% by the component of counting by weight percentage as follows.
4. the preparation method of any said transmutation spun gold of claim glaze in the claim 1,2 or 3 is characterized in that, comprises the steps:
(1) each component of transmutation spun gold glaze is mixed pulverizing, carry out wet ball mill, obtain glaze slip;
(2) above-mentioned glaze slip is put in after the biscuiting carries out direct glazing on the base substrate;
(3) after the glaze layer drying; Place kiln to fire, under oxidizing atmosphere, keep heat-up rate at 120 ~ 180 ℃/hour, the control heat-up rate is at 60 ~ 80 ℃/hour after 5 hours; After reaching 1260 ~ 1300 ℃; Heat up by 20 ~ 40 ℃/hour speed, stop when temperature reaches 1320 ℃ heating up, promptly obtain having the ceramic of transmutation spun gold glaze.
5. like the preparation method of the said transmutation spun gold of claim 4 glaze, it is characterized in that in the step (1), the fineness of gained glaze slip is that 10000-hole sieve tails over is 0.03 ~ 0.05%.
6. like the preparation method of the said transmutation spun gold of claim 4 glaze, it is characterized in that in the step (1), the processing condition of gained wet ball mill are by weight calculating, to expect: ball: water=1:1.6 ~ 2.6:0.5 ~ 0.7.
7. like the preparation method of the said transmutation spun gold of claim 4 glaze, it is characterized in that in the step (2), the mode of said glazing is for watering glaze.
8. like the preparation method of the said transmutation spun gold of claim 4 glaze, it is characterized in that in the step (2), the thickness of glaze layer is 0.5 ~ 2.5mm.
9. like the preparation method of the said transmutation spun gold of claim 4 glaze, it is characterized in that in the step (3), the total time of firing is 10 ~ 12 hours.
10. like the preparation method of the said transmutation spun gold of claim 4 glaze, it is characterized in that in the step (3), the total time of firing is 11 hours.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011103981316A CN102531681B (en) | 2011-12-05 | 2011-12-05 | furnace transmutation gold filament glaze and preparation method thereof |
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| CN2011103981316A CN102531681B (en) | 2011-12-05 | 2011-12-05 | furnace transmutation gold filament glaze and preparation method thereof |
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| CN102531681A true CN102531681A (en) | 2012-07-04 |
| CN102531681B CN102531681B (en) | 2013-11-27 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106565092A (en) * | 2016-08-31 | 2017-04-19 | 福建省德化县臻晖陶瓷有限公司 | Lightweight low-temperature fancy golden silk white glazed porcelain and manufacturing process |
| CN109809695A (en) * | 2017-11-20 | 2019-05-28 | 湖南金木陶瓷有限公司 | A kind of crystalline glaze and preparation method thereof |
| CN112225453A (en) * | 2020-09-10 | 2021-01-15 | 醴陵陶润实业发展有限公司 | Crystalline glaze and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102173874A (en) * | 2011-01-28 | 2011-09-07 | 大埔县桃源陶瓷工艺厂 | Ceramic glaze for generating natural weathering and erosion on surface of ceramic product |
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2011
- 2011-12-05 CN CN2011103981316A patent/CN102531681B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102173874A (en) * | 2011-01-28 | 2011-09-07 | 大埔县桃源陶瓷工艺厂 | Ceramic glaze for generating natural weathering and erosion on surface of ceramic product |
Non-Patent Citations (1)
| Title |
|---|
| 陈炳文: "冰花状金黄色硅酸钛结晶釉的研究", 《佛山陶瓷》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106565092A (en) * | 2016-08-31 | 2017-04-19 | 福建省德化县臻晖陶瓷有限公司 | Lightweight low-temperature fancy golden silk white glazed porcelain and manufacturing process |
| CN109809695A (en) * | 2017-11-20 | 2019-05-28 | 湖南金木陶瓷有限公司 | A kind of crystalline glaze and preparation method thereof |
| CN112225453A (en) * | 2020-09-10 | 2021-01-15 | 醴陵陶润实业发展有限公司 | Crystalline glaze and preparation method thereof |
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| CN102531681B (en) | 2013-11-27 |
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